KR910004745A - 고당량 활성 수소화합물-알킬렌 글리콜 조성물 및 이의 제법 - Google Patents

고당량 활성 수소화합물-알킬렌 글리콜 조성물 및 이의 제법 Download PDF

Info

Publication number
KR910004745A
KR910004745A KR1019900013085A KR900013085A KR910004745A KR 910004745 A KR910004745 A KR 910004745A KR 1019900013085 A KR1019900013085 A KR 1019900013085A KR 900013085 A KR900013085 A KR 900013085A KR 910004745 A KR910004745 A KR 910004745A
Authority
KR
South Korea
Prior art keywords
active hydrogen
compound
composition
amine
weight
Prior art date
Application number
KR1019900013085A
Other languages
English (en)
Inventor
카스웰 로버트
Original Assignee
리챠드 지. 워터맨
더 다우 케미칼 캄파니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 리챠드 지. 워터맨, 더 다우 케미칼 캄파니 filed Critical 리챠드 지. 워터맨
Publication of KR910004745A publication Critical patent/KR910004745A/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
    • C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
    • C08L71/12—Polyphenylene oxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/21—Urea; Derivatives thereof, e.g. biuret
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/24—Catalysts containing metal compounds of tin
    • C08G18/242—Catalysts containing metal compounds of tin organometallic compounds containing tin-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
    • C08G18/3823—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing -N-C=O groups
    • C08G18/3829—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing -N-C=O groups containing ureum groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
    • C08G18/5024—Polyethers having heteroatoms other than oxygen having nitrogen containing primary and/or secondary amino groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/6505—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen the low-molecular compounds being compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6511—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen the low-molecular compounds being compounds of group C08G18/32 or polyamines of C08G18/38 compounds of group C08G18/3203
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/797—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing carbodiimide and/or uretone-imine groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
    • C08K5/57—Organo-tin compounds
    • C08K5/58—Organo-tin compounds containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2120/00—Compositions for reaction injection moulding processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2130/00—Compositions of compatibilising agents used in mixtures of high-molecular-weight compounds having active hydrogen with other compounds having active hydrogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

내용 없음.

Description

고당량 활성 수소화합물-알킬렌 글리콜 조성물 및 이의 제법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. (A)분자 1개당 평균 약 1.8개 이상의 활성수소 함유 그룹을 함유하며 평균분자량은 활성수소 함유 그룹 1개당 500 내지 5,000인, 당량이 비교적 큰 활성수소 화합물; (B)알킬렌 글리콜; 및 (C)촉매량의 주석 머캅타이드중 하나 이상을 함유하며, 하나 이상의 N-H함유 그룹을 함유하는 화합물중 하나 이상을 함유하는 활성수소화합물-알킬렌 글리콜 조성물.
  2. 제1항에 있어서, 주석 머캅타이드가 디알킬 주석 디머캅타이드인 조성물.
  3. 제2항에 있어서, 디알킬 주석 디머캅타이드가 구조식이 다음 일반식(I)인 조성물;
    상기식에서, R1, R2, R3및 R4는 알킬 그룹 또는 아실 그룹(-C(=0)-R5)이다.
  4. 제34항에 있어서, 성분(A)가 하나 이상의 아민 말단된 폴리에테르 폴리올인 조성물.
  5. 제4항에 있어서, 하나 이상의 N-H 함유 그룹을 함유하는 화합물이, 성분(A)에 존재하는 아민화합물과 상이한 조성물.
  6. 제3항에 있어서, 성분(A)가 단지 아민 그룹 함유 물질의 조성물.
  7. 제3항에 있어서, 하나 이상의 N-H 함유 그룹을 함유하는 화합물이 비치환되거나 에테르 치환된 지방족 또는 지환족 1급-또는 2급-모노아민화합물; 트리알킬 아민; 히드록실 아민;3급-아민;분자량이 약 500 미만인 아민 말단된 폴리에테르, 헥사메틸렌 디아민 또는 디에틸렌트리아민; 히드로카빌 치환된 방향족 아민; 또는 이들의 혼합물인 조성물.
  8. 제5항 또는 제7항에 있어서, 성분(A) 100중량부에 대하여 주석 머캅타이드의 양이 0.05 내지 5중량부이고 알킬렌 글리콜의 양은 10 내지 40중량부이고; 글리콜에 대한 아민의 중량비는 0.05 내지 4인 조성물.
  9. 제5항에 있어서, 하나 이상의 N-H 함유 그룹을 함유하는 화합물이 우레아 또는 티오우레아화합물중의 하나 이상인 조성물.
  10. 제1항 내지 제9항중의 어느 한 항에 따른 조성물과 폴리이소시아네이트와 반응생성물인 폴리우레탄 중합체.
  11. (A)분자 1개당 평균 약 1.8개 이상의 활성수소 함유 그룹을 함유하며 평균분자량은 활성수소 함유 그룹 1개당 500 내지 5,000인, 당량이 비교적 큰 활성수소 화합물; (B)알킬렌 글리콜; 및 (C)촉매량의 주석 머캅타이드중 하나 이상을 함유하는 단계를 포함하여, 하나 이상의 N-H함유 그룹을 함유하는 화합물중 하나 이상을 함유하는 활성수소 화합물-알킬렌 글리콜조성물을 제조하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900013085A 1989-08-25 1990-08-24 고당량 활성 수소화합물-알킬렌 글리콜 조성물 및 이의 제법 KR910004745A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US398,806 1989-08-25
US07/398,806 US5057543A (en) 1989-08-25 1989-08-25 Blends of alkylene glycols and relatively high equivalent weight active hydrogen compounds containing additives

Publications (1)

Publication Number Publication Date
KR910004745A true KR910004745A (ko) 1991-03-29

Family

ID=23576881

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019900013085A KR910004745A (ko) 1989-08-25 1990-08-24 고당량 활성 수소화합물-알킬렌 글리콜 조성물 및 이의 제법

Country Status (7)

Country Link
US (1) US5057543A (ko)
EP (1) EP0415284A3 (ko)
JP (1) JPH0391521A (ko)
KR (1) KR910004745A (ko)
AU (1) AU6135390A (ko)
BR (1) BR9004288A (ko)
CA (1) CA2023978A1 (ko)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5240964A (en) * 1990-09-19 1993-08-31 Tokyo Seat Co., Ltd. Process for producing urethane foam with high density skin
US5212209A (en) * 1991-11-18 1993-05-18 The Dow Chemical Company Compatibilized internal mold release composition for preparations of foamed and fiber-reinforced polymeric articles
DE69527224T2 (de) * 1994-04-15 2002-10-17 Ppg Industries Ohio, Inc. Beschichtungsverfahren
US5714562A (en) * 1996-06-12 1998-02-03 Bayer Corporation Light stable elastomers having good dynamic properties

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3753933A (en) * 1972-04-24 1973-08-21 Dow Chemical Co Polyurethane foams from solid foaming agents
US3980579A (en) * 1974-10-18 1976-09-14 Olin Corporation Catalytically stable halogenated polyol composition
US4125487A (en) * 1977-05-23 1978-11-14 The Dow Chemical Company Non-cellular and cellular composites of polyurethanes and vinyl polymers
EP0002724A1 (en) * 1977-12-23 1979-07-11 Mobay Chemical Corporation Process for the production of elastomeric polyurethane moldings and the product of this process
US4239857A (en) * 1978-06-29 1980-12-16 Union Carbide Corporation Process for producing solid or microcellular polyurethane elastomers having improved green strength
US4269945A (en) * 1980-01-24 1981-05-26 The Dow Chemical Company Reaction injection molded polyurethanes employing aliphatic amine chain extenders
US4296212A (en) * 1980-08-27 1981-10-20 The Upjohn Company Elastomeric polyurethane-polyurea polymer prepared from an organic polyisocyanate a polyol and an aromatic diamine having at least one of the ortho positions to each amine lower alkyl
US4362824A (en) * 1981-05-29 1982-12-07 Texaco Inc. Method for making RIM polyurethane elastomers using as the catalyst system dimethylethanolamine, dibutyltin dilaurate and an alkyltin mercaptide
DE3147736A1 (de) * 1981-12-02 1983-06-09 Bayer Ag, 5090 Leverkusen Verfahren zur herstellung von elastischen formkoerpern
US4435349A (en) * 1982-04-05 1984-03-06 Texaco Inc. Method for making a reinforced rim elastomer
US4444910A (en) * 1982-04-23 1984-04-24 Texaco Inc. Reaction injection molded elastomers made using a polyurethane organometallic catalyst amine terminated polyethers amine terminated chain extender and aromatic polyisocyanate
US4433067A (en) * 1982-04-23 1984-02-21 Texaco Inc. Reaction injection molded elastomers prepared from amine terminated polyethers, amine terminated chain extender and aromatic polyisocyanate
US4548919A (en) * 1982-12-17 1985-10-22 American Cyanamid Company Catalyst compositions for polyaliphatic isocyanate-based polyurethanes
US4485031A (en) * 1983-09-12 1984-11-27 The Dow Chemical Company Compatible mixtures of aminated polyether polyols and low molecular weight glycols
US4485032A (en) * 1983-09-12 1984-11-27 The Dow Chemical Company Compatible polyol blends
DE3347574A1 (de) * 1983-12-30 1985-07-11 Bayer Ag, 5090 Leverkusen Einphasig lagerstabile, salzhaltige gemische und ihre verwendung zur herstellung von polyurethanen
US4547478A (en) * 1984-03-09 1985-10-15 American Cyanamid Company Catalyst systems for polyurethane compositions
US4585803A (en) * 1984-08-17 1986-04-29 The Dow Chemical Company Internal mold release compositions
US4595743A (en) * 1985-01-22 1986-06-17 The Dow Chemical Company High modulus polyurea elastomers prepared with amine-initiated polyols
US4745137A (en) * 1986-06-25 1988-05-17 The Dow Chemical Company Polyurethanes prepared from solutions or dispersions of polymers of rigid polyaromatic monomers in polyols
US4673696A (en) * 1986-07-03 1987-06-16 Ashland Oil, Inc. Thermoset molding compositions
DE3626673A1 (de) * 1986-08-07 1988-02-11 Bayer Ag Trennmittelkomposition, diese trennmittelkomposition enthaltende gemische, ein verfahren zur herstellung von elastischen formkoerpern und die nach diesem verfahren erhaltenen formkoerper
US4742091A (en) * 1986-08-13 1988-05-03 Texaco Inc. Rim elastomer
DE3631842A1 (de) * 1986-09-19 1988-03-24 Basf Ag Innere formtrennmittel, deren verwendung zur herstellung von formkoerpern nach dem polyisocyanat-polyadditionsverfahren und verfahren zur herstellung der formkoerper
US4751253A (en) * 1986-10-06 1988-06-14 Tylenda Eugene J Method of preparing dimensionally stable, flexible urethane foam and the foam produced thereby
DE3639502A1 (de) * 1986-11-20 1988-06-01 Bayer Ag Trennmittelkomposition, diese trennmittelkomposition enthaltende gemische, ein verfahren zur herstellung von elastischen formkoerpern und die nach diesem verfahren enthaltenen formkoerper
EP0268906A3 (en) * 1986-11-26 1988-12-07 The Dow Chemical Company Compatibilized blends of alpha, omega-alkylene glycols and polyether polyols and process for preparing the same
US4719247A (en) * 1987-02-10 1988-01-12 Ici Americas Inc. Deformable polyurethane having improved cure time
US4751251A (en) * 1987-05-19 1988-06-14 Dow Corning Corporation Surfactant composition for rigid urethane and isocyanurate foams
US4755321A (en) * 1987-05-22 1988-07-05 Ashland Oil, Inc. Storage stable polyol compositions
DE3726426A1 (de) * 1987-08-08 1989-02-16 Bayer Ag Verfahren zur herstellung von polyurethan-(harnstoff)-schaumstoffen

Also Published As

Publication number Publication date
AU6135390A (en) 1991-02-28
EP0415284A3 (en) 1991-04-24
EP0415284A2 (en) 1991-03-06
US5057543A (en) 1991-10-15
CA2023978A1 (en) 1991-02-26
JPH0391521A (ja) 1991-04-17
BR9004288A (pt) 1991-09-03

Similar Documents

Publication Publication Date Title
KR940000495A (ko) 수-분산성 폴리아민-에폭시 첨가생성물 및 에폭시 코우팅 조성물
KR960017719A (ko) 자체-유화 에폭시 경화제
KR910008099A (ko) 물을 사용하는 코팅 조성물. 여기에 사용되는 결합제 및 이 결합제의 제조 방법
KR900003298A (ko) 티타늄 에스테르 촉진제를 함유하는 신속히 경화되는 폴리우레탄 시일런트 조성물
KR880007634A (ko) 폴리우레탄 포움 제조를 위한 폴리실록산-폴리옥시알킬렌조성물
KR880002817A (ko) 히드록시알킬 카르바메이트와 그 제조방법 및 용도
US4178426A (en) Epoxy resin compositions
GB1114328A (en) Reaction products of alkylene oxides and urea derivatives and polyurethanes produced therefrom
KR910015622A (ko) 선형-연장된 폴리알킬렌폴리아민의 제조방법
KR910004745A (ko) 고당량 활성 수소화합물-알킬렌 글리콜 조성물 및 이의 제법
KR920004498A (ko) 고강성 폴리아세탈 수지 조성물
KR880006320A (ko) α, W-알킬렌글리콜과 폴리에테르폴리올의 혼화된 배합물 및 이의 제조방법
KR930008097A (ko) 비수성 농화제
KR900018324A (ko) 습기-경화성 봉합재 조성물
KR910004711A (ko) 다목적 첨가제를 함유하는 알킬렌 글리콜과 비교적 고당량인 활성 수소화합물의 혼합물 및 이의 제조방법
KR830007781A (ko) 폴리우 레탄 접착제
GB1456277A (en) Polyether urethane foams and polysiloxane fluids thereof
KR870005022A (ko) 이오넨 탄성체의 제법
KR960705793A (ko) 에테르화된 알킬 또는 아릴카바밀메틸화된 아미노트리아진 및 이를 함유하는 경화성 조성물(etherified alkyl or arylcarbamylmethylated aminotri-azines and curable compositions containing the same)
EP0607319B1 (en) Use of a triethanolamine product mixture
KR900006439A (ko) 피복 조성물
KR960706516A (ko) 경화성 조성물(Curable Composition)
KR920006404A (ko) 폴리글리시드아미드-폴리(메트)-아크릴로일- 폴리아미드 조성물
KR890005165A (ko) 폴리우레탄 우레아 탄성중합체의 제조 방법
KR890008193A (ko) 알콕시화 디에틸톨루엔 디아민을 첨가한 폴리우레탄

Legal Events

Date Code Title Description
WITN Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid