MX362580B - Reduccion de eteres de hmf con un catalizador metalico. - Google Patents
Reduccion de eteres de hmf con un catalizador metalico.Info
- Publication number
- MX362580B MX362580B MX2014015367A MX2014015367A MX362580B MX 362580 B MX362580 B MX 362580B MX 2014015367 A MX2014015367 A MX 2014015367A MX 2014015367 A MX2014015367 A MX 2014015367A MX 362580 B MX362580 B MX 362580B
- Authority
- MX
- Mexico
- Prior art keywords
- methanol
- alkoxymethyl
- furan
- tetrahydrofuran
- compounds
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/54—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/18—Preparation of ethers by reactions not forming ether-oxygen bonds
- C07C41/26—Preparation of ethers by reactions not forming ether-oxygen bonds by introduction of hydroxy or O-metal groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
- C07C43/04—Saturated ethers
- C07C43/13—Saturated ethers containing hydroxy or O-metal groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
- C07D307/10—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/12—Radicals substituted by oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
- C07D307/10—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/16—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/40—Radicals substituted by oxygen atoms
- C07D307/42—Singly bound oxygen atoms
- C07D307/44—Furfuryl alcohol
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Furan Compounds (AREA)
- Catalysts (AREA)
Abstract
Esta exposición describe métodos para reducir éter de hidroximetilfurfural y derivados de éster para producir, en el caso de los éteres, 5-(alcoximetil)-tetrahidrofurano-2-metanol y derivados de (5-alcoximetil)-furano-2-metanol, o en el caso de los ésteres, 5-(aciloximetil)-tetrahidrofurano-2-metanol y derivados de 5-(aciloximetil)-furano-2-metanol. Los métodos ejemplificados describen la purificación de los mismos. Además, la exposición se refiere a compuestos de n-alcoxi hexano diol, que son compuestos derivados útiles para el reemplazo de compuestos de carbitol a base de petróleo y pueden producirse mediante la reducción adicional del 5-(alcoximetil)-tetrahidrofura no-2-metanol y derivados de (5-alcoximetil)-furano-2-metanol. Los compuestos producidos por los métodos de la presente enseñanza son útiles como solventes y como materiales de inicio para producir otras composiciones que satisfacen los requerimientos de los químicos industriales de base biológica provenientes de recursos renovables.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10963408P | 2008-10-30 | 2008-10-30 | |
PCT/US2009/062778 WO2010062689A2 (en) | 2008-10-30 | 2009-10-30 | Reduction of hmf ethers with metal catalyst |
Publications (1)
Publication Number | Publication Date |
---|---|
MX362580B true MX362580B (es) | 2019-01-25 |
Family
ID=42226332
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2014015367A MX362580B (es) | 2008-10-30 | 2009-10-30 | Reduccion de eteres de hmf con un catalizador metalico. |
MX2011004526A MX2011004526A (es) | 2008-10-30 | 2009-10-30 | Reduccion de eteres de hmf con un catalizador metalico. |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2011004526A MX2011004526A (es) | 2008-10-30 | 2009-10-30 | Reduccion de eteres de hmf con un catalizador metalico. |
Country Status (9)
Country | Link |
---|---|
US (4) | US8709286B2 (es) |
EP (1) | EP2350035B1 (es) |
CN (3) | CN103626639B (es) |
AU (1) | AU2009319998B2 (es) |
BR (1) | BRPI0914384B1 (es) |
ES (1) | ES2566649T3 (es) |
HU (1) | HUE029859T2 (es) |
MX (2) | MX362580B (es) |
WO (1) | WO2010062689A2 (es) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20090156841A1 (en) * | 2007-12-12 | 2009-06-18 | Sanborn Alexandra J | Conversion of carbohydrates to hydroxymethylfurfural (hmf) and derivatives |
MX362580B (es) * | 2008-10-30 | 2019-01-25 | Archer Daniels Midland Co | Reduccion de eteres de hmf con un catalizador metalico. |
US8889922B2 (en) | 2011-12-30 | 2014-11-18 | E I Du Pont De Nemours And Company | Process for preparing 1, 6-hexanediol |
US8889912B2 (en) | 2011-12-30 | 2014-11-18 | E I Du Pont De Nemours And Company | Process for preparing 1,6-hexanediol |
BR112014015994A2 (pt) | 2011-12-30 | 2018-05-22 | Du Pont | processo. |
US8884036B2 (en) | 2011-12-30 | 2014-11-11 | E I Du Pont De Nemours And Company | Production of hydroxymethylfurfural from levoglucosenone |
US8865940B2 (en) | 2011-12-30 | 2014-10-21 | E I Du Pont De Nemours And Company | Process for preparing 1,6-hexanediol |
CN104024197A (zh) | 2011-12-30 | 2014-09-03 | 纳幕尔杜邦公司 | 己二醇的制备方法 |
US8859826B2 (en) | 2012-04-27 | 2014-10-14 | E I Du Pont De Nemours And Company | Production of alpha, omega-diols |
US9018423B2 (en) | 2012-04-27 | 2015-04-28 | E I Du Pont De Nemours And Company | Production of alpha, omega-diols |
US8846984B2 (en) | 2012-04-27 | 2014-09-30 | E I Du Pont De Nemours And Company | Production of α,ω-diols |
CN103073526B (zh) * | 2012-12-26 | 2014-12-03 | 中国科学院宁波材料技术与工程研究所 | 一种2,5-二取代的四氢呋喃类混合物的制备方法 |
EP2989094A4 (en) * | 2013-04-25 | 2016-11-02 | Archer Daniels Midland Co | CATALYTIC SYNTHESIS OF REDUCED FURANDERIVATES |
EP3083577A4 (en) * | 2013-12-19 | 2017-08-16 | Archer Daniels Midland Co. | Sulfonates of furan-2,5-dimethanol and (tetrahydrofuran-2,5-diyl)dimethanol and derivatives thereof |
SG11201805514VA (en) | 2016-01-13 | 2018-07-30 | Stora Enso Oyj | Processes for the preparation of 2,5-furandicarboxylic acid and intermediates and derivatives thereof |
WO2017222532A1 (en) * | 2016-06-23 | 2017-12-28 | Archer Daniels Midland Company | Preparation of mono- and di-alkyl halide furanic compounds from 2,5-bis(hydroxymethyl)-tetrahydrofurans (bhmthf) and derivatives thereof |
BR112020000611B1 (pt) | 2017-07-12 | 2024-03-05 | Stora Enso Oyj | Produtos purificados de via de ácido 2,5-furanoodicarboxílico |
CN115697982A (zh) * | 2020-06-22 | 2023-02-03 | 东丽精细化工株式会社 | 四氢呋喃-2-羧酸的制造方法 |
Family Cites Families (32)
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GB798318A (en) * | 1954-11-29 | 1958-07-16 | Sadolin & Holmblad As | Improvements in or relating to furan compounds and the manufacture thereof |
DE1593864A1 (de) * | 1967-03-25 | 1971-02-25 | Bayer Ag | Verfahren zur Herstellung von Hydrazincarbonsaeureestern |
US4025558A (en) * | 1974-04-12 | 1977-05-24 | The Upjohn Company | Organic compounds |
US4221726A (en) * | 1978-04-24 | 1980-09-09 | Celanese Corporation | Process of making tetrahydrofuran |
US4263443A (en) * | 1978-11-22 | 1981-04-21 | Halcon Research And Development Corp. | Conversion of aldehydes |
US4459419A (en) * | 1982-09-02 | 1984-07-10 | Ethyl Corporation | Hydrogenation process using cationic ruthenium-containing zeolite |
US4605422A (en) * | 1984-03-30 | 1986-08-12 | Union Carbide Corporation | Oil-in-alcohol microemulsion |
US4610222A (en) * | 1984-07-23 | 1986-09-09 | Union Carbide Corporation | Cooling system using an oil-in-alcohol containing consolute antifreeze composition |
JP2948286B2 (ja) * | 1990-08-24 | 1999-09-13 | キヤノン株式会社 | インクジェット用インク及びそれを用いたインクジェット記録方法 |
FR2687152A1 (fr) * | 1992-02-07 | 1993-08-13 | Roussel Uclaf | Nouveaux esters pyrethrinouides derives d'alcool furanique ou thiophenique, leur procede de preparation et leur application comme pesticides. |
WO1996028437A1 (en) * | 1995-03-10 | 1996-09-19 | Hoechst Marion Roussel, Inc. | Novel process for preparing 2,3-dihydro-benzofuranol derivatives |
ES2156363T3 (es) * | 1996-03-01 | 2001-06-16 | Basf Ag | Procedimiento para la obtencion de 1,6-hexanodiol con una pureza mayor que un 99%. |
DE19860489B4 (de) | 1998-12-28 | 2008-05-08 | Basf Ag | Verfahren zur Hydrierung von Aldehyden und Verwendung eines Katalysators zur Reduktion eines Aldehyds zu einem Alkohol |
JP2002308864A (ja) * | 2001-04-11 | 2002-10-23 | Dainippon Jochugiku Co Ltd | 5−プロパルギルフルフリルアルコールの製造法 |
GB0406917D0 (en) * | 2004-03-26 | 2004-04-28 | Photocure Asa | Compounds |
CN100424524C (zh) * | 2004-09-09 | 2008-10-08 | 中国科学院上海技术物理研究所 | 锆钛酸铅反射膜片及制备方法 |
US7393963B2 (en) * | 2004-12-10 | 2008-07-01 | Archer-Daniels-Midland Company | Conversion of 2,5-(hydroxymethyl)furaldehyde to industrial derivatives, purification of the derivatives, and industrial uses therefor |
US7317116B2 (en) * | 2004-12-10 | 2008-01-08 | Archer-Daniels-Midland-Company | Processes for the preparation and purification of hydroxymethylfuraldehyde and derivatives |
JP5428161B2 (ja) * | 2006-01-13 | 2014-02-26 | 宇部興産株式会社 | 1,6−ヘキサンジオールの製造方法 |
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EP1834950A1 (en) * | 2006-03-10 | 2007-09-19 | Avantium International B.V. | Method for the synthesis of 5-alkoxymethylfurfural ethers and their use |
JP4804187B2 (ja) * | 2006-03-28 | 2011-11-02 | キヤノン株式会社 | フラン−2,5−ジカルボン酸の製造方法 |
US7994347B2 (en) * | 2006-06-09 | 2011-08-09 | Battelle Memorial Institute | Hydroxymethylfurfural reduction methods and methods of producing furandimethanol |
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US20100212218A1 (en) * | 2007-09-07 | 2010-08-26 | Furanix Technologies B.V. | 5-(substituted methyl) 2-methylfuran |
EA017997B1 (ru) * | 2007-09-07 | 2013-04-30 | Фураникс Технолоджиз Б.В. | 5-замещенные 2-(алкоксиметил)фураны |
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EP2128227A1 (en) * | 2008-05-19 | 2009-12-02 | Furanix Technologies B.V | Monosubstituted furan derivatives via decarboxylation and use thereof as (aviation) fuel |
EP2128277A1 (en) | 2008-05-29 | 2009-12-02 | Aga AB | Method for annealing metal strips |
MX362580B (es) * | 2008-10-30 | 2019-01-25 | Archer Daniels Midland Co | Reduccion de eteres de hmf con un catalizador metalico. |
CN101735725A (zh) * | 2008-11-21 | 2010-06-16 | 上海振华造漆厂 | 一种卷材通用环保聚氨酯底漆及其应用 |
US8859788B2 (en) * | 2012-06-22 | 2014-10-14 | Eastman Chemical Company | Esterification of furan-2,5-dicarboxylic acid to a dialkyl-furan-2,5-dicarboxylate vapor with rectification |
-
2009
- 2009-10-30 MX MX2014015367A patent/MX362580B/es unknown
- 2009-10-30 WO PCT/US2009/062778 patent/WO2010062689A2/en active Application Filing
- 2009-10-30 BR BRPI0914384A patent/BRPI0914384B1/pt active IP Right Grant
- 2009-10-30 MX MX2011004526A patent/MX2011004526A/es active IP Right Grant
- 2009-10-30 CN CN201310556918.XA patent/CN103626639B/zh active Active
- 2009-10-30 CN CN201610072994.7A patent/CN105801528B/zh active Active
- 2009-10-30 ES ES09829644.5T patent/ES2566649T3/es active Active
- 2009-10-30 EP EP09829644.5A patent/EP2350035B1/en active Active
- 2009-10-30 AU AU2009319998A patent/AU2009319998B2/en active Active
- 2009-10-30 HU HUE09829644A patent/HUE029859T2/en unknown
- 2009-10-30 CN CN200980140509.3A patent/CN102177146B/zh active Active
-
2011
- 2011-04-28 US US13/096,348 patent/US8709286B2/en active Active
-
2014
- 2014-03-17 US US14/215,264 patent/US9416119B2/en active Active
- 2014-03-17 US US14/215,157 patent/US9422258B2/en active Active
-
2016
- 2016-06-21 US US15/188,075 patent/US9783516B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
CN103626639B (zh) | 2016-12-07 |
BRPI0914384B1 (pt) | 2017-04-18 |
EP2350035B1 (en) | 2016-01-13 |
US20140200299A1 (en) | 2014-07-17 |
HUE029859T2 (en) | 2017-04-28 |
CN105801528B (zh) | 2019-06-21 |
BRPI0914384A2 (pt) | 2016-10-18 |
EP2350035A4 (en) | 2012-07-25 |
US20140239230A1 (en) | 2014-08-28 |
WO2010062689A2 (en) | 2010-06-03 |
US9416119B2 (en) | 2016-08-16 |
CN103626639A (zh) | 2014-03-12 |
US9422258B2 (en) | 2016-08-23 |
US8709286B2 (en) | 2014-04-29 |
MX2011004526A (es) | 2011-12-14 |
EP2350035A2 (en) | 2011-08-03 |
US9783516B2 (en) | 2017-10-10 |
CN105801528A (zh) | 2016-07-27 |
ES2566649T3 (es) | 2016-04-14 |
AU2009319998B2 (en) | 2015-07-16 |
WO2010062689A3 (en) | 2010-07-22 |
AU2009319998A1 (en) | 2010-06-03 |
US20120261618A1 (en) | 2012-10-18 |
CN102177146B (zh) | 2016-02-10 |
CN102177146A (zh) | 2011-09-07 |
US20160297788A1 (en) | 2016-10-13 |
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