MX337111B - Activadores de catalitizador de aluminoxano que contienen agentes carbocationes y uso de los mismos en catalizadores de poliolefina. - Google Patents

Activadores de catalitizador de aluminoxano que contienen agentes carbocationes y uso de los mismos en catalizadores de poliolefina.

Info

Publication number
MX337111B
MX337111B MX2013010313A MX2013010313A MX337111B MX 337111 B MX337111 B MX 337111B MX 2013010313 A MX2013010313 A MX 2013010313A MX 2013010313 A MX2013010313 A MX 2013010313A MX 337111 B MX337111 B MX 337111B
Authority
MX
Mexico
Prior art keywords
carbocation
agents
catalyst activators
polyolefin catalysts
aluminoxane catalyst
Prior art date
Application number
MX2013010313A
Other languages
English (en)
Other versions
MX2013010313A (es
Inventor
Lubin Luo
Xiao Wu
Steven P Diefenbach
Original Assignee
Albemarle Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Albemarle Corp filed Critical Albemarle Corp
Publication of MX2013010313A publication Critical patent/MX2013010313A/es
Publication of MX337111B publication Critical patent/MX337111B/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/622—Component covered by group C08F4/62 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Esta invención se relaciona con una composición activadora que comprende: (i) un compuesto de organoaluminio; (ii) un compuesto carbocatión de la fórmula R1(X)n; en donde R1 es un hidrocarbilo; n es de 1 al número de posibles sustituciones del grupo hidrocarbilo y cada X es un grupo saliente lábil; (iii) un aluminoxano. La composición activadora puede contener además un soporte portador. Esta invención proporciona además una composición catalizadora que comprende la composición activadora descrita anteriormente y un componente de metal de transición. Esta invención proporciona además métodos para polimerizar monómeros que comprende llevar a cabo la polimerización en presencia de una o más composiciones catalizadoras de acuerdo con esta invención.
MX2013010313A 2011-03-09 2012-03-08 Activadores de catalitizador de aluminoxano que contienen agentes carbocationes y uso de los mismos en catalizadores de poliolefina. MX337111B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201161450696P 2011-03-09 2011-03-09
PCT/US2012/028188 WO2012122332A1 (en) 2011-03-09 2012-03-08 Aluminoxane catalyst activators containing carbocation agents, and use thereof in polyolefin catalysts

Publications (2)

Publication Number Publication Date
MX2013010313A MX2013010313A (es) 2014-02-11
MX337111B true MX337111B (es) 2016-02-12

Family

ID=45879038

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2013010313A MX337111B (es) 2011-03-09 2012-03-08 Activadores de catalitizador de aluminoxano que contienen agentes carbocationes y uso de los mismos en catalizadores de poliolefina.

Country Status (14)

Country Link
US (1) US9090720B2 (es)
EP (1) EP2683749B1 (es)
JP (1) JP6012640B2 (es)
KR (1) KR101902181B1 (es)
CN (1) CN103534278B (es)
BR (1) BR112013022702B1 (es)
CA (1) CA2828936C (es)
ES (1) ES2951057T3 (es)
HU (1) HUE062901T2 (es)
MX (1) MX337111B (es)
PT (1) PT2683749T (es)
SG (1) SG193257A1 (es)
TW (1) TWI555574B (es)
WO (1) WO2012122332A1 (es)

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US11021552B2 (en) 2017-10-31 2021-06-01 Exxonmobil Chemical Patents Inc. Toluene free silica supported single-site metallocene catalysts from in-situ supported alumoxane formation in aliphatic solvents
US20230242745A1 (en) 2020-06-03 2023-08-03 Exxonmobil Chemical Patents Inc Process for Production of Thermoplastic Vulcanizates using Supported Catalyst Systems and Compositions Made Therefrom
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Also Published As

Publication number Publication date
WO2012122332A1 (en) 2012-09-13
CA2828936C (en) 2019-03-26
ES2951057T3 (es) 2023-10-17
EP2683749B1 (en) 2023-06-07
CN103534278B (zh) 2016-10-05
CN103534278A (zh) 2014-01-22
KR20140007450A (ko) 2014-01-17
US20130345376A1 (en) 2013-12-26
BR112013022702B1 (pt) 2022-06-14
TW201244821A (en) 2012-11-16
SG193257A1 (en) 2013-10-30
JP2014507550A (ja) 2014-03-27
CA2828936A1 (en) 2012-09-13
BR112013022702A2 (pt) 2020-05-19
US9090720B2 (en) 2015-07-28
MX2013010313A (es) 2014-02-11
KR101902181B1 (ko) 2018-09-28
JP6012640B2 (ja) 2016-10-25
HUE062901T2 (hu) 2023-12-28
TWI555574B (zh) 2016-11-01
PT2683749T (pt) 2023-06-27
EP2683749A1 (en) 2014-01-15

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