KR920012119A - 기계적 특성이 우수하고 이력특성이 개선된 고무 가황물 - Google Patents

기계적 특성이 우수하고 이력특성이 개선된 고무 가황물 Download PDF

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KR920012119A
KR920012119A KR1019910022099A KR910022099A KR920012119A KR 920012119 A KR920012119 A KR 920012119A KR 1019910022099 A KR1019910022099 A KR 1019910022099A KR 910022099 A KR910022099 A KR 910022099A KR 920012119 A KR920012119 A KR 920012119A
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South Korea
Prior art keywords
rubber
weight
cycloalkyl
aryl
alkyl
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KR1019910022099A
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English (en)
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KR100220110B1 (ko
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솔 토마스
바이덴하우프트 헤르만-요세프
엥겔스 한스-빌헬름
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바이엘 아크티엔게젤샤프트
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Publication of KR920012119A publication Critical patent/KR920012119A/ko
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/10Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton
    • C07C323/11Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
    • C07C323/12Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08CTREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00Chemical modification of rubber
    • C08C19/20Incorporating sulfur atoms into the molecule
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/36Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/37Thiols
    • C08K5/372Sulfides, e.g. R-(S)x-R'

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

내용 없음

Description

기계적 특성이 우수하고 이력특성이 개선된 고무 가황물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (3)

  1. 하나 이상의 고무, 가교 결합제, 충전제, 임의의 기타의 고무용 보조 생성물 및 고무를 기준으로 하여 0.1내지 15중량%의 양으로 존재하며 일반식(I) 및/또는 (II)에 상응하는 하나 이상의 황화성 보강 첨가제로부터 제조된 고무 가황물.
    상기식에서, R1내지 R4는 동일하거나 상이하며, 수소, C1-C6-알킬, C5-C6-사이클로알킬, C6-C10-아릴 또는 일반식 CH2-O-R5또는 -CH2-CH2-OR5(여기서, R5는 수소, C1-C6알킬, C5-C6-사이클로알킬, C6-C10-아릴 또는 C1-C6-아실이다)의 그룹을 나타내고, x는 2 내지 6의 정수이다.
  2. 하나 이상의 고무를 120℃ 이상의 반응온도 및 1 내지 100SEC-1의 전단속도하에 고무(i)을 기준으로 하여 10 내지 120중량%, 바람직하게는 30 내지 80중량%의 충전제 및 고무(i)을 기준으로 하여 0.1 내지 15중량%, 바람직하게는 0.1 내지 7.5중량%의 일반식(I) 및/또는 (II)의 황화성 화합물과 혼합한 다음, 혼합물을 통상적인 방법으로 가황시킴을 특징으로 하여, 충전된 고무 가황물을 제조하는 방법.
    상기식에서, R1내지 R4는 동일하거나 상이하며, 수소, C1-C6-알킬, C5-C6-사이클로알킬, C6-C10-아릴 또는 일반식 CH2-O-R5또는 -CH2-CH2-OR5(여기서, R5는 수소, C1-C6알킬, C5-C6-사이클로알킬, C6-C10-아릴 또는 C1-C6-아실이다)의 그룹을 나타내고, x는 2 내지 6의 정수이다.
  3. 하기 구조식의 올리고설파이드.
    ※ 참고사항: 최초출원 내용에 의하여 공개하는 것임.
KR1019910022099A 1990-12-04 1991-12-04 기계적 특성이 우수하고 이력특성이 개선된 고무 가황물 및 이의 제조방법 KR100220110B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP4038589.2 1990-12-04
DE4038589A DE4038589A1 (de) 1990-12-04 1990-12-04 Kautschukvulkanisate mit guten mechanischen eigenschaften und verbessertem hystereseverhalten

Publications (2)

Publication Number Publication Date
KR920012119A true KR920012119A (ko) 1992-07-25
KR100220110B1 KR100220110B1 (ko) 1999-09-01

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Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019910022099A KR100220110B1 (ko) 1990-12-04 1991-12-04 기계적 특성이 우수하고 이력특성이 개선된 고무 가황물 및 이의 제조방법

Country Status (5)

Country Link
EP (1) EP0489313B1 (ko)
JP (1) JPH0543741A (ko)
KR (1) KR100220110B1 (ko)
DE (2) DE4038589A1 (ko)
ES (1) ES2075308T3 (ko)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5733963A (en) 1996-02-20 1998-03-31 The Goodyear Tire & Rubber Company Silica reinforced rubber composition and tire with tread thereof
US5723531A (en) * 1997-04-30 1998-03-03 The Goodyear Tire & Rubber Company Rubber composition and tire having tread thereof
EP1412423B1 (en) * 2001-07-18 2012-04-11 Imerys Minerals Limited Clay mineral products and their use in rubber compositions
FR2854404B1 (fr) * 2003-04-29 2005-07-01 Michelin Soc Tech Procede d'obtention d'un elastomere greffe a groupes fonctionnels le long de la chaine et compositions de caoutchouc
EP2517898A1 (de) 2011-04-29 2012-10-31 Lanxess Deutschland GmbH Kieselsäurehaltige Kautschukmischungen mit schwefelhaltigen Additiven
EP2517899A1 (de) * 2011-04-29 2012-10-31 Lanxess Deutschland GmbH Verfahren zur Herstellung von Kautschukmischungen
EP2671727A1 (de) 2012-06-06 2013-12-11 LANXESS Deutschland GmbH Kieselsäurehaltige Kautschukmischungen mit schwefelhaltigen Additiven
EP2671726A1 (de) 2012-06-06 2013-12-11 LANXESS Deutschland GmbH Kieselsäurehaltige Kautschukmischungen mit schwefelhaltigen Additiven
EP2684912A1 (de) 2012-07-09 2014-01-15 LANXESS Deutschland GmbH Kieselsäurehaltige Kautschukmischungen enthaltend w-Mercaptocarbonsäureester von mehrwertigen Alkoholen
EP2711198A1 (de) 2012-09-24 2014-03-26 LANXESS Deutschland GmbH Polysulfid-Additive, Verfahren zu deren Herstellung und deren Verwendung in Kautschukmischungen
RU2015115271A (ru) 2012-09-24 2016-11-20 ЛЕНКСЕСС Дойчланд ГмбХ Полисульфидные добавки, способ их получения и их применение в резиновых смесях
EP2724870A1 (de) 2012-10-25 2014-04-30 LANXESS Deutschland GmbH Polysulfidmischungen, Verfahren zu ihrer Herstellung und Verwendung der Polysulfidmischungen in Kautschukmischungen
DE202012013472U1 (de) 2012-10-25 2017-02-02 Lanxess Deutschland Gmbh Polysulfidmischungen, Verfahren zu ihrer Herstellung und Verwendung der Polysulfidmischungen in Kautschukmischungen
EP2727907B1 (de) 2012-10-30 2015-05-13 LANXESS Deutschland GmbH Polysulfidmischung, Verfahren zu ihrer Herstellung und Verwendung der Polysulfidmischung in Kautschukmischungen
WO2014118073A1 (en) * 2013-01-29 2014-08-07 Basf Se Polysulfide polyols, their production and use in the synthesis of polyurethanes

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE918927C (de) * 1952-03-25 1954-10-07 Bayer Ag Verfahren zur Herstellung von Bis-(ª‰-oxyalkyl)-polysulfiden
US3662004A (en) * 1968-04-23 1972-05-09 Henkel & Cie Gmbh Process for producing hydroxyalkyl mercaptans
DE3604793A1 (de) * 1986-02-15 1987-08-20 Henkel Kgaa Alkylsubstituierte 1.6-dihydroxy-3.4-sulfahexane, verfahren zu ihrer herstellung und ihre verwendung

Also Published As

Publication number Publication date
DE59106219D1 (de) 1995-09-14
EP0489313A1 (de) 1992-06-10
JPH0543741A (ja) 1993-02-23
KR100220110B1 (ko) 1999-09-01
EP0489313B1 (de) 1995-08-09
ES2075308T3 (es) 1995-10-01
DE4038589A1 (de) 1992-06-11

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