NO327150B1 - Likevekts-fluidkrakkingkatalysatorsammensetning og fremgangsmate. - Google Patents

Likevekts-fluidkrakkingkatalysatorsammensetning og fremgangsmate. Download PDF

Info

Publication number: NO327150B1
Authority: NO; Norway
Prior art keywords: catalyst; composition; weight; zeolite; percent
Prior art date: 2001-04-13

Application number

NO20034542A

Other languages

English (en)

Norwegian (no)

Other versions

NO20034542L (no

NO20034542D0 (no

Inventor

Richard Franklin Wormsbecher

Philip Stephen Deitz

Xinjin Zhao

Wu Cheng Cheng

John Allen Rudesill

Original Assignee

Grace W R & Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2001-04-13

Filing date

2003-10-09

Publication date

2009-05-04

2003-10-09 Application filed by Grace W R & Co filed Critical Grace W R & Co

2003-10-09 Publication of NO20034542D0 publication Critical patent/NO20034542D0/no

2003-12-15 Publication of NO20034542L publication Critical patent/NO20034542L/no

2009-05-04 Publication of NO327150B1 publication Critical patent/NO327150B1/no

Links

239000003054 catalyst Substances 0.000 title claims description 165
239000000203 mixture Substances 0.000 title claims description 91
238000000034 method Methods 0.000 title claims description 68
238000005336 cracking Methods 0.000 title claims description 60
230000008569 process Effects 0.000 title claims description 48
239000012530 fluid Substances 0.000 title claims description 14
239000010457 zeolite Substances 0.000 claims description 90
229910021536 Zeolite Inorganic materials 0.000 claims description 79
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 78
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 56
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 47
229910052717 sulfur Inorganic materials 0.000 claims description 46
239000011593 sulfur Substances 0.000 claims description 46
239000000047 product Substances 0.000 claims description 43
230000000694 effects Effects 0.000 claims description 41
239000002841 Lewis acid Substances 0.000 claims description 37
239000002245 particle Substances 0.000 claims description 37
150000007517 lewis acids Chemical class 0.000 claims description 35
238000006243 chemical reaction Methods 0.000 claims description 32
229930195733 hydrocarbon Natural products 0.000 claims description 19
150000002430 hydrocarbons Chemical class 0.000 claims description 19
239000011159 matrix material Substances 0.000 claims description 19
239000002184 metal Substances 0.000 claims description 17
229910052751 metal Inorganic materials 0.000 claims description 17
239000004215 Carbon black (E152) Substances 0.000 claims description 16
229910052761 rare earth metal Inorganic materials 0.000 claims description 15
-1 rare earth metal ions Chemical class 0.000 claims description 11
238000004523 catalytic cracking Methods 0.000 claims description 9
229910052782 aluminium Inorganic materials 0.000 claims description 8
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 7
238000009835 boiling Methods 0.000 claims description 7
238000004231 fluid catalytic cracking Methods 0.000 claims description 6
229910052725 zinc Inorganic materials 0.000 claims description 6
229910052759 nickel Inorganic materials 0.000 claims description 5
239000011230 binding agent Substances 0.000 claims description 4
239000012535 impurity Substances 0.000 claims description 4
239000007788 liquid Substances 0.000 claims description 4
239000002131 composite material Substances 0.000 claims description 3
229910052809 inorganic oxide Inorganic materials 0.000 claims description 3
239000012263 liquid product Substances 0.000 claims description 3
150000002898 organic sulfur compounds Chemical class 0.000 claims description 3
239000004411 aluminium Substances 0.000 claims description 2
229910052793 cadmium Inorganic materials 0.000 claims description 2
229910052802 copper Inorganic materials 0.000 claims description 2
229910052738 indium Inorganic materials 0.000 claims description 2
229910052742 iron Inorganic materials 0.000 claims description 2
229910052745 lead Inorganic materials 0.000 claims description 2
229910052749 magnesium Inorganic materials 0.000 claims description 2
229910052748 manganese Inorganic materials 0.000 claims description 2
229910052750 molybdenum Inorganic materials 0.000 claims description 2
229910052709 silver Inorganic materials 0.000 claims description 2
229910052718 tin Inorganic materials 0.000 claims description 2
QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims 2
MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims 2
239000000654 additive Substances 0.000 description 29
239000000463 material Substances 0.000 description 27
230000000996 additive effect Effects 0.000 description 18
230000009467 reduction Effects 0.000 description 15
229930192474 thiophene Natural products 0.000 description 14
150000003577 thiophenes Chemical class 0.000 description 13
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 11
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 9
YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 9
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 8
239000012013 faujasite Substances 0.000 description 8
239000011236 particulate material Substances 0.000 description 8
150000001875 compounds Chemical class 0.000 description 7
230000009849 deactivation Effects 0.000 description 7
230000008929 regeneration Effects 0.000 description 7
238000011069 regeneration method Methods 0.000 description 7
150000003464 sulfur compounds Chemical class 0.000 description 7
239000011701 zinc Substances 0.000 description 7
FCEHBMOGCRZNNI-UHFFFAOYSA-N 1-benzothiophene Chemical compound C1=CC=C2SC=CC2=C1 FCEHBMOGCRZNNI-UHFFFAOYSA-N 0.000 description 6
238000001354 calcination Methods 0.000 description 6
150000002910 rare earth metals Chemical class 0.000 description 6
230000000717 retained effect Effects 0.000 description 6
239000000377 silicon dioxide Substances 0.000 description 6
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 5
230000003197 catalytic effect Effects 0.000 description 5
229910052746 lanthanum Inorganic materials 0.000 description 5
FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 5
239000004927 clay Substances 0.000 description 4
238000009826 distribution Methods 0.000 description 4
238000005470 impregnation Methods 0.000 description 4
125000004430 oxygen atom Chemical group O* 0.000 description 4
229910052710 silicon Inorganic materials 0.000 description 4
239000010703 silicon Substances 0.000 description 4
239000011734 sodium Substances 0.000 description 4
239000000758 substrate Substances 0.000 description 4
239000011787 zinc oxide Substances 0.000 description 4
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 3
238000013459 approach Methods 0.000 description 3
239000000571 coke Substances 0.000 description 3
239000003546 flue gas Substances 0.000 description 3
239000007789 gas Substances 0.000 description 3
229910052739 hydrogen Inorganic materials 0.000 description 3
239000001257 hydrogen Substances 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
229910044991 metal oxide Inorganic materials 0.000 description 3
150000004706 metal oxides Chemical class 0.000 description 3
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 3
239000003921 oil Substances 0.000 description 3
229910001404 rare earth metal oxide Inorganic materials 0.000 description 3
229910052708 sodium Inorganic materials 0.000 description 3
239000000243 solution Substances 0.000 description 3
229910052815 sulfur oxide Inorganic materials 0.000 description 3
239000012808 vapor phase Substances 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 2
238000002441 X-ray diffraction Methods 0.000 description 2
239000002253 acid Substances 0.000 description 2
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
229910052921 ammonium sulfate Inorganic materials 0.000 description 2
235000011130 ammonium sulphate Nutrition 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
229910052788 barium Inorganic materials 0.000 description 2
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 2
230000008901 benefit Effects 0.000 description 2
230000033228 biological regulation Effects 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
230000007423 decrease Effects 0.000 description 2
238000004821 distillation Methods 0.000 description 2
238000001035 drying Methods 0.000 description 2
238000005194 fractionation Methods 0.000 description 2
229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
238000002156 mixing Methods 0.000 description 2
239000002808 molecular sieve Substances 0.000 description 2
239000003208 petroleum Substances 0.000 description 2
239000003209 petroleum derivative Substances 0.000 description 2
239000011148 porous material Substances 0.000 description 2
239000000843 powder Substances 0.000 description 2
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
239000002994 raw material Substances 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
239000007787 solid Substances 0.000 description 2
239000007921 spray Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 2
229910052720 vanadium Inorganic materials 0.000 description 2
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 2
ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 2
JCCCMAAJYSNBPR-UHFFFAOYSA-N 2-ethylthiophene Chemical compound CCC1=CC=CS1 JCCCMAAJYSNBPR-UHFFFAOYSA-N 0.000 description 1
XQQBUAPQHNYYRS-UHFFFAOYSA-N 2-methylthiophene Chemical compound CC1=CC=CS1 XQQBUAPQHNYYRS-UHFFFAOYSA-N 0.000 description 1
BTXIJTYYMLCUHI-UHFFFAOYSA-N 2-propylthiophene Chemical compound CCCC1=CC=CS1 BTXIJTYYMLCUHI-UHFFFAOYSA-N 0.000 description 1
229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
229910052684 Cerium Inorganic materials 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
QENGPZGAWFQWCZ-UHFFFAOYSA-N Methylthiophene Natural products CC=1C=CSC=1 QENGPZGAWFQWCZ-UHFFFAOYSA-N 0.000 description 1
239000004115 Sodium Silicate Substances 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
239000005864 Sulphur Substances 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
JIAARYAFYJHUJI-UHFFFAOYSA-L Zinc chloride Inorganic materials [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 1
ZQRGREQWCRSUCI-UHFFFAOYSA-N [S].C=1C=CSC=1 Chemical compound [S].C=1C=CSC=1 ZQRGREQWCRSUCI-UHFFFAOYSA-N 0.000 description 1
SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 description 1
ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
210000000988 bone and bone Anatomy 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
229910052681 coesite Inorganic materials 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
238000010959 commercial synthesis reaction Methods 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
239000010949 copper Substances 0.000 description 1
229910052906 cristobalite Inorganic materials 0.000 description 1
239000010779 crude oil Substances 0.000 description 1
239000013078 crystal Substances 0.000 description 1
239000002178 crystalline material Substances 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
238000011161 development Methods 0.000 description 1
230000018109 developmental process Effects 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
238000005984 hydrogenation reaction Methods 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
239000011572 manganese Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
239000011707 mineral Substances 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
239000011238 particulate composite Substances 0.000 description 1
238000002161 passivation Methods 0.000 description 1
238000005504 petroleum refining Methods 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
238000012545 processing Methods 0.000 description 1
238000011027 product recovery Methods 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
238000011084 recovery Methods 0.000 description 1
239000012266 salt solution Substances 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
239000010944 silver (metal) Substances 0.000 description 1
229910001388 sodium aluminate Inorganic materials 0.000 description 1
125000004436 sodium atom Chemical group 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
229910052911 sodium silicate Inorganic materials 0.000 description 1
239000011949 solid catalyst Substances 0.000 description 1
229910052566 spinel group Inorganic materials 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
230000006641 stabilisation Effects 0.000 description 1
238000011105 stabilization Methods 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
229910052682 stishovite Inorganic materials 0.000 description 1
238000012360 testing method Methods 0.000 description 1
RAOIDOHSFRTOEL-UHFFFAOYSA-N tetrahydrothiophene Chemical compound C1CCSC1 RAOIDOHSFRTOEL-UHFFFAOYSA-N 0.000 description 1
150000003568 thioethers Chemical class 0.000 description 1
229910052905 tridymite Inorganic materials 0.000 description 1
229910000368 zinc sulfate Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/084—Y-type faujasite
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/19—Catalysts containing parts with different compositions
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Materials Engineering (AREA)
Crystallography & Structural Chemistry (AREA)
Oil, Petroleum & Natural Gas (AREA)
General Chemical & Material Sciences (AREA)
Catalysts (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

NO20034542A 2001-04-13 2003-10-09 Likevekts-fluidkrakkingkatalysatorsammensetning og fremgangsmate. NO327150B1 (no)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US09/833,601 US6635168B2 (en)	2001-04-13	2001-04-13	Gasoline sulfur reduction catalyst for fluid catalytic cracking process
PCT/US2002/010035 WO2002083300A1 (en)	2001-04-13	2002-03-28	Gasoline sulfur reduction catalyst for fluid catalytic cracking process

Publications (3)

Publication Number	Publication Date
NO20034542D0 NO20034542D0 (no)	2003-10-09
NO20034542L NO20034542L (no)	2003-12-15
NO327150B1 true NO327150B1 (no)	2009-05-04

Family

ID=25264839

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO20034542A NO327150B1 (no)	2001-04-13	2003-10-09	Likevekts-fluidkrakkingkatalysatorsammensetning og fremgangsmate.

Country Status (20)

Country	Link
US (1)	US6635168B2 (ko)
EP (1)	EP1381461B1 (ko)
JP (1)	JP4065201B2 (ko)
KR (1)	KR100863822B1 (ko)
CN (1)	CN100482340C (ko)
AR (1)	AR033144A1 (ko)
AT (1)	ATE404281T1 (ko)
AU (1)	AU2002254479B2 (ko)
BR (1)	BR0207562A (ko)
CA (1)	CA2444461C (ko)
CZ (1)	CZ20032731A3 (ko)
DE (1)	DE60228222D1 (ko)
MX (1)	MXPA03008196A (ko)
NO (1)	NO327150B1 (ko)
NZ (1)	NZ527498A (ko)
PL (1)	PL204611B1 (ko)
PT (1)	PT1381461E (ko)
RU (1)	RU2266782C2 (ko)
TW (1)	TWI231231B (ko)
WO (1)	WO2002083300A1 (ko)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2852864B1 (fr) *	2003-03-24	2005-05-06	Inst Francais Du Petrole	Catalyseur comprenant au moins une zeolithe choisie parmi zbm-30, zsm-48, eu-2 et eu-11 et au moins une zeolithe y et procede d'hydroconversion de charges hydrocarbonees utilisant un tel catalyseur
CN1261216C (zh) *	2003-05-30	2006-06-28	中国石油化工股份有限公司	一种含分子筛的烃类裂化催化剂及其制备方法
US8084383B2 (en) *	2004-03-16	2011-12-27	W.R. Grace & Co.-Conn.	Gasoline sulfur reduction catalyst for fluid catalytic cracking process
US20050205466A1 (en) *	2004-03-19	2005-09-22	Beswick Colin L	Zn-containing FCC catalyst and use thereof for the reduction of sulfur in gasoline
TWI523688B (zh)	2005-02-25	2016-03-01	ＷＲ康格雷氏公司	減少觸媒裂解石油餾分之硫含量之方法及流體觸媒裂解程序
MY146107A (en) *	2006-03-15	2012-06-29	Basf Catalysts Llc	Catalyst composition for reducing gasoline sulfur content in catalytic cracking process
US8623199B2 (en) *	2006-06-28	2014-01-07	Saudi Arabian Oil Company	Clay additive for reduction of sulfur in catalytically cracked gasoline
US8409428B2 (en)	2006-06-28	2013-04-02	Saudi Arabian Oil Company	Catalyst additive for reduction of sulfur in catalytically cracked gasoline
KR101544619B1 (ko)	2007-02-21	2015-08-17	더블유.알. 그레이스 앤드 캄파니-콘.	유체 접촉 분해 방법을 위한 휘발유 황 감소 촉매
EP2310122B1 (en) *	2008-07-30	2017-05-24	Saudi Arabian Oil Company	Metallic clay based fcc gasoline sulfur reduction additive compositions
RU2522432C2 (ru) *	2008-12-08	2014-07-10	В.Р.Грейс Энд Ко.-Конн.	Способ крекинга биосырья с использованием катализаторов с высоким отношением площади поверхности цеолита к площади поверхности матрицы
FR2940265B1 (fr) *	2008-12-22	2011-06-10	Total Raffinage Marketing	Zeolithes y modifiees, leur procede de fabrication et leur utilisation
US9242234B2 (en)	2008-12-22	2016-01-26	Centre National De La Recherche Scientifique	Modified Y-type zeolites having a trimodal intracrystalline structure, method for making same, and use thereof
CN101862675B (zh) *	2009-04-17	2012-02-29	中国石油化工股份有限公司	一种负载三氟甲磺酸锌的催化剂、制法及应用
CN102806099B (zh) *	2011-05-30	2014-04-30	中国石油化工股份有限公司	一种含稀土的y型分子筛裂化催化剂及其制备方法
CN102806098B (zh) *	2011-05-30	2014-05-28	中国石油化工股份有限公司	一种含稀土的y型分子筛裂化催化剂及其制备方法
CN102806096B (zh) *	2011-05-30	2014-12-31	中国石油化工股份有限公司	一种含稀土的y型分子筛裂化催化剂及其制备方法
SG188753A1 (en) *	2011-09-30	2013-04-30	Bharat Petroleum Corp Ltd	Sulphur reduction catalyst additive composition in fluid catalytic cracking and method of preparation thereof
CN106566234B (zh) *	2015-10-13	2021-02-19	上海杰事杰新材料(集团)股份有限公司	一种阻燃增强耐高温尼龙复合材料及制备方法
US10507460B2 (en)	2015-11-24	2019-12-17	Basf Corporation	Fluid catalytic cracking catalysts for increasing butylene yields
FR3085005B1 (fr) *	2018-08-20	2022-05-13	China Petroleum & Chem Corp	Tamis moléculaire de type Y modifié, catalyseur de craquage catalytique comprenant celui-ci, leur préparation et leur application
US11566185B1 (en)	2022-05-26	2023-01-31	Saudi Arabian Oil Company	Methods and catalysts for cracking hydrocarbon oil
US11725149B1 (en)	2022-06-13	2023-08-15	Saudi Arabian Oil Company	Fluidized catalytic cracking processes and additives for improving gasoline yield and quality

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3293192A (en)	1965-08-23	1966-12-20	Grace W R & Co	Zeolite z-14us and method of preparation thereof
US3402996A (en)	1966-12-19	1968-09-24	Grace W R & Co	Ion exchange of crystalline zeolites
CA967136A (en)	1969-07-28	1975-05-06	Apparao T. Lengade	Hydrocarbon conversion catalyst
US3607043A (en)	1969-11-19	1971-09-21	Grace W R & Co	Cation and thermal stabilization of a faujasite-type zeolite
US3676368A (en)	1970-08-26	1972-07-11	Grace W R & Co	Rare earth-hydrogen exchanged zeolites
US3957689A (en)	1974-08-02	1976-05-18	W. R. Grace & Co.	Process for preparing an attrition resistant zeolite hydrocarbon conversion catalyst
US4126579A (en)	1977-03-22	1978-11-21	W. R. Grace & Co.	Hydrocarbon conversion catalyst manufacture
US4226743A (en)	1979-03-12	1980-10-07	W. R. Grace & Co.	Silica-alumina hydrogel catalyst
US4957892A (en)	1980-07-29	1990-09-18	Uop	Process for combusting solid sulfur containing material
US4458023A (en)	1981-08-10	1984-07-03	W. R. Grace & Co.	Catalyst manufacture
JPS59150539A (ja) *	1983-02-16	1984-08-28	Res Assoc Residual Oil Process<Rarop>	炭化水素転化触媒
US4606813A (en) *	1983-02-25	1986-08-19	Engelhard Corporation	Fluid catalytic cracking catalyst for cracking sulfur containing petroleum feedstocks and a process for using it
FR2563445B1 (fr) *	1984-04-26	1986-08-14	Pro Catalyse Ste Fse Prod Cata	Nouveau catalyseur d'hydrocraquage destine a la production de distillats moyens
EP0188841B2 (en) *	1984-12-21	1992-01-15	Catalysts & Chemicals Industries Co., Ltd.	Hydrocarbon catalytic cracking catalyst compositions and method therefor
US4790982A (en)	1986-04-07	1988-12-13	Katalistiks International, Inc.	Metal-containing spinel composition and process of using same
US4957718A (en)	1987-11-24	1990-09-18	Uop	Process for reducing emissions of sulfur oxides and composition useful in same
US5376608A (en)	1993-01-27	1994-12-27	W. R. Grace & Co.-Conn.	Sulfur reduction in FCC gasoline
US6036847A (en) *	1996-03-26	2000-03-14	W. R. Grace & Co.-Conn.	Compositions for use in catalytic cracking to make reduced sulfur content gasoline

2001
- 2001-04-13 US US09/833,601 patent/US6635168B2/en not_active Expired - Lifetime
2002
- 2002-03-28 PL PL373505A patent/PL204611B1/pl not_active IP Right Cessation
- 2002-03-28 EP EP02723710A patent/EP1381461B1/en not_active Expired - Lifetime
- 2002-03-28 AT AT02723710T patent/ATE404281T1/de not_active IP Right Cessation
- 2002-03-28 BR BR0207562-8A patent/BR0207562A/pt not_active Application Discontinuation
- 2002-03-28 MX MXPA03008196A patent/MXPA03008196A/es active IP Right Grant
- 2002-03-28 RU RU2003133133/04A patent/RU2266782C2/ru active
- 2002-03-28 JP JP2002581096A patent/JP4065201B2/ja not_active Expired - Fee Related
- 2002-03-28 CA CA2444461A patent/CA2444461C/en not_active Expired - Fee Related
- 2002-03-28 PT PT02723710T patent/PT1381461E/pt unknown
- 2002-03-28 CZ CZ20032731A patent/CZ20032731A3/cs unknown
- 2002-03-28 CN CNB028081692A patent/CN100482340C/zh not_active Expired - Fee Related
- 2002-03-28 DE DE60228222T patent/DE60228222D1/de not_active Expired - Lifetime
- 2002-03-28 KR KR1020037013390A patent/KR100863822B1/ko not_active IP Right Cessation
- 2002-03-28 WO PCT/US2002/010035 patent/WO2002083300A1/en active Search and Examination
- 2002-03-28 NZ NZ527498A patent/NZ527498A/en unknown
- 2002-03-28 AU AU2002254479A patent/AU2002254479B2/en not_active Ceased
- 2002-04-08 TW TW091106976A patent/TWI231231B/zh not_active IP Right Cessation
- 2002-04-10 AR ARP020101316A patent/AR033144A1/es active IP Right Grant
2003
- 2003-10-09 NO NO20034542A patent/NO327150B1/no not_active IP Right Cessation

Also Published As

Publication number	Publication date
NO20034542L (no)	2003-12-15
WO2002083300A1 (en)	2002-10-24
EP1381461B1 (en)	2008-08-13
CZ20032731A3 (cs)	2004-11-10
PL204611B1 (pl)	2010-01-29
RU2003133133A (ru)	2005-05-10
RU2266782C2 (ru)	2005-12-27
BR0207562A (pt)	2004-09-14
TWI231231B (en)	2005-04-21
AR033144A1 (es)	2003-12-03
JP2005510337A (ja)	2005-04-21
KR20040004585A (ko)	2004-01-13
US20020179492A1 (en)	2002-12-05
EP1381461A1 (en)	2004-01-21
CA2444461C (en)	2010-10-26
US6635168B2 (en)	2003-10-21
CA2444461A1 (en)	2002-10-24
NZ527498A (en)	2005-07-29
KR100863822B1 (ko)	2008-10-15
CN100482340C (zh)	2009-04-29
JP4065201B2 (ja)	2008-03-19
PT1381461E (pt)	2008-10-08
DE60228222D1 (de)	2008-09-25
MXPA03008196A (es)	2004-01-29
CN1630552A (zh)	2005-06-22
NO20034542D0 (no)	2003-10-09
PL373505A1 (en)	2005-09-05
AU2002254479B2 (en)	2007-03-15
ATE404281T1 (de)	2008-08-15

Legal Events

Date	Code	Title	Description
2010-11-01	MM1K	Lapsed by not paying the annual fees

Publication	Publication Date	Title
NO327150B1 (no)	2009-05-04	Likevekts-fluidkrakkingkatalysatorsammensetning og fremgangsmate.
JP4864261B2 (ja)	2012-02-01	流体接触分解法におけるガソリンの脱硫
KR101318000B1 (ko)	2013-10-14	유동상 접촉 분해 공정을 위한 가솔린 황 감소 촉매
RU2540859C2 (ru)	2015-02-10	Усовершенствованный сокатализатор улавливания тяжелых металлов для процесса флюид каталитического крекинга
AU2005224255B2 (en)	2011-05-12	Gasoline sulfur reduction catalyst for fluid catalytic cracking process
AU2002254479A1 (en)	2003-04-17	Gasoline sulfur reduction catalyst for fluid catalytic cracking process
AU779963B2 (en)	2005-02-24	Gasoline sulfur reduction in fluid catalytic cracking
JP5335697B2 (ja)	2013-11-06	流動接触分解プロセスのためのガソリンイオウ分減少触媒
JP5283745B2 (ja)	2013-09-04	接触分解ガソリン用脱硫触媒の製造方法
JP4859358B2 (ja)	2012-01-25	接触分解ガソリンの脱硫触媒およびそれを用いた接触分解ガソリンの脱硫方法
JP4931555B2 (ja)	2012-05-16	接触分解ガソリン用脱硫触媒およびその触媒を用いた接触分解ガソリンの脱硫方法
ZA200306365B (en)	2004-07-07	Gasoline sulfur reduction catalyst for fluid catalytic cracking process.
MXPA06009287A (en)	2007-04-10	Gasoline sulfur reduction catalyst for fluid catalytic cracking process