KR890008193A - 알콕시화 디에틸톨루엔 디아민을 첨가한 폴리우레탄 - Google Patents

알콕시화 디에틸톨루엔 디아민을 첨가한 폴리우레탄 Download PDF

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KR890008193A
KR890008193A KR1019880015278A KR880015278A KR890008193A KR 890008193 A KR890008193 A KR 890008193A KR 1019880015278 A KR1019880015278 A KR 1019880015278A KR 880015278 A KR880015278 A KR 880015278A KR 890008193 A KR890008193 A KR 890008193A
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diethyltoluenediamine
crosslinking agent
alkoxylated
agent according
sum
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KR1019880015278A
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알프레드 테일러 글렌
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윌리암 에프.마쉬
에어프로덕츠 앤드 케미칼스 인코오포레이티드
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Publication of KR890008193A publication Critical patent/KR890008193A/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3271—Hydroxyamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
    • C08G18/5033—Polyethers having heteroatoms other than oxygen having nitrogen containing carbocyclic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/6505—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen the low-molecular compounds being compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6523—Compounds of group C08G18/3225 or C08G18/3271 or polyamines of C08G18/38
    • C08G18/6529—Compounds of group C08G18/3225 or polyamines of C08G18/38
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0008—Foam properties flexible
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0025—Foam properties rigid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/0058—≥50 and <150kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2115/00—Oligomerisation
    • C08G2115/02—Oligomerisation to isocyanurate groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2120/00—Compositions for reaction injection moulding processes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

내용 없음

Description

알콕시화 디에틸톨루엔 디아민을 첨가한 폴리우레탄
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (17)

  1. 알콕시화 디에틸톨루엔디아민을 포함하는 가교제 시스템을 이용한 것을 특징으로 하는 유기 폴리이소시아네이트, 폴리올, 및 가교제 시스템을 포함하는 폴리우레탄 포움 포뮬레이션.
  2. 제1항에 있어서, 상기 알콕시화 디에닐톨루엔디아민이 1 내지 25중량%의 폴리올중에 포함되는 것을 특징으로 하는 포뮬레이션.
  3. 제2항에 있어서, 상기 폴리올이 약 300 내지 15,000의 분자량을 지닌 중합체 폴리올인 것을 특징으로 하는 포뮬레이션.
  4. 제3항에 있어서, 상기 알콕시화 디에틸톨루엔디아민이 에톡시화 또는 프로폭시화 디에틸톨루엔디아민인 것을 특징으로 하는 포뮬레이션.
  5. 제4항에 있어서, 상기 에톡시화 또는 프로폭시화 디에틸톨루엔디아민 중의 에틸렌 옥사이드 또는 프로필렌 옥사이드 단위의 평균수가 1.5 내지 2.5인 것을 특징으로 하는 포뮬레이션.
  6. 디에틸톨루엔디아민 1목당 1.5 내지 2.5몰의 알콕시기를 가지는 알콕시화 디에틸톨루엔디아민을 포함하는 연질 폴리우레탄 시스템을 제조하는데 적합한 가교제.
  7. 제6항에 있어서, 상기 디에틸톨루엔디아민 유도체가 에틸렌 옥사이드 또는 프로필렌 옥사이드 디에틸톨루엔디아민 유도체인 것을 특징으로 하는 가교제.
  8. 제7항에 있어서, 상기 알콕시화 알킬화 톨루엔디아민 유도체가 디에틸톨루엔디아민의 에톡시화 또는 프로폭시화 유도체이며, 에틸렌 옥사이드 또는 프로필렌단위의 평균수는 1.5 내지 2.5인 것을 특징으로 하는 가교제.
  9. 디에틸 톨루엔디아민의 알킬렌 옥사이드 부가물의 가교재를 이용하는 것을 특징으로 하는 유기 폴리이소시아네이트, 약 300 내지 15,000의 분자량을 지니는 폴리에테르 폴리올 및 알콕시화 방향족 디아민 가교제를 반응시키는 것을 포함하는 폴리우레탄 시스템의 제조방법.
  10. 제9항에 있어서, 상기가교제가 1 내지 15중량%의 디에틸톨루엔디아민의 알킬렌 옥사이드 부가물을 함유하는 것을 특징으로 하는 방법.
  11. 10항에 있어서, 상기 알킬렌 옥사이드가 에틸렌 옥사이드 또는 프로필렌 옥사이드이며, 평균 단위수는 디에틸톨루엔디아민 1몰당 1.5 내지 2.5몰의 에틸렌 또는 프로필렌 옥사이드인 것을 특징으로 하는 방법.
  12. 하기 일반식으로 표기되는 디에틸톨루엔디아민의 알킬렌 옥사이드 유도체를 포함하는 폴리우레탄 시스템의 제조에 유용한 가교제.
    3 및 5위치에 이틸기(Et)를 지닌 디에틸톨루엔 디아민(2,4- 및 2,6-이성체) 상기식에서, R은 H 또는 CH3-이고, a, b, c 및 d는 이들의 합이 1 내지 15이고, 바람직하게는 a, b, c 및 d의 합이 1.5 내지 2.5이고, 아민기는 2,4- 및 2,6- 위치에 존재한다.
  13. 제12항에 있어서, 상기 정수 a, b, c 및 d의 합이 1 내지 6인 것을 특징으로 하는 가교제.
  14. 제13항에 있어서, 상기 R이 H인 것을 특징으로 하는 가교제.
  15. 제13항에 있어서, 상기 R이 CH3-인 것을 특징으로 하는 가교제.
  16. 제14항에 있어서, 상기 정수 a, b, c 및 d의 합이 1.5 내지 2.5인 것을 특징으로 하는 가교제.
  17. 제15항에 있어서, 상기 정수 a, b, c 및 d의 합이 1.5 내지 2.5인 것을 특징으로 하는 가교제.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880015278A 1987-11-20 1988-11-18 알콕시화 디에틸톨루엔 디아민을 첨가한 폴리우레탄 KR890008193A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US123,083 1987-11-20
US07/123,083 US4992484A (en) 1987-11-20 1987-11-20 Polyurethane systems incorporating alkoxylated diethyltoluenediamine

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KR890008193A true KR890008193A (ko) 1989-07-10

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US (1) US4992484A (ko)
EP (1) EP0316851A3 (ko)
JP (1) JPH01167324A (ko)
KR (1) KR890008193A (ko)
AU (1) AU594591B2 (ko)
BR (1) BR8806132A (ko)
ZA (1) ZA888667B (ko)

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Publication number Priority date Publication date Assignee Title
US8293808B2 (en) * 2003-09-30 2012-10-23 Cargill, Incorporated Flexible polyurethane foams prepared using modified vegetable oil-based polyols
US7691914B2 (en) 2005-04-25 2010-04-06 Cargill, Incorporated Polyurethane foams comprising oligomeric polyols
JP5136750B2 (ja) * 2007-06-11 2013-02-06 株式会社ブリヂストン 断熱材組成物、ポリウレタン発泡断熱材及び断熱施工方法
JP2009067913A (ja) * 2007-09-14 2009-04-02 Bridgestone Corp 断熱材組成物及びポリウレタン発泡断熱材
US20090287007A1 (en) * 2008-05-13 2009-11-19 Cargill, Incorporated Partially-hydrogenated, fully-epoxidized vegetable oil derivative
DE102015207792A1 (de) * 2015-04-28 2016-11-03 Henkel Ag & Co. Kgaa Polyurethan-basiertes Bindemittel-System
US20170055600A1 (en) * 2015-08-28 2017-03-02 Damon Howard Hawkins Anti-Slip Slip-On Slip-Over Roof Safety Shorts

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EP0316851A3 (en) 1990-08-08
AU594591B2 (en) 1990-03-08
US4992484A (en) 1991-02-12
JPH01167324A (ja) 1989-07-03
EP0316851A2 (en) 1989-05-24
ZA888667B (en) 1990-07-25
AU2509388A (en) 1989-05-25
BR8806132A (pt) 1989-08-15

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