NO742605L - - Google Patents
Info
- Publication number
- NO742605L NO742605L NO742605A NO742605A NO742605L NO 742605 L NO742605 L NO 742605L NO 742605 A NO742605 A NO 742605A NO 742605 A NO742605 A NO 742605A NO 742605 L NO742605 L NO 742605L
- Authority
- NO
- Norway
- Prior art keywords
- substituted
- salt
- benzothiadiazinone
- dioxide
- salts
- Prior art date
Links
- 150000003839 salts Chemical class 0.000 claims description 37
- 239000000203 mixture Substances 0.000 claims description 25
- 125000000217 alkyl group Chemical group 0.000 claims description 18
- 150000001875 compounds Chemical class 0.000 claims description 14
- 239000001257 hydrogen Substances 0.000 claims description 14
- 229910052739 hydrogen Inorganic materials 0.000 claims description 14
- 230000002363 herbicidal effect Effects 0.000 claims description 12
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 9
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 6
- 239000000460 chlorine Substances 0.000 claims description 6
- 229910052801 chlorine Inorganic materials 0.000 claims description 6
- 150000002431 hydrogen Chemical class 0.000 claims description 6
- 239000004009 herbicide Substances 0.000 claims description 5
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 4
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052794 bromium Inorganic materials 0.000 claims description 4
- 229910052740 iodine Inorganic materials 0.000 claims description 4
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 2
- CTBNYRDNMZZICP-UHFFFAOYSA-N [O-][N+](I)=O Chemical compound [O-][N+](I)=O CTBNYRDNMZZICP-UHFFFAOYSA-N 0.000 claims description 2
- 125000003545 alkoxy group Chemical group 0.000 claims description 2
- 125000001188 haloalkyl group Chemical group 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002367 halogens Chemical class 0.000 claims description 2
- 239000011630 iodine Substances 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 125000003107 substituted aryl group Chemical group 0.000 claims description 2
- -1 R means Chemical class 0.000 description 33
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 26
- 239000013543 active substance Substances 0.000 description 22
- 241000196324 Embryophyta Species 0.000 description 21
- 150000002148 esters Chemical class 0.000 description 16
- 150000001408 amides Chemical class 0.000 description 15
- 239000000126 substance Substances 0.000 description 15
- 239000003795 chemical substances by application Substances 0.000 description 12
- 159000000000 sodium salts Chemical class 0.000 description 12
- 239000003921 oil Substances 0.000 description 11
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Substances CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 9
- 239000002253 acid Substances 0.000 description 6
- 150000007513 acids Chemical class 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 6
- 239000000839 emulsion Substances 0.000 description 6
- SLCGUGMPSUYJAY-UHFFFAOYSA-N Benzoylprop-ethyl Chemical compound C=1C=C(Cl)C(Cl)=CC=1N(C(C)C(=O)OCC)C(=O)C1=CC=CC=C1 SLCGUGMPSUYJAY-UHFFFAOYSA-N 0.000 description 5
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 5
- 230000012010 growth Effects 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000012876 carrier material Substances 0.000 description 4
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 239000012141 concentrate Substances 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 229910003002 lithium salt Inorganic materials 0.000 description 3
- 150000002790 naphthalenes Chemical class 0.000 description 3
- 229920000151 polyglycol Polymers 0.000 description 3
- 239000010695 polyglycol Substances 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000003559 2,4,5-trichlorophenoxyacetic acid Substances 0.000 description 2
- 239000005631 2,4-Dichlorophenoxyacetic acid Substances 0.000 description 2
- IUQJDHJVPLLKFL-UHFFFAOYSA-N 2-(2,4-dichlorophenoxy)acetate;dimethylazanium Chemical compound CNC.OC(=O)COC1=CC=C(Cl)C=C1Cl IUQJDHJVPLLKFL-UHFFFAOYSA-N 0.000 description 2
- PKAUICCNAWQPAU-UHFFFAOYSA-N 2-(4-chloro-2-methylphenoxy)acetic acid;n-methylmethanamine Chemical compound CNC.CC1=CC(Cl)=CC=C1OCC(O)=O PKAUICCNAWQPAU-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- UOCUSOBVEHOMMB-UHFFFAOYSA-N 2h-1$l^{6},2,3-benzothiadiazine 1,1-dioxide Chemical class C1=CC=C2S(=O)(=O)NN=CC2=C1 UOCUSOBVEHOMMB-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- 235000013877 carbamide Nutrition 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- 239000003630 growth substance Substances 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- NRXQIUSYPAHGNM-UHFFFAOYSA-N ioxynil Chemical compound OC1=C(I)C=C(C#N)C=C1I NRXQIUSYPAHGNM-UHFFFAOYSA-N 0.000 description 2
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
- 229920005610 lignin Polymers 0.000 description 2
- 159000000002 lithium salts Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
- 150000003956 methylamines Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 2
- 230000001069 nematicidal effect Effects 0.000 description 2
- 239000005645 nematicide Substances 0.000 description 2
- YDCVQGAUCOROHB-UHFFFAOYSA-N oxadiazolidine-4,5-dione Chemical class O=C1NNOC1=O YDCVQGAUCOROHB-UHFFFAOYSA-N 0.000 description 2
- 239000006072 paste Substances 0.000 description 2
- SIOXPEMLGUPBBT-UHFFFAOYSA-N picolinic acid Chemical class OC(=O)C1=CC=CC=N1 SIOXPEMLGUPBBT-UHFFFAOYSA-N 0.000 description 2
- 230000008635 plant growth Effects 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- LUDUIQAQFKIYND-UHFFFAOYSA-M potassium;2-(2,4,5-trichlorophenoxy)acetate Chemical compound [K+].[O-]C(=O)COC1=CC(Cl)=C(Cl)C=C1Cl LUDUIQAQFKIYND-UHFFFAOYSA-M 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- SMYMJHWAQXWPDB-UHFFFAOYSA-N (2,4,5-trichlorophenoxy)acetic acid Chemical compound OC(=O)COC1=CC(Cl)=C(Cl)C=C1Cl SMYMJHWAQXWPDB-UHFFFAOYSA-N 0.000 description 1
- FTDGDIFUDKDKAW-UHFFFAOYSA-N 1,1a,5,5a,6,6a-hexahydrocyclopropa[a]indene Chemical class C12C(CC3CC=CC=C13)C2 FTDGDIFUDKDKAW-UHFFFAOYSA-N 0.000 description 1
- FNQJDLTXOVEEFB-UHFFFAOYSA-N 1,2,3-benzothiadiazole Chemical class C1=CC=C2SN=NC2=C1 FNQJDLTXOVEEFB-UHFFFAOYSA-N 0.000 description 1
- CSNIZNHTOVFARY-UHFFFAOYSA-N 1,2-benzothiazole Chemical class C1=CC=C2C=NSC2=C1 CSNIZNHTOVFARY-UHFFFAOYSA-N 0.000 description 1
- ZLOTYHZOJPLLGG-UHFFFAOYSA-N 1-sulfanylidenethiadiazinane Chemical class S=S1CCCNN1 ZLOTYHZOJPLLGG-UHFFFAOYSA-N 0.000 description 1
- XUJLWPFSUCHPQL-UHFFFAOYSA-N 11-methyldodecan-1-ol Chemical compound CC(C)CCCCCCCCCCO XUJLWPFSUCHPQL-UHFFFAOYSA-N 0.000 description 1
- HXKWSTRRCHTUEC-UHFFFAOYSA-N 2,4-Dichlorophenoxyaceticacid Chemical compound OC(=O)C(Cl)OC1=CC=C(Cl)C=C1 HXKWSTRRCHTUEC-UHFFFAOYSA-N 0.000 description 1
- JCRNSBKSAQHNIN-UHFFFAOYSA-N 2,4-dibutylnaphthalene-1-sulfonic acid Chemical class C1=CC=CC2=C(S(O)(=O)=O)C(CCCC)=CC(CCCC)=C21 JCRNSBKSAQHNIN-UHFFFAOYSA-N 0.000 description 1
- OPQYFNRLWBWCST-UHFFFAOYSA-N 2-(2-chlorophenoxy)acetic acid Chemical compound OC(=O)COC1=CC=CC=C1Cl OPQYFNRLWBWCST-UHFFFAOYSA-N 0.000 description 1
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- ROGDGDPDLIVQFZ-UHFFFAOYSA-N 2-(4-chloro-2-methylphenoxy)propanoate;dimethylazanium Chemical compound CNC.OC(=O)C(C)OC1=CC=C(Cl)C=C1C ROGDGDPDLIVQFZ-UHFFFAOYSA-N 0.000 description 1
- NFAOATPOYUWEHM-UHFFFAOYSA-N 2-(6-methylheptyl)phenol Chemical class CC(C)CCCCCC1=CC=CC=C1O NFAOATPOYUWEHM-UHFFFAOYSA-N 0.000 description 1
- QTDIEDOANJISNP-UHFFFAOYSA-N 2-dodecoxyethyl hydrogen sulfate Chemical class CCCCCCCCCCCCOCCOS(O)(=O)=O QTDIEDOANJISNP-UHFFFAOYSA-N 0.000 description 1
- KSOIGNBVKZQBGW-UHFFFAOYSA-N 3,5-dibromo-4-hydroxybenzonitrile Chemical compound OC1=C(Br)C=C(C#N)C=C1Br.OC1=C(Br)C=C(C#N)C=C1Br KSOIGNBVKZQBGW-UHFFFAOYSA-N 0.000 description 1
- PJPJHLCKZATSDK-UHFFFAOYSA-N 3-ethyl-2lambda4,1,3-benzothiadiazine 2-oxide Chemical compound C(C)N1S(N=C2C(=C1)C=CC=C2)=O PJPJHLCKZATSDK-UHFFFAOYSA-N 0.000 description 1
- SOPHXJOERHTMIL-UHFFFAOYSA-N 3-methyl-4,6-dinitro-2-propan-2-ylphenol Chemical compound CC(C)C1=C(C)C([N+]([O-])=O)=CC([N+]([O-])=O)=C1O SOPHXJOERHTMIL-UHFFFAOYSA-N 0.000 description 1
- HQQTZCPKNZVLFF-UHFFFAOYSA-N 4h-1,2-benzoxazin-3-one Chemical class C1=CC=C2ONC(=O)CC2=C1 HQQTZCPKNZVLFF-UHFFFAOYSA-N 0.000 description 1
- LRDPQMJVRJVAOH-UHFFFAOYSA-N 6-methylheptyl 2-(2,4,5-trichlorophenoxy)acetate Chemical compound CC(C)CCCCCOC(=O)COC1=CC(Cl)=C(Cl)C=C1Cl LRDPQMJVRJVAOH-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 241000209219 Hordeum Species 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 239000005574 MCPA Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- 229930192627 Naphthoquinone Natural products 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 240000004713 Pisum sativum Species 0.000 description 1
- 235000010582 Pisum sativum Nutrition 0.000 description 1
- 241000209504 Poaceae Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical class C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 description 1
- 244000082988 Secale cereale Species 0.000 description 1
- 235000007238 Secale cereale Nutrition 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000007244 Zea mays Nutrition 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 239000001166 ammonium sulphate Substances 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 150000001448 anilines Chemical class 0.000 description 1
- 230000002303 anti-venom Effects 0.000 description 1
- 239000000729 antidote Substances 0.000 description 1
- 229940075522 antidotes Drugs 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 229940111121 antirheumatic drug quinolines Drugs 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- BUSBFZWLPXDYIC-UHFFFAOYSA-N arsonic acid Chemical class O[AsH](O)=O BUSBFZWLPXDYIC-UHFFFAOYSA-N 0.000 description 1
- 125000003785 benzimidazolyl group Chemical class N1=C(NC2=C1C=CC=C2)* 0.000 description 1
- JFDZBHWFFUWGJE-UHFFFAOYSA-N benzonitrile Substances N#CC1=CC=CC=C1 JFDZBHWFFUWGJE-UHFFFAOYSA-N 0.000 description 1
- 150000005130 benzoxazines Chemical class 0.000 description 1
- TWVMOBWHILUBSS-UHFFFAOYSA-N benzoylcarbamic acid Chemical class OC(=O)NC(=O)C1=CC=CC=C1 TWVMOBWHILUBSS-UHFFFAOYSA-N 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Inorganic materials [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 1
- 239000001175 calcium sulphate Substances 0.000 description 1
- 235000011132 calcium sulphate Nutrition 0.000 description 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 125000004802 cyanophenyl group Chemical group 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 229960002887 deanol Drugs 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 229940043237 diethanolamine Drugs 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 150000005332 diethylamines Chemical class 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- IOLPQKZYGWAYQO-UHFFFAOYSA-N dimethylazanium;2-(2,4,5-trichlorophenoxy)propanoate Chemical compound C[NH2+]C.[O-]C(=O)C(C)OC1=CC(Cl)=C(Cl)C=C1Cl IOLPQKZYGWAYQO-UHFFFAOYSA-N 0.000 description 1
- 239000012972 dimethylethanolamine Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 150000002019 disulfides Chemical class 0.000 description 1
- 239000012990 dithiocarbamate Substances 0.000 description 1
- 150000004659 dithiocarbamates Chemical class 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229940031098 ethanolamine Drugs 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000000194 fatty acid Chemical class 0.000 description 1
- 229930195729 fatty acid Chemical class 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N heptadecan-1-ol Chemical class CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical class CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- 150000001469 hydantoins Chemical class 0.000 description 1
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 235000012245 magnesium oxide Nutrition 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- KDKIQPRSLMHYNN-UHFFFAOYSA-N n-methylmethanamine;2-(2,4,5-trichlorophenoxy)acetic acid Chemical compound C[NH2+]C.[O-]C(=O)COC1=CC(Cl)=C(Cl)C=C1Cl KDKIQPRSLMHYNN-UHFFFAOYSA-N 0.000 description 1
- 150000002791 naphthoquinones Chemical class 0.000 description 1
- QNMLMAVEXUCXRG-UHFFFAOYSA-N oxadiazinane-4,5-dione Chemical class O=C1CONNC1=O QNMLMAVEXUCXRG-UHFFFAOYSA-N 0.000 description 1
- SDRLFDJOSQLRPB-UHFFFAOYSA-N oxadiazine-4,5-dione Chemical class O=C1CON=NC1=O SDRLFDJOSQLRPB-UHFFFAOYSA-N 0.000 description 1
- 150000004866 oxadiazoles Chemical class 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- QIIPQYDSKRYMFG-UHFFFAOYSA-N phenyl hydrogen carbonate Chemical class OC(=O)OC1=CC=CC=C1 QIIPQYDSKRYMFG-UHFFFAOYSA-N 0.000 description 1
- REJGOFYVRVIODZ-UHFFFAOYSA-N phosphanium;chloride Chemical class P.Cl REJGOFYVRVIODZ-UHFFFAOYSA-N 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 150000003053 piperidines Chemical class 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- BWILYWWHXDGKQA-UHFFFAOYSA-M potassium propanoate Chemical compound [K+].CCC([O-])=O BWILYWWHXDGKQA-UHFFFAOYSA-M 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 150000003217 pyrazoles Chemical class 0.000 description 1
- BFZYLUGEHGYJKJ-UHFFFAOYSA-N pyrazolidine-3-thione Chemical class S=C1CCNN1 BFZYLUGEHGYJKJ-UHFFFAOYSA-N 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 150000005299 pyridinones Chemical class 0.000 description 1
- 150000003230 pyrimidines Chemical class 0.000 description 1
- 150000008318 pyrimidones Chemical class 0.000 description 1
- NYCVCXMSZNOGDH-UHFFFAOYSA-N pyrrolidine-1-carboxylic acid Chemical class OC(=O)N1CCCC1 NYCVCXMSZNOGDH-UHFFFAOYSA-N 0.000 description 1
- 150000003235 pyrrolidines Chemical class 0.000 description 1
- 150000004040 pyrrolidinones Chemical class 0.000 description 1
- 150000003246 quinazolines Chemical class 0.000 description 1
- 150000003248 quinolines Chemical class 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 125000005624 silicic acid group Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- JXKPEJDQGNYQSM-UHFFFAOYSA-M sodium propionate Chemical compound [Na+].CCC([O-])=O JXKPEJDQGNYQSM-UHFFFAOYSA-M 0.000 description 1
- RFOHRSIAXQACDB-UHFFFAOYSA-M sodium;2-(2,4-dichlorophenoxy)acetate Chemical compound [Na+].[O-]C(=O)COC1=CC=C(Cl)C=C1Cl RFOHRSIAXQACDB-UHFFFAOYSA-M 0.000 description 1
- STAPBGVGYWCRTF-UHFFFAOYSA-M sodium;2-(4-chloro-2-methylphenoxy)acetate Chemical compound [Na+].CC1=CC(Cl)=CC=C1OCC([O-])=O STAPBGVGYWCRTF-UHFFFAOYSA-M 0.000 description 1
- QGKPUZOFTJQTHL-UHFFFAOYSA-M sodium;4-cyano-2,6-diiodophenolate Chemical compound [Na+].[O-]C1=C(I)C=C(C#N)C=C1I QGKPUZOFTJQTHL-UHFFFAOYSA-M 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 125000003011 styrenyl group Chemical class [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 1
- OLPRIZQBWZMBAS-UHFFFAOYSA-N thiadiazolidine 1,1-dioxide Chemical class O=S1(=O)CCNN1 OLPRIZQBWZMBAS-UHFFFAOYSA-N 0.000 description 1
- 150000003566 thiocarboxylic acids Chemical class 0.000 description 1
- 150000003582 thiophosphoric acids Chemical class 0.000 description 1
- 150000003585 thioureas Chemical class 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- 150000003852 triazoles Chemical group 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical class CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 244000045561 useful plants Species 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/46—N-acyl derivatives
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/88—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
"Herbicid" • • • © • • •
Den foreliggende oppfinnelse angår nye verdifulle herbicider som inneholder blandinger av forskjellige virksomme stoffer.
Det er kjent at bénzoylaminokarboksylsyrer, din'i-érofenol-derivater, hydroksybenzonitriler, hydroksybenzaldoksimaryletere, benzotiadiazinondioksyder og fenoksykarboksylsyrer har en herbicid virkning. Denne er imidlertid ikke alltid tilstrekkelig.
Det ble funnet at en blanding av
a) en forbindelse med formelen
hvor x betyr halogen, alkyl, ha(logenalkyl, alkoksy, R betyr, hydrogen, lavere alkyl, R i betyr lavere alkyl og n har verdier fra 0 til 3, og/eller
b) en forbindelse med formelen
hvor R betyr lavere alkyl, R betyr hydrogen og saltene, eksempelvis ammonium-, kalium-, natrium-, litium-, kalsium-, magnesium-, etylamin-, dimetylamin-, dietylamin-, dietanol-amin-, etanolamin-, dimetyletanolamin-, trimetylamin-saltene,
og/eller
c) en forbindelse med formelen
hvor x betyr klor, brom, nitro, jod, cyan, lavere alkyl,
n har verdier fra 0 til 3, R betyr hydrogen og saltene, eksempelvis natriumsaltet, litiumsaltet, og R ennvidere betyr
hvor Y betyr klor,
jod eller brom, R1 betyr lavere alkyl, -C-alkyl, hydrogen og
ti
saltene, eksempelvis natriumsaltet, og R<2>og R^ betyr hydrogen, lavere alkyl, eventuelt en substituert arylrest,
og/eller
d) en forbindelse med formelen
hvor Y og X betyr klor, metyl, n har verdier fra 0 til 3,
R betyr hydrogen, lavere alkyl, m har verdier fra 0 til 2,
R"*" betyr alkyl, hydrogen og saltene, eksempelvis natrium-, ;kalium-, dimetylamin-, dietylamin-Jsaltene,;har en bedre herbicid virkning enn enkeltstoffene.;Blandingene kan inneholde en eller flere forbindelser med formelen a) og forbindelser med formlene b)-d). ;Blandingsforholdet er 1:0,1 til 10 vektdeler av de virksomme stoffer. ;Den mengde som anvendes av midlene ifølge oppfinnelsen, kan variere. Den mengde som anvendes, avhenger hovedsakelig av arten av den ønskede virkning. Mengden ligger vanligvis mellom 0,1 og 30 eller mer, fortrinnsvis 0,2-6 kg virksomt stoff pr. hektar. ;Midlene ifølge oppfinnelsen kan blant annet anvendes ved metoder;hvor midlene påføres etter plantingen eller etter at kulturplantene eller de uønskjede planter er kommet opp av jorden, og midlene kan anvendes en eller flere ganger. ;Blandingene er egnet til å bekjempe uønskede planter i kul-turer av nytteplanter, for eksempeliTriticum spp., Hordeum spp., ;Zea mays, Solanum tuberosum, Pisum sativum, Phaseolus vulgaris,;Secale cereale, Oryza sativa, Glycine Max.;Blandingene kan også anvendes som totalmiddel ved graver,;langs elver og bekker, langs jernbaneskinner, på øde flater etc. ;Blandingene a + b, a + c, a^+ d, a+b+c, a+b+d, a+c+dogb+c+d foretrekkes. ;Påføringen skjer eksempelvis i fo[rV av direkte sprøytbare løsninger, pulvere, suspensjoner eller dispersjoner, emulsjoner, oljedispersjoner, pastaer, støvformige midler, strømidler eller granulater, ved utsprøyting, forstøvning, utstrøing eller uthelling.Bruksformene retter seg helt etter anvendelsesformålet; man tar imidlertid alltid sikte på å oppnå best mulig fordeling av de virksomme stoffer. ;For fremstilling av direkte sprøytbare løsninger, emulsjoner, pastaer og oljedispersjoner kan man bruke mineraloljefraksjoner med midlere til høyt kokepunkt, så som kerosin eller dieselolje, ennvidere kulltjæreoljer etc, samt oljer av vegetabilsk eller animalsk opprinnelse, alifatiske, cykliske og aromatiske hydrokarboner, for ;.xylen, paraffin, tetrahydronaftalin, alky-lerte naftaliner eller deres derivater, for eksempel metanol, etanol, propanol, butanol, kloroform, karbontetraklorid, cykloheksanol, cykloheksanon, klorbenzen, isoforon etc, sterkt polare løsningsmidler, så som dimetylformamid, dimetylsulfoksyd, N-metylpyrrolidon, vann etc ;Vandige bruksformer kan fremstilles av emulsjonskonsentrater, pastaer eller fuktbare pulvere (sprøytepulvere), oljedispersjoner, ved tilsetning av vann. Til fremstilling av emulsjoner, pastaer eller oljedispersjoner kan stoffene som sådanne eller løst i olje eller løsningsmiddel homogeniseres i vann ved hjelp av fukte-, klebe-, dispergerings- eller emulgeringsmidler.. Det kan imidlertid også fremstilles konsentrater bestående av virksomt stoff, fukte-, klebe-, dispergerings- eller emulgerigsmiddel og eventuelt løsningsmiddel-eller olje, hvilke konsentrater er egnet til å fortynnes med vann. ;Blant overflateaktive stoffer kan nevnes: alkali-, jordalkali-og ammoniumsalter av ligninsulfonsyre, naftalinsuifonsyre, fenol-sulfonsyrer, alkylarylsulfonater, alkylsulfater, alkylsulfonater, alkali- og jordalkalisalter av dibutylnaftalinsulfonsyre, lauryleter-sulfat, fettalkoholsulfater, fettsure alkali- og jordalkalisalter, salter av sulfaterte heksadekanoler, heptadekanoler, oktadekanoler, salt av sulfatert fettalkoholglykoleter, kondensasjonsprodukter av sulfonert naftalin og naftalinderivater med formaldehyd, kondensasjonsprodukter av naftalin eller naftalinsulfonsyrer med fenol og formaldehyd, polyoksyetylen-oktylfenoleter, etoksylert isooktylfenol, -oktylfenol, -nonylfenol, alkylfenolpolyglykoleter, tributylfenyl-polyglykoleter, alkylarylpolyeteralkoholer, isotridecylalkohol, fett-alkoholetylenoksyd-kondensater, etoksylert ricinusolje, polyoksy-etylenalkyleter, etoksylert polyoksypropylen, laurylalkoholpolygly-koleteracetal, sorbitolester, lignin, sulfittavluter og metylcellu-lose. ;Pulver, strø- og støvformige midler kan fremstilles ved blanding eller sammaling i av' de virksomme stoffer med et fast bærémate-riale. ;Granulater, for eksempel omhyllings-, impregnerings- og homo-gengranulater, kan fremstilles ved binding av de virksomme stoffer på faste bærematerialer. Faste bærematerialer er eksempelvis mine-ralmaterialer så som silikagel, kiselsyrer, kiselgeler, silikater, talkum, kaolin, attaclay, kalkstein, kalk, kritt, bolus, løss, leire, dolomitt, diatoméjord, kalsium- og magnesiumsulfat, magnesiumoksyd, malte harpikser, gjødningsstoffer som for eksempel ammoniumsulfat, ammoniumfosfat, ammoniumnitrat, urinstoffer og vegetabilske produkter så som mel av korn, bark, tre og nøtteskall, cellulosepulver og andre faste bærematerialer. ;Preparatene inneholder mellom 0,1 og 95 vekt% virksomt stoff, fortrinnsvis mellom 0,5 og 90 vekt%. ;Til blandingene eller de enkelte virksomme stoffer kan man, eventuelt først umiddelbart før anvendelsen (tankblanding), tilsette oljer av forskjellige typer, herbicider, fungicider, nematocider, insekticider, baktericider, sporelementer, gjødningsstoffer, skum-hindrende midler (eksempelvis silikoner), vekstregulatorer, motgift-midler eller andre herbicid virksomme forbindelser, som for eksempel substituerte aniliner ;substituerte aryloksykarboksylsyrer og deres salter, estere og ;amider;substituerte etere;substituerte arsonsyrer og deres salter, estere og amider substituerte benzimidazoler ;substituerte benzisotiazoler;substituerte benztiadiazinondioksyder;substituerte benzoksaziner;substituerte benzoksazinoner;substituerte benztiadiazoler;substituerte biureter;substituerte kinoliner;substituerte karbamater;substituerte alifatiske karboksylsyrer og deres salter, estere;og amider;substituerte aromatiske karboksylsyrer og deres salter, estere;og amider;substituerte karbamoylalkyl-tiol eller ditiofosfater substituerte kinazoliner ;substituerte cykloalkylamidokarbontiolsyrer og deres salter, ;estere og amider substituerte cykloalkylkarbonamido-tiazoler ;substituerte dikarboksylsyrer og deres salter, estere og amider substituerte dihydrobenzofuranylsulfonater ;substituerte disulfider;substituerte dipyridyliumsalter;substituerte ditiokarbamater;substituerte ditiofosforsyrer og deres salter, estere og amider substituerte urinstoffer ;substituerte heksahydro-lH-karbotioater;substituerte hydantoiner;substituerte hydrazider;substituerte hydrazoniumsalter;substituerte isooksazolpyrimidoner;substituerte imidazoler;substituerte isotiazolpyrimidoner;substituerte ketoner;substituerte naftokinoner;substituerte alifatiske nitriler;substituerte aromatiske nitriler;substituerte oksadiazoler;substituerte oksasiazinoner;substituerte oksadiazolidindioner;substituerte oksadiazindioner;substituerte fenoler og deres salder og estere substituerte fosfonsyrer og deres salter, estere og amider substituerte fosfoniumklorider ;substituerte fosfonalkylglyciner;substituerte fosfitter;substituerte fosforsyrer og deres salter, estere og amider substituerte piperidiner ;substituerte pyrazoler;substituerte pyrazolalkylkarboksylsyrer og deres salter, estere ;og amider;substituerte pyrazoliumsalter;substituerte pyrazoliumalkylsulfater;substituerte pyriSa/ziner;substituerte pyridazoner;substituerte pyridinkarboksylsyrer og deres salter, estere og ;amider;substituerte pyridiner;substituerte pyridinkarboksylater;substituerte pyridinoner;substituerte pyrimidiner;substituerte pyrimidoner;substituerte pyrrolidinkarboksylsyrer og deres salter, estere og ;amider;substituerte pyrrolidiner;substituerte pyrrolidoner;substituerte arylsulfonsyrer og deres salter, estere og ;amider;substituerte styrener;substituerte tetrahydro-oksadiazindioner;substituerte tetrahydro-oksadiazoldioner;substituerte tetrahydrometanoindener;substituerte tetrahydro-diazol-tioner;substituerte tetrahydro-tiadiazin-tioner;substituerte tetrahydro-tiadiazoldioner;substituerte aromatiske tiokarboksylsyréamider;substituerte tiokarboksylsyrer og deres salter, estere og;amider;substituerte tiolkarbamater;substituerte tiourinstoffer;substituerte tiofosforsyrer og deres salter, estere og amider substituerte triaziner ;substituerte triazoler substituerte uraciler ;substituerte uretidindioner;De sistnevnte herbicide forbindelser kan etter ønske anvendes før;eller etter de virksomme enkeltstoffer eller blandinger ifølge oppfinnelsen. ;Tilblandingen av disse midler til herbicidene ifølge oppfinnelsen kan skje i vektforholdet 1:10 til 10:1. Det samme gjelder for olje, fungicider, nematocider, insekticider, baktericider, mot-giftmidler og vekstregulatorer. ;Midlene oppviser en sterk herbicid virkning og kan derfor anvendes som ugrasdrepende midler eller til bekjempelse av uønskede plantevekster. Om midlene virker som totale eller selektive midler, avhenger hovedsakelig av den mengde virksomt stoff som anvendes pr. flateenhet. ;Med ugras eller uønskede plantevekster menes alle enfrø-bladede og tofrøbladede planter som vokser på steder hvor de ikke er ønsket. ;Således kan eksempelvis følgende planter bekjempes med;midlene ifølge oppfinnelsen.;Planter av grasfamilien, så som ; ;
De følgende forbindelser ble i drivhus og på friland utprøvet;i forskjellige blandinger overfor de i eksemplene nevnte planter: 3-metyl-2,I,3-benzotiadiazinon-(4)-2,2-dioksyd ;3-etyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd ;3-propyl-2/1,3-benzotiadiazinon-(4)-2,2-dioksyd ;3-butyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd ;3-isobutyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd ;3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-natriumsalt 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2, 2-dioksyd-dimetyl- ;aminsalt ;3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dietanol-;aminsalt ;3,5-dibrom-4-hydroksy-benzaldoksim-0-(2',4'-dinitrofenyl)-eter 3,5-dibrom-4-hydroksy-benzaldoksim-0-(2<1>,4'-dinitrofenyl)-eter-natriumsalt ;3, 5-dibrom-4-acetyloksy-benzaldoksim-0-(2'i-cyan-4' -nitrofenyl) -;eter ;3,5-dibrom-4-hydroksy-benzaldoksim-0-(2'-cyan-4'-nitrofenyl)-eter 3,5-dibrom-4-hydroksy-benzaldoksim-0-(2'-nitro-4<1->cyanfenyl)-eter 3,5-dibrom-4-hydroksy-benzaldoksim-0-(2<1->cyan-4'-nitrofenyl)-eter-natriumsalt ;3,5-dibrom-4-propionyloksy-benzaldoksim-0-(2'-cyan-4'-nitrofenyl)-;eter ;3,5-dijod-4-hydroksy-benzaldoksim-0-(2'-cyan-4'-nitrofenyl)-eter 3,5-dijod-4-hydroksy-benzaldoksim-0-(2'-cyan-4'-nitrofenyl)-eter-natriumsalt ;3,5-dijod-4-hydroksybenzonitril ;3,5-dijod-4-hydroksybenzonitril-natriumsalt ;3,5-dijod-4-hydroksybenzonitril-litiumsalt ;3,5-dibrom-4-hydroksybenzonitril ;3,5-dibrom-4-hydroksybenzonitril-natriumsalt ;3,5-dibrom-4-oktanyloksy-benzonitril ;2-metyl-4,6-dinitrofenyl-natriumsalter ;2-sek.butyl-4,6-dinitrofenylacetat;2-tert.butyl-4,6-dinitrofenylacetat ;2-tert.butyl-5-metyl-4,6-dinitrofenylacetat ;2-isopropyl-3-metyl-4,6-dinitrofenol ;2- sek.butyl-4,6-dinitrofenol-natriumsalt ;3,5-dibrom-4-fenylkarbamoyloksy-0-(2'-cyan-4'-nitrofenyl)-eter 3,5-dibrom-4-isopropylkarbamoyloksy-0-(2'-cyan-4'-nitrofenyl)- ;eter ;3- isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-metylaminsalt 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-trimetyl- ;aminsalt ;3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-etylamin-salt 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dietylarain-salt ;3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-etanolamin-;salt ;3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-anilinsalt 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-pyridinsalt 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-fenylen- ;diaminsalt ;3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-cykloheksyl-aminsalt ;3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dodecylheksa-metylenirainsalt ;3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-hydrazinsalt 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-magnesiumsalt 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-kalsiumsalt 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-ammoniumsalt 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-kaliumsalt 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-litiumsalt 3-isobutyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-natriumsalt 3-isobutyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dimetylaminsalt ;3-isobutyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dietanol-aminsalt ;3-sek.butyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-natriumsalt 3-sek.butyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dimetylaminsalt ;3-sek.butyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dietanol-aminsalt ;3-n-butyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-natriumsalt 3-n-butyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dimetylaminsalt 3-n-butyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dietanol-aminsalt ;3-n-propyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-natriumsalt 3-n-propyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dimetyl-"amlnsalt ;3-n-propyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dietanol-aminsalt ;3-etyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-natriumsalt 3-etyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dimetylamirisalt 3-etyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dietanolamin- ;salt 3-metyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-natriumsalt 3-metyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dimetylamin- ;salt ;3-metyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dietanolamin-;salt ;2-sek.amyl-4,6-dinitrofenol;2-(1-metylbutyl)-4,6-dinitrofenol ;etyl-N-benzoyl-N-(3,4-diklorfenyl)-2-aminopropionat a-(2,4-diklorfenoksy)-propionsyre-dimetylaminsalt ;a-(2-metyl-4-klorfenoksy)-propionsyre-dimetylaminsalt a-(2-metyl-4-klorfenoksy)-propionsyre-natriumsalt ;a-(2-raetylfenoksy)-propionsyre-dimetylaminsalt ;a-(2,4-diklorfenoksy)-propionsyre-natriumsalt ;a-(2,4,5-triklorfenoksy)-propionsyre-kaliumsalt ;a-(4-klorfenoksy)-propionsyre-dimetylaminsalt ;a-(2-metylfenoksy)-propionsyre-isooktylester ;a-(2-metylfenoksy)-propionsyre-natriumsalt ;a-(2-metyl-4-klorfenoksy)-propionsyre-dietanolaminsalt a-(2-metyl-4-klorfenoksy)-propionsyre-kaliumsalt a-( 2,4-diklorfenoksy)-propionsyre-isooktylester ;2,4,5-triklorfenoksyeddiksyre-amylester ;2,4,5-triklorfenoksyeddiksyre-isooktylester ;2,4,5-triklorfenoksyeddiksyre-dietylaminsalt ;2,4-diklorfenoksyeddiksyre-dimetylaminsalt ;2-metyl-4-klorfenoksyeddiksyre-dimetylaminsalt ;2-metyl-4-klorfenoksyeddiksyre-natriumsalt ;2,4,5-triklorfenoksyeddiksyre-kaliumsalt ;2,4,5-triklorfenoksyeddiksyre-dimetylaminsalt ;4-klorfenoksyeddiksyre-dimetylaminsalt ;2-klorfenoksyeddiksyre-dimetylaminsalt ;2-metyl-4-klorfenoksyeddiksyre-isooktylester ;2,4-diklorfenoksyéddiksyre-natriumsalt ;2,4-diklorfenoksyeddiksyre-isooktylester ;Y- (2,4-diklorfenoksy)-smørsyre-dimetylaminsalt ;X-(2,4-diklorfenoksy)-smørsyre-isooktylester ;Jf- (2,4-diklorfenoksy)-smørsyre-isooktylester ;o/'-(2-metyl-4-klorfenoksy) -smørsyre-natriumsalt ;^-(2,4,5-troklorfenoksy)-smørsyre-dimetylaminsalt ^-(4-klorfenoksy)-smørsyre ;){- (2, 4-diklorfenoksy) -krotonsyre-dimetylaminsalt ;De anførtefinidler har en tilsvarende biologisk virkning som de i eksemplene anførte forbindelser. ;Eksempel 1;I et drivhus ble forskjellige planter ved en veksthøyde på 2-18 cm behandlet med de, følgende virksomme enkeltstoffer og deres blandinger som emulsjon eller oljedispersjonj ;I etyl-N-benzoyl-N-(3,4-diklorfenyl)-2-aminopropionat;II 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2>2-dioksyd;III 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-natriumsalt ;IV 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dimetylaminsalt ;V 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dietanolaminsalt ;i hvert tilfelle 0,5 - 0,75 - 1,0 og 1,5 kg/ha aktivt stoff. ;I+II, I+III, I+IV, I+V;i hvert tilfelle 0,5+1?1+0,5; 0,75+0,75 kg/ha aktivt stoff. ;Etter 14-18 dager ble det slått fast at blandingene viste en bedre herbicid virkning ved samme forenlighet med kulturplantene enn enkeltstoffene. ;Forsøksresultatet vil fremgå av den følgende tabell. ;
Eksempel 2;I et drivhus ble forskjellige planter ved en veksthøyde på 3-25 cm behandlet med de følgende virksomme enkeltstoffer og deres blandinger som dispersjon: ;I etyl-N-benzoyl-N-(3,4-diklorfenyl)-2-aminopropionat;II 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd;III 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-natriumsalt ;IV 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dimetylaminsalt ;V 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dietanolaminsalt ;i hvert tilfelle 0,5 - 1,5 - 2,5 og 3 kg/ha aktivt stoff. ;I+II, I+III, IV+I, I+V i hvert tilfelle 2,5+0,5; 0,5+2,5 og 1,5+1,5 ;kg/ha aktivt stoff.;Etter 15-18 dager ble det slått fast at blandingene viste en bedre herbicid virkning* ved samme forenlighet med kulturplantene enn enkeltstoffene.
Forsøksresultatet vil fremgå av den følgende tabell.
Eksempel 3
I et veksthus ble forskjellige planter ved en veksthøyde på 2-20 cm behandlet med de følgende virksomme enkeltstoffer og deres blandinger som pasta:
I etyl-N-benzoyl-N'-(3,4-diklorfenyl)-2-aminopropionat
IV 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dimetylaminsalt
VI 2-sek.butyl-4,6-dinitrofenylacetat
VII 3,5-dijod-4-hydroksybenzonitril
VIII 3,5-dibrom-4-hydroksybenzaldoksim-0-(2',4'-dinitrofenyl)-eter
IX 3,5-dibrom-4-hydroksybenzaldoksim-0-(2'-cyan-4-nitrofenyl)-eter-natriumsalt
i hvert tilfelle 0,25 - 1 - 1,5 kg/ha aktivt stoff
I+IV+VII, I+IV+VIII, I+IV+IX, I+IV+VI
i hvert tilfelle 1,0+0,25+0,25; 0,25+1,0+0,25; 0,25+0,25+1,0 kg/ha aktivt stoff.
Etter 12-14 dager ble det slått fast at blandingene viste en bedre herbicid virkning ved samme forenlighet med kulturplantene enn enkeltstoffene.
'Forsøksresultatet vil fremgå av den følgende tabell.
Eksempel 4
På friland ble forskjellige planter IvecL en veksthøyde på 2-24 cm behandlet med de følgende virksomme enkeltstoffer og deres blandinger som emulsjon-dispersjon-tankblanding:
I etyl-N-benzoyl-N-(3,4-diklorfenyl)-2-aminopropionat
II 3-isopropyl-2,1/3-benzotiadiazinon-(4)-2,2-dioksyd
III 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-natriumsalt
IV 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dimetylaminsalt
V 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dietanolaminsalt
VI 2-sek.butyl-4,6-dinitro-fenylacetat
VII 3, 5~ dijod-4-hydroksy-benzonitril-litiumsalt
VIII 3,5-dibrom-4-hydroksybenzaldoksim-0-(2,4-dinitrofenyl)-eter-natriumsalt
IX 3,5-dibrom-4-hydroksybenzaldoksim-0-(2'-cyan-4'-nitrofenyl) -eter-natriumsalt
X 3,5-dibrom-4-hydroksy-benzonitril-natriumsalt
XI a-(2-metyl-4-klor-fenoksy)-propionsyre-dimetylamin-
salt
XII a-(2,4-diklor-fenoksy)-propionsyre-dimetylaminsalt
XIII 2,4-diklor-fenoksy-eddiksyre-dimetylaminsalt.
XIV 2-metyl-4-klor-fenoksy-eddiksyre-dimetylaminsalt
XV a-(2,4,5-triklor-fenoksy)-propionsyre-dimetylaminsalt
XVI 2,4,5-triklor-fenoksy-eddiksyre-kaliumsalt
XVII f-(2,4-diklor-fenoksy)-smørsyre-dimetylaminsalt
i hvert tilfelle 0,25, 1 og 1,5 kg/ha aktivt stoff
I+II+VI, I+II+VII, I+II+VIII, I+II+IX, I+II+X, I+III+VI, I+III+VII, I+III+VIII, I+III+IX, I+III+X, I+V+VI, I+V+VII,
i+v+viii, i+v+ix, i+y+x,~ i+iv+x, i+ii+ix, i+ii+xii, i+n+xiii, i+ii+xiv, 'i+ii+xv, i+ii+xvi, i+iii+xi, i+iii+xii, i+m+xiii,
I+III+XIV, I+III+XV, I+III+XVI, I+IV+XI, I+IV+XII, I+IV+XIII, I+IV+XIV, I+IV+XV, I+IV+XVI, I+V+XI, I+V+XII, I+V+XIII,
I+V+XIV, I+V+XV, I+V+XVI, I+VI+XI, I+VI+XII' I+VI+XIII,
I+VI+XIV, I+VI+XV, I+VI+XVI, I+VII+XI, I+VII+XII, I+VII+XIII, I+VII+XIV, I+VII+XV, I+VII+XVI, I+VIII+XI, I+VIII+XII, I+VIII+ XIII, I+VIII+XIV, I+VIII+XV, I+VIII+XVI, I+IX+XI, I+IX+XII,
I+IX+XIII, I+IX+XIV, I+IX+XV, I+IX+XVI, I+X+XI, I+X+XII,
I+X+XIII, I+X+XIV, I+X+XV, I+X+XVI, I+XVI+XI, I+XVI+XII, I+XVI+XIII, I+XVI+XIV, I+XIII+XI, I+XIII+XIV, I+II+XVII, I+III+XVII, I+IV+XII, I+V+XVII, I+VI+XVII, I+VII+XVII,
I+VIII+XVII, I+IX+XVlt, I+X+XVII
i hvert tilfelle 1+0,25+0,25?0, 25+(li+0, 25 og 0,25+0,25+1 kg/ha aktivt stoff.
Etter 12-14 dager ble det slått fast at blandingene viste en bedre herbicid virkning ved samme forenlig/het] med kulturplantene enn enkeltstoffene.
Forsøksresultatet vil fremgå av den følgende tabell.
Eksempel 5
I ét drivhus ble forskjellige planter ved en veksthøyde
på 2-24 cm behandlet med de følgende virksomme enkeltstoffer og deres blandinger som emulsjon-løsning-tankblanding:
I etyl-N-benzoyl-N-(3,4-diklorfenyl)-2-aminopropionat
II 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd
III 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-natriumsalt
IV 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dimetylaminsalt
V 3-isopropyl-2,1,3-benzotiadiazinon-(4)-2,2-dioksyd-dietanolaminsalt
XI a-(2-metyl-4-klor-fenoksy)-propionsyre-dimetylaminsalt
XII a-( 2,4-diklor-fenoksy)-propionsyre-dimetylaminsalt
XIII 2,4-diklor-fenoksy-eddiksyre-dimetylaminsalt
XIV 2-metyl-4-klor-fenoksy-eddiksyre-dimetylaminsalt
•XVI 2,4,5-triklor-if^noksy-eddiksyre-kaliumsalt
I til V med0,5 og 1,5 kg/ha aktivt stoff,
XI til XVI med 0,25 og 1,5 kg/ha aktivt stoff.
T+ii+xii+xvf,' i+iii+xii+xvi, ' i+iv+xii+xvi, i+v+xi.i+xvi,.
I+II+XIV+XVI, I+III+XIV+XVI, I+IV+XIV+XVI, I+V+XIV+XVI,
I+II+XIII+XVI, I+III+XIII+XVI, I+IV+XIII+XVI, I+V+XIII+XVI,
I+II+XI+XVI, I+III+XI+XVI, I+IV+XI+XVI, I+V+XI+XVI,
I+II+XIII+XI, I+III+XIII+XI, I+IV+XIII+XI, I+V+XIII+XI, I+II+XIII+XIV, I+III+XIII+XIV, I+V+XIII+XIV, I+V+XIII+XIV
i hvert tilfelle 0,5+0,25+0,25+0,25 kg/ha aktivt stoff.
Etter 12-15 dager ble det slått fast at blandingene viste en bedre herbicid virkning ved samme forenlighet med kulturplantene enn enkeltstoffene.
Forsøksresultatet vil fremgå av den følgende tabell.
Eksempel 6
I et drivhus ble forskjellige planter ved en veksthøyde på 2-24 cm behandlet med de følgende virksomme enkeltstoffer og deres blandinger som emulsjon og løsning:
I+VI, I+VII, I+VIII, I+IX, I+X, I+XI, I+XII, I+XIII, I+XIV,
I+XV, I+XVI, I+XVII
i hvert tilfelle 0,5+1, 1+0,5, 0,75+0,75 kg/ha aktivt stoff.
Etter 12^-15 dager ble det slått fast at blandingene viste
en bedre herbicid virkning ved samme forenlighet med kulturplantene enn enkeltstoffene.
Forsøksresultatet vil fremgå av den følgende tabell.
Claims (1)
- Herbicid, karakterisert ved at det inneholder en blanding ava) en forbindelse med formelenhvor X betyr halogen, alkyl, halogenalkyl, alkoksy, R betyr hydrogen, lavere alkyl, R"'' betyr lavere alkyl og n har verdier fra0 til 3, og/eller b) en forbindelse med formelenhvor R betyr lavere alkyl, betyr hydrogen og saltene, f~_ j og/eller c) en forbindelse med formelen hvor X betyr klor, brom, nitro, jod, cyan, lavere alkyl, n har verdier fra 0 til 3, R betyr hydrogen og saltene, R dessuten betyrhvor Y betyr klor, jod eller brom, R betyr lavere alkyl, -C-alkyl, hydrogen og saltene og R <2> og R <3> betyr hydrogen, ii • <::> o~"~ lavere alkyl, en eventuelt substituert arylrest, og/eller d) en forbindelse med formelenhvor Y og X betyr klor, metyl, n har verdier fra 0 til 3, R betyr hydrogen, lavere alkyl, m har verdier fra 0 til 2, R''" betyr alkyl, hydrogen og saltene.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19732336444 DE2336444A1 (de) | 1973-07-18 | 1973-07-18 | Herbizid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO742605L true NO742605L (no) | 1975-02-17 |
Family
ID=5887242
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO742605A NO742605L (no) | 1973-07-18 | 1974-07-17 |
Country Status (26)
| Country | Link |
|---|---|
| US (1) | US3976468A (no) |
| JP (1) | JPS5040744A (no) |
| AR (1) | AR219469A1 (no) |
| AT (1) | AT336338B (no) |
| BE (1) | BE817764A (no) |
| BG (1) | BG25777A3 (no) |
| BR (1) | BR7405673D0 (no) |
| CA (1) | CA1040881A (no) |
| CH (1) | CH585006A5 (no) |
| CS (1) | CS189659B2 (no) |
| DD (1) | DD112335A5 (no) |
| DE (1) | DE2336444A1 (no) |
| DK (1) | DK383074A (no) |
| ES (1) | ES428395A1 (no) |
| FR (1) | FR2245282B1 (no) |
| GB (1) | GB1470257A (no) |
| HU (1) | HU169822B (no) |
| IL (1) | IL45235A (no) |
| LU (1) | LU70540A1 (no) |
| NL (1) | NL7409398A (no) |
| NO (1) | NO742605L (no) |
| PL (1) | PL91363B1 (no) |
| RO (1) | RO72284A (no) |
| SE (1) | SE416439B (no) |
| SU (1) | SU533321A3 (no) |
| ZA (1) | ZA744559B (no) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1546375A (en) * | 1975-04-30 | 1979-05-23 | Shell Int Research | Wild oat herbicide |
| US4246429A (en) * | 1978-06-23 | 1981-01-20 | Janssen Pharmaceutica, N.V. | Novel α-amino-phenylacetic acid derivatives |
| GB8704671D0 (en) * | 1987-02-27 | 1987-04-01 | Shell Int Research | Glycine compounds |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3708277A (en) * | 1966-08-30 | 1973-01-02 | Basf Ag | Herbicidal method |
| GB1164160A (en) * | 1966-12-30 | 1969-09-17 | Shell Int Research | N,N-Disubstituted Amino Acid Derivatives and their use as Herbicides |
| US3846113A (en) * | 1969-03-19 | 1974-11-05 | Basf Ag | Herbicide |
-
1973
- 1973-07-18 DE DE19732336444 patent/DE2336444A1/de active Pending
-
1974
- 1974-07-10 IL IL45235A patent/IL45235A/xx unknown
- 1974-07-10 BR BR5673/74A patent/BR7405673D0/pt unknown
- 1974-07-10 RO RO7479450A patent/RO72284A/ro unknown
- 1974-07-10 US US05/487,374 patent/US3976468A/en not_active Expired - Lifetime
- 1974-07-11 NL NL7409398A patent/NL7409398A/xx not_active Application Discontinuation
- 1974-07-11 CA CA204,588A patent/CA1040881A/en not_active Expired
- 1974-07-11 SE SE7409132A patent/SE416439B/xx unknown
- 1974-07-12 AR AR254663A patent/AR219469A1/es active
- 1974-07-15 CH CH972374A patent/CH585006A5/xx not_active IP Right Cessation
- 1974-07-16 JP JP49080814A patent/JPS5040744A/ja active Pending
- 1974-07-16 BG BG7400027255A patent/BG25777A3/xx unknown
- 1974-07-16 PL PL1974172791A patent/PL91363B1/xx unknown
- 1974-07-16 CS CS745080A patent/CS189659B2/cs unknown
- 1974-07-16 LU LU70540A patent/LU70540A1/xx unknown
- 1974-07-16 DD DD179942A patent/DD112335A5/xx unknown
- 1974-07-16 HU HUBA3116A patent/HU169822B/hu unknown
- 1974-07-17 SU SU2046505A patent/SU533321A3/ru active
- 1974-07-17 NO NO742605A patent/NO742605L/no unknown
- 1974-07-17 GB GB3163374A patent/GB1470257A/en not_active Expired
- 1974-07-17 FR FR747424896A patent/FR2245282B1/fr not_active Expired
- 1974-07-17 ZA ZA00744559A patent/ZA744559B/xx unknown
- 1974-07-17 BE BE146660A patent/BE817764A/xx not_active IP Right Cessation
- 1974-07-17 ES ES428395A patent/ES428395A1/es not_active Expired
- 1974-07-17 DK DK383074A patent/DK383074A/da unknown
- 1974-07-17 AT AT592374A patent/AT336338B/de not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| AT336338B (de) | 1977-04-25 |
| DE2336444A1 (de) | 1975-02-06 |
| AU7111974A (en) | 1976-01-15 |
| BG25777A3 (en) | 1978-12-12 |
| ES428395A1 (es) | 1977-01-01 |
| DD112335A5 (no) | 1975-04-12 |
| US3976468A (en) | 1976-08-24 |
| RO72284A (ro) | 1982-05-10 |
| SE416439B (sv) | 1981-01-05 |
| IL45235A0 (en) | 1974-10-22 |
| GB1470257A (en) | 1977-04-14 |
| LU70540A1 (no) | 1974-11-28 |
| CA1040881A (en) | 1978-10-24 |
| BR7405673D0 (pt) | 1975-05-20 |
| HU169822B (no) | 1977-02-28 |
| BE817764A (fr) | 1975-01-17 |
| IL45235A (en) | 1978-06-15 |
| ZA744559B (en) | 1975-08-27 |
| SU533321A3 (ru) | 1976-10-25 |
| SE7409132L (no) | 1975-01-20 |
| FR2245282A1 (no) | 1975-04-25 |
| CH585006A5 (no) | 1977-02-28 |
| AR219469A1 (es) | 1980-08-29 |
| ATA592374A (de) | 1976-08-15 |
| NL7409398A (nl) | 1975-01-21 |
| JPS5040744A (no) | 1975-04-14 |
| CS189659B2 (en) | 1979-04-30 |
| DK383074A (no) | 1975-03-03 |
| FR2245282B1 (no) | 1979-02-09 |
| PL91363B1 (no) | 1977-02-28 |
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