KR950017887A - 알칸온 및/또는 알칸올의 제조방법 - Google Patents
알칸온 및/또는 알칸올의 제조방법 Download PDFInfo
- Publication number
- KR950017887A KR950017887A KR1019940036148A KR19940036148A KR950017887A KR 950017887 A KR950017887 A KR 950017887A KR 1019940036148 A KR1019940036148 A KR 1019940036148A KR 19940036148 A KR19940036148 A KR 19940036148A KR 950017887 A KR950017887 A KR 950017887A
- Authority
- KR
- South Korea
- Prior art keywords
- alkali metal
- aqueous phase
- carrier material
- basic aqueous
- catalyst
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
- C07C27/10—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxidation of hydrocarbons
- C07C27/12—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxidation of hydrocarbons with oxygen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
- C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
- C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
본 발명은 3내지 30개의 탄소원자를 갖는 알칸 및/또는 알켄을 산소로 산화시켜 알킬히드로퍼옥시드를 형성한 후, 담체 물질상에서 움직이지 않는 금속 화합물을 함유하는 촉매의 존재에서 알킬히드로퍼옥시드를 분해함으로써 알칸온 및/또는 알칸올을 제조하는 방법에 관한 것으로서, 분해중에 8.5 이상의 pH를 갖는 분리 수상이 존재하고, 상기 촉매의 금속은 Mn, Fe, Ce, Ni및 Cu로 구성된 군으로부터 선택되고 담체물질이 분리된 염기성 수상의 존재에서 안정한 것을 특징으로 한다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (14)
- 알칸온 및/또는 알칸올을 제조하는 방법에 있어서, 분해중에 8. 5 이상의 pH를 갖는 분리된 수상이 존재하고 촉매 금속은 Mn, Fe, Ce, Ni및 Cu로 구성된 구성된 군으로부터 선택되고 담체 물질은 상기 분리된 염기성 수상의 존재시 안정한 것을 특징으로 하는 3내지 30개의 탄소 원자를 갖는 알칸 및/또는 알켄올 산소와 함께 산화시켜 알킬히드로퍼옥시드를 형성하고, 담체 물질상에서 움직이지 않는 금속 화합물을 함유하는 촉매의 존재하에 형성된 알킬히드로퍼옥시드를 분해하여 알칸온 및/또는 알칸올을 제조하는 방법.
- 제1항에 있어서, 상기 담체 물질이 무기 담체 물질인 것을 특징으로 하는 방법.
- 제2항에 있어서, 상기 유기 담체 물질이 TiO2, ZrO2, MnO2및 탄소로 구성된 군으로부터 선택되는 것을 특징으로 하는 방법.
- 제1항 내지 제3항 중의 어느 한 항에 있어서, 담체 물질에 대한 금속의 중량 % 가 0. 2내지 4중량 % 인 것을 특징으로 하는 방법.
- 제1항 내지 제4항 중의 어느 한 항에 있어서, 상기 염기성 수용액이 알칼리 금속 수산화물, 알칼리 금속 탄산염 및/또는 알칼리 금속 인산염을 함유하는 용액인 것을 특징으로 하는 방법.
- 제1항 내지 제5항 중의 어느 한 항에 있어서, 산화 혼합물과 수상의 중량비가 100 : 1 내지 1 : 1인 것을 특징으로 하는 방법.
- 제1항 내지 제7항 중의 어느 한 항에 있어서, 상기 수상의 pH 가 9 이상인 것을 특징으로 하는 방법.
- 제1항 내지 제7항 중의 어느 한 항에 있어서, 분해가 패킹된 베드 반응기내에서 일어나고 촉매가 0.7 내지 3 mm 의 입자 크기를 갖는 입자로 구성된 것을 특징으로 하는 방법.
- 제1항 내지 제8항 중의 어느 한 항에 있어서, 알칸이 6 내지 12개의 탄소 원자를 갖는 시클로알칸인 것을 특징으로 하는 방법.
- 제9항에 있어서, 상기 시를로알칸이 시클로헥산인 것을 특징으로 하는 방법.
- 제1항 내지 제10항 중의 어느 한 항에 있어서, 염기성 수상이 용해된 탄산나트륨을 함유하고 있는 것을 특징으로 하는 방법.
- 제1항 내지 제12항 중의 어느 한 항에 있어서, 연속적인 방법에서 상기 수상이 분해단계 후에 분리되며, 분해단계로 부분적으로 재순환되는 것을 특징으로 하는 방법.
- 제1항 내지 제12항 중의 어느 한 항에 있어서, 상기 염기성 수상이 알칼리 금속 탄산염을 함유하며, 상기 수상은 550 내지 1200℃ 에서 분해한 후 연소되며, 고체 알칼리 금속 탄산염이 수득되어 알칼리 금속 탄산염이 염기성 수용액을 제조하는데 재사용되는 것을 특징으로 하는 방법.
- 명세서, 도면 및 실시예서 실질적으로 기술된 것과 같은 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE9301446A BE1007904A3 (nl) | 1993-12-23 | 1993-12-23 | Werkwijze voor de bereiding van een alkanol en/of een alkanon. |
BE09301446 | 1993-12-23 |
Publications (1)
Publication Number | Publication Date |
---|---|
KR950017887A true KR950017887A (ko) | 1995-07-20 |
Family
ID=3887673
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019940036148A KR950017887A (ko) | 1993-12-23 | 1994-12-23 | 알칸온 및/또는 알칸올의 제조방법 |
Country Status (17)
Country | Link |
---|---|
US (1) | US5859301A (ko) |
EP (1) | EP0659726B1 (ko) |
JP (1) | JPH07247230A (ko) |
KR (1) | KR950017887A (ko) |
CN (1) | CN1071301C (ko) |
BE (1) | BE1007904A3 (ko) |
BR (1) | BR9405216A (ko) |
CA (1) | CA2138751A1 (ko) |
CZ (1) | CZ327894A3 (ko) |
DE (1) | DE69421506T2 (ko) |
ES (1) | ES2139047T3 (ko) |
HU (1) | HU218388B (ko) |
MX (1) | MX9500220A (ko) |
PL (1) | PL179828B1 (ko) |
RU (1) | RU94044355A (ko) |
SK (1) | SK158294A3 (ko) |
TW (1) | TW358800B (ko) |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE1009662A3 (nl) * | 1995-10-13 | 1997-06-03 | Dsm Nv | Werkwijze voor het ontleden van cycloalkylhydroperoxide. |
DE69810944T2 (de) * | 1997-02-11 | 2003-11-13 | Du Pont | Hydroperoxidzersetzungsverfahren |
BE1011041A3 (nl) * | 1997-03-12 | 1999-04-06 | Dsm Nv | Werkwijze voor het ontleden van cycloalkylhydroperoxide. |
US6160183A (en) * | 1998-02-10 | 2000-12-12 | E. I. Du Pont De Nemours And Company | Direct oxidation of cycloalkanes |
FR2802526B1 (fr) * | 1999-12-17 | 2003-04-18 | Rhodia Polyamide Intermediates | Procede de preparation de melanges alcools/cetones |
US6700022B2 (en) * | 2002-06-05 | 2004-03-02 | E. I. Du Pont De Nemours And Company | High yield cyclohexyl hydroperoxide decompostition process |
AU2003233738A1 (en) * | 2002-06-05 | 2003-12-22 | University Technologies International Inc. | Oxygen reduction catalyst |
US20040158103A1 (en) * | 2003-02-11 | 2004-08-12 | Solutia Inc. | Cyclohexane oxidation catalysts |
US7081552B2 (en) * | 2004-08-17 | 2006-07-25 | Solutia Inc. | Catalysts for cycloalkanes oxidation and decomposition of cycloalkyl hydroperoxide |
WO2006033740A1 (en) * | 2004-08-24 | 2006-03-30 | Invista Technologies S.A.R.L. | Method for reducing cyclohexenone content of a cyclohexenone-containing organic mixture |
PL1841721T3 (pl) * | 2005-01-25 | 2018-10-31 | Cap Iii Bv | Sposób wytwarzania cykloheksanonu i cykloheksanolu |
US7199271B2 (en) | 2005-03-17 | 2007-04-03 | Invista North America S.A.R.L. | Method for reducing cyclohexenone content of a cyclohexenone-containing organic mixture |
US7834217B2 (en) | 2006-12-05 | 2010-11-16 | Daicel Chemical Industries, Ltd. | Method for producing oxidation product of cycloalkane |
WO2012063048A1 (en) | 2010-11-08 | 2012-05-18 | Kymab Limited | Cells & vertebrates for enhanced somatic hypermutation and class switch recombination |
ES2612935T3 (es) | 2011-09-19 | 2017-05-19 | Kymab Limited | Anticuerpos, dominios variables y cadenas adaptados para su uso en seres humanos |
WO2013041845A2 (en) | 2011-09-19 | 2013-03-28 | Kymab Limited | Animals, repertoires & methods |
EP2761008A1 (en) | 2011-09-26 | 2014-08-06 | Kymab Limited | Chimaeric surrogate light chains (slc) comprising human vpreb |
GB2496375A (en) | 2011-10-28 | 2013-05-15 | Kymab Ltd | A non-human assay vertebrate comprising human antibody loci and human epitope knock-in, and uses thereof |
GB201122047D0 (en) | 2011-12-21 | 2012-02-01 | Kymab Ltd | Transgenic animals |
WO2013144567A1 (en) | 2012-03-28 | 2013-10-03 | Kymab Limited | Transgenic non-human vertebrate for the expression of class - switched, fully human, antibodies |
GB2502127A (en) | 2012-05-17 | 2013-11-20 | Kymab Ltd | Multivalent antibodies and in vivo methods for their production |
JP6565926B2 (ja) * | 2014-10-31 | 2019-09-04 | 宇部興産株式会社 | ケトン及び/又はアルコールの製造方法及びそのシステム |
CN110871063B (zh) * | 2018-08-29 | 2022-09-27 | 中国石油化工股份有限公司 | 一种碳材料处理液及其制备方法、碳材料及其应用 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2851496A (en) * | 1954-07-27 | 1958-09-09 | Du Pont | Preparation of oxidation products of cyclohexane |
BE637653A (ko) * | 1963-09-19 | |||
DE2127520A1 (de) * | 1971-06-03 | 1972-12-14 | Badische Anilin- & Soda-Fabrik Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von Cycloalkanol- und Cycloalkanon-Gemischen |
DE2148322B2 (de) * | 1971-09-28 | 1977-02-10 | Davy International Ag, 6000 Frankfurt | Kreislaufverfahren zur entfernung der bei der partiellen oxidation von cycloalkan entstandenen carbonsaeuren und carbonsaeurederivate aus den erhaltenen oxidationsprodukten |
US4042630A (en) * | 1973-10-19 | 1977-08-16 | Stamicarbon B.V. | Process for the preparation of cycloalkanones and cycloalkanols |
NL7802125A (nl) * | 1978-02-25 | 1979-08-28 | Stamicarbon | Werkwijze voor het bereiden van cycloalkanolen en cycloalkanonen. |
NL8201695A (nl) * | 1982-04-23 | 1983-11-16 | Stamicarbon | Werkwijze voor de bereiding van cyclohexanol en cyclohexanon. |
DE3222144A1 (de) * | 1982-06-11 | 1983-12-15 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von cyclohexanol und cyclohexanon |
NL9100521A (nl) * | 1991-03-25 | 1992-10-16 | Stamicarbon | Werkwijze voor de bereiding van een alkanon en/of alkanol. |
NL9200187A (nl) * | 1992-02-03 | 1993-09-01 | Dsm Nv | Werkwijze voor de bereiding van cycloalkanon en/of cycloalkanol. |
US5206441A (en) * | 1992-04-06 | 1993-04-27 | E. I. Du Pont De Nemours And Company | High rate process for preparation of cyclohexanol and cyclohexanone |
-
1993
- 1993-12-23 BE BE9301446A patent/BE1007904A3/nl not_active IP Right Cessation
-
1994
- 1994-12-13 TW TW083111600A patent/TW358800B/zh active
- 1994-12-19 DE DE69421506T patent/DE69421506T2/de not_active Expired - Fee Related
- 1994-12-19 EP EP94203682A patent/EP0659726B1/en not_active Expired - Lifetime
- 1994-12-19 ES ES94203682T patent/ES2139047T3/es not_active Expired - Lifetime
- 1994-12-21 PL PL94306450A patent/PL179828B1/pl unknown
- 1994-12-21 HU HU9403725A patent/HU218388B/hu not_active IP Right Cessation
- 1994-12-21 JP JP6318840A patent/JPH07247230A/ja active Pending
- 1994-12-21 SK SK1582-94A patent/SK158294A3/sk unknown
- 1994-12-21 CA CA002138751A patent/CA2138751A1/en not_active Abandoned
- 1994-12-22 RU RU94044355/04A patent/RU94044355A/ru unknown
- 1994-12-22 BR BR9405216A patent/BR9405216A/pt not_active IP Right Cessation
- 1994-12-22 CZ CZ943278A patent/CZ327894A3/cs unknown
- 1994-12-22 CN CN94113210A patent/CN1071301C/zh not_active Expired - Fee Related
- 1994-12-23 US US08/363,238 patent/US5859301A/en not_active Expired - Fee Related
- 1994-12-23 KR KR1019940036148A patent/KR950017887A/ko not_active Application Discontinuation
-
1995
- 1995-01-02 MX MX9500220A patent/MX9500220A/es unknown
Also Published As
Publication number | Publication date |
---|---|
CA2138751A1 (en) | 1995-06-24 |
EP0659726A1 (en) | 1995-06-28 |
CN1107829A (zh) | 1995-09-06 |
DE69421506D1 (de) | 1999-12-09 |
RU94044355A (ru) | 1996-10-27 |
MX9500220A (es) | 1997-04-30 |
HUT69062A (en) | 1995-08-28 |
HU218388B (hu) | 2000-08-28 |
JPH07247230A (ja) | 1995-09-26 |
CZ327894A3 (en) | 1995-10-18 |
EP0659726B1 (en) | 1999-11-03 |
TW358800B (en) | 1999-05-21 |
CN1071301C (zh) | 2001-09-19 |
ES2139047T3 (es) | 2000-02-01 |
BR9405216A (pt) | 1995-08-01 |
HU9403725D0 (en) | 1995-03-28 |
SK158294A3 (en) | 1995-08-09 |
US5859301A (en) | 1999-01-12 |
PL306450A1 (en) | 1995-06-26 |
DE69421506T2 (de) | 2000-07-06 |
PL179828B1 (pl) | 2000-11-30 |
BE1007904A3 (nl) | 1995-11-14 |
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A201 | Request for examination | ||
E902 | Notification of reason for refusal | ||
E601 | Decision to refuse application |