KR970042659A - Water Dispersible Copolyester Resin Composition - Google Patents

Water Dispersible Copolyester Resin Composition Download PDF

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Publication number
KR970042659A
KR970042659A KR1019950066616A KR19950066616A KR970042659A KR 970042659 A KR970042659 A KR 970042659A KR 1019950066616 A KR1019950066616 A KR 1019950066616A KR 19950066616 A KR19950066616 A KR 19950066616A KR 970042659 A KR970042659 A KR 970042659A
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KR
South Korea
Prior art keywords
resin composition
copolyester resin
water
dicarboxylic acid
dispersible copolyester
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Application number
KR1019950066616A
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Korean (ko)
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KR100369848B1 (en
Inventor
진채문
이종술
Original Assignee
김준웅
주식회사 선경인더스트리
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Priority to KR1019950066616A priority Critical patent/KR100369848B1/en
Publication of KR970042659A publication Critical patent/KR970042659A/en
Application granted granted Critical
Publication of KR100369848B1 publication Critical patent/KR100369848B1/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66—Polyesters containing oxygen in the form of ether groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/46—Polyesters chemically modified by esterification
    • C08G63/48—Polyesters chemically modified by esterification by unsaturated higher fatty oils or their acids; by resin acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/52—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/688—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur
    • C08G63/6884—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/6886—Dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/08—Polyesters modified with higher fatty oils or their acids, or with resins or resin acids

Abstract

본 발명은 수분산성 코폴리에스테르 수지조성물에 관한 것으로서, 더욱 상세하게는 알킬페놀 폴리머, 설폰산 금속염기를 함유하는 디카르본산 또는 이들의 유도체, 또다른 디카르본산 또는 이들의 유도체, 그리고 이가 알코올을 공중합시킨 수분산성 코폴리에스테르 수지조성물에 관한 것으로 본 발명의 수분산성 코폴리에스테르 수지조성물은 수분산성, 인쇄안정성, 내수성, 접착성, 유연성 등의 물성이 우수하여 필름에 도포할 시 도포면이 부스러지거나 점착되지 않으면서 필름에 우수한 인쇄성능, 광택 및 열접착성을 부여하는 특성이 있고, 또한 본 발명의 수분산성 코폴리에스테르 수지조성물이 도포된 필름의 표면에 알루미늄등의 금속을 증착한 후 다시 상기의 수분산성 코폴리에스테르 수지조성물을 도포할 경우 그 증착막을 보호할 수 있다.The present invention relates to a water dispersible copolyester resin composition, and more particularly to an alkylphenol polymer, a dicarboxylic acid containing a sulfonic acid metal base or a derivative thereof, another dicarboxylic acid or a derivative thereof, and a dihydric alcohol. The present invention relates to a water-dispersible copolyester resin composition obtained by copolymerizing a water-dispersible copolyester resin composition. It has the property of imparting excellent printing performance, gloss and heat adhesiveness to the film without sticking or sticking, and also depositing a metal such as aluminum on the surface of the film coated with the water dispersible copolyester resin composition of the present invention. When the water-dispersible copolyester resin composition is applied, the deposited film can be protected.

Description

수분산성 코폴리에스테르 수지조성물Water Dispersible Copolyester Resin Composition

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (3)

설폰산 금속염기를 함유하는 디카르본산 또는 이들의 유도체, 또다른 디카르본산 또는 이들의 유도체, 그리고 이가 알코올을 공중합시킨 수시조성물에 있어서, 상기 설폰산 금속염기를 함유하는 디카르본산 또는 이들의 유도체와 또는 이들의 유도체와 또다른 디카르본산 또는 이들의 유도체로 이루어진 카르본산 화합물 총사용량 100 중량부에 대하여 다음 구조식(I)로 표시되는 알킬페놀 폴리머를 0.5 내지 30 중량부를 첨가하여 공중합시킨 것임을 특징으로 하는 수분산성 코폴리에테르 수지조성물.In the dicarboxylic acid or derivative thereof containing a sulfonic acid metal base, another dicarboxylic acid or a derivative thereof, and a copolymer containing a dihydric alcohol, the dicarboxylic acid containing the sulfonic acid metal base or the like It is copolymerized by adding 0.5 to 30 parts by weight of an alkylphenol polymer represented by the following formula (I) to 100 parts by weight of the total amount of the carboxylic acid compound composed of derivatives or derivatives thereof and another dicarboxylic acid or derivatives thereof. A water dispersible copolyether resin composition. 상기식에서,In the above formula, X는 수소원자 또는 탄소원자수 1 내지 10의 알킬기이고,X is a hydrogen atom or an alkyl group having 1 to 10 carbon atoms, m과 n은 각각 0 내지 20의 정수이며, 단 m+n = 0 이다.m and n are each an integer of 0-20, provided m + n = 0. 제1항에 있어서, 상기 설폰산 금속염기를 함유하는 디카르본산 또는 이들의 유도체를 또다른 디카르본산 또는 이들의 유도체로 이루어진 카르본산 화합물 총사용량 100 중량부에 대하여 5 내지 10 중량부를 첨가하여 공중합시킨 것임을 특징으로 하는 수분산성 코폴리에스테르 수지조성물.The dicarboxylic acid or derivatives thereof containing the sulfonic acid metal base are added in an amount of 5 to 10 parts by weight based on 100 parts by weight of the total amount of the carboxylic acid compound composed of another dicarboxylic acid or derivatives thereof. Water-dispersible copolyester resin composition characterized in that the copolymerized. 제1항에 있어서, 상기 수분산성 코폴리에스테르 수지조성물은 30℃에서 측정한 고유점도가 0.15 내지 0.70dl/g이고, 유리전이온도가 15 내지 70℃인 것임을 특징으로 하는 수분산성 코폴리에스테르 수지조성물.The water-dispersible copolyester resin of claim 1, wherein the water-dispersible copolyester resin composition has an intrinsic viscosity of 0.15 to 0.70 dl / g and a glass transition temperature of 15 to 70 ° C. Composition.
KR1019950066616A 1995-12-29 1995-12-29 Water dispersion copolyester resin composition KR100369848B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019950066616A KR100369848B1 (en) 1995-12-29 1995-12-29 Water dispersion copolyester resin composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019950066616A KR100369848B1 (en) 1995-12-29 1995-12-29 Water dispersion copolyester resin composition

Publications (2)

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KR970042659A true KR970042659A (en) 1997-07-24
KR100369848B1 KR100369848B1 (en) 2003-04-03

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Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3119967A1 (en) * 1981-05-20 1982-12-16 Basf Ag, 6700 Ludwigshafen METHOD FOR PRODUCING CONCENTRATED POLYACRYLATE DISPERSIONS
US5300572A (en) * 1991-06-14 1994-04-05 Polyplastics Co., Ltd. Moldable polyester resin compositions and molded articles formed of the same
JPH0519509U (en) * 1991-08-29 1993-03-12 三菱自動車工業株式会社 Engine oil jet structure
JP2735791B2 (en) * 1993-08-26 1998-04-02 インターナショナル・ビジネス・マシーンズ・コーポレイション Method and apparatus for rotary actuator arc compensation correction in direct access storage (DASD)

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