KR940005648A - 윤활 첨가제로서 유용한 비스디티오인산 유도체 - Google Patents
윤활 첨가제로서 유용한 비스디티오인산 유도체 Download PDFInfo
- Publication number
- KR940005648A KR940005648A KR1019930009980A KR930009980A KR940005648A KR 940005648 A KR940005648 A KR 940005648A KR 1019930009980 A KR1019930009980 A KR 1019930009980A KR 930009980 A KR930009980 A KR 930009980A KR 940005648 A KR940005648 A KR 940005648A
- Authority
- KR
- South Korea
- Prior art keywords
- alkyl
- phenyl
- group
- hydrogen
- general formula
- Prior art date
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- 239000003879 lubricant additive Substances 0.000 title 1
- 125000000217 alkyl group Chemical group 0.000 claims abstract 8
- 150000001875 compounds Chemical class 0.000 claims abstract 8
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract 8
- 239000001257 hydrogen Substances 0.000 claims abstract 8
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract 8
- 239000000203 mixture Substances 0.000 claims abstract 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract 6
- 125000005037 alkyl phenyl group Chemical group 0.000 claims abstract 4
- 125000002947 alkylene group Chemical group 0.000 claims abstract 4
- 239000012530 fluid Substances 0.000 claims abstract 4
- 239000000654 additive Substances 0.000 claims abstract 2
- 125000000753 cycloalkyl group Chemical group 0.000 claims abstract 2
- 150000002431 hydrogen Chemical class 0.000 claims abstract 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract 2
- 239000000314 lubricant Substances 0.000 claims 4
- 239000010721 machine oil Substances 0.000 claims 3
- 125000006834 (C4-C20) alkylene group Chemical group 0.000 claims 1
- 239000005069 Extreme pressure additive Substances 0.000 claims 1
- 230000000996 additive effect Effects 0.000 claims 1
- 239000007866 anti-wear additive Substances 0.000 claims 1
- 239000003963 antioxidant agent Substances 0.000 claims 1
- 230000002708 enhancing effect Effects 0.000 claims 1
- 239000006078 metal deactivator Substances 0.000 claims 1
- 239000010705 motor oil Substances 0.000 claims 1
- 239000003381 stabilizer Substances 0.000 claims 1
- 239000002199 base oil Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M167/00—Lubricating compositions characterised by the additive being a mixture of a macromolecular compound, a non-macromolecular compound and a compound of unknown or incompletely defined constitution, each of these compounds being essential
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
- C07F9/1651—Esters of thiophosphoric acids with hydroxyalkyl compounds with further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M137/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
- C10M137/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
- C10M137/04—Phosphate esters
- C10M137/10—Thio derivatives
- C10M137/105—Thio derivatives not containing metal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/047—Thioderivatives not containing metallic elements
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/08—Hydraulic fluids, e.g. brake-fluids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/251—Alcohol fueled engines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/252—Diesel engines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/252—Diesel engines
- C10N2040/253—Small diesel engines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/255—Gasoline engines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/255—Gasoline engines
- C10N2040/26—Two-strokes or two-cycle engines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/255—Gasoline engines
- C10N2040/28—Rotary engines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Lubricants (AREA)
Abstract
본 발명은 윤활성 조성물, 유압액 및 기재유용 첨가제로서 사용하기에 특히 적합한 하기 일반식(Ⅰ)의 화합물에 관한 것이다.
상기식에서, R1및 R2은 각각 독립적으로 C3-C18알킬, C5-C12시클로알킬, C5-C6시클로알킬메틸, C9-C10비시클로알킬메틸, C9-C10트리시클로알킬메틸, 페닐, C7-C24알킬페닐 또는 함께 결합된
이고, R3는 중간에 -O-, -S-, 또는 -NR4-가 연결된 C2-C18알킬렌이거나, 또는 하기 일반식의 기
R4는 수소, C1-C18알킬, 페닐-C1-C4알킬, 페닐 또는 C1-C6알킬치환된 페닐이고, R5는 수소 또는 메틸
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (14)
- 하기 일반식(Ⅰ)의 화합물,상기식에서, R1및 R2은 각각 독립적으로 C3-C18알킬, C5-C12시클로알킬, C5-C6시클로알킬메틸, C9-C10비시클로알킬메틸, C9-C10트리시클로알킬메틸, 페닐, C7-C24알킬페닐 또는 함께 결합된이고, R3는 중간에 -O-, -S-, 또는 -NR4-가 연결된 C2-C18알킬렌이거나, 또는 하기 일반식의 기R4는 수소, C1-C18알킬, 페닐-C1-C4알킬, 페닐 또는 C1-C6알킬치환된 페닐이고, R5는 수소 또는 메틸 이며, b는 3 내지 18의 정수이다.
- 제1항에 있어서, R1및 R2기 각각 독립적으로 C3-C10알킬, C5-C6시클로알킬, C5-C6시클로알킬메틸. C9-Cl0비시클로알킬메틸, C9-C10트티시클로알킬메틸, 페닐, C7-C18알킬페닐 또는 함께 결합된이고, R3는 -(CH2)B-, 중간에 -O- 또는 -NR4가 연결된 C4-C20알킬렌이거나, 또는 하기 일반식의 기R4는 수소 또는 C1-C4알킬이고, b가 3 내지 10의 정수인 화합물.
- 제1항에 있어서. R3가 -(CH2)b-, 중간에 -0- 또는 NR4가 연결된 C4-C12알킬렌, 또는 하기 일반식의 기R4는 C1-C4알킬이고 b는 3 내지 6의 정수인 화합물.
- 제1항에 있어서, R1및 R2가 C3-C8알킬인 화합물.
- 제1항에 있어서, R5가 수소인 화합물.
- 하기 물질을 포함하는 조성물 : a) 윤활제, 기계유 또는 유압액, 및 b) 제1항에 따른 일반식(Ⅰ)의 화합물.
- 제6항에 있어서, Rl및 R2가 각각 독립적으로 C3-C10알킬. C5-C6시클로알킬, C5-C6-시클로알킬메틸, C9-C10비시클로알킬메틸, C9-C10트리시클로알킬메틸, 페닐. C7-Cl8알킬페닐 또는 함께 결합된이고, R3는 -(CH2)b-, 중간에 -0- 또는 NR4가 연결된 C4-C20알킬렌, 또는 하기 일반식의 기이며, R4는 수소 또는 Cl-C4알킬이고 b가 3 내지 10의 정수인 조성물.
- 제6항에 있어서, R3가 -(CH2)b-, 중간에 -0- 또는 NR4가 연결된 C4-C12알킬렌, 또는 하기 일반식의 기이며, R4가 C1-C4알킬이고 b가 3 내지 6의 정수인 조성물.
- 제6항에 있어서, R5가 수소인 조성물.
- 제6항에 있어서, 성분 a)가 윤활제인 조성물.
- 제10항에 있어서, 상기 윤활제가 엔진 오일인 조성물.
- 제6항에 있어서, 산화 방지제, 금속 탈활성화제로 이루어진 군으로부터 선택된 안정화제, 극압 및 마모방지 첨가제와 유동점 강하제를 부가적으로 포함하는 조성물.
- 제1항에 정의된 일반식 (Ⅰ) 화합물의 윤활제, 유압액 및 기계유용 첨가제로서의 용도.
- 제1항에 정의된 일반식 (Ⅰ) 화합물 1이상을 부가함으로써 윤활성 조성물, 유압액 및 기계유의 기능 특성을 증진시키는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH177392 | 1992-06-02 | ||
CH92-4/1773 | 1992-06-02 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR940005648A true KR940005648A (ko) | 1994-03-22 |
KR100274362B1 KR100274362B1 (ko) | 2000-12-15 |
Family
ID=4218272
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019930009980A KR100274362B1 (ko) | 1992-06-02 | 1993-06-01 | 윤활 첨가제로서 유용한 비스디티오인산 유도체 |
Country Status (10)
Country | Link |
---|---|
US (2) | US6380139B1 (ko) |
JP (1) | JP3577600B2 (ko) |
KR (1) | KR100274362B1 (ko) |
CA (1) | CA2097383C (ko) |
DE (1) | DE4317980B9 (ko) |
FR (1) | FR2691708B1 (ko) |
GB (1) | GB2267493B (ko) |
IT (1) | IT1270822B (ko) |
MX (1) | MX9303254A (ko) |
TW (1) | TW229226B (ko) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE59703420D1 (de) * | 1996-07-15 | 2001-05-31 | Ciba Sc Holding Ag | Beta-Dithiophosphorylierte Propionsäure in Schmierstoffen |
EP1405898A1 (en) * | 2002-10-02 | 2004-04-07 | Infineum International Limited | Lubricant composition |
CN1497043A (zh) * | 2002-10-02 | 2004-05-19 | 英菲诺姆国际有限公司 | 润滑油组合物 |
US7759294B2 (en) * | 2003-10-24 | 2010-07-20 | Afton Chemical Corporation | Lubricant compositions |
US7601677B2 (en) * | 2004-08-11 | 2009-10-13 | Daniel Graiver | Triglyceride based lubricant |
US8466096B2 (en) * | 2007-04-26 | 2013-06-18 | Afton Chemical Corporation | 1,3,2-dioxaphosphorinane, 2-sulfide derivatives for use as anti-wear additives in lubricant compositions |
CN106317109B (zh) * | 2015-06-17 | 2019-01-25 | 徐工集团工程机械股份有限公司 | 一种硫代磷酸酯型抗磨剂 |
KR101827503B1 (ko) * | 2016-03-24 | 2018-03-23 | 한국화학연구원 | 디알킬 디티오포스페이트 그룹을 포함하는 디카르복실산 유도체 및 이를 포함하는 내마모제 및 윤활제 조성물 |
KR101785337B1 (ko) * | 2016-04-11 | 2017-10-18 | 한국화학연구원 | 중금속이 함유되지 않은 디카르복실산 유도체 및 이를 포함하는 내마모제 및 윤활제 조성물 |
KR101907871B1 (ko) * | 2017-03-31 | 2018-10-16 | 한국화학연구원 | 디카르복실산 유도체 및 이를 포함하는 내마모제 및 윤활유 조성물 |
WO2024005185A1 (ja) * | 2022-06-30 | 2024-01-04 | 出光興産株式会社 | 潤滑油用添加剤組成物及び潤滑油組成物 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1154095B (de) * | 1961-12-23 | 1963-09-12 | Basf Ag | Verfahren zur Herstellung von O, O-Dialkyldithiophosphorylessigsaeureestern |
US3350348A (en) * | 1965-04-05 | 1967-10-31 | Mobil Oil Corp | Lubricating oil additives |
US3567638A (en) * | 1968-09-26 | 1971-03-02 | Mobil Oil Corp | Novel phosphorus-containing adducts in oil compositions containing the same |
GB1287331A (en) * | 1970-01-29 | 1972-08-31 | Ciba Geigy Uk Ltd | Phosphorodithioic acid esters |
GB1367633A (en) * | 1970-08-14 | 1974-09-18 | Girling Ltd | Abutment assembly for internal shoe vehicle drum brakes |
US3712878A (en) | 1970-08-25 | 1973-01-23 | Uniroyal Inc | O,o,s-triesters of phosphorodithioic acid as accelerators in the sulfur vulcanization of epdm rubbers |
GB1347845A (en) * | 1970-09-05 | 1974-02-27 | Ciba Geigy Uk Ltd | Lubricating compositions containing phosphorodithioate esters |
US4081387A (en) | 1977-03-25 | 1978-03-28 | The Lubrizol Corporation | Phosphorus-containing lubricating compositions |
US4544492A (en) * | 1983-05-09 | 1985-10-01 | Ciba-Geigy Corporation | Lubricant compositions |
CH668265A5 (de) * | 1985-09-09 | 1988-12-15 | Lonza Ag | Verfahren zur herstellung von schmierwirkstoffen in pulvriger bis pastoeser form. |
ATE142250T1 (de) * | 1990-06-29 | 1996-09-15 | Tonen Corp | Hydraulik-, schmier- und kupplungsmittelzusammensetzung, die einen organopolysiloxan und einen phosphor enthaltenden additiv enthält. |
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1993
- 1993-05-12 TW TW082103722A patent/TW229226B/zh active
- 1993-05-26 GB GB9310859A patent/GB2267493B/en not_active Expired - Lifetime
- 1993-05-28 DE DE4317980A patent/DE4317980B9/de not_active Expired - Lifetime
- 1993-05-31 JP JP15279193A patent/JP3577600B2/ja not_active Expired - Lifetime
- 1993-05-31 CA CA002097383A patent/CA2097383C/en not_active Expired - Lifetime
- 1993-06-01 KR KR1019930009980A patent/KR100274362B1/ko not_active IP Right Cessation
- 1993-06-01 MX MX9303254A patent/MX9303254A/es not_active IP Right Cessation
- 1993-06-01 IT ITMI931152A patent/IT1270822B/it active IP Right Grant
- 1993-06-01 FR FR9306510A patent/FR2691708B1/fr not_active Expired - Lifetime
-
1995
- 1995-05-26 US US08/451,378 patent/US6380139B1/en not_active Expired - Lifetime
-
2002
- 2002-03-28 US US10/112,436 patent/US20020151444A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
GB2267493B (en) | 1995-09-27 |
US6380139B1 (en) | 2002-04-30 |
JP3577600B2 (ja) | 2004-10-13 |
US20020151444A1 (en) | 2002-10-17 |
FR2691708B1 (fr) | 1996-10-31 |
GB9310859D0 (en) | 1993-07-14 |
KR100274362B1 (ko) | 2000-12-15 |
JPH0641160A (ja) | 1994-02-15 |
GB2267493A (en) | 1993-12-08 |
FR2691708A1 (fr) | 1993-12-03 |
TW229226B (ko) | 1994-09-01 |
DE4317980A1 (de) | 1993-12-09 |
DE4317980B4 (de) | 2007-03-22 |
ITMI931152A1 (it) | 1994-12-01 |
MX9303254A (es) | 1994-01-31 |
CA2097383C (en) | 2005-11-15 |
IT1270822B (it) | 1997-05-13 |
CA2097383A1 (en) | 1993-12-03 |
ITMI931152A0 (it) | 1993-06-01 |
DE4317980B9 (de) | 2007-07-26 |
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