MX2009000597A - Proceso para preparar acidos alfa-hidroxicarboxilicos. - Google Patents
Proceso para preparar acidos alfa-hidroxicarboxilicos.Info
- Publication number
- MX2009000597A MX2009000597A MX2009000597A MX2009000597A MX2009000597A MX 2009000597 A MX2009000597 A MX 2009000597A MX 2009000597 A MX2009000597 A MX 2009000597A MX 2009000597 A MX2009000597 A MX 2009000597A MX 2009000597 A MX2009000597 A MX 2009000597A
- Authority
- MX
- Mexico
- Prior art keywords
- alpha
- alcohol
- hydroxycarboxamide
- ammonia
- bar
- Prior art date
Links
- 239000002253 acid Substances 0.000 title 1
- 150000007513 acids Chemical class 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 5
- 229910021529 ammonia Inorganic materials 0.000 abstract 4
- 239000003054 catalyst Substances 0.000 abstract 4
- 239000000376 reactant Substances 0.000 abstract 4
- 150000002148 esters Chemical class 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- 238000010924 continuous production Methods 0.000 abstract 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/18—Preparation of carboxylic acid esters by conversion of a group containing nitrogen into an ester group
- C07C67/20—Preparation of carboxylic acid esters by conversion of a group containing nitrogen into an ester group from amides or lactams
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
- C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
- C07C69/67—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids
- C07C69/675—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids of saturated hydroxy-carboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Un proceso continuo para la preparación de ésteres alfahidroxicarboxílicos, en el cual los reactivos que reaccionaron son alfa-hidroxicarboxamida con alcohol en presencia de un catalizador para obtener una mezcla del producto que comprende un éster alfa-hidroxícarboxílico, amoniaco, alfa-hidroxicarboxamida no convertida y alcohol, y catalizador; caracterizado por que a') los flujos de reactivo comprendiendo, como reactivos, un alfa-hjdroxjcarboxamjda, un alcohol y un catalizador son alimentados en un reactor de presión; b') los flujos de reactivo se hacen reaccionar entre si en el reactor de presión a una presión en el rango superior a 1 bar a 100 bar; c') la mezcla del producto que resulta del paso b') y que comprende un éster alfa-hidroxicarboxílico, alfa 20 hidroxicarboxamida no convertida, alcohol amoniacal y el catalizador es descargada del reactor de presión; y ci') la mezcla del producto es empobrecida en alcohol y amoniaco mediante separación por destilación del amoniaco a una presión que se mantiene constantemente superior a 1 bar sin la ayuda del agente de separación adicional. El proceso continuo puede ser empleado en una forma particularmente ventajosa a escala industrial.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102006034273A DE102006034273A1 (de) | 2006-07-21 | 2006-07-21 | Verfahren zur Herstellung von Alpha-Hydroxycarbonsäuren |
| PCT/EP2007/055072 WO2008009503A1 (de) | 2006-07-21 | 2007-05-25 | Verfahren zur herstellung von alpha-hydroxycarbonsäuren |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2009000597A true MX2009000597A (es) | 2009-06-02 |
Family
ID=38441538
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2009000597A MX2009000597A (es) | 2006-07-21 | 2007-05-25 | Proceso para preparar acidos alfa-hidroxicarboxilicos. |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US20090209781A1 (es) |
| EP (1) | EP2043994A1 (es) |
| JP (1) | JP2009544640A (es) |
| KR (1) | KR20090039730A (es) |
| CN (1) | CN101489973A (es) |
| BR (1) | BRPI0715435A2 (es) |
| CA (1) | CA2658590A1 (es) |
| DE (1) | DE102006034273A1 (es) |
| MX (1) | MX2009000597A (es) |
| RU (1) | RU2009105822A (es) |
| TW (1) | TW200829548A (es) |
| WO (1) | WO2008009503A1 (es) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102006025821A1 (de) * | 2006-06-02 | 2007-12-06 | Degussa Gmbh | Ein Enzym zur Herstellung von Mehylmalonatsemialdehyd oder Malonatsemialdehyd |
| DE102007015583A1 (de) * | 2007-03-29 | 2008-10-02 | Albert-Ludwigs-Universität Freiburg | Ein Enzym zur Herstellung von Methylmalonyl-Coenzym A oder Ethylmalonyl-Coenzym A sowie dessen Verwendung |
| US8759566B2 (en) | 2009-04-03 | 2014-06-24 | Mitsubishi Gas Chemical Company, Inc. | Method for producing α-hydroxycarboxylic acid ester |
| DE102011081256A1 (de) * | 2011-08-19 | 2013-02-21 | Evonik Röhm Gmbh | Verfahren zur Herstellung von Alpha-Hydroxycarbonsäureestern |
| DE102013000602A1 (de) | 2013-01-16 | 2014-07-17 | Evonik Industries Ag | Verfahren zur Herstellung von Acrylsäure |
| DE102013213699A1 (de) * | 2013-07-12 | 2015-01-15 | Evonik Industries Ag | Verfahren zur Herstellung von alpha-Hydroxycarbonsäureestern |
| DE102014205304A1 (de) * | 2014-03-21 | 2015-09-24 | Evonik Industries Ag | Verfahren zur Abtrennung von Ammoniak aus alkoholischer Lösung in Gegenwart von Kohlensäureverbindungen |
| WO2016016073A1 (de) * | 2014-08-01 | 2016-02-04 | Evonik Röhm Gmbh | Verfahren zur herstellung von alpha-hydroxycarbonsäureestern in der gasphase |
| WO2016037928A1 (de) * | 2014-09-10 | 2016-03-17 | Evonik Röhm Gmbh | Verfahren zur herstellung von alpha-hydroxycarbonsäureestern unter rezyklierung von ammoniak |
| WO2023117754A1 (de) | 2021-12-23 | 2023-06-29 | Röhm Gmbh | Verfahren zur herstellung von alkylmethacrylaten mit verbesserter ausbeute und verminderten emissionen flüchtiger organischer verbindungen |
| WO2023169810A1 (de) | 2022-03-11 | 2023-09-14 | Röhm Gmbh | Verfahren zur herstellung von alpha-hydroxyisobuttersäuremethylester und dessen anwendung in der elektronik-industrie |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2315498A1 (fr) * | 1975-06-26 | 1977-01-21 | Roehm Gmbh | Procede de preparation d'esters d'acides carboxyliques a partir d'amines d'acides carboxyliques |
| JPS5855444A (ja) * | 1981-09-25 | 1983-04-01 | Mitsubishi Gas Chem Co Inc | カルボン酸エステルの製造法 |
| DD252364A1 (de) * | 1986-09-01 | 1987-12-16 | Leipzig Chemieanlagen | Verfahren zur abtrennung der leicht fluechtigen komponenten aus dem abwasser der druckvergasung von braunkohle |
| ES2200429T3 (es) * | 1998-03-25 | 2004-03-01 | Mitsubishi Gas Chemical Company, Inc. | Procedimiento de preparacion de alfa-hidroxicarboxilato. |
| DE10034194A1 (de) * | 2000-07-13 | 2003-09-11 | Roehm Gmbh | Verfahren zur Herstellung von Cyanwasserstoff |
| DE10200171A1 (de) * | 2002-01-04 | 2003-07-10 | Roehm Gmbh | Verfahren zur kontinuierlichen Herstellung von Alkyl(meth)acrylaten |
| DE10301007A1 (de) * | 2003-01-13 | 2004-07-22 | Röhm GmbH & Co. KG | Verbessertes Verfahren zur kontinuierlichen Herstellung von Alkyl(meth)acrylaten mit mehrfacher Katalysatorrezyklierung. |
| DE10309209A1 (de) * | 2003-02-28 | 2004-09-09 | Degussa Ag | Verfahren zur Herstellung von Cyanwasserstoff nach dem BMA-Verfahren und Katalysator zu seiner Durchführung |
| DE10323699A1 (de) * | 2003-05-22 | 2004-12-09 | Röhm GmbH & Co. KG | Verfahren zur kontinuierlichen Herstellung von Alkylamino(meth)acrylamiden |
| DE102004006826A1 (de) * | 2004-02-11 | 2005-08-25 | Röhm GmbH & Co. KG | Verfahren zur Herstellung von alpha-Hydroxy-carbonsäuren und deren Ester |
| DE102004013847A1 (de) * | 2004-03-20 | 2005-10-06 | Degussa Ag | Cyanidtolerante Nitrilhydratasen |
| DE102004013824A1 (de) * | 2004-03-20 | 2005-10-13 | Degussa Ag | Nitrilhydratasen aus Rhodococcus opacus |
| DE502005008156D1 (de) * | 2004-11-23 | 2009-10-29 | Evonik Roehm Gmbh | Verfahren zur kontinuierlichen herstellung von alkylaminoacrylamiden |
| DE102005023976A1 (de) * | 2005-05-20 | 2006-11-23 | Röhm Gmbh | Verfahren zur Umesterung |
| DE102005023975A1 (de) * | 2005-05-20 | 2006-11-23 | Röhm Gmbh | Verfahren zur Herstellung von Alkyl(meth)acrylaten |
| DE102005043719A1 (de) * | 2005-09-13 | 2007-03-15 | Röhm Gmbh | Vorrichtung und Verfahren für kontinuierlich durchgeführte Gleichgewichtsreaktionen |
| DE102006029318B3 (de) * | 2006-06-23 | 2007-10-11 | Röhm Gmbh | Verfahren zur kontinuierlichen Herstellung von ungesättigten Carbonsäureanhydriden |
-
2006
- 2006-07-21 DE DE102006034273A patent/DE102006034273A1/de not_active Withdrawn
-
2007
- 2007-05-25 RU RU2009105822/04A patent/RU2009105822A/ru not_active Application Discontinuation
- 2007-05-25 CA CA002658590A patent/CA2658590A1/en not_active Abandoned
- 2007-05-25 JP JP2009521175A patent/JP2009544640A/ja not_active Withdrawn
- 2007-05-25 KR KR1020097001190A patent/KR20090039730A/ko not_active Application Discontinuation
- 2007-05-25 US US12/307,773 patent/US20090209781A1/en not_active Abandoned
- 2007-05-25 MX MX2009000597A patent/MX2009000597A/es not_active Application Discontinuation
- 2007-05-25 CN CNA2007800276310A patent/CN101489973A/zh active Pending
- 2007-05-25 EP EP07729501A patent/EP2043994A1/de not_active Withdrawn
- 2007-05-25 BR BRPI0715435-6A patent/BRPI0715435A2/pt not_active IP Right Cessation
- 2007-05-25 WO PCT/EP2007/055072 patent/WO2008009503A1/de active Application Filing
- 2007-07-18 TW TW096126163A patent/TW200829548A/zh unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JP2009544640A (ja) | 2009-12-17 |
| KR20090039730A (ko) | 2009-04-22 |
| WO2008009503A1 (de) | 2008-01-24 |
| US20090209781A1 (en) | 2009-08-20 |
| TW200829548A (en) | 2008-07-16 |
| BRPI0715435A2 (pt) | 2013-01-08 |
| EP2043994A1 (de) | 2009-04-08 |
| DE102006034273A1 (de) | 2008-01-24 |
| CA2658590A1 (en) | 2008-01-24 |
| RU2009105822A (ru) | 2010-08-27 |
| CN101489973A (zh) | 2009-07-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FA | Abandonment or withdrawal |