KR940701425A - 경화할 수 있는 오르가노(폴리)실록산 조성물 - Google Patents

경화할 수 있는 오르가노(폴리)실록산 조성물

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KR940701425A
KR940701425A KR1019930703952A KR930703952A KR940701425A KR 940701425 A KR940701425 A KR 940701425A KR 1019930703952 A KR1019930703952 A KR 1019930703952A KR 930703952 A KR930703952 A KR 930703952A KR 940701425 A KR940701425 A KR 940701425A
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siloxane
unit
different
poly
same
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KR0134903B1 (ko
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스텝 미하엘
뮬러 요한
브렌넨스툴 베르너
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에리히 프랑크·칼-하인즈 림빅
와커-헤미 게엠베하
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C08L83/06—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes
    • C09D183/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C08L83/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/12—Polysiloxanes containing silicon bound to hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C08G77/18—Polysiloxanes containing silicon bound to oxygen-containing groups to alkoxy or aryloxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C08G77/28—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen sulfur-containing groups
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S522/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S522/904—Monomer or polymer contains initiating group

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  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Silicon Polymers (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Cosmetics (AREA)
  • Filling Or Emptying Of Bunkers, Hoppers, And Tanks (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
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Abstract

(A) 다음일반식(I)의 단위와, (B) 조사에 의해 가교시킬 수 있는 실록산단위와, 선택적으로 (C) 광개시제로서 작용하는 실록산단위를 포함한 경화할 수 있는 오르가노(폴리)실록산 조성물에 대한 것이다.

Description

경화할 수 있는 오르가노(폴리)실록산 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. (A) 다음일반식(I)의 단위와, (B) 조사에 의해 가교시킬 수 있는 실록산단위와, 적합할 경우 (C) 광개시제로서 작용하는 실록산단위로 구성됨을 특징으로 하는 오르가노(폴리)실록산 조성물.
    위식에서, R1및 R2는 서로 각각 각 경우 같거나 다르며, 1가의 선택치환되는 탄화수소 래디컬이다. a는 1 또는 2이다.
  2. 제1항에 있어서, 조사에 의해 가교시킬 수 있는 실록산단위(B)는 다음일반식(II) 및/또는 일반식(III)의 단위임을 특징으로 하는 오르가노(폴리)실록산 조성물.
    위식에서, G는 같거나 다르며, 적어도 하나의 티올기를 가진 1가의 유기래디컬이며, R3는 같거나 다르며, 1가의 선택치환되는 탄화수소래디컬이고, b는 0,1 또 2이고, h는 1,2 또는 3이며, R4는 적어도 하나의 지방족 탄소-탄소다중결합을 가진 1가의 유기래디컬이고, R5는 같거나 다르며, 1가의 선택치환되는 탄화수소래디컬이며, C는 0,1 또는 2이고, i는 1,2 또는 3이다. 단, b+h의 합과 c+i의 합은 각각의 경우 3과 같거나 더 작다.
  3. 제1항 또는 제2항에 있어서, 광개시제로서 작용하는 실록산단위(C)는 다음일반식(V)의 실록산단위임을 특징으로 하는 오르가노(폴리)실록산.
    위식에서, R7은 같거나 다르며, 1가의 선택치환되는 탄화수소래디컬이고, R8은 같거나 다르며, 1가의 선택치환되는 탄화수소래디컬이며, Z는 같거나 다르며 조사에 의해 프리래디컬을 생성하는 기이고, d는 0 또는 1이고, e는 0 또는 1이며, g는 1 또는 2이다. 단, 일반식(V)에서, d, e 및 g의 합은 3과 같거나 더 작다.
  4. 제1항 내지 제3항중 어느 한 항에 있어서, 일반식(VI)의 단위를 구성함을 특징으로 하는 오르가노(폴리)실록산 조성물.
    위식에서, R은 같거나 다르며, 1가의 선택치환되는 탄화수소래디컬이고, K는 0,1,2 또는 3이다.
  5. 국제특허출원 PCT/EP91/00795(Wacker-chemic GmbH, 1991. 4. 25, 출원)의 일반식(I)과 독일특허출원 P 411 4554. 7(Wacker-Chemic GmbH, 1991. 4. 25, 출원)의 일반식(I)에 포함된 오르가노(폴리)실록산을 제외하며, (A) 일반식(I)의 단위와 (B) 조사에 의해 가교할 수 있는 실록산단위로 구성됨을 특징으로 하는 오르가노(폴리)실록산.
    위식에서, R1및 R2는 서로 각각 각 경우 같거나 다르며, 1가의 선택치환되는 탄화수소래디컬이고, a는 1 또는 2다.
  6. (A) 일반식(I)의 단위와, (B) 조사에 의해 가교시킬 수 있는 실록산단위와, (C) 광개시제로서 작용하는 실록산단위를 구성함을 특징으로 하는 오르가노(폴리)실록산.
    위식에서, R1및 R2는 서로 각각, 각 경우 같거나 다르며 1가의 선택치환되는 탄화수소래디컬이고, a는 1 또는 2이다.
  7. (A) 일반식(I)의 단위와, (B) 광개시제로서 작용하는 실록산단위를 구성함을 특징으로 하는 오르가노(폴리)실록산.
    위식에서, R1및 R2는 서로 각각 각 경우 같거나 다르며, 1가의 선택치환되는 탄화수소래디컬이고, a는 1 또는 2이다.
  8. (B) 조사에 의해 가교시킬 수 있는 실록산단위와 (C) 광개시제로서 작용하는 실록산단위를 구성함을 특징으로 하는 오르가노(폴리)실록산.
  9. 적어도 하나의 다음일반식(V)의 단위를 구성함을 특징으로 하는 오르가노(폴리)실록산.
    위식에서, R7은 R8은 서로 각각 각 경우 같거나 다르며 1가의 선택치환되는 탄화수소래디컬이고, Z는 같거나 다르며, 조사에 의해 프리래디컬을 생성하는 기이며, d는 0 또는 1이고, e는 0 또는 1이며, g는 1 또는 2이다.
    단, 일반식(V)에서, d, e 및 g의 합은 2와 같거나 더 작다.
  10. 코팅제조용으로 제1항에 의한 오르가노(폴리)실록산 조성물의 사용.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930703952A 1991-06-20 1992-06-19 경화할 수 있는 오르가노(폴리)실록산 조성물 KR0134903B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DEP4120418.2 1991-06-20
DE4120418A DE4120418A1 (de) 1991-06-20 1991-06-20 Haertbare organo(poly)siloxanmassen
PCT/EP1992/001385 WO1993000405A1 (de) 1991-06-20 1992-06-19 Härtbare organo(poly)siloxanmassen

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KR940701425A true KR940701425A (ko) 1994-05-28
KR0134903B1 KR0134903B1 (ko) 1998-04-20

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Country Link
US (1) US5420222A (ko)
EP (1) EP0590020B1 (ko)
JP (1) JP2641623B2 (ko)
KR (1) KR0134903B1 (ko)
AT (1) ATE127504T1 (ko)
BR (1) BR9206164A (ko)
CA (1) CA2110980A1 (ko)
DE (2) DE4120418A1 (ko)
ES (1) ES2076770T3 (ko)
FI (1) FI935723A (ko)
MX (1) MX9203046A (ko)
NO (1) NO934680D0 (ko)
TW (1) TW248566B (ko)
WO (1) WO1993000405A1 (ko)

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US5420222A (en) 1995-05-30
KR0134903B1 (ko) 1998-04-20
EP0590020B1 (de) 1995-09-06
JP2641623B2 (ja) 1997-08-20
ES2076770T3 (es) 1995-11-01
NO934680L (no) 1993-12-17
MX9203046A (es) 1993-08-01
DE4120418A1 (de) 1992-12-24
FI935723A0 (fi) 1993-12-20
EP0590020A1 (de) 1994-04-06
DE59203597D1 (de) 1995-10-12
CA2110980A1 (en) 1993-01-07
JPH06503124A (ja) 1994-04-07
BR9206164A (pt) 1994-12-06
ATE127504T1 (de) 1995-09-15
WO1993000405A1 (de) 1993-01-07
TW248566B (ko) 1995-06-01
NO934680D0 (no) 1993-12-17
FI935723A (fi) 1993-12-20

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