MX2010006201A - Lubricating composition for four stroke engine with low ash content. - Google Patents
Lubricating composition for four stroke engine with low ash content.Info
- Publication number
- MX2010006201A MX2010006201A MX2010006201A MX2010006201A MX2010006201A MX 2010006201 A MX2010006201 A MX 2010006201A MX 2010006201 A MX2010006201 A MX 2010006201A MX 2010006201 A MX2010006201 A MX 2010006201A MX 2010006201 A MX2010006201 A MX 2010006201A
- Authority
- MX
- Mexico
- Prior art keywords
- astm
- integer
- standard
- ash content
- measured according
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M161/00—Lubricating compositions characterised by the additive being a mixture of a macromolecular compound and a non-macromolecular compound, each of these compounds being essential
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/102—Aliphatic fractions
- C10M2203/1025—Aliphatic fractions used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/026—Butene
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
- C10M2205/0285—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/287—Partial esters
- C10M2207/289—Partial esters containing free hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/043—Ammonium or amine salts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/045—Metal containing thio derivatives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/04—Detergent property or dispersant property
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/40—Low content or no content compositions
- C10N2030/42—Phosphor free or low phosphor content compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/40—Low content or no content compositions
- C10N2030/43—Sulfur free or low sulfur content compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/40—Low content or no content compositions
- C10N2030/45—Ash-less or low ash content
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/54—Fuel economy
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The invention relates to a lubricating composition for a four-stroke engine with a low ash content, that comprises : a) one or more base oils selected from oils of groups I to V, preferably from oils of groups III or FV of the API classification; b) at least one compound (b) selected from the group of heavy PAO with a kinematic viscosity at 100°C of between 75 and 3000 est, optionally mixed with one or more compounds selected in the group of polymer compounds of the polyisobutene (PIB) type or a mixture thereof; and c) at least one ester of the formula R(OH)m, (COOR' (OH)p)n in which m is an integer from 0 to 8, preferably from 1 to 4, n is an integer from 1 to 8, preferably from 1 to 4, and p is an integer from 0 to 8, preferably from 1 to 4, wherein the sum p+m is strictly higher than zero, R and Râ independently represent a linear or branched, saturated or unsaturated hydrocarbon group optionally substituted by one or more aromatic groups and including from 1 to 30 carbon atoms, or the borate derivatives thereof; wherein said composition has a sulphated ash content lower than or equal 0.5% as measured according to the ASTM D874 standard, a phosphorus content lower than or equal to 500 ppm as measured according to the ASTM D5185 standard, and a sulphur content lower than 0.2% as measured according to the ASTM D5185 standard. The composition has good detergency properties, and the use thereof enhances fuel savings.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0708423A FR2924439B1 (en) | 2007-12-03 | 2007-12-03 | LUBRICATING COMPOSITION FOR FOUR-STROKE ENGINE WITH LOW ASH RATES |
PCT/FR2008/001668 WO2009101276A1 (en) | 2007-12-03 | 2008-12-02 | Lubricating composition for four stroke engine with low ash content |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2010006201A true MX2010006201A (en) | 2010-08-26 |
Family
ID=39561733
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2010006201A MX2010006201A (en) | 2007-12-03 | 2008-12-02 | Lubricating composition for four stroke engine with low ash content. |
Country Status (10)
Country | Link |
---|---|
US (1) | US20110059877A1 (en) |
EP (1) | EP2245125A1 (en) |
JP (1) | JP5651015B2 (en) |
KR (1) | KR20100111268A (en) |
CN (1) | CN101932683A (en) |
BR (1) | BRPI0822348A2 (en) |
CA (1) | CA2707668A1 (en) |
FR (1) | FR2924439B1 (en) |
MX (1) | MX2010006201A (en) |
WO (1) | WO2009101276A1 (en) |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2891701B1 (en) * | 2009-08-18 | 2019-07-03 | The Lubrizol Corporation | Lubricating composition containing a corrosion inhibitor |
BR112012003696A2 (en) * | 2009-08-18 | 2016-03-29 | Lubrizol Corp | anti-wear composition and lubrication method of an internal combustion engine |
FR2951456B1 (en) * | 2009-10-16 | 2011-12-09 | Total Raffinage Marketing | ENGINE LUBRICANT |
UA109139C2 (en) | 2010-06-25 | 2015-07-27 | APPLICATIONS AND COMPOSITIONS | |
PL2633009T3 (en) | 2010-10-26 | 2016-10-31 | Non-aqueous lubricant and fuel compositions comprising fatty acid esters of hydroxy- carboxylic acids, and uses thereof | |
CA2827472C (en) | 2011-02-16 | 2019-08-20 | The Lubrizol Corporation | Lubricating composition and method of lubricating driveline device |
FR2974111B1 (en) | 2011-04-14 | 2013-05-10 | Total Raffinage Marketing | LUBRICANT CYLINDER FOR MARINE ENGINE TWO TIMES |
FR2980799B1 (en) | 2011-09-29 | 2013-10-04 | Total Raffinage Marketing | LUBRICATING COMPOSITION FOR MARINE ENGINE |
FR2990213B1 (en) | 2012-05-04 | 2015-04-24 | Total Raffinage Marketing | LUBRICATING COMPOSITION FOR ENGINE |
FR2992655B1 (en) * | 2012-06-29 | 2015-07-31 | Total Raffinage Marketing | LUBRICANT COMPOSITION |
FR2998303B1 (en) | 2012-11-16 | 2015-04-10 | Total Raffinage Marketing | LUBRICANT COMPOSITION |
FR3000103B1 (en) | 2012-12-21 | 2015-04-03 | Total Raffinage Marketing | LUBRICATING COMPOSITION BASED ON POLYGLYCEROL ETHER |
CN103045333B (en) * | 2013-01-28 | 2014-08-13 | 中国人民解放军总装备部军械技术研究所 | Synthetic lubricating oil composition for high and low temperature and preparation method thereof |
FR3005474B1 (en) | 2013-05-07 | 2016-09-09 | Total Raffinage Marketing | LUBRICANT FOR MARINE ENGINE |
GB201317278D0 (en) | 2013-09-30 | 2013-11-13 | Croda Int Plc | Gear oil composition |
US11041137B2 (en) | 2013-10-29 | 2021-06-22 | Croda, Inc. | Lubricant composition comprising hydroxycarboxylic acid derived friction modifier |
FR3018079B1 (en) | 2014-02-28 | 2017-06-23 | Total Marketing Services | LUBRICATING COMPOSITION BASED ON METALLIC NANOPARTICLES |
JP6569146B2 (en) * | 2015-03-31 | 2019-09-04 | 出光興産株式会社 | Lubricating oil composition for 4-cycle engine |
WO2016159215A1 (en) * | 2015-03-31 | 2016-10-06 | 出光興産株式会社 | Lubricating oil composition for four stroke engine |
JP6572597B2 (en) * | 2015-03-31 | 2019-09-11 | 出光興産株式会社 | Lubricating oil composition for 4-cycle engine |
JP6687347B2 (en) * | 2015-08-28 | 2020-04-22 | コスモ石油ルブリカンツ株式会社 | Engine oil composition |
FR3053697B1 (en) * | 2016-07-07 | 2019-08-16 | Total Marketing Services | LUBRICATING COMPOSITION FOR GAS ENGINE |
CN107312598B (en) * | 2017-06-30 | 2021-02-02 | 北京雅士科莱恩石油化工有限公司 | Low-temperature overweight load synthetic gear oil |
WO2019173427A1 (en) | 2018-03-06 | 2019-09-12 | Valvoline Licensing And Intellectual Property Llc | Traction fluid composition |
CN109735382A (en) * | 2018-12-29 | 2019-05-10 | 北京特森特能源科技有限公司 | Energy-saving environmental-protection petrol engine lubricating oil and preparation method thereof |
CA3130106C (en) | 2019-03-13 | 2023-05-02 | Valvoline Licensing And Intellectual Property Llc | Novel traction fluid with improved low temperature properties |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7014A (en) * | 1850-01-15 | Folding bedstead | ||
FR2512458A1 (en) * | 1981-09-10 | 1983-03-11 | Lubrizol Corp | COMPOSITIONS, CONCENTRATES, LUBRICATING COMPOSITIONS AND METHODS FOR INCREASING FUEL SAVINGS IN INTERNAL COMBUSTION ENGINES |
JP5127102B2 (en) * | 2001-09-06 | 2013-01-23 | Jx日鉱日石エネルギー株式会社 | Lubricating oil composition for internal combustion engines |
CA2474959C (en) * | 2003-08-07 | 2009-11-10 | Infineum International Limited | A lubricating oil composition |
US7256162B2 (en) * | 2003-09-26 | 2007-08-14 | Arizona Chemical Company | Fatty acid esters and uses thereof |
JP2005200447A (en) * | 2004-01-13 | 2005-07-28 | Mitsui Chemicals Inc | Lubricating oil additive and lubricating oil composition |
US7696136B2 (en) * | 2004-03-11 | 2010-04-13 | Crompton Corporation | Lubricant compositions containing hydroxy carboxylic acid and hydroxy polycarboxylic acid esters |
US7867955B2 (en) * | 2004-07-30 | 2011-01-11 | Infineum International Limited | Lubricating oil composition |
EP1632552A1 (en) * | 2004-09-06 | 2006-03-08 | Infineum International Limited | Lubricating oil composition |
US7807611B2 (en) * | 2004-10-12 | 2010-10-05 | The Lubrizol Corporation | Tartaric acid derivatives as fuel economy improvers and antiwear agents in crankcase oils and preparation thereof |
US20070142242A1 (en) * | 2005-12-15 | 2007-06-21 | Gleeson James W | Lubricant oil compositions containing GTL base stock(s) and/or base oil(s) and having improved resistance to the loss of viscosity and weight and a method for improving the resistance to loss of viscosity and weight of GTL base stock(s) and/or base oil(s) lubricant oil formulations |
-
2007
- 2007-12-03 FR FR0708423A patent/FR2924439B1/en not_active Expired - Fee Related
-
2008
- 2008-12-02 CN CN2008801260511A patent/CN101932683A/en active Pending
- 2008-12-02 WO PCT/FR2008/001668 patent/WO2009101276A1/en active Application Filing
- 2008-12-02 CA CA2707668A patent/CA2707668A1/en not_active Abandoned
- 2008-12-02 KR KR1020107012133A patent/KR20100111268A/en not_active Application Discontinuation
- 2008-12-02 JP JP2010536500A patent/JP5651015B2/en not_active Expired - Fee Related
- 2008-12-02 BR BRPI0822348A patent/BRPI0822348A2/en not_active IP Right Cessation
- 2008-12-02 US US12/745,861 patent/US20110059877A1/en not_active Abandoned
- 2008-12-02 MX MX2010006201A patent/MX2010006201A/en unknown
- 2008-12-02 EP EP08872409A patent/EP2245125A1/en not_active Withdrawn
Also Published As
Publication number | Publication date |
---|---|
KR20100111268A (en) | 2010-10-14 |
US20110059877A1 (en) | 2011-03-10 |
FR2924439A1 (en) | 2009-06-05 |
FR2924439B1 (en) | 2010-10-22 |
JP2011505484A (en) | 2011-02-24 |
CN101932683A (en) | 2010-12-29 |
JP5651015B2 (en) | 2015-01-07 |
WO2009101276A1 (en) | 2009-08-20 |
CA2707668A1 (en) | 2009-08-20 |
EP2245125A1 (en) | 2010-11-03 |
BRPI0822348A2 (en) | 2016-11-01 |
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