MXPA99000662A - Composiciones de liberacion de molde interna que contiene esteres de fosfato. - Google Patents

Composiciones de liberacion de molde interna que contiene esteres de fosfato.

Info

Publication number
MXPA99000662A
MXPA99000662A MXPA99000662A MX9900662A MXPA99000662A MX PA99000662 A MXPA99000662 A MX PA99000662A MX PA99000662 A MXPA99000662 A MX PA99000662A MX 9900662 A MX9900662 A MX 9900662A MX PA99000662 A MXPA99000662 A MX PA99000662A
Authority
MX
Mexico
Prior art keywords
alkyl phosphate
mono
alkyl
mixture
groups
Prior art date
Application number
MXPA99000662A
Other languages
English (en)
Inventor
Boryslawski Joseph
Original Assignee
Essilor Int
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Essilor Int filed Critical Essilor Int
Publication of MXPA99000662A publication Critical patent/MXPA99000662A/es

Links

Classifications

    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • G02B1/041Lenses
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • B29C33/56Coatings, e.g. enameled or galvanised; Releasing, lubricating or separating agents
    • B29C33/60Releasing, lubricating or separating agents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/38Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3855Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur
    • C08G18/3876Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing mercapto groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/38Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3878Low-molecular-weight compounds having heteroatoms other than oxygen having phosphorus
    • C08G18/3882Low-molecular-weight compounds having heteroatoms other than oxygen having phosphorus having phosphorus bound to oxygen only
    • C08G18/3885Phosphate compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/51Phosphorus bound to oxygen
    • C08K5/52Phosphorus bound to oxygen only
    • C08K5/521Esters of phosphoric acids, e.g. of H3PO4
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2125/00Compositions for processes using internal mould release agents

Landscapes

  • Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)

Abstract

En la presente se describen composiciones de liberacion de molde internas para moldear poliuretano y politiouretano. La composicion incluye una mezcla de (a) un fosfato de monoalquilo de C2-C6; b) un fosfato de dialquilo de C2-C6, en donde los grupos alquilo de fosfato de dialquilo pueden ser iguales o diferentes y en donde los grupos alquilo de fosfato de mono y dialquilo pueden ser iguales o diferentes; y (c) un fosfato de mono y/o dialquilo de C7-C18. Tambien se describe una composicion polimerizable que incluye (a) uno o mas monomeros que contienen dos o mas grupos de isocianato; (b) uno o mas monomeros que contiene dos o mas grupos funcionales seleccionados de un grupo tiol y un grupo hidroxilo; (c) una mezcla de un fosfato de monoalquilo de C2-C6 y un fosfato de dialquilo de C2-C6, en donde los grupos alquilo del fosfato de dialquilo pueden ser iguales o diferentes y en donde los grupos alquilo de la mezcla de fosfato de mono y dialquilo pueden ser iguales o diferentes, en donde el fosfato de monoalquilo de C2-Coest presente en una cantidad de -> 20% en peso, basado en peso total de la mezcla de fosfato de monoalquilo de C2-C6 y el fosfato de dialquilo de C2-C6. La composicion tambien puede incluir opcionalmente el fosfato de mono y/o dialquilo de C7-C18.
MXPA99000662A 1996-07-17 1997-07-16 Composiciones de liberacion de molde interna que contiene esteres de fosfato. MXPA99000662A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US68207896A 1996-07-17 1996-07-17
PCT/EP1997/003801 WO1998003582A1 (en) 1996-07-17 1997-07-16 Internal mold release compositions containing phosphate esters

Publications (1)

Publication Number Publication Date
MXPA99000662A true MXPA99000662A (es) 2004-11-22

Family

ID=24738107

Family Applications (1)

Application Number Title Priority Date Filing Date
MXPA99000662A MXPA99000662A (es) 1996-07-17 1997-07-16 Composiciones de liberacion de molde interna que contiene esteres de fosfato.

Country Status (6)

Country Link
US (1) US5962561A (es)
EP (1) EP0912632B1 (es)
JP (1) JP3954108B2 (es)
DE (1) DE69732485T2 (es)
MX (1) MXPA99000662A (es)
WO (1) WO1998003582A1 (es)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6852266B2 (en) * 2001-01-19 2005-02-08 Korry Electronics Co. Ultrasonic assisted deposition of anti-stick films on metal oxides
US6783719B2 (en) 2001-01-19 2004-08-31 Korry Electronics, Co. Mold with metal oxide surface compatible with ionic release agents
US20050148676A1 (en) * 2002-03-18 2005-07-07 Yasuhiro Doi Resin composition and optical element
JP3905409B2 (ja) * 2002-04-10 2007-04-18 タレックス光学工業株式会社 光学レンズ成型用ポリウレタン樹脂組成物および耐衝撃性合成樹脂レンズ
FR2860597B1 (fr) * 2003-10-03 2006-01-27 Essilor Int Materiau thermodur antiplastifie comportant des atomes de soufre et lentille ophtalmique comprenant un materiau thermodur antiplastifie
US20050189677A1 (en) * 2004-02-26 2005-09-01 Steven Lucka Method for producing a cast of hydrated thermo-set materials with polyurethane elastomer molds
US7309252B2 (en) * 2005-02-22 2007-12-18 Tyco Electronics Corporation Low profile surface mount connector
US8597016B2 (en) 2005-11-23 2013-12-03 Milgard Manufacturing Incorporated System for producing pultruded components
US8101107B2 (en) 2005-11-23 2012-01-24 Milgard Manufacturing Incorporated Method for producing pultruded components
US7901762B2 (en) 2005-11-23 2011-03-08 Milgard Manufacturing Incorporated Pultruded component
US7875675B2 (en) 2005-11-23 2011-01-25 Milgard Manufacturing Incorporated Resin for composite structures
EP1988110B1 (en) * 2006-02-23 2017-01-04 Mitsui Chemicals, Inc. Internal mold release agent for production of polythiourethane optical material
IT1400108B1 (it) 2010-05-20 2013-05-17 Acomon Ag Catalizzatore di polimerizzazione per politiouretani, composizione liquida polimerizzabile e procedimento per la produzione di vetri organici politiouretanici ad alto indice di rifrazione
US8524134B2 (en) 2010-07-12 2013-09-03 Graham J. Hubbard Method of molding polymeric materials to impart a desired texture thereto
KR101745811B1 (ko) 2012-11-21 2017-06-09 미쓰이 가가쿠 가부시키가이샤 광학 재료용 중합성 조성물
KR101739248B1 (ko) 2013-03-26 2017-05-23 미쯔이가가꾸가부시끼가이샤 광학 재료용 중합성 조성물 및 그로부터 얻어지는 광학 재료 및 그 제조 방법
US10294198B2 (en) * 2014-04-11 2019-05-21 Covestro Deutschland Ag Method for producing xylylene diisocyanates in the gaseous phase
US10544283B2 (en) 2015-03-12 2020-01-28 Hoya Lens Thailand Ltd. Iso(thio)cyanate composition, and resin composition including same for optical member
EP3589672B1 (de) * 2017-03-02 2022-01-12 Covestro Intellectual Property GmbH & Co. KG Reaktionsgemische von isocyanaten und polyolen mit verlängerter topfzeit
KR101910131B1 (ko) * 2018-02-23 2018-10-19 에스케이씨 주식회사 인계 이형제, 이를 포함하는 광학용 중합성 조성물 및 이의 제조방법

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US4500669A (en) * 1977-10-27 1985-02-19 Swedlow, Inc. Transparent, abrasion resistant coating compositions
US4258169A (en) * 1980-03-26 1981-03-24 The Upjohn Company Polyisocyanate compositions containing in-situ formed pyrophosphate mold release agent and process of making
JPS60199016A (ja) * 1984-03-23 1985-10-08 Mitsui Toatsu Chem Inc チオカルバミン酸s―アルキルエステル系レンズ用樹脂の製造方法
US4780522A (en) * 1984-04-11 1988-10-25 Mitsui Toatsu Chemicals, Incorporated Sulfur-containing polyurethane base lens resin
JPS6154331A (ja) * 1984-08-23 1986-03-18 Nippon Denso Co Ltd 車両用冷蔵庫
US4622376A (en) * 1985-06-27 1986-11-11 Ppg Industries, Inc. Composition of aromatic poly(allylcarbonate), styrene materials, and crosslinker containing three or more ethylenically unsaturated groups for producing polymer of high refractive index and low yellowness
JPS6292685A (ja) * 1985-10-18 1987-04-28 Matsushita Electric Ind Co Ltd ビデオ信号処理装置
JPH0777733B2 (ja) * 1986-12-15 1995-08-23 三井東圧化学株式会社 含硫ウレタン樹脂製レンズの注型重合方法
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CA1320806C (en) * 1988-02-17 1993-08-03 Teruyuki Nagata Plastic lenses having a high-refracting index and process for the preparation thereof
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CA1316315C (en) * 1988-02-22 1993-04-20 Nobuyuki Kajimoto Highly-refractive plastic lens and process for making the lens
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US5693738A (en) * 1994-04-08 1997-12-02 Mitsui Toatsu Chemicals, Inc. Composition for urethane-base plastic lens, urethane-base plastic lens obtained from the composition, and process for the production of the plastic lens

Also Published As

Publication number Publication date
EP0912632B1 (en) 2005-02-09
DE69732485T2 (de) 2006-01-05
JP3954108B2 (ja) 2007-08-08
JP2001505232A (ja) 2001-04-17
US5962561A (en) 1999-10-05
EP0912632A1 (en) 1999-05-06
WO1998003582A1 (en) 1998-01-29
DE69732485D1 (de) 2005-03-17

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