LV10471B - Method for producing of combined polymeric materials - Google Patents

Method for producing of combined polymeric materials Download PDF

Info

Publication number
LV10471B
LV10471B LVP-93-135A LV930135A LV10471B LV 10471 B LV10471 B LV 10471B LV 930135 A LV930135 A LV 930135A LV 10471 B LV10471 B LV 10471B
Authority
LV
Latvia
Prior art keywords
polymer
poly
electron
combined polymeric
alkyl
Prior art date
Application number
LVP-93-135A
Other languages
English (en)
Other versions
LV10471A (lv
Inventor
Isterholm Jan-Erik
Laakso Jukka
Karjalainen Sari
Mononen Pirjo
Original Assignee
Neste Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Neste Oy filed Critical Neste Oy
Publication of LV10471A publication Critical patent/LV10471A/lv
Publication of LV10471B publication Critical patent/LV10471B/lv

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C08G61/126—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one sulfur atom in the ring
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/124—Intrinsically conductive polymers
    • H01B1/128—Intrinsically conductive polymers comprising six-membered aromatic rings in the main chain, e.g. polyanilines, polyphenylenes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Description

LV 10471
Cnocoč nojiyyeHHH κομ6ηημροβ8ηηογο ποπημθρηογο
MaTepnajia
MsoPpeTeHne othocmtch k cnocoČaM nojiyweHMH κομ6μημροβ3Ηηηχ nojiHMe?Hbix MaTepnajioB, a ημθηηο, k cnoco(5y nojiyweHMH ajieKTpo-npoBOflHinero κομΡμηηροββηηογο MaTepnajia, cocTOHmero M3 προβολη-mero JierHpoBaHHoro nojinMepa h MaTpHUbi HenpoBonnmero nojiMMepa. 3jieKTponpoBOHfimne nojTMMepn cocTaBJinfOT rpynny MaTepnanoB, 3aMeHHX)uinx MeTaJiJiimecKHe προβολημκμ h noJiynpoBOHHHKH βο μηογηχ OTpaCJIHX npOMblUIJieHHOCTM, HanpMMep, H3 ΗΗΧ H3rOTaBJĪ?IBaiOT ČaTapeM, οβθτοβηθ θλθμθητη, netiaTHbie njiaTH, aHTHCTaTHuecKMe ynaK0B0t-īHbie MaTepnajibi η θλθκτρομβγημτηηθ aKpaHbi. S^eKTponpoBOflHiņne nojiMMepHue MaTepnaJībi odu^Ho nojiy^aioT ομθμθηηθμ caHH, yrjiepoflHbix bojiokoh, MeTajiJiHwecKHx yacTnu hjih MeTajiJiHwecKMx bojiokoh c MaTpHiieH H3 nojiHMepa b pacnjiaBJieHHOM coctohhhm. B MaTepnajiax θτογο THna προβολημοοτβ 33Βηοκτ ot B3aHMHbIX K0HT3KT0B CpeflH ^aCTHLI HanOJIHHTeJIH. OObRHO ΗβΟδΧΟ,Π,ΗΜ ΧΟΡΟΙΙΙΟ HHDnepCHUH HanOJIHHTeJIb B KOJIHyeC- τβθ πρΗΜβρΗΟ 10-50 Mac.%. TaKOH MaTepnaji μμθθτ cjiejiyiomHe Ηθ,αο-cTaTKH i MexaHMwecKne CBoftcTBa ero yxy,mua!OTCH npn yBejinyeHHH KOHpeHTpamiH HanojiHHTejiH, npoBOflMMOCTbio TpyqHO ynpaBJiHTb, oco-60hho b AManasoHe nojiynpoBoa;HHKOB, TpyAHO oPecne^MTb roMoreHHyro HMcnepcH» HanojiHHTejiH b MaTDnue. M3BeCT6H cnocoč nOJiyweHHH paCTBOpHMOrO 3JieKTponpOBOIIfllflerO nojiHMepHoro MaTepnaJia B3aMMOfleftCTBneM 3-aJiKHJiTH0$eHa π nupojuia /1/. O^Hano, noJiy^eHHbiH no 3T0My cnoco6y nojiHMepHbifi MaTepnaji očJiauaeT HeflocTaTOUHO bhcokhmh $H3HK0-MexaHntjecKHMH οβομοτεβμη.
Hanfiojiee 6jih3KHm k cnoco6y no ΗοοδρβΤθΗΗΚ) HBJiHeTCH cnoco(5 nojiyyeHHH κομΡμηηροββηηογο nojiHMepHoro MaTepnajia, cocTonmero H3 njieHKn, nojiyueHHofi H3 pacTBopa b opraHimecKOM pacTBopHTejie ajiKMJi3aMemeHHoro πο;ιμτμοΦθη3 m noJiMMepHoii πολποκκη /2/.
HeflocTaTKow βτογο cnocofia HBJiHeTCH to, ^to nojiyyeHHbin wa-Tepnaji He oPjiaflaeT cotieTaHneM bhcokom προβολημοοτη η βηοοκηχ 'in3MK0-MexaHMwecKHX nonasaTejien.
Uejibto H3o6peTeHHH HBJiHeTCH nojiyMeHne sjieKTponpoBoiiHiiiero KOMfiHHHpoBaHHoro nojiHMepHoro MaTepnajia c bhcokmmh Φη3ηκο-μθχ3-HMMeCKMMM n0K33aTeJIHMM . 2.
yKasaHHafi uexb ,ποοτμγβθτρη τθμ, wto e cnoccče noxyveHWH KCM6HHMpOBaHHOrC· ΠΟΧΗΜΘΟΗΟΓΟ Μ3Τβρ78Χ3 Ha 0CH0B8 a.’IKKJISSMe-uieHHcrc ποχητηοΧθηβ e Ka^scTee a χ κ μ x 3 a μ θ ir θ η η o r o ncx7T7C*8Ha iicnoJib3y:-3T γίο.π·/Ι-/5-2.τκηχτκο|θη/, κοτοομμ ββοεητ a κοητβκτ c Η β Π 3 C B 0,11 ΗII! 7.V ncX7.V3pCM E pacnX8BXeHH0M C0CT0HH77 Ξ Κ0Χ7*ίΘ0ΤΒ8 0,1-20,0 % ot 0511167 t/accn ποχχμθροβ. ΠP-3HMyIL1 SCT3SΗKO 5 Κ3<ί90Τ3δ Π0Χ7/ύ-3ΧΚ7ΧΤ70ί8ΗΒ / ’/CHOJlb-SVKIT ΠΟΧ7/3-ΟΚΤ7ΧΤ7θΧ8Η/ . Πο.πh/3-axκχχτλoieη/ mokho beopmtb b κοητβκτ c nenpoBO-aHHIMM ΠΟΧΗΜβρΟΜ Hanpecco3KoJi C HHM. "HenpCBCHHUlMM ΓΤΟΧΜΜβΟΟΜ /V.&TVAUeV. / M0JH8T ČfclTb ."-3ČOM Τβρ-MonxacT, KOToptifi mokho očpačaTtiBaTb b pacnxaExeHHCM coctohhhm, 7 C0BM8CT7MbI7 C Π0Χ7/3-3ΧΗ7ΧΤ70Χ8Η0Μ/. KOMČHHaiIHfl, B KOTOpO/1 MaT?HWHb!M ΠΟΧΜΜβΌΟΜ Η3ΧΗ8ΤΡΗ OJTei7-HGBblfl Π0ΧΜΜ8Ρ 7X7 0JT8X'Η0 = ΒΓίί ΟΟΠΟΧΗΜΘΡ, Η ΓΤρΟΒΟΕΗίϊϊίΜ ΗΡΜΠΟΗΘΗ-ΤΟΜ HBXH8TCfl Γ!0Χ7/5-ΒΧΚ7ΧΤ70Χ8Η/, ΚΒΚ γΟΤΒΗΟΒΧδΗΟ, ΗΒΧΗβΤΟΗ 0C0Č8HH0 πΌ8Ιΐπθ'-ΪΤ7Τ0ΧΒΗΟ7 . flOCJie BBepSH/lH Ε Η0ΗΤ3ΚΤ ΠΟΧ7/2-3ΧΚ7.7ΙΤ7θί8Η3 / Β ΟΒΟΠΧΒΕ-X 8 Η Η Ο Μ COCTOHHMK C Η8Γ.ρ0Ε0ΧΗ1117Μ ΠΟΧΜΜβρΟΜ ΜδΤβρΗδΧ ΚΘΧΒΤδΧΒΗΟ Χ8Γ7?0Ε£ΤΒ SKUenTCDOM 3Χ8ΚΤ00Η03.
JlerHD0BaH78 KCMČKHMpCBaHHCTC Μ8ΤβρΚ3Λβ ΕΚυθΠΤΟΌΒΜΗ 3Χ8Κ-TpOHCB ΜΟ.ΐΗΟ ΟΟΥ'ΧδΟΤΒΗΤΒ ΛΚόΟ XHMKWeCKH, X7Č0 3JieKT?0XKMKUeCKK. EbirCHHC OČpaČCTaTb Π0Χ7ΜΘΡΗΗ7 Κ0ΜΠ03ΚΤ CņeC07, Κ0Τ008Η COCTOHT 73 J-Cl-.. CT07 Cp8£07 Μ03ΘΤ SbITb ΓφΚδΜΛΘΜΚΗ 0ΡΓΕΚ7<·1Θ0Κ77 paCTBCpMT8Xb, ΗΗΠΟΗΜβρ, Η7Τ?0ΜΘΤδΗ, 7X7 ΧΏΡΟ?: HpyFC7 pāCTSODM- τθχβ , άλά cycneH3H0HHSH cpena, κοτορβΗ ηθ OKasKEasT βοθιιηογο EospeiicTBiiH Ha npc-uecc χθγηόοεβη'/η, «anpMMep, 3a cust pacTBo-ρβΗΚΗ ncxH/S-axKHXTHoXeHa/. CčimHO, mokho ηοποχββοβητβ οόγεηη-M8CK78 paCTB0pH?8X7, HOTOOHS paCTEOpfl-OT COXb 7 Β 3T0 *8 ΒΟΘΜΗ PSCTHΓ7Β310Τ ΜβΤρΚίίΗΗΗ ΠΧδΟΤΗΚ TEK, WTO CTaHOBMTCH B03M0KHHM X9rnpOBaH/ie. Πoc.n8 jisruposaH/tH ncxiyueHH:y:o πχβκκγ mmcto npovHBa-oT ot OCTaTKa npHCanKH ΠΡΚ9ΜΧΗΜΗΜ paCTBOP'/TSiīeM, ΠΟδΠΠΟίίΤΜΤβΧΒΗΟ paCT6Pp^!T8XēM, HCnOJ! B3ySMHM Ε ΧΘΓϊφΟΒδΗΗΗ, Μ Κ0ΜΠ03ΗΤ ΟγΐϋβΤ. Γργτοί: Π0Χ83Η07 npKCanKCK HEJIH8TCH Hoa, ΚΟΤΟΡΗΓ: 7CrT0Xb-3γΐΟΤ KEK ΤΗΧΟΕΟΧ ΠΧΗ yB8JI7ueH7K Π p Ο Ε ΟII7 M 0 C T 7 ΓΟΧ7/3-3X77,1-
TiioleHa/. C30F:CTBaM7 npOBOpMMOCTH Χ8Γ70033ΗΗ0ΓΟ ΚΟΜΰΗΗΜΟΟΒΒΗΗΟΓΟ waTepnaxa mokho υπρββχητβ, peryxMoyH KOHLieHTpaiiM'o noMcasKM, LV 10471 nepZOII .ΠΘΓΜΡ0Ε3ΗΚΗ, ΤΘΜΠΘΟΗΤνρ.ν Η ΚΟΗΙΙΘΗΤΟδΙΙΜ'Ο ΠΟ.ΠΜ/3-ajiKMJīTHOteHa/ ε ?:ομπο3μτ8 . ΙΊ3θ6ρβτβΗΜΘ H.njiK)CTpKpyeTCH cjieayioiBHMM πριίΜβρβΜκ. Πρ'/.Mep 1. b- OKTMJīT^oish no/:/wa:oT cjienyKU]/iM o6pa30M:
CooTBeTCTBV^cm/'f; peaKTiiB Γρκηεηρε noJiywa-0T v.2 μβγηηη /06θ3Β0Η8ΗΗΗ/! , 1,C MOJlb/ H OKTHJlSpOMMpa /OČeSBOF.eHHHM 1,5 MOJIH/ B flHOTHJIOBGM Sļupe. ιΜΒΓΗΜΓ: V. 3.pMD ΠΟΜ8Ε3·ΟΤ Ε ΡΘ3ΚΤ00, μμθοιιιχΓι aTMOciepy aproHa, μ ποοτβπδκκο nodaBJinioT εόγοημόοββηηημ OKTUJIČDOMMJI. ŪJIH ΟδΛΘΓΜΘΗΗΗ Ha^aJia peaKUMM IIOČaB.IHiOT KpHCTaJIJI nona.
KoHueHTpapnK) no;iyueHHoro peareHTa onpeaejiHi-oT c.T!9ny:'0inwM odpascM.
10 mj: npočy no6aBJiHioT e 150 mji ,um c t m ji ji η p o 3 a η η o ? bohh. ŪOPaBJIHFjT MHIļHKaTOp H npOBOCHT ΤΜΤΡ0Ε3ΗΗ9 C 0,2 M :'aOH npM ?o°c.
PearsHT nspenocHT b npyro:“: psaKTOp /aTMOC.tepa sprona/, E KCTODb!? HOČaBJTHfOT S-5pOM-TMOŽSH B MOJīHDHOM COOTHCl'eHHH, COOT-BeTCT3yai!iey KOHueHTpaunii peareHTa, h KaTajinsaTOp /ir/xjiop-l,3-čhc-(aHieHK,J!ioc$HHO) nponaH/HZKejib /Π/. Una Hauaaa peaKUHM peaKTOp HarpesaFOT. Cf.iecb narpeBaroT ripu Te\inepaType īrniJierMauHn 4 u. nocJie STorc peaKTop noMemaioT na Jie,nHHyO 6 a η® h nejiasoT cvecb KKCJlOfl npH Π0Μ01ΙΙΚ 1,0 H. --C1 . CMSCb ΠΡ0ΜΗΒ3®Τ 30H0M B H8JIHT8JībH0Či BOPOHHS /TpH pa3S/ ΗΗΟΗΙϋβΗΗΗΜ PaFiCO, /TDH 0333/ m saTetv! o6e3BOSHBaK)T cacu. CMecb οτγοηηιότ y. noJiywax)T προιιγχ? S-oKTHJīTHoieH /t.k. 255^*0, βηχοπ; 65 %/. 2,5-ΠΗΗΟίίΗΒ-3-0ΚΤΗ.1ΤΜ0φβΗ ΠΟ™ 'VaiOT CJ!ejiy!Ofl!I!M OČpaSOM. 2,50 MJ! J3MX.i:OpMeTaHa, 0,4 MCJIfl 3-CKTHJ!TWO$eHa, nOJP/USHHOrO Bfciiūe, m 0,5 mojih nopa no6aBJifi-0T b peaKTop /aTMocļepa aproHa/. 20 mji ομθοη ascTa Ά eoph /1:1/ MemieHHO aodaBJiHtOT v. TeMnepaTyoy CΜΘCV\ MSP.neHHO nOBHHMaiOT £0 45uc . CMecb BbipepHHBafOT npH ΤβΜΓΤβ-paType peiJierMaunn 4,5 flocjie δτοτο peaKUHOHHy:<j cvecb npoMH-Bar-οτ sopo? /τρη paša/, 10 % xao:i /toh pa3s/ ά bopcm /pBaapbi ŽMJIbTpF/F-OT Η ΟΦΗΙΕδΏΤ B KOJIOHKe /KpeMHē36M + reKC3H/. ilOJiyii8HHHM npOHyKTOM HEJIH8TCE 2,5-DHKOJlH3-3-OKTHJITMOteH /ΒΗΧΟΠ 73 %/. floJi/i /3- cxTi-’.iTX0'teH/ nojiy*iaK)T cjienyr-omm očpasoM. 0,3 mojih 2,Γ-ΗΧΗθΠΗΐι-3-oKTMnTHOieHa, nojiyueHHoro Bbiine, 0,3 MOJIH Μ3ΓΗΜΗ H 200 MJĪ ΤβΤΟΘ rHppOjyDSHa /ΤΓ?/ ΠΟΜβΤΗΙΟΤ Β 4 . peaKTop w ΠθφΛθΓΜΗργροτ 2 u. 0,C01 MOJifl KaTa.7!M3aTopa /axxjiop/l,3-(.nMieHMJītociiiHo) nponaH/HHKe/īb /Π/ ao6asjiHroT e peaKTop. Γ)
PeaKTop oxjia»narOT ao 20 C nepea aoČaBJieHHeM KaTaaMsaTopa. Τθμ-nepaTy?y nopHM.va^T ao 70^C v. cMecb aetaerMHpy?)T 20 u. fioay-usHHb!'/. npoay:-:T BUJUisaioT s Me?aHca / 1200 mji MSTaHO.na + 5 % nei /. Ci/'ecb nepeMSEHea-OT 2 v. $HJibT?aiiMfi, npoMtiEKa γοοπηθμ Boaoa κ μθτ8ηολομ. SKCTparnņoBaHMe μθτβηολομ h ο6θ3βοημεβημθ e BaKyywe. noayueHHfci:·.· npoayKTOM ηβληθτοη ncan /3-CKTHJiTHOteH/ /tsmhoko-pnuHeBfciii nopomoK, Bbixoa 95 %/. .,iloay^eHMe κ ο m 6 η η μ ρ o e a η η o r o MaTepnajia. ΠρΗΚ'θρ 2.
Hafl ncayweKMH κομ6κηηροβ3ηηογο vaTepnajia Hcnoabsy:oT 10 Mac.? neasi /3-OKTMJiTHoieHa/ ά 90 Mac.?. ccnojimieņa sTKaeHa c BMHHJiaiisTāTOM :itx 229 c MoaapHOii Maccoii 68000 r/MCJīb.
Ma?epnaa noayqa:-0T b μειιιηηθ BpačeHaeoa /Maui^na $mdmm -~st-Ov/. TeN'nepaTypa cmsch 170 C. riepnoa ομθ!π·!εεημη 10 mmh, umcjīo oPodotob 30 Ha mmh. npiiMSp 3 .
KoMčnHMpoBaHHfciM MaTspHaa, noayueHHHH b npHMepe 2, npeccj'OT e pacnaaBaeHHOM coctohhhm Ha jīmct πρ;ι πομοειμ πρημογο npeccoaa-HKH. fiepiioa esama Čfcui paBen 5 mmh, TeMnepaTypa 170^0 v. aas-aeHKS ICO čap.
[IpHMSp 4. KOMČMHHOOBaHHHH Μ3ΤΘΡΗΕΛ, !10JīyueHHHiĪ B ΠΡΜΜβρβ 2, H3MeJIfc-yaioT 3 rpaHyafci, v. θβτθμ noayya:-0T nojniMepHyīo Kowno3HTHy:-o π.τιθηκ:/ 3KCTpyst'i8'“! c ByayBaHM8M. TewnepaTypbi οθκτοροβ Bpačennepa dyaM 150-170^0. ToaBiMHa πλθηκμ 0,09 mm.
[ļpMMep 5. riponeaypa aHa.iornwHa ποημθόβμ 2 n 3, ho Μβτρπυβίί hbjihstch conoanMep STMaena m 6yTMaaKpnaaTa, coaepsatiaii' 17 Mac.? 5yTna-a:-:pMaaTHHx p.oetophk)uit/xch 3Β8Ηβθβ μ μμθιοιιπιμ MOJiHpHy?o waccy 5000 r/S'OJlb /npoayKT 7071 JupMfc! ;-:eetc ?clvcti?n Ab/. np/iMsp 6. n?oueaypa aHajicrsmHa npM.vepaM 2-4, ho Macpnusn ηβοηθτοη noaMBTMaeH PE-8517 c mojihdhom MaccoK 350000 r/Moab /Jkdms ~· v /. ϋθΓΚΡΟΒΗΗΗΘ. LV 10471 5. Π p V. Μ Θ p 7. Κ Ο Μ 6 Μ Η! Μ ρ 0 Β 3 Η Η fc! Κ ΜβΤβρΜβΛ, ΠΟ.ΒγνίθΗΗΗ/Ι Β ΠΡΜΜβρδΧ 2 '/ S, jierMpy’:OT. VaTepnan norpy?KaK)T β κοΗυθΗτρίφΟΒβΗΗΗ/ pacTBop Tc'Zi. -HHTpoMeTaHa /cyxox, aTMOCtepa aproHa/. llocjīe Maccsoro jierupoBaHHH npoMHBaroT b saKyyMe ημτρομθτηηομ v. oSesEo^’/Ba-oT. npOBOpHMOCTL· 0,6 C/CM /C- CHM8HC/. npHMep 8. nponepypa aHajicri^Ha npMMepaM 2, 3 h 7, ho MaTepnajī copep-«mt nojiti / 3 - okth jitmo$sh / b KOJinviecTBe 5 j/ac.% V\ neperi JierMpC-EaHKSM BbiiļepsaH 8 u. Προβοπημοοτβ pasna cxlO_c C/cm. flpMMep S. npoueaypa aHajiornuHa npHMepau 2, 3, 7 m 8, ho MaTepnajr COfleOif.HT flOJIH /3-OKTK.riTHOTeH/ B KOJIHtieCTBe 20 Mac..? Μ Π90/0ϋ J10ΓΜΡ033ΗΜΗ Ρ3ΕΘΗ 2 ΜΜΗ . UpOBOflHMOCTb 7x10 ^ C/CM. ΠΟΗΜθρ 10. npou8n.ypa aHa.norxHHa npnMepy 9 h npoBoanMocTb onoene.nHKT Kan :tyHKUM:-o nspnoiia Jierr/.poBaHHH. ΠρΜΜβρ 11. Π jī e η κ y πόλη / 3 - ο κ τ hji τ h ο$θ h a / .npeccyK)T b pacnJiaBJieHHOM COCTOHHHH /170^0/ npHMbIM ΠΟβΟΟΟΒεΗΚΘΜ HH nOHJIOMK.y / Π OJIM 3 Tī'iJIeH — TepejTajiaTa/. Ee JierupvaT b EaKyywe, HcnojibsyH nap nona. npOBOpnMOCTb 10 C/CM. ΠρπΜθρ 12.
Fa6oTa:-0T no v8tohmk8 npnwepOB 2, 3, 7-9, ho Hcnojib3y-:T 3 Mac.? nojiH /3-oKTMJiTHoieHa/ v. nepnon Bsenenna erc οβεθη n 2 VI. npOBOHMMOCTb 1.10 C/CM. flpM HCn0.JIb30BaHHH, Η3ΠΡΗΜ8Ρ, ΠΟΛΗ /3-ΓΘΚ0ηΛΤΗ0φ8Η3/, nojin /3-neuHJiTM0$eHa/, nojin/3-HOHMJiTHO«ieHa/, nojin/3-renTn.’i-Tno$ena/ nojryuaH)T anajiornviHtie pe3yjib?aTH, τ,κ. ajiKmībHne 3aM8CTMT8JIH Β ΗΗΧ 0Κ33Η39ΏΤ T3K08 *8 BJIHHHH8 H3 nJiaBKOCTb 1-1 COEMeCTUMOCTb 33Μ8Ι1!8ΗΗ0Γ0 ΠΟΛΤΗΟφβΗδ, K3K Κ ΒδΜΘΟΤΗΤΘ.ΊΒ LV 10471
50Ρ·.:ν.ΠΑ H3C5PETEHHH 1. Cnocofi nOJiyW8HHH KOMČHH'/pOBāHKOrC ΠΟΛΗΜΘΡΗΟΓΟ M3T8DH-a:ia Ha οοηοβθ ajiKHJisaMenieHHoro noJinTHofena, otJivmamiviv.cn τθμ, utc, c usJībio nojiyweHMH sJieKTponpoBoziHiiiero κομ6ηητ/ιροβεηηογο noJiMMepHoro Ma?epna;ia c εβιοοκκμμ i-H3MK0-MexaHnuecKMMn noitasa-TejiHMH, 3 KauecTBe ajiKnjisaMeineHHoro noJiTMO'JeHa McnojibsvsT nOJIH/S-aJIKHJITHO$eH/, KOTODbM BBOPHT E KCHTSKT C HenpOBOHHISHM nOJIHMepCM B pacnJiaBJieHHCM COCTOHHMM B K0J!MW8CTBe 0,1-20,0 % ot oduisvi Macca πολκμθροε. 2. Cnocoč no n.l, cTJinuaioumMCH τθμ, uto b Ka^ecTBe ::o/iM-/3-a^KKJiTHo£eHa/ Hcnojīb3yK)T πο.πμ/3-οκτμ;ττηο$8η/. 3. CnocoČ no n.l, oTJintiasoīDHflcfl τθμ, mto nojiK/3-ajiKiiJiTMC-φβΗ/ BBOflHT B KOHT3KT C ΗβΠρΟΒΟϋΗΙΙΙΜΜ ΠΟϋΜΜΘΡΟΜ HanpeCCOBKOČ C HHM. 4. Cnocoč no n.l, oTJiMuaraiiinncH tom, ^to noc:ie ββββθηχη b KOHTaKT nojin/S-ajiKM^THOteHa/ b pacnjiaBJ!9HH0M cocTOHHnn c HenpoBOflHuiHM nojiHMepoM MaTepnaji Jiernpy:-DT aKuenTopoM sjīsktdohob. īsacii 1986 /56/ 1. PacTEODHMbie s^eKTponpoEOHHiUMe nojiMMepbt ,/nta /i3aiiperHfl3:OLiy, Hatar. i’ochnol., 1987, 5, v 10, c.530-533; ΡΗΧ $ 4 c 537. 1983. 2. SaHBKa ĒP 203438, kji. H 01 B 1/12, cny6x.

Claims (4)

  1. LV 10471 . Izgudrojuma formula. Kombinētā polimēru materiāla iegūšanas paņēmiens. 1. Kombinētā polimēru materiāla uz alkilaizvietotā poliolefina bāzes iegāšanās paņēmiens, atšķiras ar to, ka lai iegūtu elektrovadāmu •kombinētu polimēru materiālu ar augstām fizikāli-mehāniskām Īpašībām, kā alkilaizvietoto poliolefinu izmanto poli-(3-alkiltiofenu), kuru kontaktē ar elektronevadāmu polimēru izkausētā stāvokli daudzumā 0,1 - 20,0% no kopējās polimēru masas.
  2. 2. Paņēmiens saskaņā arl.p., atšķiras ar to, ka kā poli-(3~al-kiltiofenu) izmanto poli-(3-oktiltiofenu).
  3. 3. Paņēmiens saskaņā ar l.p., atšķiras ar to, ka poli-(3-alkil-tiofenu) kontaktē ar elektronevadošu polimēru, sapresējot ar to.
  4. 4. Paņēmiens saskaņā arl.p., atšķiras ar to, ka pēc poli-(3-alkiltiofena) izkausētā stāvokli kontaktēšanas ar elektronevadošu polimēru materiālu leģē ar elektronu akceptoru.
LVP-93-135A 1987-07-29 1993-02-23 Method for producing of combined polymeric materials LV10471B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI873308A FI82702C (fi) 1987-07-29 1987-07-29 Elledande plastkompositer, som innehaoller poly (3-alkyltiofen)
PCT/FI1988/000122 WO1989001015A1 (en) 1987-07-29 1988-07-29 Conductive plastic composites

Publications (2)

Publication Number Publication Date
LV10471A LV10471A (lv) 1995-02-20
LV10471B true LV10471B (en) 1996-04-20

Family

ID=8524842

Family Applications (1)

Application Number Title Priority Date Filing Date
LVP-93-135A LV10471B (en) 1987-07-29 1993-02-23 Method for producing of combined polymeric materials

Country Status (13)

Country Link
US (1) US5151221A (lv)
EP (1) EP0324842A1 (lv)
JP (1) JPH07734B2 (lv)
CN (1) CN1021231C (lv)
CA (1) CA1337222C (lv)
DD (1) DD282020A5 (lv)
DK (1) DK94089A (lv)
FI (1) FI82702C (lv)
LT (1) LT3244B (lv)
LV (1) LV10471B (lv)
NO (1) NO174629C (lv)
RU (1) RU1836393C (lv)
WO (1) WO1989001015A1 (lv)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5219492A (en) * 1987-07-29 1993-06-15 Neste Oy Conductive plastic composites
FI86880C (fi) * 1989-10-05 1992-10-26 Neste Oy Elledande plastkomposit, dess anvaendning och framstaellning
JPH05506819A (ja) * 1990-01-24 1993-10-07 ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア 導電性ポリマーブレンドおよびその製造方法
FI89377C (fi) * 1990-03-30 1993-09-27 Neste Oy Foerfarande foer framstaellning av en elledande polymerprodukt
FI90325C (fi) * 1990-12-14 1994-01-25 Neste Oy Menetelmä sähköäjohtavan muovituotteen valmistamiseksi
FI90324C (fi) * 1990-12-14 1994-01-25 Neste Oy Menetelmä sähköäjohtavan muovituotteen valmistamiseksi
FI89720C (fi) * 1991-03-14 1993-11-10 Neste Oy Framstaellningsfoerfarande foer elledande polymer
DE69229253T2 (de) * 1991-10-08 1999-11-04 Americhem, Inc. Verfahren zur Herstellung eines eigenleitfähigen Polymeren und dieses enthaltende Gegenstände aus thermoplastischer Polymermischung
EP0705306A1 (en) * 1992-05-20 1996-04-10 Neste Oy Electrically conducting liquid-crystal polymer blends and process for the preparation thereof
FI91743C (fi) * 1992-09-15 1994-08-10 Neste Oy Rikkiä ja fosforia sisältävän prosessijätteen regenerointimenetelmä
JP3118103B2 (ja) * 1992-12-21 2000-12-18 矢崎総業株式会社 電気回路用導電部材、電気回路体及びその製造方法
USH1523H (en) * 1993-03-08 1996-04-02 The United States Of America As Represented By The Secretary Of The Army Method of making a polymer film having a conductivity gradient along its thickness and polymer film so made
US5520852A (en) * 1994-06-08 1996-05-28 Neste Oy Processible electrically conducting polyaniline compositions
FR2732501B1 (fr) * 1995-03-28 1997-04-30 Commissariat Energie Atomique Procede de fabrication de materiaux a rigidite dielectrique amelioree, et utilisation des materiaux obtenus par ce procede dans la fabrication de cables de transport d'energie
JP2001118570A (ja) * 1999-10-19 2001-04-27 Nec Corp ポリマー二次電池用電極の製造方法
JP3963693B2 (ja) * 2001-10-15 2007-08-22 富士通株式会社 導電性有機化合物及び電子素子
CN100489028C (zh) * 2007-05-23 2009-05-20 中国科学院长春应用化学研究所 一种高电导率的聚噻吩复合材料及其制备方法
ES2701157T3 (es) * 2007-11-27 2019-02-21 Uppsala Univ Projekt Ab Materiales compuestos que incluyen un polímero intrínsecamente conductor, y métodos y dispositivos
DE102010028206A1 (de) 2010-04-26 2011-10-27 Tesa Se Optisch durchgängige, tiefziehfähige Elektrode und diese enthaltendes Flächenelement für EL-Folie/-Lampen
DE112011102707A5 (de) 2010-08-13 2013-05-29 Tesa Se Insbesondere tiefziehfähige Leuchtmittel
WO2013149251A1 (en) 2012-03-30 2013-10-03 University Of Washington Through Its Center For Commercialization Composites incorporating a conductive polymer nanofiber network
CN108912614B (zh) * 2018-08-01 2020-08-18 广东佳瑞达科技有限公司 一种电磁屏蔽塑料及其制备方法
CN116199975B (zh) * 2023-05-06 2023-08-01 江西亚美达环保再生资源股份有限公司 一种聚丙烯改性材料及其制备方法和应用

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2527844B1 (fr) * 1982-06-01 1986-01-24 Thomson Csf Dispositif electrochromique pouvant servir au stockage d'energie et systeme d'affichage electrochromique
DE3321281A1 (de) 1982-06-22 1983-12-22 ASEA AB, 72183 Västerås Verfahren zur erhoehung der elektrischen leitfaehigkeit impraegnierbarer materialien
EP0145843A3 (en) * 1983-12-14 1987-01-07 W.R. Grace & Co. Electrically conductive composites comprising p-doped acetylene having conductive coatings and conjugated aromatic polymers and process therefor
DE3419788A1 (de) * 1984-05-26 1985-11-28 Battelle-Institut E.V., 6000 Frankfurt Copolymere und blends von polymeren mit konjugiertem (pi)-system
US4604427A (en) 1984-12-24 1986-08-05 W. R. Grace & Co. Method of forming electrically conductive polymer blends
DE3510031A1 (de) * 1985-03-20 1986-09-25 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von elektrisch leitfaehigen schaumstoffen
EP0203438A1 (en) 1985-05-31 1986-12-03 Corporation Allied Solution processible forms of neutral and electrically conductive poly(substituted heterocycles)
FI74715C (fi) * 1985-07-24 1988-03-10 Neste Oy Elledande polytiofen och foerfarande foer dess framstaellning och anvaendning.
CA1306904C (en) * 1985-10-09 1992-09-01 Tetsumi Suzuki Electrically conductive material and secondary battery using the electrically conductive material
FR2596566B1 (fr) * 1986-04-01 1989-03-10 Solvay Polymeres conducteurs derives de 3-alkylthiophenes, procede pour leur fabrication et dispositifs electroconducteurs les contenant

Also Published As

Publication number Publication date
CA1337222C (en) 1995-10-03
FI82702B (fi) 1990-12-31
LV10471A (lv) 1995-02-20
FI873308A (fi) 1989-01-30
NO890845L (no) 1989-02-28
LTIP435A (en) 1994-10-25
JPH01503242A (ja) 1989-11-02
DK94089D0 (da) 1989-02-28
FI873308A0 (fi) 1987-07-29
DK94089A (da) 1989-02-28
DD282020A5 (de) 1990-08-29
EP0324842A1 (en) 1989-07-26
CN1031547A (zh) 1989-03-08
WO1989001015A1 (en) 1989-02-09
LT3244B (en) 1995-04-25
NO174629B (no) 1994-02-28
NO174629C (no) 1994-06-08
CN1021231C (zh) 1993-06-16
FI82702C (fi) 1991-04-10
RU1836393C (ru) 1993-08-23
US5151221A (en) 1992-09-29
JPH07734B2 (ja) 1995-01-11
NO890845D0 (no) 1989-02-28

Similar Documents

Publication Publication Date Title
LV10471B (en) Method for producing of combined polymeric materials
FI963339A (fi) Ruiskutusmenetelmä, joissa käytetään kaasuvirtausta, biohajoavien fibrillien valmistamiseksi, biohajoavia fibrillejä sisältäviä kuitukankaita ja mainitunlaisia kuitukankaita käsittäviä tuotteita
DE3069753D1 (en) Electrochromic cell with improved electrolyte system
EP2363619A3 (en) Saturated aircraft brake preform including coal tar pitch and preparation thereof
MX166219B (es) Procedimiento para preparar una superficie polimerica reforzante para una union directa con hule
DE3751885D1 (de) Neue kohlenfasern, verfahren zu ihrer herstellung und diese enthaltende zusammensetzungen
GB9828270D0 (en) An electro kinetic geosynthetic structure
EP1100097A4 (en) SOLID ELECTROLYTE CAPACITOR AND METHOD OF MANUFACTURE
ATE450058T1 (de) Verfahren zur herstellung von organischen elektrolumineszenten vorrichtungen
HK1046583A1 (zh) 隔離電鍍工藝部件的方法和設備
EP0332704A4 (en) Process for producing conductive polymer film.
ES2057704T3 (es) Capas de bismaleinimida termoestables, ultradelgadas, asi como un procedimiento para su fabricacion.
IT8322285A0 (it) Procedimento chimico per laproduzione di perfluorocarburi a catena lunga e ad elevato punto di fusione mediante decomposizione termica di perfluorocarbonsulfonil-alogenuri.
ES2017902T3 (es) Procedimiento para mejorar el indice de cetano de los gasoleos de viscorreduccion.
SG146652A1 (en) Tunable mask apparatus and process
ATE278242T1 (de) Herstellung von elektrisch leitfähigen verbundkörpern durch abscheidung eines leitfähigen polymers auf einem porösen isolierenden substrat und lösung, die für diese zubereitung verwendet wird
Fukuda et al. Vibronic structures and anisotropy observed in linear and nonlinear optical spectra of vacuum-deposited polythiophene thin films
TWI256530B (en) Conductive roller
JPS56131602A (en) Production of acetylene high polymer having high electrical conductivity
JPS6411126A (en) Production of electroconductive high polymer film
EP0154175A3 (en) Rapid stabilization process for carbon fiber precursors
WO2019059569A3 (ko) 전극 촉매용 담체의 제조 방법, 전극 촉매용 담체의 전구체 및 이를 포함하는 전극 촉매용 담체
JPS6428887A (en) Manufacture of conductive composite body
JPS5258754A (en) Process for producing aromatic polyamide films
KR950008778A (ko) 고강도 탄소섬유 제조용 내염화 장치 및 이를 이용한 고강도 탄소섬유의 제조방법