NO751119L - - Google Patents
Info
- Publication number
- NO751119L NO751119L NO751119A NO751119A NO751119L NO 751119 L NO751119 L NO 751119L NO 751119 A NO751119 A NO 751119A NO 751119 A NO751119 A NO 751119A NO 751119 L NO751119 L NO 751119L
- Authority
- NO
- Norway
- Prior art keywords
- dmt
- distillation
- carrier
- methanol
- boiling
- Prior art date
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 129
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 claims description 95
- 238000000034 method Methods 0.000 claims description 50
- 238000004821 distillation Methods 0.000 claims description 40
- 238000009835 boiling Methods 0.000 claims description 34
- 239000002253 acid Substances 0.000 claims description 31
- 238000004519 manufacturing process Methods 0.000 claims description 28
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 claims description 24
- 230000003647 oxidation Effects 0.000 claims description 22
- 238000007254 oxidation reaction Methods 0.000 claims description 22
- 150000004702 methyl esters Chemical class 0.000 claims description 16
- 239000013067 intermediate product Substances 0.000 claims description 15
- 125000005440 p-toluyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1C(*)=O)C([H])([H])[H] 0.000 claims description 15
- 238000005886 esterification reaction Methods 0.000 claims description 13
- 239000003054 catalyst Substances 0.000 claims description 11
- 230000032050 esterification Effects 0.000 claims description 11
- 239000006227 byproduct Substances 0.000 claims description 9
- 150000007513 acids Chemical class 0.000 claims description 5
- 239000000047 product Substances 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 4
- 238000000926 separation method Methods 0.000 claims description 4
- 238000011084 recovery Methods 0.000 claims description 2
- MZZUATUOLXMCEY-UHFFFAOYSA-N cobalt manganese Chemical compound [Mn].[Co] MZZUATUOLXMCEY-UHFFFAOYSA-N 0.000 claims 1
- 239000007791 liquid phase Substances 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 description 18
- REIDAMBAPLIATC-UHFFFAOYSA-N 4-methoxycarbonylbenzoic acid Chemical compound COC(=O)C1=CC=C(C(O)=O)C=C1 REIDAMBAPLIATC-UHFFFAOYSA-N 0.000 description 10
- 238000001256 steam distillation Methods 0.000 description 9
- -1 terephthalaldehyde acid methyl ester Chemical class 0.000 description 7
- 230000008901 benefit Effects 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 230000035484 reaction time Effects 0.000 description 6
- 238000000605 extraction Methods 0.000 description 5
- 238000001914 filtration Methods 0.000 description 5
- 229910001385 heavy metal Inorganic materials 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- 229910017052 cobalt Inorganic materials 0.000 description 4
- 239000010941 cobalt Substances 0.000 description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 3
- 238000004587 chromatography analysis Methods 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 229910052748 manganese Inorganic materials 0.000 description 3
- 239000011572 manganese Substances 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- 238000005292 vacuum distillation Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000004305 biphenyl Substances 0.000 description 2
- 235000010290 biphenyl Nutrition 0.000 description 2
- 125000006267 biphenyl group Chemical group 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000000543 intermediate Substances 0.000 description 2
- 239000012074 organic phase Substances 0.000 description 2
- LPNBBFKOUUSUDB-UHFFFAOYSA-N p-toluic acid Chemical compound CC1=CC=C(C(O)=O)C=C1 LPNBBFKOUUSUDB-UHFFFAOYSA-N 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 2
- OBETXYAYXDNJHR-UHFFFAOYSA-N 2-Ethylhexanoic acid Chemical class CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- 238000005904 alkaline hydrolysis reaction Methods 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 150000001869 cobalt compounds Chemical class 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- VNGOYPQMJFJDLV-UHFFFAOYSA-N dimethyl benzene-1,3-dicarboxylate Chemical compound COC(=O)C1=CC=CC(C(=O)OC)=C1 VNGOYPQMJFJDLV-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000013529 heat transfer fluid Substances 0.000 description 1
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000002697 manganese compounds Chemical class 0.000 description 1
- QSSJZLPUHJDYKF-UHFFFAOYSA-N methyl 4-methylbenzoate Chemical compound COC(=O)C1=CC=C(C)C=C1 QSSJZLPUHJDYKF-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
- C07C69/80—Phthalic acid esters
- C07C69/82—Terephthalic acid esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
- C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2427875A DE2427875C3 (de) | 1974-06-10 | 1974-06-10 | Verfahren zur Gewinnung von Dimethylterephthalat und von Zwischenprodukten der Dimethylterephthalat-Herstellung |
Publications (1)
Publication Number | Publication Date |
---|---|
NO751119L true NO751119L (ja) | 1975-12-11 |
Family
ID=5917731
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO751119A NO751119L (ja) | 1974-06-10 | 1975-04-02 |
Country Status (26)
Country | Link |
---|---|
US (1) | US4092481A (ja) |
JP (1) | JPS5330699B2 (ja) |
AR (1) | AR204271A1 (ja) |
AU (1) | AU8200075A (ja) |
BE (1) | BE830013A (ja) |
BG (1) | BG38786A3 (ja) |
BR (1) | BR7503661A (ja) |
CS (1) | CS183805B2 (ja) |
DD (1) | DD118607A5 (ja) |
DE (1) | DE2427875C3 (ja) |
DK (1) | DK257275A (ja) |
ES (1) | ES436738A1 (ja) |
FI (1) | FI750871A (ja) |
FR (1) | FR2273794A1 (ja) |
GB (1) | GB1516214A (ja) |
IT (1) | IT1035319B (ja) |
LU (1) | LU72681A1 (ja) |
NL (1) | NL169309C (ja) |
NO (1) | NO751119L (ja) |
PL (1) | PL103738B1 (ja) |
RO (1) | RO67906A (ja) |
SE (1) | SE7506440L (ja) |
SU (1) | SU676161A3 (ja) |
TR (1) | TR19101A (ja) |
YU (1) | YU40120B (ja) |
ZA (1) | ZA753684B (ja) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2923681C2 (de) * | 1979-06-12 | 1981-11-05 | Dynamit Nobel Ag, 5210 Troisdorf | Verfahren zur Gewinnung und Wiederverwendung von Schwermetalloxidationskatalysator aus dem Wittem-DMT-Prozeß |
DE3045332C2 (de) * | 1980-12-02 | 1982-11-25 | Dynamit Nobel Ag, 5210 Troisdorf | Verfahren zur Gewinnung und Wiederverwendung von Schwermetalloxidationskatalysator aus Rückständen im Witten-DMT-Prozeß |
DE3407925C1 (de) * | 1984-03-03 | 1985-09-05 | Dynamit Nobel Ag, 5210 Troisdorf | Verfahren zur Herstellung von Terephthalsaeuredimethylester aus p-Xylol und Methanol |
US4760165A (en) * | 1985-11-13 | 1988-07-26 | Teijin Petrochemical Industries, Ltd. | Recovering useful components at least containing dimethyl terephthalate from high-boiling byproducts occurring in the production of dimethyl terephthalate |
DE3904586A1 (de) * | 1989-02-16 | 1990-08-23 | Huels Chemische Werke Ag | Verfahren zur herstellung von dmt-zwischenprodukt bestimmter reinheit sowie dessen weiterverarbeitung zu reinst-dmt und/oder mittel- oder hochreiner terephthalsaeure |
JPH053094U (ja) * | 1991-01-28 | 1993-01-19 | 薫 高下 | 乗車船 |
US5236959A (en) * | 1992-03-12 | 1993-08-17 | Hoechst Celanese Corporation | Process for recycling polyester/cotton blends |
AU5359398A (en) * | 1996-11-18 | 1998-06-10 | Robbins Scientific Corporation | Apparatus for multi-well microscale synthesis |
DE19724390A1 (de) * | 1997-06-10 | 1998-12-17 | Huels Chemische Werke Ag | Methanolyse von Destillationsrückstand der Rohesterdestillation im Witten-Hercules-Verfahren zur Herstellung von Dimethylterephthalat |
DE19724391A1 (de) * | 1997-06-10 | 1998-12-17 | Huels Chemische Werke Ag | Verfahren zur Auftrennung des Rohestergemisches aus der Herstellung von Dimethylteraphthalat nach dem Witten-Hercules-Verfahren |
KR100814597B1 (ko) * | 2006-10-13 | 2008-03-17 | 에스케이에너지 주식회사 | 메틸 4-포밀벤조에이트와 디메틸테레프탈레이트의 분리방법 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1142858B (de) * | 1961-07-19 | 1963-01-31 | Witten Gmbh Chem Werke | Verfahren zur Gewinnung von Diphenylpolycarbonsaeuremethylestern |
JPS5620303B2 (ja) * | 1972-03-03 | 1981-05-13 | ||
DE2327773A1 (de) * | 1973-05-30 | 1974-12-19 | Teijin Hercules Chem Co Ltd | Verfahren zur gewinnung von dimethylterephthalat und seiner zwischenprodukte |
-
1974
- 1974-06-10 DE DE2427875A patent/DE2427875C3/de not_active Expired
-
1975
- 1975-01-01 AR AR258187A patent/AR204271A1/es active
- 1975-03-24 FI FI750871A patent/FI750871A/fi not_active Application Discontinuation
- 1975-04-02 NO NO751119A patent/NO751119L/no unknown
- 1975-04-12 BG BG7529634A patent/BG38786A3/xx unknown
- 1975-04-15 IT IT49109/75A patent/IT1035319B/it active
- 1975-04-18 ES ES436738A patent/ES436738A1/es not_active Expired
- 1975-05-06 JP JP5412475A patent/JPS5330699B2/ja not_active Expired
- 1975-06-02 YU YU1409/75A patent/YU40120B/xx unknown
- 1975-06-05 SE SE7506440A patent/SE7506440L/xx unknown
- 1975-06-06 SU SU752141280A patent/SU676161A3/ru active
- 1975-06-09 ZA ZA00753684A patent/ZA753684B/xx unknown
- 1975-06-09 GB GB21994/75A patent/GB1516214A/en not_active Expired
- 1975-06-09 LU LU72681A patent/LU72681A1/xx unknown
- 1975-06-09 CS CS7500004029A patent/CS183805B2/cs unknown
- 1975-06-09 BE BE157145A patent/BE830013A/xx unknown
- 1975-06-09 RO RO7582474A patent/RO67906A/ro unknown
- 1975-06-09 FR FR7517967A patent/FR2273794A1/fr active Granted
- 1975-06-09 DK DK257275A patent/DK257275A/da unknown
- 1975-06-10 AU AU82000/75A patent/AU8200075A/en not_active Expired
- 1975-06-10 PL PL1975181084A patent/PL103738B1/pl unknown
- 1975-06-10 US US05/585,760 patent/US4092481A/en not_active Expired - Lifetime
- 1975-06-10 NL NLAANVRAGE7506889,A patent/NL169309C/xx not_active IP Right Cessation
- 1975-06-10 TR TR19101A patent/TR19101A/xx unknown
- 1975-06-10 DD DD186552A patent/DD118607A5/xx unknown
- 1975-06-10 BR BR4696/75D patent/BR7503661A/pt unknown
Also Published As
Publication number | Publication date |
---|---|
JPS5330699B2 (ja) | 1978-08-29 |
US4092481A (en) | 1978-05-30 |
CS183805B2 (en) | 1978-07-31 |
SE7506440L (sv) | 1975-12-11 |
AU8200075A (en) | 1976-12-16 |
ZA753684B (en) | 1976-05-26 |
YU140975A (en) | 1982-02-28 |
PL103738B1 (pl) | 1979-07-31 |
BR7503661A (pt) | 1976-06-29 |
FI750871A (ja) | 1975-12-11 |
SU676161A3 (ru) | 1979-07-25 |
GB1516214A (en) | 1978-06-28 |
DE2427875B2 (de) | 1979-07-19 |
DE2427875A1 (de) | 1975-12-11 |
JPS50157329A (ja) | 1975-12-19 |
YU40120B (en) | 1985-08-31 |
AR204271A1 (es) | 1975-12-10 |
DE2427875C3 (de) | 1980-03-20 |
FR2273794B1 (ja) | 1980-09-12 |
LU72681A1 (ja) | 1975-09-29 |
NL169309C (nl) | 1982-07-01 |
NL169309B (nl) | 1982-02-01 |
NL7506889A (nl) | 1975-12-12 |
RO67906A (ro) | 1982-02-01 |
DK257275A (da) | 1975-12-11 |
BE830013A (fr) | 1975-10-01 |
ES436738A1 (es) | 1977-01-01 |
TR19101A (tr) | 1978-05-25 |
BG38786A3 (en) | 1986-02-28 |
IT1035319B (it) | 1979-10-20 |
FR2273794A1 (fr) | 1976-01-02 |
DD118607A5 (ja) | 1976-03-12 |
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