MX9801348A - Composiciones que contienen carbamatos de 1,3,5-triazina y compuestos epoxi. - Google Patents
Composiciones que contienen carbamatos de 1,3,5-triazina y compuestos epoxi.Info
- Publication number
- MX9801348A MX9801348A MX9801348A MX9801348A MX9801348A MX 9801348 A MX9801348 A MX 9801348A MX 9801348 A MX9801348 A MX 9801348A MX 9801348 A MX9801348 A MX 9801348A MX 9801348 A MX9801348 A MX 9801348A
- Authority
- MX
- Mexico
- Prior art keywords
- coatings
- curable compositions
- present
- linker
- compositions containing
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
- C08G59/4014—Nitrogen containing compounds
- C08G59/4057—Carbamates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
- C08G59/5046—Amines heterocyclic
- C08G59/5053—Amines heterocyclic containing only nitrogen as a heteroatom
- C08G59/508—Amines heterocyclic containing only nitrogen as a heteroatom having three nitrogen atoms in the ring
- C08G59/5086—Triazines; Melamines; Guanamines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34922—Melamine; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/062—Copolymers with monomers not covered by C09D133/06
- C09D133/068—Copolymers with monomers not covered by C09D133/06 containing glycidyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08L61/32—Modified amine-aldehyde condensates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
- Epoxy Resins (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Phenolic Resins Or Amino Resins (AREA)
Abstract
se describen composiciones curables las cuales incluyen un reticulante de carbamato de 1,3,5-triazina y una resina epoxi polifuncional así como sus usos en revestimientos. Las presentes composiciones curables de manera adicional pueden contener un correticulante y/o un material que contiene un grupo hidroxi polifuncional. Mediante la utilizacion de las composiciones curables de la presente invencion, se puede obtener una reduccion significativa en los niveles de emision de formaldehído en relacion a los revestimientos basados en resina aminoplástica sin pérdida de las propiedades finales de película. Las composiciones curables de la presente invencion son utilizables en revestimientos, particularmente en revestimientos del tipo utilizado comunmente en fabricacion de equipo original y en aplicaciones de revestimientos industriales generales.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US295095P | 1995-08-30 | 1995-08-30 | |
PCT/US1996/013831 WO1997008235A1 (en) | 1995-08-30 | 1996-08-28 | Compositions containing 1,3,5-triazine carbamates and epoxy compounds |
Publications (2)
Publication Number | Publication Date |
---|---|
MX9801348A true MX9801348A (es) | 1998-07-31 |
MX211961B MX211961B (es) | 2002-12-10 |
Family
ID=21703339
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX9801348A MX211961B (es) | 1995-08-30 | 1996-08-28 | Composiciones que contienen carbamatos de 1,3,5-triazina y compuestos epoxi. |
Country Status (11)
Country | Link |
---|---|
US (1) | US5852133A (es) |
EP (1) | EP0847417B1 (es) |
JP (1) | JP3287575B2 (es) |
KR (1) | KR19990044020A (es) |
AT (1) | ATE283312T1 (es) |
BR (1) | BR9610137A (es) |
CA (1) | CA2230604C (es) |
DE (1) | DE69633927T2 (es) |
ES (1) | ES2235195T3 (es) |
MX (1) | MX211961B (es) |
WO (1) | WO1997008235A1 (es) |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0885214A1 (en) * | 1996-03-01 | 1998-12-23 | Cytec Technology Corp. | Cyclic imido-1,3,5-triazine crosslinking agents |
DE19622878A1 (de) * | 1996-06-07 | 1997-12-11 | Basf Lacke & Farben | Mehrschichtige Lackierung, Verfahren zu deren Herstellung und hierfür geeigneter nicht-wäßriger Decklack |
KR20000052900A (ko) * | 1996-10-30 | 2000-08-25 | 마이클 제이. 켈리 | 1,3,5-트리아진 카바메이트/아미노플라스트 수지 혼합물을 함유하는 액상의 가교결합제 조성물 |
WO1998027166A2 (de) | 1996-12-18 | 1998-06-25 | Basf Coatings Ag | Beschichtungsmittel und verfahren zu dessen herstellung |
JP4191802B2 (ja) * | 1996-12-18 | 2008-12-03 | ビーエーエスエフ コーティングス アクチェンゲゼルシャフト | コーティング剤およびその製造方法 |
DE19709465C2 (de) | 1997-03-07 | 2001-07-12 | Basf Coatings Ag | Beschichtungsmittel, Verfahren zur Herstellung von Mehrschichtlackierungen und Verwendung der Beschichtungsmittel hierfür |
ES2196609T3 (es) | 1997-09-20 | 2003-12-16 | Basf Coatings Ag | Laca transparente en polvo. |
MX237828B (en) | 1997-09-20 | 2006-06-15 | Basf Coatings Ag | Powder varnish dispersion |
AU3978999A (en) | 1998-06-16 | 2000-01-05 | Cytec Technology Corp. | Process for the preparation of triazine carbamates |
US6331582B1 (en) | 1999-05-03 | 2001-12-18 | Solutia Inc. | Low gloss coating |
US6174659B1 (en) * | 1999-09-08 | 2001-01-16 | Eastman Kodak Company | Method for forming a base for an imaging element, and an imaging element comprising such base, with improved crosslinking agent |
AU1810701A (en) * | 1999-12-03 | 2001-06-12 | Cytec Technology Corp. | Formaldehyde free 1,3,5-triazine carbamate crosslinkers and curable compositionscontaining same |
US6950669B2 (en) | 2000-07-05 | 2005-09-27 | Telefonaktiebolaget Lm Ericsson (Publ) | Power control algorithm for packet data based on queue/channel utilization |
US20040006185A1 (en) * | 2002-07-01 | 2004-01-08 | Basf Corporation | Carbamate-functional polymer, curable coating composition thereof, and method of preparing the polymer |
US20040116558A1 (en) * | 2002-11-08 | 2004-06-17 | Akzo Nobel N.V. | New carbamate - melamine formaldehyde cross-linking agents |
US20050129865A1 (en) * | 2003-12-15 | 2005-06-16 | Campbell Donald H. | Blocked isocyanates for clearcoats without usage restrictions |
DE102004018546A1 (de) | 2004-04-14 | 2005-11-03 | Basf Ag | Strahlungshärtbare 1,3,5-Triazincarbamate und -harnstoffe |
DE102004018544A1 (de) | 2004-04-14 | 2005-11-03 | Basf Ag | Verfahren zur Herstellung von 1,3,5-Triazincarbamaten und -harnstoffen |
US20050249879A1 (en) * | 2004-05-10 | 2005-11-10 | Jenkins Steven A | Packaging coating containing 1,3,5-triazine carbamate crosslinker |
EP2679611A1 (en) * | 2005-09-13 | 2014-01-01 | Dow Global Technologies LLC | Distannoxane catalysts for polyurethanes |
US7759436B2 (en) * | 2006-10-26 | 2010-07-20 | Basf Coatings Gmbh | Film-former of resin with nonionic metal coordinating structure and crosslinker-reactive group |
US7772334B2 (en) * | 2006-10-26 | 2010-08-10 | Basf Coatings Gmbh | Crosslinker of reactive functional groups and nonionic metal coordinating structure-containing alkyl or aromatic compound |
US9676532B2 (en) | 2012-08-15 | 2017-06-13 | Avery Dennison Corporation | Packaging reclosure label for high alcohol content products |
JP6601394B2 (ja) * | 2014-04-22 | 2019-11-06 | 日本ゼオン株式会社 | 感放射線性樹脂組成物、樹脂膜、および電子部品 |
EP3169716B1 (en) * | 2014-07-17 | 2018-04-04 | Dow Global Technologies LLC | Epoxy systems employing triethylaminetetraamine and tin catalysts |
US20220227718A1 (en) * | 2019-06-28 | 2022-07-21 | 3M Innovative Properties Company | Hydroxy-Functionalized Triazine Compounds, Curable Fluoropolymer Compositions Comprising Such Compounds and Cured Articles Therefrom |
Family Cites Families (49)
Publication number | Priority date | Publication date | Assignee | Title |
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BE541693A (es) * | 1954-10-04 | 1900-01-01 | ||
US3418392A (en) * | 1964-10-21 | 1968-12-24 | Geigy Chem Corp | Crosslinking compositions comprising a polycycloaliphatic polyepoxide and a hexaalkyloxymethylaminotriazine for acrylic interpolymers |
US3730930A (en) * | 1971-08-16 | 1973-05-01 | Ford Motor Co | Compositions for powder coatings containing acrylate polymers or esters of fluorinated fatty acids as flow control agents |
US3781380A (en) * | 1971-08-16 | 1973-12-25 | Ford Motor Co | Powder coating compositions containing glycidyl ester copolymers,carboxy terminated polymeric crosslinking agents,and flow control agents |
US3752870A (en) * | 1971-08-16 | 1973-08-14 | Ford Motor Co | Powder coating compositions containing polymer of ethylenically unsaturated glycidyl esters dicarboxylic acids and flow control agents |
BE795704A (fr) * | 1972-02-22 | 1973-06-18 | Ford Motor Co | Procede de preparation de compositions de revetement en poudre |
JPS511535A (es) * | 1974-06-04 | 1976-01-08 | Kansai Paint Co Ltd | |
DE2507884B2 (de) * | 1975-02-24 | 1981-02-05 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung wäßriger Dispersionen von pigmentierten Überzugsmitteln |
DE2749576C3 (de) * | 1977-11-05 | 1980-04-24 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler, 6000 Frankfurt | Verfahren zur Herstellung eines Glycidylgruppen aufweisenden Acrylharzes und dessen Verwendung |
EP0006213B1 (de) * | 1978-06-21 | 1982-09-01 | Ciba-Geigy Ag | Lichtstabilisierung von sauerkatalysierten Einbrennlacken |
US4379911A (en) * | 1978-07-21 | 1983-04-12 | American Cyanamid Company | Cross-linking agents for cationic polymers |
US4346144A (en) * | 1980-07-21 | 1982-08-24 | E. I. Du Pont De Nemours And Company | Powder coating composition for automotive topcoat |
US4435559A (en) * | 1982-08-18 | 1984-03-06 | Ppg Industries, Inc. | β-Hydroxy urethane low temperature curing agents |
DE3424700A1 (de) * | 1984-07-05 | 1986-02-06 | Basf Ag, 6700 Ludwigshafen | Faserverbundwerkstoffe auf basis von epoxidharzen |
US4619956A (en) * | 1985-05-03 | 1986-10-28 | American Cyanamid Co. | Stabilization of high solids coatings with synergistic combinations |
US4650718A (en) * | 1985-08-19 | 1987-03-17 | Ppg Industries, Inc. | Color plus clear coatings employing polyepoxides and polyacid curing agents |
US4681811A (en) * | 1985-08-19 | 1987-07-21 | Ppg Industries, Inc. | Color plus clear coatings employing polyepoxides and polyacid curing agents in the clear coat |
US4703101A (en) * | 1985-08-19 | 1987-10-27 | Ppg Industries, Inc. | Liquid crosslinkable compositions using polyepoxides and polyacids |
US4764430A (en) * | 1986-03-07 | 1988-08-16 | Ppg Industries, Inc. | Crosslinkable compositions containing polyepoxides and polyacid curing agents |
EP0256369A3 (en) * | 1986-08-04 | 1989-09-13 | The Glidden Company | Glycidyl acrylic powder coatings |
US5001173A (en) * | 1987-05-11 | 1991-03-19 | Morton Coatings, Inc. | Aqueous epoxy resin compositions and metal substrates coated therewith |
US4855386A (en) * | 1987-12-31 | 1989-08-08 | Shell Oil Company | Curing agents for epoxy resins comprising diamines with the di(p-aminophenyl)-diisopropyl benzene structure |
DE3829587A1 (de) * | 1988-09-01 | 1990-03-15 | Bayer Ag | Beschichtungsmittel, ein verfahren zu ihrer herstellung und die verwendung von ausgewaehlten zweikomponenten-polyurethansystemen als bindemittel fuer derartige beschichtungsmittel |
US4939213A (en) * | 1988-12-19 | 1990-07-03 | American Cyanamid Company | Triazine crosslinking agents and curable compositions containing the same |
US5084541A (en) * | 1988-12-19 | 1992-01-28 | American Cyanamid Company | Triazine crosslinking agents and curable compositions |
ES2100878T3 (es) * | 1989-12-05 | 1997-07-01 | Ciba Geigy Ag | Material organico estabilizado. |
GB9000564D0 (en) * | 1990-01-10 | 1990-03-14 | Dow Rheinmuenster | Modified polyoxyethlene epoxy resin amphiphiles and stable aqueous epoxy dispersions thereof |
DE59106390D1 (de) * | 1990-02-16 | 1995-10-12 | Ciba Geigy Ag | Gegen Schädigung durch Licht, Wärme und Sauerstoff stabilisierte Ueberzugsmittel. |
DE69030249T2 (de) * | 1990-02-28 | 1997-08-28 | Cytec Tech Corp | Stabilisierung von Überzügen mit hohem Festkörpergehalt mit flüssigen Zusammenstellungen von UV absorbierenden Triazinen |
ES2081458T3 (es) * | 1990-03-30 | 1996-03-16 | Ciba Geigy Ag | Composicion de pintura. |
JP2914745B2 (ja) * | 1990-10-12 | 1999-07-05 | 三井化学株式会社 | 粉体塗料用樹脂組成物 |
ATE150056T1 (de) * | 1990-10-29 | 1997-03-15 | Cytec Tech Corp | Hydroxyaryltriazine und tetraalkylpiperidine enthaltende synergistische uv-absorbermischung |
US5196485A (en) * | 1991-04-29 | 1993-03-23 | Ppg Industries, Inc. | One package stable etch resistant coating |
US5116892A (en) * | 1991-07-22 | 1992-05-26 | Eastman Kodak Company | Thermosetting powder coating compositions |
US5288865A (en) * | 1991-11-15 | 1994-02-22 | American Cyanamid Company | Process for preparing amide derivatives from haloaminotriazines and acid halides |
US5342878A (en) * | 1991-12-30 | 1994-08-30 | Ppg Industries, Inc. | Base neutralized, stable, aqueous dispersion of a hydroxyl functional acrylic polymer and coating compositions prepared therefrom |
EP0568134A1 (en) * | 1992-04-16 | 1993-11-03 | Akzo Nobel N.V. | Aqueous coating compositions |
JPH08501341A (ja) * | 1992-09-14 | 1996-02-13 | サイテク・テクノロジー・コーポレーシヨン | Vocを含んでいない水系エポキシプライマー組成物 |
US5574103A (en) * | 1992-12-29 | 1996-11-12 | Cytec Technology Corp. | Aminoresin based coatings containing 1,3,5-triazine tris-carbamate co-crosslinkers |
TW328955B (en) * | 1993-05-14 | 1998-04-01 | Cytec Tech Corp | Process for preparing bis- or tris-carbamate functional 1,3,5-triazines, substantially halogen contamination free crosslinker compositions and new bis-or tris-carbamate functional 1,3,5-triazines |
US6197957B1 (en) * | 1993-10-15 | 2001-03-06 | Cytec Technology Corp. | Process for preparing derivatives of (halo)amino-1,3,5-triazines by carbonylation |
TW321660B (es) * | 1994-01-14 | 1997-12-01 | Cytec Tech Corp | |
US5556971A (en) * | 1994-05-06 | 1996-09-17 | Cytec Technology Corp. | Process for preparing isocyanate and isocyanate-based derivatives of certain amino-1,3,5-triazines by direct phosgenation |
US5556973A (en) * | 1994-07-27 | 1996-09-17 | Ciba-Geigy Corporation | Red-shifted tris-aryl-s-triazines and compositions stabilized therewith |
US6204382B1 (en) * | 1994-08-05 | 2001-03-20 | Cytec Technology Corp. | Carboxylated amino-1,3,5-triazines, derivatives thereof and processes for preparing the same |
US6448398B1 (en) * | 1994-10-18 | 2002-09-10 | Cytec Technology Corp. | Process for preparing acid amides from (Si, Ge, or Sn substituted amino)-1,3,5-triazines and acid halides |
US5596047A (en) * | 1994-11-16 | 1997-01-21 | Cytec Technology Corp. | Water-dispersible and curable waterborne compositions containing 1,3,5-triazine carbamates |
US5462992A (en) * | 1995-03-31 | 1995-10-31 | Ppg Industries, Inc. | Acetoacetylated polymers crosslinked with carbamylmethylaminotriazines |
US5565243A (en) * | 1995-05-01 | 1996-10-15 | Ppg Industries, Inc. | Color-clear composite coatings having improved hardness, acid etch resistance, and mar and abrasion resistance |
-
1996
- 1996-08-28 DE DE69633927T patent/DE69633927T2/de not_active Expired - Lifetime
- 1996-08-28 EP EP96929088A patent/EP0847417B1/en not_active Expired - Lifetime
- 1996-08-28 AT AT96929088T patent/ATE283312T1/de not_active IP Right Cessation
- 1996-08-28 WO PCT/US1996/013831 patent/WO1997008235A1/en active IP Right Grant
- 1996-08-28 KR KR1019980701252A patent/KR19990044020A/ko not_active Application Discontinuation
- 1996-08-28 JP JP51054297A patent/JP3287575B2/ja not_active Expired - Fee Related
- 1996-08-28 ES ES96929088T patent/ES2235195T3/es not_active Expired - Lifetime
- 1996-08-28 BR BR9610137A patent/BR9610137A/pt not_active IP Right Cessation
- 1996-08-28 CA CA002230604A patent/CA2230604C/en not_active Expired - Lifetime
- 1996-08-28 MX MX9801348A patent/MX211961B/es unknown
- 1996-08-29 US US08/705,472 patent/US5852133A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
ES2235195T3 (es) | 2005-07-01 |
MX211961B (es) | 2002-12-10 |
DE69633927D1 (de) | 2004-12-30 |
WO1997008235A1 (en) | 1997-03-06 |
JPH11500773A (ja) | 1999-01-19 |
BR9610137A (pt) | 1999-02-02 |
JP3287575B2 (ja) | 2002-06-04 |
EP0847417B1 (en) | 2004-11-24 |
US5852133A (en) | 1998-12-22 |
EP0847417A1 (en) | 1998-06-17 |
CA2230604C (en) | 2008-12-02 |
ATE283312T1 (de) | 2004-12-15 |
CA2230604A1 (en) | 1997-03-06 |
KR19990044020A (ko) | 1999-06-25 |
DE69633927T2 (de) | 2005-11-24 |
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