NO142246B - TREE PROTECTION AGENT WITH BIOCID EFFECT - Google Patents
TREE PROTECTION AGENT WITH BIOCID EFFECT Download PDFInfo
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- NO142246B NO142246B NO744120A NO744120A NO142246B NO 142246 B NO142246 B NO 142246B NO 744120 A NO744120 A NO 744120A NO 744120 A NO744120 A NO 744120A NO 142246 B NO142246 B NO 142246B
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- wood
- effect
- mixtures
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Links
- 230000000694 effects Effects 0.000 title description 2
- 239000011814 protection agent Substances 0.000 title 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 20
- 230000003115 biocidal effect Effects 0.000 claims description 14
- 239000000126 substance Substances 0.000 claims description 11
- 239000003921 oil Substances 0.000 claims description 9
- 239000000049 pigment Substances 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 7
- 239000003208 petroleum Substances 0.000 claims description 5
- 229920003002 synthetic resin Polymers 0.000 claims description 5
- 239000000057 synthetic resin Substances 0.000 claims description 5
- 239000003171 wood protecting agent Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 description 22
- 239000002023 wood Substances 0.000 description 17
- 235000019198 oils Nutrition 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
- 239000011347 resin Substances 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 5
- 241000233866 Fungi Species 0.000 description 4
- 230000035515 penetration Effects 0.000 description 4
- IZUPBVBPLAPZRR-UHFFFAOYSA-N pentachlorophenol Chemical compound OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl IZUPBVBPLAPZRR-UHFFFAOYSA-N 0.000 description 4
- 241000935931 Diplodia sapinea Species 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 229920000180 alkyd Polymers 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000002274 desiccant Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000855 fungicidal effect Effects 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 241000894007 species Species 0.000 description 2
- OFQCQIGMURIECL-UHFFFAOYSA-N 2-[2-(diethylamino)ethyl]-2',6'-dimethylspiro[isoquinoline-4,4'-oxane]-1,3-dione;phosphoric acid Chemical compound OP(O)(O)=O.O=C1N(CCN(CC)CC)C(=O)C2=CC=CC=C2C21CC(C)OC(C)C2 OFQCQIGMURIECL-UHFFFAOYSA-N 0.000 description 1
- BTXXTMOWISPQSJ-UHFFFAOYSA-N 4,4,4-trifluorobutan-2-one Chemical compound CC(=O)CC(F)(F)F BTXXTMOWISPQSJ-UHFFFAOYSA-N 0.000 description 1
- BQACOLQNOUYJCE-FYZZASKESA-N Abietic acid Natural products CC(C)C1=CC2=CC[C@]3(C)[C@](C)(CCC[C@@]3(C)C(=O)O)[C@H]2CC1 BQACOLQNOUYJCE-FYZZASKESA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 241000238876 Acari Species 0.000 description 1
- 241000223678 Aureobasidium pullulans Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 241000257303 Hymenoptera Species 0.000 description 1
- 241000218657 Picea Species 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 241000779819 Syncarpia glomulifera Species 0.000 description 1
- 241000256856 Vespidae Species 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- HKIOYBQGHSTUDB-UHFFFAOYSA-N folpet Chemical compound C1=CC=C2C(=O)N(SC(Cl)(Cl)Cl)C(=O)C2=C1 HKIOYBQGHSTUDB-UHFFFAOYSA-N 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- JLYXXMFPNIAWKQ-GNIYUCBRSA-N gamma-hexachlorocyclohexane Chemical compound Cl[C@H]1[C@H](Cl)[C@@H](Cl)[C@@H](Cl)[C@H](Cl)[C@H]1Cl JLYXXMFPNIAWKQ-GNIYUCBRSA-N 0.000 description 1
- 238000011534 incubation Methods 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 235000013980 iron oxide Nutrition 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 229960002809 lindane Drugs 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- ZDCHZHDOCCIZIY-UHFFFAOYSA-N phthalic acid;propane-1,2,3-triol Chemical compound OCC(O)CO.OC(=O)C1=CC=CC=C1C(O)=O ZDCHZHDOCCIZIY-UHFFFAOYSA-N 0.000 description 1
- 239000001739 pinus spp. Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229940036248 turpentine Drugs 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/50—Mixtures of different organic impregnating agents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
- A01N31/10—Pentachlorophenol
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/343—Heterocyclic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/36—Aliphatic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/38—Aromatic compounds
- B27K3/40—Aromatic compounds halogenated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K5/00—Treating of wood not provided for in groups B27K1/00, B27K3/00
- B27K5/02—Staining or dyeing wood; Bleaching wood
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Forests & Forestry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Medicines Containing Material From Animals Or Micro-Organisms (AREA)
- Medicines Containing Plant Substances (AREA)
- Paints Or Removers (AREA)
Description
Foreliggende oppfinnelse angår et trebeskyttelsesmiddel med The present invention relates to a wood preservative with
biocid virkning, bestående i det vesentlige av,5 til 50 vekt- biocidal effect, consisting essentially of 5 to 50 wt.
deler oljer eller syntetiske harpikser, 0 til 6 vektdeler pigmenter, 1 til 10 vektdeler biocide stoffer og 40 til 85 vektdeler av ett eller flere vanlige petroleumsløsningsmidler, parts oils or synthetic resins, 0 to 6 parts by weight pigments, 1 to 10 parts by weight biocidal substances and 40 to 85 parts by weight of one or more common petroleum solvents,
og det særegne ved trebeskyttelsesmidlet i henhold til oppfinnelsen er at det dessuten inneholder 2 til 20 vektprosent N-metyl-2-pyrrolidon, beregnet i forhold til summen av de and the distinctive feature of the wood preservative according to the invention is that it also contains 2 to 20 percent by weight of N-methyl-2-pyrrolidone, calculated in relation to the sum of the
andre bestanddeler. other components.
Det har i mange år vært kjent at trevirke kan beskyttes på effektiv måte ved å impregnere det på overflaten med fungi- It has been known for many years that wood can be effectively protected by impregnating the surface with fungi-
cide og/eller insekticide midler. Impregneringen av trevirket skjer vanligvis ved påstryking, neddypping eller trykkimpreg-nering. I de fleste tilfeller bruker man de biocide midler i form av oppløsninger eller suspensjoner i alifatiske og/eller aromatiske petroleumsoppløsningsmidler, f.eks. i tungbensin ("white spirit"). cide and/or insecticidal agents. The impregnation of the wood usually takes place by brushing on, dipping or pressure impregnation. In most cases, the biocidal agents are used in the form of solutions or suspensions in aliphatic and/or aromatic petroleum solvents, e.g. in white spirit ("white spirit").
I nyere tid har man funnet midler som tillater utførelse i et eneste arbeidstrinn av på den ene side den ovenfor nevnte biodide behandling og på den annen side en "estetisk" behandling som består i å behandle trevirket med oljer eller harpikser som er farget med pigmenter. Slike midler består vanligvis av 10 til 50 vektdeler oljer eller harpikser, 1 til 6 deler pigmenter, 1 til 10 deler biocide stoffer og 40 til 85 deler av et vanlig petroleumsoppløsningsmiddel, såsom tungbensin. In recent times, means have been found which allow the execution in a single work step of, on the one hand, the above-mentioned biocidal treatment and, on the other hand, an "aesthetic" treatment which consists in treating the wood with oils or resins which are colored with pigments. Such agents usually consist of 10 to 50 parts by weight of oils or resins, 1 to 6 parts of pigments, 1 to 10 parts of biocidal substances, and 40 to 85 parts of a common petroleum solvent, such as naphtha.
Selvom disse midler, uansett som de var basert på oljer eller Although these remedies, no matter how they were based on oils or
på harpikser, med eller uten fargede pigmenter, hittil har vært ansett tilfredstillende, anser man nå at beskyttelsen mot insekter eller sopp ikke er tilfredsstillende i forhold til mengden av de innførte biocide stoffer. Undersøkelser har vist at den forholdsvis dårlige virkning av disse aktive stoffer i hovedsaken skyldtes deres dårlige inntrengning i trevirket. on resins, with or without colored pigments, has hitherto been considered satisfactory, it is now considered that the protection against insects or fungi is not satisfactory in relation to the quantity of the introduced biocidal substances. Investigations have shown that the relatively poor effect of these active substances was mainly due to their poor penetration into the wood.
Man har f.eks. konstatert at pentaklorfenol i en olje-basert blanding bare trenger inn i en dybde av 1 til 2 mm i grantre-virke. Dette tall er ennå lavere når man f.eks. bruker et preparat på basis av syntetiske harpikser av alkydtypen, da de vanskeliggjør diffusjonen av det biocide stoff gjennom delemembraner. Nærvær av fargepigmenter gjør saken enda verre, .da de tilstopper inntregningskanalene i trevirket. One has e.g. found that pentachlorophenol in an oil-based mixture only penetrates to a depth of 1 to 2 mm in spruce wood. This number is even lower when you e.g. uses a preparation based on synthetic resins of the alkyd type, as they make it difficult for the biocidal substance to diffuse through dividing membranes. The presence of color pigments makes matters even worse, as they clog the penetration channels in the wood.
Det eksisterer således et virkelig behov for å finne et middel som på merkbar måte tillater å øke inntrengningen av de biocide stoffer som finnes i blandinger for beskyttelse av trevirket. Dette middel bør ikke kreve bruken av spesielt materiale, da blandingene ofte brukes av ikke-fagfolk ved enkel påstryking, påsprøyting eller kortvarig neddypping (1 til 3 minutter). There is thus a real need to find a means which allows to noticeably increase the penetration of the biocidal substances contained in mixtures for the protection of the wood. This agent should not require the use of special material, as the mixtures are often used by non-professionals by simple application, spraying or short-term immersion (1 to 3 minutes).
Den erkjennelse som ligger til grunn for oppfinnelsen er at det faktisk er tilstrekkelig å tilsette blandingene 2 til 20 vektprosent N-metyl-2-pyrrolidon. The realization that underlies the invention is that it is actually sufficient to add 2 to 20% by weight of N-methyl-2-pyrrolidone to the mixtures.
N-metyl-2-pyrrolidon er et ugiftig oppløsningsmiddel med lite damptrykk (mindre enn 1 mm kvikksølv) som kan brukes uten risiko. Dets innhold i blandingen bør være minst lik 2% av den samlede vekt av de andre bestanddeler, idet det forutsettes at mengder på over 20 % ikke medfører tilstrekkelig forbedring av inntrengningen når man tar prisen av blandingen i betrakt-ning. N-methyl-2-pyrrolidone is a non-toxic solvent with a low vapor pressure (less than 1 mm of mercury) that can be used without risk. Its content in the mixture should be at least equal to 2% of the total weight of the other components, it being assumed that amounts of more than 20% do not lead to sufficient improvement in penetration when the price of the mixture is taken into account.
Valget av mengden av oljer eller syntetiske har<p>ikser i blandingene er avhengig av arten av den ønskede blanding. Generelt kan man klassifisere alle blandinger i tre hoved-kategorier: The choice of the amount of oils or synthetic resins in the mixtures depends on the nature of the desired mixture. In general, all mixtures can be classified into three main categories:
A) Blandinger som utelukkende skal beskytte trevirket A) Mixtures that are exclusively intended to protect the wood
B) Blandinger som torker langsomt og som skal gjore trevirket penere og beskytte det, C) Blandinger som torker hurtig og som skal gjore trevirket B) Mixtures that dry slowly and which should make the wood look nicer and protect it, C) Mixtures which dry quickly and which should make the wood
penere og beskytte det. prettier and protect it.
I tilfellet A) bruker man en liten mengde, vanligvis mellom 5 og 10 deler, av en oljeblanding av typen terpentinolje og en In case A) a small amount, usually between 5 and 10 parts, of an oil mixture of the turpentine type and a
harpiks, f.eks. abietinsyreharpiks for å fiksere de biocide stoffer. resin, e.g. abietic acid resin to fix the biocidal substances.
I tilfellet B) bruker man en stor mengde, vanligvis mellom 10 og 50 deler, av en torrende olje, f.eks. linolje, i forbindelse med en mengde torkemidler som vanligvis brukes for å torre blandingen. In case B) a large quantity, usually between 10 and 50 parts, of a drying oil, e.g. linseed oil, in conjunction with a quantity of drying agents commonly used to dry the mixture.
I tilfellet C) bruker man 10 til 50 deler av en syntetisk harpiks, særlig alkydharpiks. De harpikser som mest brukes er glycerol-ftalsyre-harpikser som eventuelt er modifisert ved podning medjtorrende fettsyrer. Bruken av slike harpikser krever, som velkjent for fagfolk, at man i blandingen innforer torkemidler som vanligvis består av kalsium-, mangan-, kobolt, zirkonium-eller blysalter av organiske syrer med mer enn 6 karbonatomer. In case C) 10 to 50 parts of a synthetic resin, particularly alkyd resin, are used. The resins most commonly used are glycerol-phthalic acid resins which are possibly modified by grafting with drying fatty acids. The use of such resins requires, as is well known to those skilled in the art, that drying agents which usually consist of calcium, manganese, cobalt, zirconium or lead salts of organic acids with more than 6 carbon atoms are introduced into the mixture.
I de to tilfeller B) og C) innforer man ofte fargepigmenter som skal farge trevirket. Avhengig av den onskede farge og nyanse bruker man 1 til 6 deler pigment, som f.eks. jernoksyder eller kjonrok. In the two cases B) and C), color pigments are often introduced to color the wood. Depending on the desired color and shade, one uses 1 to 6 parts of pigment, such as e.g. iron oxides or carbon black.
I alle tilfeller velges de biocide stoffer i det vesentlige ut fra deres fungicide og insekticide virkning på trevirket. In all cases, the biocidal substances are essentially selected based on their fungicidal and insecticidal effect on the wood.
Sopparter som forårsaker en blå-farging av trevirket, f.eks., Macrophoma pinea, Pullularia pullulans, Sclerophoma pithyophyla, er meget aktive mikroorganismer, og de biocide stoffer må derfor være spesielt aktive mot dem. Man kan eksempelvis nevne pentaklorfenol, N-(briklormetyltio)-cykiohesen-dikarboksimid, eller N-(triklormetyltio)-ftalimid. Fungal species that cause a blue staining of the wood, e.g., Macrophoma pinea, Pullularia pullulans, Sclerophoma pithyophyla, are very active microorganisms, and the biocidal substances must therefore be particularly active against them. Examples include pentachlorophenol, N-(brichloromethylthio)-cyclohesene-dicarboximide, or N-(trichloromethylthio)-phthalimide.
De insektarter som oftest forårsaker skader i trevirket er anobiider, lyctideer, hveps og midder samt maur. De bekjempes ved hjelp av slike produkter som JT-isomeren av heksaklorcyklo-heksan eller fosforsyreestere. De biocide stoffer inngår i blandingene i en mengde av 1 til 10 vektdeler. The insect species that most often cause damage to the wood are anobiids, lyctids, wasps and mites as well as ants. They are fought with the help of such products as the JT isomer of hexachlorocyclohexane or phosphoric acid esters. The biocidal substances are included in the mixtures in an amount of 1 to 10 parts by weight.
Bestanddelen som utgjor storstedelen av blandingen er ett eller flere alifatiske og/eller aromatiske petroleum-opplosnings-stoffer, såsom tungbensin, alkylbenzener o.s.v. De utgjor 40 til 85 deler av blandingen. The component that makes up the majority of the mixture is one or more aliphatic and/or aromatic petroleum solvents, such as naphtha, alkylbenzenes, etc. They make up 40 to 85 parts of the mixture.
De folgende utforelseseksempler av oppfinnelsen viser tydelig den forbedring av beskyttelsen av trevirket som oppnås ved innforing av N-metyl-2-pyrrolidon i blandingene. The following embodiments of the invention clearly show the improvement in the protection of the wood which is achieved by introducing N-methyl-2-pyrrolidone into the mixtures.
Eksempel 1. Example 1.
Prover av trevirke ble behandlet ifolge fransk norm X2-Bois-doc Samples of wood were treated according to the French norm X2-Bois-doc
71. Uten å omtale i detaljer denne norm som fagfolk uten 71. Without mentioning in detail this norm that professionals without
,v vanskelighet kan konsultere, er arbeidsmåten som folger: Prover av furuved i form av rektangulære parallelle pipeder med kvadratisk tverrsnitt (20 x 4 x 4 cm) ble behandlet i 3 min. ved neddypping i de blandinger som skal undersokes. Mån uttar prover (8 x 4 x 1 cm) som utsettes for kulturer av en sopp dyrket isolert i 4 uker i dyrkingskolber ved 26°C og under 85% fuktighet. Man bruker tre arter for å utfore forsokene ,v difficulty can consult, the working method is as follows: Samples of pine wood in the form of rectangular parallel pipes with a square cross-section (20 x 4 x 4 cm) were treated for 3 min. by immersion in the mixtures to be examined. Moon takes samples (8 x 4 x 1 cm) which are exposed to cultures of a fungus grown in isolation for 4 weeks in culture flasks at 26°C and under 85% humidity. Three species are used to carry out the experiments
- Pallularia pullulens - Pallularia pullulens
- Macrophoma pinea - Macrophoma pinea
- Sclerophoma pithyophila - Sclerophoma pithyophila
For å bestemme den minste beskyttelsesdybde i mm, deler man proven i fire stykker og måler den sokte storrelse på de utskårede avsnitt. Nærvær av sopp kan konstateres ved en fargning som er synlig for oyet^To determine the minimum protection depth in mm, the sample is divided into four pieces and the desired size is measured on the cut sections. The presence of fungi can be ascertained by a color that is visible to the eye^
En annen rekke av målinger utfores med prover som var lagret i 40 dager ved 25°C og 6% fuktighet, etter en inkubasjonstid for soppen på 4 uker ved 26°C og 85% fuktighet. Another series of measurements is carried out with samples that were stored for 40 days at 25°C and 6% humidity, after an incubation period for the fungus of 4 weeks at 26°C and 85% humidity.
En forste rekke av forsok ble utfort med blandinger som inneholdt N-metyl-2-pyrrolidon, mén som ikke inneholdt biocide stoffer, viste at opplosningsmidlet ikke i. seg selv har noen fungicid virkning. A first series of tests was carried out with mixtures containing N-methyl-2-pyrrolidone, but which did not contain biocidal substances, showing that the solvent does not in itself have any fungicidal effect.
Man har også undersokt folgende blandinger: The following mixtures have also been investigated:
Preparat I (kjent teknikk) Preparation I (known technique)
Tilfelle B: uten N-metyl-2-pyrrolidon Case B: without N-methyl-2-pyrrolidone
Preparat II (oppfinnelsen)- Preparation II (the invention)-
Tilfelle B: identisk med det forangående, men inneholdende dessuten 10 vektprosent N-metyl-2-pyrrolidon i forhold til de andre bestanddeler. Case B: identical to the preceding, but also containing 10% by weight of N-methyl-2-pyrrolidone in relation to the other components.
Preparat III (kjent teknikk) Preparation III (prior art)
Tilfelle C: uten N-metyl-2-pyrrolidon Case C: without N-methyl-2-pyrrolidone
Preparat IV (oppfinnelsen) Preparation IV (the invention)
Tilfelle Cs identisk med et forangående, men inneholdende dessuten N-metyl-2-pyrrolidon 10 vektprosent i forhold til de andre bestanddeler. Case Cs identical to the preceding one, but also containing N-methyl-2-pyrrolidone 10% by weight in relation to the other components.
De minste beskyttelsesdybder erholdt med disse preparater er angitt i den folgende tabell: The minimum protection depths obtained with these preparations are indicated in the following table:
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7341906A FR2251417B1 (en) | 1973-11-19 | 1973-11-19 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO744120L NO744120L (en) | 1975-05-21 |
| NO142246B true NO142246B (en) | 1980-04-14 |
| NO142246C NO142246C (en) | 1980-07-23 |
Family
ID=9128204
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO744120A NO142246C (en) | 1973-11-19 | 1974-11-15 | TREE PROTECTION AGENT WITH BIOCID EFFECT |
Country Status (10)
| Country | Link |
|---|---|
| AT (1) | AT352988B (en) |
| BE (1) | BE822319A (en) |
| DE (1) | DE2454531B2 (en) |
| DK (1) | DK136408B (en) |
| FR (1) | FR2251417B1 (en) |
| GB (1) | GB1460214A (en) |
| LU (1) | LU71301A1 (en) |
| NL (1) | NL7415056A (en) |
| NO (1) | NO142246C (en) |
| SE (1) | SE399378B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2711639C2 (en) * | 1977-03-17 | 1986-04-24 | Desowag-Bayer Holzschutz GmbH, 4000 Düsseldorf | Preparations for the preservation of wood and wood-based materials, process for the production of the agent and use of the agent |
| DE3024467A1 (en) * | 1980-06-28 | 1982-01-28 | Desowag-Bayer Holzschutz GmbH, 4000 Düsseldorf | AGENTS FOR THE PRESERVATION OF WOOD AND WOOD MATERIALS |
| US4547597A (en) * | 1983-05-17 | 1985-10-15 | The Dow Chemical Company | Preparation of halogenated phenols |
| GB2142239A (en) * | 1983-06-27 | 1985-01-16 | Shy Ying Wang Robert | Insecticide paint |
| DE3621360A1 (en) * | 1986-06-26 | 1988-01-28 | Wolman Gmbh Dr | WOOD PRESERVATIVES |
| CH681440A5 (en) * | 1990-04-26 | 1993-03-31 | Warmoctro Bv | |
| CH681438A5 (en) * | 1990-04-26 | 1993-03-31 | Warmoctro Bv |
-
1973
- 1973-11-19 FR FR7341906A patent/FR2251417B1/fr not_active Expired
-
1974
- 1974-09-26 SE SE7412111A patent/SE399378B/en unknown
- 1974-10-10 GB GB4400174A patent/GB1460214A/en not_active Expired
- 1974-11-15 DK DK596274AA patent/DK136408B/en unknown
- 1974-11-15 NO NO744120A patent/NO142246C/en unknown
- 1974-11-16 DE DE19742454531 patent/DE2454531B2/en active Granted
- 1974-11-18 LU LU71301A patent/LU71301A1/xx unknown
- 1974-11-18 BE BE150619A patent/BE822319A/en unknown
- 1974-11-19 NL NL7415056A patent/NL7415056A/en not_active Application Discontinuation
- 1974-11-19 AT AT927474A patent/AT352988B/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| DK596274A (en) | 1975-07-21 |
| AT352988B (en) | 1979-10-25 |
| BE822319A (en) | 1975-05-20 |
| FR2251417A1 (en) | 1975-06-13 |
| GB1460214A (en) | 1976-12-31 |
| DE2454531B2 (en) | 1976-02-26 |
| SE7412111L (en) | 1975-05-20 |
| DK136408B (en) | 1977-10-10 |
| NL7415056A (en) | 1975-05-21 |
| FR2251417B1 (en) | 1977-09-23 |
| NO142246C (en) | 1980-07-23 |
| LU71301A1 (en) | 1976-03-17 |
| DE2454531A1 (en) | 1975-05-22 |
| SE399378B (en) | 1978-02-13 |
| DK136408C (en) | 1978-03-13 |
| NO744120L (en) | 1975-05-21 |
| ATA927474A (en) | 1979-03-15 |
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