NO139610B - Fremgangsmaate for fremstilling av alkalihydroksyd og klor eller hydrogen eller klor ved elektrolyse - Google Patents
Fremgangsmaate for fremstilling av alkalihydroksyd og klor eller hydrogen eller klor ved elektrolyse Download PDFInfo
- Publication number
- NO139610B NO139610B NO4781/72A NO478172A NO139610B NO 139610 B NO139610 B NO 139610B NO 4781/72 A NO4781/72 A NO 4781/72A NO 478172 A NO478172 A NO 478172A NO 139610 B NO139610 B NO 139610B
- Authority
- NO
- Norway
- Prior art keywords
- cell
- electrolysis
- chlorine
- anode
- membrane
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 22
- 229910052801 chlorine Inorganic materials 0.000 title claims abstract description 20
- 239000000460 chlorine Substances 0.000 title claims abstract description 20
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 10
- 239000001257 hydrogen Substances 0.000 title claims abstract description 9
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 9
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 title description 4
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 32
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 18
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims abstract description 6
- 229910001854 alkali hydroxide Inorganic materials 0.000 claims abstract description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 48
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 38
- 239000012528 membrane Substances 0.000 claims description 36
- 229920001577 copolymer Polymers 0.000 claims description 26
- 239000003518 caustics Substances 0.000 claims description 22
- 239000000463 material Substances 0.000 claims description 21
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 claims description 20
- 239000012267 brine Substances 0.000 claims description 19
- 239000000243 solution Substances 0.000 claims description 18
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 16
- -1 perfluoro Chemical group 0.000 claims description 9
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 6
- OBTWBSRJZRCYQV-UHFFFAOYSA-N sulfuryl difluoride Chemical group FS(F)(=O)=O OBTWBSRJZRCYQV-UHFFFAOYSA-N 0.000 claims description 5
- 229910001514 alkali metal chloride Inorganic materials 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 125000000542 sulfonic acid group Chemical group 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 30
- 239000007788 liquid Substances 0.000 description 16
- 239000011780 sodium chloride Substances 0.000 description 15
- 150000002500 ions Chemical class 0.000 description 11
- 239000003513 alkali Substances 0.000 description 9
- 238000013508 migration Methods 0.000 description 9
- 230000005012 migration Effects 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000002253 acid Substances 0.000 description 8
- 239000003792 electrolyte Substances 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 239000010959 steel Substances 0.000 description 5
- RRZIJNVZMJUGTK-UHFFFAOYSA-N 1,1,2-trifluoro-2-(1,2,2-trifluoroethenoxy)ethene Chemical class FC(F)=C(F)OC(F)=C(F)F RRZIJNVZMJUGTK-UHFFFAOYSA-N 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 229910001415 sodium ion Inorganic materials 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920002313 fluoropolymer Polymers 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 229910001925 ruthenium oxide Inorganic materials 0.000 description 2
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical group 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920001875 Ebonite Polymers 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 150000001265 acyl fluorides Chemical group 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 229910001508 alkali metal halide Inorganic materials 0.000 description 1
- 150000008045 alkali metal halides Chemical class 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000010406 cathode material Substances 0.000 description 1
- 239000003729 cation exchange resin Substances 0.000 description 1
- 229940023913 cation exchange resins Drugs 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 229920001429 chelating resin Polymers 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000011953 free-radical catalyst Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000012811 non-conductive material Substances 0.000 description 1
- 150000003022 phthalic acids Chemical class 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000012047 saturated solution Substances 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
- C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
- C08J5/2218—Synthetic macromolecular compounds
- C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
- C08J5/2237—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/34—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis
- C25B1/46—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis in diaphragm cells
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Electrochemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NO750337A NO141420C (no) | 1971-12-27 | 1975-02-03 | Fremgangsmaate for aa reparere partier av et skadet ko-polymerdiafragma for elektrolyseceller |
NO750338A NO750338L (es) | 1971-12-27 | 1975-02-03 | |
NO750336A NO750336L (es) | 1971-12-27 | 1975-02-03 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US21217171A | 1971-12-27 | 1971-12-27 |
Publications (1)
Publication Number | Publication Date |
---|---|
NO139610B true NO139610B (no) | 1979-01-02 |
Family
ID=22789846
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO4781/72A NO139610B (no) | 1971-12-27 | 1972-12-27 | Fremgangsmaate for fremstilling av alkalihydroksyd og klor eller hydrogen eller klor ved elektrolyse |
Country Status (15)
Country | Link |
---|---|
JP (1) | JPS4878097A (es) |
AR (1) | AR196895A1 (es) |
BE (1) | BE793078A (es) |
BR (1) | BR7209151D0 (es) |
CS (3) | CS190446B2 (es) |
DD (1) | DD101821A5 (es) |
ES (2) | ES410045A1 (es) |
IL (3) | IL41038A (es) |
IT (1) | IT972820B (es) |
MX (1) | MX3133E (es) |
NO (1) | NO139610B (es) |
RO (1) | RO66346A (es) |
SE (3) | SE383477B (es) |
SU (1) | SU659078A3 (es) |
ZA (1) | ZA728589B (es) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3976549A (en) * | 1973-02-26 | 1976-08-24 | Hooker Chemicals & Plastics Corporation | Electrolysis method |
JPS551351B2 (es) * | 1974-03-07 | 1980-01-12 | ||
JPS5111098A (en) * | 1974-07-19 | 1976-01-28 | Asahi Glass Co Ltd | Suisankakariumuno seizohoho |
JPS5154082A (ja) * | 1974-11-08 | 1976-05-12 | Asahi Glass Co Ltd | Yoionkokanmaku |
JPS5291783A (en) * | 1976-01-29 | 1977-08-02 | Teikoku Piston Ring Co Ltd | Method of protecting diaphragm in electrodialusis or electrolysis |
JPS5337198A (en) * | 1977-07-15 | 1978-04-06 | Asahi Chem Ind Co Ltd | Electrolytic method of sodium chloride |
FR2948121B1 (fr) | 2009-07-15 | 2011-08-05 | Commissariat Energie Atomique | Copolymeres fluores, membranes preparees a partir de ceux-ci et dispositif de pile a combustible comprenant ces membranes |
-
1972
- 1972-12-05 ZA ZA728589A patent/ZA728589B/xx unknown
- 1972-12-08 IL IL41038A patent/IL41038A/en unknown
- 1972-12-08 IL IL48546A patent/IL48546A/en unknown
- 1972-12-15 MX MX100198U patent/MX3133E/es unknown
- 1972-12-15 AR AR245688A patent/AR196895A1/es active
- 1972-12-20 BE BE793078D patent/BE793078A/xx unknown
- 1972-12-22 IT IT33474/72A patent/IT972820B/it active
- 1972-12-22 SE SE7216914A patent/SE383477B/xx unknown
- 1972-12-23 RO RO7273282A patent/RO66346A/ro unknown
- 1972-12-26 JP JP48004563A patent/JPS4878097A/ja active Pending
- 1972-12-26 ES ES410045A patent/ES410045A1/es not_active Expired
- 1972-12-27 CS CS751903A patent/CS190446B2/cs unknown
- 1972-12-27 CS CS728958A patent/CS190401B2/cs unknown
- 1972-12-27 NO NO4781/72A patent/NO139610B/no unknown
- 1972-12-27 CS CS758249A patent/CS190447B2/cs unknown
- 1972-12-27 SU SU721866652A patent/SU659078A3/ru active
- 1972-12-27 BR BR9151/72A patent/BR7209151D0/pt unknown
- 1972-12-27 DD DD167913A patent/DD101821A5/xx unknown
-
1975
- 1975-05-30 ES ES438085A patent/ES438085A1/es not_active Expired
- 1975-07-31 SE SE7508695A patent/SE7508695L/ not_active Application Discontinuation
- 1975-07-31 SE SE7508694A patent/SE412608B/xx unknown
- 1975-11-26 IL IL48546A patent/IL48546A0/xx unknown
Also Published As
Publication number | Publication date |
---|---|
IL48546A (en) | 1976-11-30 |
CS190446B2 (en) | 1979-05-31 |
SE7508694L (sv) | 1975-07-31 |
AR196895A1 (es) | 1974-02-28 |
RO66346A (fr) | 1979-07-15 |
MX3133E (es) | 1980-04-28 |
SE383477B (sv) | 1976-03-15 |
IT972820B (it) | 1974-05-31 |
ES410045A1 (es) | 1976-06-01 |
DD101821A5 (es) | 1973-11-20 |
ES438085A1 (es) | 1977-02-01 |
IL41038A (en) | 1976-08-31 |
JPS4878097A (es) | 1973-10-19 |
IL48546A0 (en) | 1976-01-30 |
IL41038A0 (en) | 1973-02-28 |
BE793078A (en) | 1973-06-20 |
BR7209151D0 (pt) | 1974-12-24 |
SE7508695L (sv) | 1975-07-31 |
SE412608B (sv) | 1980-03-10 |
ZA728589B (en) | 1974-01-30 |
CS190401B2 (en) | 1979-05-31 |
SU659078A3 (ru) | 1979-04-25 |
CS190447B2 (en) | 1979-05-31 |
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