MX2014006759A - Produccion de xilenos por metilacion de compuestos aromaticos. - Google Patents
Produccion de xilenos por metilacion de compuestos aromaticos.Info
- Publication number
- MX2014006759A MX2014006759A MX2014006759A MX2014006759A MX2014006759A MX 2014006759 A MX2014006759 A MX 2014006759A MX 2014006759 A MX2014006759 A MX 2014006759A MX 2014006759 A MX2014006759 A MX 2014006759A MX 2014006759 A MX2014006759 A MX 2014006759A
- Authority
- MX
- Mexico
- Prior art keywords
- xylenes
- methylation
- production
- aromatic compounds
- methanol
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
- C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
- C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/02—Monocyclic hydrocarbons
- C07C15/067—C8H10 hydrocarbons
- C07C15/08—Xylenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
El método inventivo se dirige a la producción de xilenos por metilación de compuestos aromáticos con metanol. El proceso usa reactores de lecho fijo, opera a una presión menor, y sin la necesidad de hidrógeno u otro reciclaje de gas.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201161568313P | 2011-12-08 | 2011-12-08 | |
PCT/US2012/068477 WO2013086342A1 (en) | 2011-12-08 | 2012-12-07 | Production of xylenes by methylation of aromatic compounds |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2014006759A true MX2014006759A (es) | 2015-03-03 |
Family
ID=48572604
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2014006759A MX2014006759A (es) | 2011-12-08 | 2012-12-07 | Produccion de xilenos por metilacion de compuestos aromaticos. |
Country Status (13)
Country | Link |
---|---|
US (1) | US20130150640A1 (es) |
EP (1) | EP2788304A4 (es) |
JP (1) | JP6276193B2 (es) |
KR (1) | KR102049289B1 (es) |
CN (1) | CN104169242B (es) |
AU (1) | AU2012347625A1 (es) |
BR (1) | BR112014013927A8 (es) |
IL (1) | IL232961A (es) |
MX (1) | MX2014006759A (es) |
RU (1) | RU2624013C2 (es) |
SA (1) | SA116370705B1 (es) |
TW (1) | TWI623511B (es) |
WO (1) | WO2013086342A1 (es) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9919984B2 (en) * | 2013-08-23 | 2018-03-20 | Hindustan Petroleum Corporation Limited | Process for the preparation of isomers of xylene |
RU2558955C1 (ru) * | 2014-08-12 | 2015-08-10 | Общество С Ограниченной Ответственностью "Новые Газовые Технологии-Синтез" | Способ получения концентрата ароматических углеводородов из жидких углеводородных фракций и установка для его осуществления |
CN105018128B (zh) * | 2014-04-24 | 2017-03-22 | 中国石油化工股份有限公司 | 制备高辛烷值汽油组分的方法及催化剂 |
CN105272797B (zh) * | 2014-06-03 | 2017-05-24 | 中国石油化工股份有限公司 | 一种苯与甲醇烷基化反应的方法 |
CN104109065B (zh) * | 2014-06-07 | 2016-01-06 | 宁夏宝塔石化科技实业发展有限公司 | 一种由苯和甲醇烷基化制二甲苯的方法 |
WO2016032636A1 (en) * | 2014-08-26 | 2016-03-03 | Exxonmobil Chemical Patents Inc. | Treatment of off-gas in the production of para-xylene by the methylation of toluene and/or benzene |
KR101972842B1 (ko) * | 2015-05-27 | 2019-04-26 | 한양대학교 산학협력단 | 글리세롤을 이용한 바이오 방향족 화합물의 제조방법 |
WO2018118592A1 (en) * | 2016-12-20 | 2018-06-28 | Uop Llc | Processes and apparatuses for toluene methylation in an aromatics complex |
CN107413375A (zh) * | 2017-04-12 | 2017-12-01 | 兰州理工大学 | 苯烷基化制备甲苯的催化剂制备方法 |
CN108794287B (zh) * | 2017-04-27 | 2020-08-11 | 中国科学院大连化学物理研究所 | 一种制低碳烯烃联产对二甲苯的方法 |
CN107649172B (zh) * | 2017-09-08 | 2020-04-17 | 浙江大学 | 一种甲苯烷基化制对二甲苯的催化剂的制备方法 |
CN108623428B (zh) * | 2018-06-27 | 2020-11-03 | 大连理工大学 | 一种苯和甲醇烷基化的反应方法 |
CN112521243B (zh) * | 2019-09-19 | 2023-07-04 | 中国石油化工股份有限公司 | 一种长周期运转甲苯甲醇甲基化反应的方法及*** |
CN110746256A (zh) * | 2019-11-07 | 2020-02-04 | 常州瑞华化工工程技术股份有限公司 | 一种苯和/或甲苯甲基化提高甲基化率的方法 |
CN114057538B (zh) * | 2020-07-31 | 2023-11-10 | 中国石油化工股份有限公司 | 一种含乙烯气体和苯气相烷基化制乙苯的方法 |
JP7321207B2 (ja) * | 2021-04-30 | 2023-08-04 | 千代田化工建設株式会社 | パラキシレンの製造方法 |
Family Cites Families (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3755483A (en) * | 1972-04-28 | 1973-08-28 | Mobil Oil | Vapor phase alkylation in presence of crystalline aluminosilicate catalyst |
US3751506A (en) * | 1972-05-12 | 1973-08-07 | Mobil Oil Corp | Vapor-phase alkylation in presence of crystalline aluminosilicate catalyst |
US4001346A (en) * | 1975-01-06 | 1977-01-04 | Mobil Oil Corporation | Selective production of para-xylene |
US4029716A (en) * | 1975-12-08 | 1977-06-14 | Mobil Oil Corporation | Selective production of para-xylene |
US4090981A (en) * | 1976-09-23 | 1978-05-23 | Mobile Oil Corporation | Catalyst for selective production of para dialkyl substituted benzenes |
US4117026A (en) * | 1976-05-12 | 1978-09-26 | Mobil Oil Corporation | Selective production of para dialkyl substituted benzenes |
US4390414A (en) * | 1981-12-16 | 1983-06-28 | Exxon Research And Engineering Co. | Selective dewaxing of hydrocarbon oil using surface-modified zeolites |
US4491678A (en) * | 1982-10-19 | 1985-01-01 | Idemitsu Kosan Company Limited | Process for the production of para-xylene |
US4447666A (en) * | 1982-12-30 | 1984-05-08 | Mobil Oil Corporation | Para-selective alkylation catalysts and processes |
US5336821A (en) * | 1993-05-06 | 1994-08-09 | Uop | Alkylation process with reactor effluent heat recovery |
JP4240339B2 (ja) * | 1994-10-03 | 2009-03-18 | 山陽石油化学株式会社 | 芳香族炭化水素の製造方法 |
KR100228997B1 (ko) * | 1994-10-03 | 1999-11-01 | 테라사끼 이와오 | 방향족 탄화수소의 제조방법 |
CA2206891C (en) * | 1994-11-23 | 2007-03-20 | Exxon Chemical Patents, Inc. | Hydrocarbon conversion process using a zeolite bound zeolite catalyst |
EP0912473B1 (en) * | 1996-05-29 | 2003-04-16 | ExxonMobil Chemical Patents Inc. | Methylation of toluene to para-xylene |
ZA978671B (en) * | 1996-10-02 | 1999-03-26 | Mobil Oil Corp | Selective para-xylene production by toluene methylation |
US6046372A (en) * | 1996-10-02 | 2000-04-04 | Mobil Oil Corporation | Process for producing light olefins |
US6423879B1 (en) * | 1997-10-02 | 2002-07-23 | Exxonmobil Oil Corporation | Selective para-xylene production by toluene methylation |
AU2484099A (en) * | 1998-01-30 | 1999-08-16 | Exxon Chemical Patents Inc. | Reactive distillation process for the production of xylenes |
US6642426B1 (en) * | 1998-10-05 | 2003-11-04 | David L. Johnson | Fluid-bed aromatics alkylation with staged injection of alkylating agents |
US7186873B2 (en) * | 2002-06-19 | 2007-03-06 | Exxonmobil Chemical Patents Inc. | Manufacture of xylenes by reactive distillation of reformate |
US7119239B2 (en) * | 2002-06-19 | 2006-10-10 | Exxonmobil Chemical Patents Inc. | Manufacture of xylenes using reformate |
GB0303659D0 (en) * | 2003-02-18 | 2003-03-19 | Johnson Matthey Plc | Process |
JP4843501B2 (ja) * | 2003-12-31 | 2011-12-21 | エクソンモービル・ケミカル・パテンツ・インク | 芳香族のアルキル化プロセス |
US6943131B1 (en) * | 2004-03-02 | 2005-09-13 | Saudi Basic Industries Corporation | Selective zeolite catalyst modification |
US8134036B2 (en) * | 2008-03-13 | 2012-03-13 | Fina Technology Inc | Process for liquid phase alkylation |
US8115041B2 (en) * | 2008-04-02 | 2012-02-14 | Saudi Basic Industries Corporation | Pretreatment of a phosphorus-modified zeolite catalyst for an aromatic alkylation process |
JP5732189B2 (ja) * | 2009-03-19 | 2015-06-10 | Jx日鉱日石エネルギー株式会社 | トルエンのアルキル化反応又は不均化反応によるパラキシレン製造用の触媒及びその製造方法、並びにそれを用いたパラキシレンの製造方法 |
US8558046B2 (en) * | 2009-05-28 | 2013-10-15 | Saudi Basic Industries Corporation | Aromatic alkylation process |
US8399727B2 (en) * | 2009-10-21 | 2013-03-19 | Exxonmobil Chemical Patents Inc. | Production of para-xylene by the methylation of benzene and/or toluene |
CN103596907B (zh) * | 2011-06-10 | 2016-04-27 | 埃克森美孚化学专利公司 | 对二甲苯的生产 |
-
2012
- 2012-12-07 EP EP12855150.4A patent/EP2788304A4/en not_active Withdrawn
- 2012-12-07 RU RU2014127190A patent/RU2624013C2/ru active
- 2012-12-07 KR KR1020147018748A patent/KR102049289B1/ko active IP Right Grant
- 2012-12-07 TW TW101146080A patent/TWI623511B/zh active
- 2012-12-07 AU AU2012347625A patent/AU2012347625A1/en not_active Abandoned
- 2012-12-07 US US13/708,249 patent/US20130150640A1/en not_active Abandoned
- 2012-12-07 BR BR112014013927A patent/BR112014013927A8/pt not_active IP Right Cessation
- 2012-12-07 MX MX2014006759A patent/MX2014006759A/es unknown
- 2012-12-07 JP JP2014546123A patent/JP6276193B2/ja active Active
- 2012-12-07 WO PCT/US2012/068477 patent/WO2013086342A1/en active Application Filing
- 2012-12-07 CN CN201280060525.3A patent/CN104169242B/zh not_active Expired - Fee Related
- 2012-12-08 SA SA116370705A patent/SA116370705B1/ar unknown
-
2014
- 2014-06-05 IL IL232961A patent/IL232961A/en active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
KR20140110912A (ko) | 2014-09-17 |
SA116370705B1 (ar) | 2017-08-24 |
EP2788304A4 (en) | 2015-08-26 |
CN104169242B (zh) | 2017-07-14 |
BR112014013927A2 (pt) | 2017-06-13 |
KR102049289B1 (ko) | 2019-11-27 |
CN104169242A (zh) | 2014-11-26 |
TW201332941A (zh) | 2013-08-16 |
JP2015507612A (ja) | 2015-03-12 |
US20130150640A1 (en) | 2013-06-13 |
BR112014013927A8 (pt) | 2017-06-13 |
TWI623511B (zh) | 2018-05-11 |
AU2012347625A1 (en) | 2014-07-17 |
IL232961A (en) | 2017-01-31 |
WO2013086342A1 (en) | 2013-06-13 |
RU2624013C2 (ru) | 2017-06-30 |
IL232961A0 (en) | 2014-08-03 |
RU2014127190A (ru) | 2016-01-27 |
JP6276193B2 (ja) | 2018-02-07 |
EP2788304A1 (en) | 2014-10-15 |
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