MX2019002553A - Catalizador mejorado para la oxidacion selectiva de sulfuro de hidrogeno. - Google Patents

Catalizador mejorado para la oxidacion selectiva de sulfuro de hidrogeno.

Info

Publication number
MX2019002553A
MX2019002553A MX2019002553A MX2019002553A MX2019002553A MX 2019002553 A MX2019002553 A MX 2019002553A MX 2019002553 A MX2019002553 A MX 2019002553A MX 2019002553 A MX2019002553 A MX 2019002553A MX 2019002553 A MX2019002553 A MX 2019002553A
Authority
MX
Mexico
Prior art keywords
hydrogen sulfide
catalyst
selective oxidation
improved catalyst
metal oxide
Prior art date
Application number
MX2019002553A
Other languages
English (en)
Inventor
Van Warners Anne
Roelofs Tobias
Original Assignee
Jacobs Nederland Bv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jacobs Nederland Bv filed Critical Jacobs Nederland Bv
Publication of MX2019002553A publication Critical patent/MX2019002553A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8603—Removing sulfur compounds
    • B01D53/8612—Hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/638—Pore volume more than 1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/10—Oxidants
    • B01D2251/102—Oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/204—Alkaline earth metals
    • B01D2255/2047—Magnesium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20723—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/2073—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20738—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20746—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20761—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/02—Processes carried out in the presence of solid particles; Reactors therefor with stationary particles
    • B01J2208/023—Details
    • B01J2208/024—Particulate material
    • B01J2208/025—Two or more types of catalyst

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)

Abstract

La invención se dirige a un lecho de catalizador para la oxidación selectiva de sulfuro de hidrógeno, el lecho de catalizador comprende una primera capa de catalizador y una segunda capa de catalizador, en donde la primera capa de catalizador comprende primeras partículas de catalizador que comprenden un primer material de soporte y un primer óxido de metal y la segunda capa de catalizador comprende segundas partículas de catalizador que comprenden un segundo material de soporte y un segundo óxido de metal, en donde las primeras partículas de catalizador tienen una mayor carga de óxido de metal a diferencia de las segundas partículas de catalizador. En aspectos adicionales, la invención se dirige a un proceso para la oxidación selectiva de sulfuro de hidrógeno, que comprende pasar una corriente de gas que comprende sulfuro de hidrógeno por un lecho de catalizador y a un proceso para la oxidación selectiva de sulfuro de hidrógeno que comprende el lecho de catalizador.
MX2019002553A 2016-09-26 2017-09-26 Catalizador mejorado para la oxidacion selectiva de sulfuro de hidrogeno. MX2019002553A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL2017533A NL2017533B1 (en) 2016-09-26 2016-09-26 Improved catalyst for the selective oxidation of hydrogen sulfide
PCT/NL2017/050644 WO2018056828A1 (en) 2016-09-26 2017-09-26 Improved catalyst for the selective oxidation of hydrogen sulfide

Publications (1)

Publication Number Publication Date
MX2019002553A true MX2019002553A (es) 2019-09-18

Family

ID=57394646

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2019002553A MX2019002553A (es) 2016-09-26 2017-09-26 Catalizador mejorado para la oxidacion selectiva de sulfuro de hidrogeno.

Country Status (10)

Country Link
EP (1) EP3515591B1 (es)
CN (1) CN109789394B (es)
CA (1) CA3035005A1 (es)
ES (1) ES2957293T3 (es)
FI (1) FI3515591T3 (es)
MX (1) MX2019002553A (es)
NL (1) NL2017533B1 (es)
RU (1) RU2719369C1 (es)
SA (1) SA519401283B1 (es)
WO (1) WO2018056828A1 (es)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2766555C1 (ru) * 2021-05-21 2022-03-15 Акционерное общество "Специальное конструкторско-технологическое бюро "Катализатор" Катализатор для селективного окисления сероводорода и способ его применения

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL8600959A (nl) 1986-04-16 1987-11-16 Veg Gasinstituut Nv Katalysator voor de selectieve oxydatie van zwavelhoudende verbindingen, in het bizonder zwavelwaterstof tot elementaire zwavel; werkwijze voor de bereiding van de katalysator alsmede werkwijze voor de selectieve oxydatie van zwavelhoudende verbindingen, in het bizonder zwavelwaterstof tot elementaire zwavel.
NL8901893A (nl) * 1989-07-21 1991-02-18 Veg Gasinstituut Nv Katalysator voor de selectieve oxidatie van zwavelverbindingen tot elementaire zwavel, werkwijze voor de bereiding van een dergelijke katalysator en werkwijze voor de selectieve oxidatie van zwavelverbindingen tot elementaire zwavel.
WO2000010693A1 (en) * 1998-08-25 2000-03-02 Gastec N.V. A process for the recovery of sulphur from a hydrogen sulphide, containing gas
EP1090675A1 (en) * 1999-09-30 2001-04-11 Gastec N.V. Process for the removal of sulphur compounds from gases
AU2002245146B2 (en) * 2000-12-18 2007-12-13 Phillips 66 Company Sulfur recovery process
EP1442781A1 (en) * 2003-01-31 2004-08-04 Jacobs Nederland B.V. Process for the removal of SO2 in a gas stream
EP1555241A1 (en) * 2004-01-16 2005-07-20 Jacobs Nederland B.V. Recovery of sulfur from a hydrogen sulfide containing gas
RU2276097C2 (ru) * 2004-07-23 2006-05-10 Институт Катализа Им. Г.К. Борескова Сибирского Отделения Российской Академии Наук Способ селективного каталитического окисления сероводорода в серу
RU2430014C1 (ru) * 2010-03-31 2011-09-27 Открытое акционерное общество "Гипрогазоочистка" Способ получения серы из кислых газов с низким содержанием сероводорода
US8486365B2 (en) * 2011-04-01 2013-07-16 Tofik Gasan Alkhazov Process of conversion of hydrogen sulfide into elemental sulfur on solid oxide catalysts
MX2013015351A (es) * 2011-06-21 2014-04-25 Jacobs Nederland Bv Desgasificacion de azufre catalitico.
RU2535041C2 (ru) * 2012-12-25 2014-12-10 Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук Способ очистки газовых потоков от сероводорода
CN104248966B (zh) * 2013-06-25 2016-08-17 中国石油化工股份有限公司 硫化氢选择氧化制硫催化剂及其制备方法
CN104475104B (zh) * 2014-11-05 2018-03-23 杨楠 选择性催化氧化硫化氢催化剂、尾气焚烧催化剂及深度催化氧化硫化氢为硫磺的工艺
CN105347311B (zh) * 2015-11-23 2018-05-08 山东迅达化工集团有限公司 H2s选择性氧化生成单质硫的工艺方法
CN105314607B (zh) * 2015-12-01 2018-05-08 山东迅达化工集团有限公司 中间浓度酸性气的低硫排放硫磺回收工艺

Also Published As

Publication number Publication date
CN109789394B (zh) 2022-03-01
WO2018056828A1 (en) 2018-03-29
EP3515591B1 (en) 2023-09-06
NL2017533B1 (en) 2018-04-04
FI3515591T3 (fi) 2023-09-25
CA3035005A1 (en) 2018-03-29
ES2957293T3 (es) 2024-01-16
SA519401283B1 (ar) 2022-05-22
RU2719369C1 (ru) 2020-04-17
CN109789394A (zh) 2019-05-21
EP3515591A1 (en) 2019-07-31

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