KR980002071A - 올레핀 중합을 위한 유기-알루미녹산 조성물의 제조 방법 - Google Patents

올레핀 중합을 위한 유기-알루미녹산 조성물의 제조 방법 Download PDF

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Publication number
KR980002071A
KR980002071A KR1019970023231A KR19970023231A KR980002071A KR 980002071 A KR980002071 A KR 980002071A KR 1019970023231 A KR1019970023231 A KR 1019970023231A KR 19970023231 A KR19970023231 A KR 19970023231A KR 980002071 A KR980002071 A KR 980002071A
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South Korea
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solvent
aluminoacid
composition
organic
mixture
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KR1019970023231A
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English (en)
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시리악 죠셉 팔락칼
멜빈 브루스 웰치
롤프 레너드 기어츠
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비. 엠. 달러
필립스 페트롤륨 캄파니
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Publication of KR980002071A publication Critical patent/KR980002071A/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/61925—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Lubricants (AREA)

Abstract

유기- 알루미녹산 조성물을 생산하기 위한 방법이 제공된다. 본 방법은 유기-알루미녹산 분자를 포함하는 제1조성물을 생성하기 위해 용매와 혼합된 유기-알루미녹산 분자를 포함하는 제1혼합물 건조; 유기-알루미녹산 분자 및 상기 용매를 포함하는 제2혼합물을 생성하기 위해 용매와 제1조성물을 혼합; 유기-알루미녹산 조성물을 생성하기 위해 불용화제와 제2혼합물을 접촉하는 단계를 포함한다. 유기-알루미녹산 조성물을 포함하는 촉매를 사용한 중합 방법이 또한 제공된다.

Description

올레핀 중합을 위한 유기-알루미녹산 조성물의 제조 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (15)

  1. (a) 용매와 혼합된 유기-알루미녹산 분자를 포함하는 제1혼합물 건조시켜 유기-알루미녹산 분자를 포함하는 제1조성물을 생성시키고; (b) 제1조성물을 용매와 혼합하여 유기-알루미녹산 분자 및 제2용매를 포함하는 제2혼합물을 생성시킨다음; (c) 제2혼합물을 불용화제와 접촉시켜 유기-알루미녹산 조성물을 생성하는 단계를 포함하는, 유기-알루미녹산 조성물의 제조 방법.
  2. 제1항에 있어서, 단계(b) 및 (c)를 제2용매와 제1조성물을 혼합하기 전에 제2용매와 불용화제를 혼합함으로써 동시에 수행하는 방법.
  3. 제1항에 있어서, 접촉 단계가 미립자 물질의 존재하에서 수행되는 방법.
  4. 제3항에 있어서, 접촉단계가 미립자 물질이 실리카를 포함하는 방법.
  5. 제1항에 있어서, 건조 단계가 진공 건조를 포함하는 방법.
  6. 제1항에 있어서, 건조 단계가 미립자 물질의 존재하에서 수행되는 방법.
  7. 제6항에 있어서, 미립자 물질이 실리카를 포함하는 방법.
  8. 제1항에 있어서, 불용화제가 옥사이드, 퍼옥사이드, 알킬렌 옥사이드, 유기 카보네이트, 붕소-함유 유기 화합물, 또는 다하이드로카빌 ⅡA족 금속 화합물인 방법.
  9. 제1항에 있어서, 단계(a) 및/또는 단계(b)에서 사용된 용매가 지방족인 방법.
  10. 제9항에 있어서, 지방족 용매가 피라핀족인 방법.
  11. 제1항에 있어서, 단계(a) 및/또는 단계(b)에서 사용된 용매가 약 -80℃내지 약 175℃의 온도 및 약 0 psi 내지 약 1000 psi의 압력에서 액체인 직쇄, 측쇄, 또는 시클릭 알칸인 방법.
  12. 제11항에 있어서, 용매가 펜탄, 헥산, 헵탄, 옥탄, 노난, 데칸, 이소부탄, 이소펜탄, 이소헥산, 이소헵탄, 이소옥탄, 이소노난, 이소데칸, 또는 임의의 2종 이상의 용매의 혼합물인 방법.
  13. 제1항 내지 제12항 중 어느 한 항에 따른 방법에 의해 제조된 유기- 알루미녹산 조성물을 포함하는 촉매의 존재하에 중합을 수행하는 것을 포함하는 올레핀 중합 방법.
  14. 제13항에 있어서, 올레핀이 에틸렌, 프로필렌, 1-부텐, 3-메틸-1-부텐, 3-메틸-1펜텐, 3-에틸-1-헥센, 1-헥센, 4-메틸-1-펜텐, 1-옥텐, 1-헥사데센, 시클로펜텐, 노르보넨, 스티렌, 4-메틸 스티렌, 비닐 시크로헥산, 부타디엔, 또는 임의의 이들 올레핀의 2종 이상의 혼합물인 방법.
  15. 제13항에 있어서, 슬러리 중합 조건하에서 수행되는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019970023231A 1996-06-12 1997-06-05 올레핀 중합을 위한 유기-알루미녹산 조성물의 제조 방법 KR980002071A (ko)

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US66098296A 1996-06-12 1996-06-12
US08/660,982 1996-06-12

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KR980002071A true KR980002071A (ko) 1998-03-30

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US (2) US6096915A (ko)
EP (1) EP0812860B1 (ko)
KR (1) KR980002071A (ko)
CN (1) CN1170002A (ko)
CA (1) CA2207459C (ko)
DE (1) DE69702953T2 (ko)
ES (1) ES2149531T3 (ko)
SG (1) SG84505A1 (ko)

Families Citing this family (2)

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Publication number Priority date Publication date Assignee Title
EP1172385A1 (fr) * 2000-07-14 2002-01-16 SOLVAY POLYOLEFINS EUROPE - BELGIUM (Société Anonyme) Procédé pour la polymérisation des alpha-oléfines
WO2007081530A2 (en) * 2006-01-03 2007-07-19 Med Institute, Inc. Endoluminal medical device for local delivery of cathepsin inhibitors

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4536484A (en) * 1983-05-25 1985-08-20 Atochem Process for preparation of a transition metal component for a catalytic system of polymerization of olefins
EP0557107A2 (en) * 1992-02-21 1993-08-25 Idemitsu Petrochemical Company Limited Polyolefin resin and method for the preparation thereof
US5411925A (en) * 1993-02-12 1995-05-02 Phillips Petroleum Company Organo-aluminoxy product and use
EP0683179A1 (en) * 1994-05-16 1995-11-22 Phillips Petroleum Company Metallocene catalyst systems, preparation, and use

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Publication number Priority date Publication date Assignee Title
JPH0742301B2 (ja) * 1987-02-14 1995-05-10 三井石油化学工業株式会社 微粒子状アルミノオキサン、その製法およびその用途
JP2538588B2 (ja) * 1987-04-03 1996-09-25 三井石油化学工業株式会社 オレフイン重合用固体触媒の製法
KR920006464B1 (ko) * 1988-09-14 1992-08-07 미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤 올레핀중합용 촉매성분, 올레핀중합용 촉매 및 이 올레핀중합용 촉매를 사용한 올레핀의 중합방법
CA2068939C (en) * 1991-05-20 1996-04-09 Takashi Ueda Olefin polymerization catalyst and olefin polymerization
US5354721A (en) * 1993-06-22 1994-10-11 Phillips Petroleum Company Organo-aluminoxy product and use
US5436212A (en) * 1994-04-15 1995-07-25 Phillips Petroleum Company Organoaluminoxy product, preparation, and use
EP0685494B1 (de) * 1994-06-03 1998-10-07 PCD Polymere AG Katalysatorträger, geträgerte Metallocenkatalysatoren und deren Verwendung für die Herstellung von Polyolefinen

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4536484A (en) * 1983-05-25 1985-08-20 Atochem Process for preparation of a transition metal component for a catalytic system of polymerization of olefins
EP0557107A2 (en) * 1992-02-21 1993-08-25 Idemitsu Petrochemical Company Limited Polyolefin resin and method for the preparation thereof
US5411925A (en) * 1993-02-12 1995-05-02 Phillips Petroleum Company Organo-aluminoxy product and use
EP0683179A1 (en) * 1994-05-16 1995-11-22 Phillips Petroleum Company Metallocene catalyst systems, preparation, and use

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CA2207459A1 (en) 1997-12-12
CN1170002A (zh) 1998-01-14
ES2149531T3 (es) 2000-11-01
DE69702953D1 (de) 2000-10-05
US6353071B1 (en) 2002-03-05
EP0812860A1 (en) 1997-12-17
US6096915A (en) 2000-08-01
EP0812860B1 (en) 2000-08-30
DE69702953T2 (de) 2001-02-01
CA2207459C (en) 2001-05-08
SG84505A1 (en) 2001-11-20

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