MX366027B - Líquidos zwitteriónicos geminales base sulfobetaína e hidroxisultaína, proceso de obtención y uso como modificadores de la mojabilidad con propiedades inhibitorias de la corrosión. - Google Patents
Líquidos zwitteriónicos geminales base sulfobetaína e hidroxisultaína, proceso de obtención y uso como modificadores de la mojabilidad con propiedades inhibitorias de la corrosión.Info
- Publication number
- MX366027B MX366027B MX2014015226A MX2014015226A MX366027B MX 366027 B MX366027 B MX 366027B MX 2014015226 A MX2014015226 A MX 2014015226A MX 2014015226 A MX2014015226 A MX 2014015226A MX 366027 B MX366027 B MX 366027B
- Authority
- MX
- Mexico
- Prior art keywords
- zwitterionic liquids
- hydroxysultaine
- sulfobetaine
- production
- geminal zwitterionic
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
- C07C309/01—Sulfonic acids
- C07C309/02—Sulfonic acids having sulfo groups bound to acyclic carbon atoms
- C07C309/03—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
- C07C309/17—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton containing carboxyl groups bound to the carbon skeleton
- C07C309/18—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton containing carboxyl groups bound to the carbon skeleton containing amino groups bound to the same carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
- C07C309/01—Sulfonic acids
- C07C309/02—Sulfonic acids having sulfo groups bound to acyclic carbon atoms
- C07C309/03—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
- C07C309/13—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton containing nitrogen atoms, not being part of nitro or nitroso groups, bound to the carbon skeleton
- C07C309/14—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton containing nitrogen atoms, not being part of nitro or nitroso groups, bound to the carbon skeleton containing amino groups bound to the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
- C07C303/22—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof from sulfonic acids, by reactions not involving the formation of sulfo or halosulfonyl groups; from sulfonic halides by reactions not involving the formation of halosulfonyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
- C07C309/63—Esters of sulfonic acids
- C07C309/64—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms
- C07C309/69—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms of a carbon skeleton substituted by nitrogen atoms, not being part of nitro or nitroso groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/54—Compositions for in situ inhibition of corrosion in boreholes or wells
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/58—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
- C09K8/584—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific surfactants
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
La presente invención se relaciona con la obtención y uso de líquidos zwitteriónicos geminales base sulfobetaína e hidroxisultaína, como modificadores de la mojabilidad de rocas como caliza, dolomita, arenisca, cuarzo o litologías heterogéneas, en presencia de salmueras con alto contenido de iones divalentes como calcio, magnesio, bario y estroncio, alta temperatura y alta presión en procesos de recuperación mejorada de petróleo para incrementar la producción de petróleo. Los líquidos zwitteriónicos geminales de la presente invención tienen además la propiedad de actuar como inhibidores de la corrosión de metales ferrosos utilizados en ductos y equipos para operaciones de extracción, producción, transporte y almacenamiento de aceite crudo. Una ventaja adicional que presentan los líquidos zwitteriónicos derivada de su estructura molecular es que pueden ser disueltos en agua destilada, salmuera, solventes hidrocarbonados, aromáticos y alcoholes.
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
MX2014015226A MX366027B (es) | 2014-12-11 | 2014-12-11 | Líquidos zwitteriónicos geminales base sulfobetaína e hidroxisultaína, proceso de obtención y uso como modificadores de la mojabilidad con propiedades inhibitorias de la corrosión. |
CA2970268A CA2970268C (en) | 2014-12-11 | 2015-11-27 | Geminal zwitterionic liquids, sulfobetaine- and hydroxisultaine-base, process of obtaining and using as wettability modifier with corrosion inhibitory properties |
US15/535,323 US11014875B2 (en) | 2014-12-11 | 2015-11-27 | Hydroxysultaine- and sulfobetaine-based geminal zwitterionic liquids, method for obtaining same, and use thereof as wettability modifiers having corrosion inhibiting properties |
PCT/MX2015/050001 WO2016093688A2 (es) | 2014-12-11 | 2015-11-27 | Líquidos zwitteriónicos geminales base sulfobetaína e hidroxisultaína, proceso de obtención y uso como modificadores de la mojabilidad con propiedades inhibitorias de la corrosión |
EP15867255.0A EP3231791B1 (en) | 2014-12-11 | 2015-11-27 | Hydroxysultaine- and sulfobetaine-based geminal zwitterionic liquids, method for obtaining same, and use thereof as wettability modifiers having corrosion inhibiting properties |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
MX2014015226A MX366027B (es) | 2014-12-11 | 2014-12-11 | Líquidos zwitteriónicos geminales base sulfobetaína e hidroxisultaína, proceso de obtención y uso como modificadores de la mojabilidad con propiedades inhibitorias de la corrosión. |
Publications (2)
Publication Number | Publication Date |
---|---|
MX2014015226A MX2014015226A (es) | 2016-06-10 |
MX366027B true MX366027B (es) | 2019-06-11 |
Family
ID=56108338
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2014015226A MX366027B (es) | 2014-12-11 | 2014-12-11 | Líquidos zwitteriónicos geminales base sulfobetaína e hidroxisultaína, proceso de obtención y uso como modificadores de la mojabilidad con propiedades inhibitorias de la corrosión. |
Country Status (5)
Country | Link |
---|---|
US (1) | US11014875B2 (es) |
EP (1) | EP3231791B1 (es) |
CA (1) | CA2970268C (es) |
MX (1) | MX366027B (es) |
WO (1) | WO2016093688A2 (es) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2020005840A1 (en) * | 2018-06-25 | 2020-01-02 | Adaptive Surface Technologies, Inc. | Polyoxyalkylene coupled zwitterionic moiety and surface active reactive polymers, coating compositions and fouling control coatings thereof |
MX2019005132A (es) | 2019-05-02 | 2020-11-03 | Mexicano Inst Petrol | Bipolimeros tribloques poe-pop-poe, con terminaciones anfotericas, como agentes desemulsionantes de aceites crudos pesados. |
CN111848468B (zh) * | 2020-07-29 | 2021-07-30 | 河南大学 | 一种半胱胺衍生物及其制备方法和作为碳钢酸洗缓蚀剂的应用 |
CN115093351B (zh) * | 2022-07-15 | 2022-11-29 | 山东新港化工有限公司 | 改性甜菜碱型双子表面活性剂及其制备方法和应用 |
CN116341764B (zh) * | 2023-05-24 | 2023-09-26 | 中国石油大学(华东) | 基于历史数据的成品油管道混油浓度分布预测方法及*** |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3643738A (en) | 1970-05-28 | 1972-02-22 | Marathon Oil Co | Wettability control in an oil recovery process |
US4039336A (en) | 1975-12-03 | 1977-08-02 | Exxon Research And Engineering Company | Diacetylenic alcohol corrosion inhibitors |
US4216097A (en) * | 1977-07-15 | 1980-08-05 | Mobil Oil Corporation | Waterflooding employing amphoteric surfactants |
US4383054A (en) * | 1981-05-28 | 1983-05-10 | Texaco Inc. | Hydrophilic high polymers prepared from aqueous solutions or dispersions of polyoxypropylene polyamine N-N'-polymethylene sulfonates |
US4509951A (en) | 1984-06-13 | 1985-04-09 | Ethyl Corporation | Corrosion inhibitor for alcohol and gasohol fuels |
US4900458A (en) | 1987-01-08 | 1990-02-13 | Chevron Research Company | Polyalkylenepolyamines as corrosion inhibitors |
US4842065A (en) | 1988-05-11 | 1989-06-27 | Marathon Oil Company | Oil recovery process employing cyclic wettability alteration |
US5084210A (en) | 1990-02-07 | 1992-01-28 | Chemlink Incorporated | Corrosion inhibitor |
US5042580A (en) | 1990-07-11 | 1991-08-27 | Mobil Oil Corporation | Oil recovery process for use in fractured reservoirs |
US5275744A (en) | 1991-09-30 | 1994-01-04 | Chevron Research And Technology Company | Derivatives of polyalkylenepolyamines as corrosion inhibitors |
US6118000A (en) | 1996-11-04 | 2000-09-12 | Hydrochem Industrial Services, Inc. | Methods for preparing quaternary ammonium salts |
US8999315B2 (en) | 2004-07-15 | 2015-04-07 | Nalco Company | Bis-quaternary ammonium salt corrosion inhibitors |
EP2173832B1 (en) | 2007-07-20 | 2017-09-13 | Solvay USA Inc. | Method for recovering crude oil from a subterranean formation |
US8105987B2 (en) | 2008-10-06 | 2012-01-31 | Nalco Company | Corrosion inhibitors for an aqueous medium |
MX2009013704A (es) * | 2009-12-15 | 2011-06-15 | Mexicano Inst Petrol | Nuevos surfactantes geminales, proceso de obtencion y uso como inhibidores de corrosion multifuncionales. |
MX2010012348A (es) | 2010-11-12 | 2012-05-15 | Mexicano Inst Petrol | Composicion base liquidos zwitterionicos geminales como modificadores de la mojabilidad en procesos de recuperacion mejorada de petroleo. |
US9850265B2 (en) * | 2011-05-26 | 2017-12-26 | Gri Bio, Inc. | Amino- or ammonium-containing sulfonic acid, phosphonic acid and carboxylic acid derivatives and their medical use |
MX360195B (es) * | 2012-09-26 | 2018-10-11 | Mexicano Inst Petrol | Composicion con propiedades modificadoras de mojabilidad y viscosificantes para procesos de recuperacion mejorada de hidrocarburos en yacimientos con alta temperatura y salinidad. |
MX338862B (es) | 2012-12-05 | 2016-04-28 | Mexicano Inst Petrol | Composicion espumante con propiedades modificadoras de la mojabilidad e inhibitorias de la corrosion para alta temperatura y ulra alta temperatura. |
-
2014
- 2014-12-11 MX MX2014015226A patent/MX366027B/es active IP Right Grant
-
2015
- 2015-11-27 US US15/535,323 patent/US11014875B2/en active Active
- 2015-11-27 WO PCT/MX2015/050001 patent/WO2016093688A2/es active Application Filing
- 2015-11-27 CA CA2970268A patent/CA2970268C/en active Active
- 2015-11-27 EP EP15867255.0A patent/EP3231791B1/en active Active
Also Published As
Publication number | Publication date |
---|---|
EP3231791B1 (en) | 2021-09-15 |
US20170320817A1 (en) | 2017-11-09 |
WO2016093688A3 (es) | 2016-08-04 |
EP3231791A4 (en) | 2018-05-09 |
EP3231791A2 (en) | 2017-10-18 |
CA2970268C (en) | 2021-04-13 |
US11014875B2 (en) | 2021-05-25 |
WO2016093688A2 (es) | 2016-06-16 |
MX2014015226A (es) | 2016-06-10 |
WO2016093688A9 (es) | 2016-09-22 |
CA2970268A1 (en) | 2016-06-16 |
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Legal Events
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