KR900003265A - 양이온 중합성 물질에 대한 활성화된 경화제 조합물 및 이들을 함유하는 경화성 조성물 - Google Patents

양이온 중합성 물질에 대한 활성화된 경화제 조합물 및 이들을 함유하는 경화성 조성물 Download PDF

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KR900003265A
KR900003265A KR1019890011232A KR890011232A KR900003265A KR 900003265 A KR900003265 A KR 900003265A KR 1019890011232 A KR1019890011232 A KR 1019890011232A KR 890011232 A KR890011232 A KR 890011232A KR 900003265 A KR900003265 A KR 900003265A
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보이만 디이터
마이어 쿠르트
마르고테 베르너
뮐러 베아트
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베르너 발데크
시바-가이기 아게
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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
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    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2252—Sulfonate ligands
    • B01J31/2256—Sulfonate ligands being perfluorinated, i.e. comprising at least one perfluorinated moiety as substructure in case of polyfunctional ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
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    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
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Abstract

내용 없음

Description

양이온 중합성 물질에 대한 활성화된 경화제 조합물 및 이들을 함유하는 경화성 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (17)

  1. A) 하기 일반식(I)의 호합물인 성분 i)을 폴리카르보길산, 폴리카르복실산을 기본한 무수물 또는 폴리이소시아네이트로 구성된 군에서 선정된 성분 ⅱ)에 용해시키거나 또는 분산시키고 ; 또 B) 성분 i) 및 ⅱ)를 함유하는 용액 또는 분산액을 화학선 조사 또는 가열에 의하여 활성화시켜 성분 i)이 실질적으로 더 이상 상기 용액 또는 분산액에서 검출되지 않게 수득할 수 있는 물질의 조성물.
    [(R1)(R2Fe11)a]+nanaX-(I)
    상기식에서, R1은 π-아렌이고, R2는 π-아렌 또는 π-아렌의 음이온이고, a 및 n은 서로 독립적으로 1 또는 2이며 또 X는 음이온[LQm]-또는 불소화되지 않거나, 부분적으로 불소화되거나 또는 과불소화된 지방족, 시클로지방족, 방향족 또는 방향지방족 카르복시산 또는 술폰산의 음이온이고, L은 B,P,As,Sb 및 Bi으로 구성된 군에서 선정되며, Q는 할로겐 원자이고 또 m은 1개씩 증가된 L원자가에 상응한다.
  2. 제1항에 있어서, R1및 R2가 방향족 고리에서 6 내지 24개의 탄소원자를 갖는 카르보시클릭-방향족 탄화수소이거나 또는 방향족 고리에서 4 내지 11개의 탄소원자 및 1 또는 2개의 산소원자 또는 황원자를 갖는 헤테로시클릭-방향족 탄화수소인 물질의 조성물.
  3. 제1항에 있어서, R2가 시클로펜타디엔일 음이온인 물질의 조성물.
  4. 제1항에 있어서, X-이 PF- 6, AsF- 6,SbF- 6,BIF- 6또는 퍼플루오로지방족 또는 퍼플루오로방향족 술폰산의 음이온인 물질의 조성물.
  5. 제1항에 있어서, 성분 ⅱ)가 폴리이소시아네이트인 물질의 조성물.
  6. 제1항에 있어서, 성분 ⅱ)가 폴리카르복시산의 무수물 또는 이 무수물 형태의 혼합물인 물질의 조성물.
  7. 제6항에 있어서, 성분 ⅱ)가 50℃ 아래의 온도에서 물질의 조성물.
  8. 제1항에 있어서, 성분 i) 및 ⅱ)와 이들의 양이 이들 성분으로부터 용액이 제조될 수 있도록 선정되는 물질의 조성물.
  9. 제1항에 있어서, 성분 i)이 제1항에 정의한 바와같고, 성분 ⅱ)가 폴리카르복시산의 무수물이며 또 성분 ⅲ)이 폴리카르복시산 또는 적어도 1개의 이가 알코올 및/또는 적어도 1개의 이가 페놀에 대한 폴리카르복시산 또는 그의 에스테르 형성 유도체중 어느 하나의 카르복시로 종결된 부가 반응 생성물일때, A) 성분 i)을 성분 ⅱ)와 다른 성분 ⅲ)과의 조합물에 용해시키고 또 B) 이 용액을 제1항에 따른 방법으로 활성화시키는 것에 의하여 수득 가능한 물질의 조성물.
  10. 제1항에 있어서, 출발 혼합물에서 성분, i) 및 ⅱ)의 중량비 또는 성분 i) alc ii) +ⅲ)의 중량비가 0.5 : 100 내지 5 : 100인 물질의 조성물.
  11. 제1항에 있어서, 성분 i)로서 사용될 수 있는 화합물이, a 및 n이 1이고, R1은 비치환되거나 또는 C1-C4알킬 또는 C1-C4알콕시에 의해 일-또는 이치환된 벤젠 또는 나프탈렌 라디칼이거나 또는 스틸벤라디칼이며, R2는 비치환된 시클로펜타디엔일 음이온이고 또는 X-는 PF- 6, AsF- 6, SbF- 6, BiF- 6으로 구성된 군에서 선정된 음이온, 퍼플루오로지방족 또는 퍼플루오로방향족 술폰산의 음이온, 특히 CF3, -SO- 3, C2F5-SO3, C3F7-SO- 3, C4F9-SO- 3, C6F13-SO- 3, S8F17-SO- 3, C6F5-SO- 3및 CF3-C6F4-SO- 3인 일반식(I)의 화합물인 물질의 조성물.
  12. a) 양이온 중합성 유기 물질 및 b) 제1항에 따른 활성화된 경화제 조합물을 함유하는 경화성 조성물.
  13. 제12항에 있어서, 성분 a)가 분자당 평균 적어도 2개의 1,2-에폭시기를 갖는 화합물인 경화성 조성물.
  14. 제12항에 있어서, 성분 a)가 시클로지방족 에폭시 수지이고 또 성분 b)가 제1항에 따른 활성화된 경화제 조합물이며, 성분 ⅱ)가 폴리이소시아네이트인 경화성 조성물.
  15. 제12항에 따른 경화성 조성물을 사용하는 것을 포함하는, 경화성 조성물을 가열하는 것에 의한 경화 제품의 제조방법.
  16. 제15항에 있어서, 경화성 조성물이 제13항에 정의된 바와같은 경화 제품의 제조방법.
  17. 제15항에 있어서, 경화성 조성물이 제14항에 정의된 바와같은 경화 제품의 제조방법.
    ※참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890011232A 1988-08-04 1989-08-04 양이온 중합성 물질에 대한 활성화된 경화제 조합물 및 이들을 함유하는 경화성 조성물 KR0135756B1 (ko)

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CH295988 1988-08-04
CH0295988-8 1988-08-04

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KR0135756B1 KR0135756B1 (ko) 1998-04-23

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US (1) US5047376A (ko)
EP (1) EP0354181B1 (ko)
JP (2) JPH0822906B2 (ko)
KR (1) KR0135756B1 (ko)
AT (1) ATE117702T1 (ko)
CA (1) CA1338945C (ko)
DE (1) DE58908927D1 (ko)

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US5179179A (en) * 1989-03-21 1993-01-12 Ciba-Geigy Corporation Initiators for materials which can be polymerized cationically
ES2085294T3 (es) * 1989-03-21 1996-06-01 Ciba Geigy Ag Iniciadores para materiales de polimerizacion cationica.
US5494943A (en) * 1993-06-16 1996-02-27 Minnesota Mining And Manufacturing Company Stabilized cationically-curable compositions
EP0673104B1 (de) * 1994-03-16 1999-07-07 Ciba SC Holding AG Ein-Komponenten-Epoxidharz-Systeme für das Träufelverfahren und Heisstauchrollierverfahren
JP2001089639A (ja) * 1999-09-24 2001-04-03 Mitsubishi Heavy Ind Ltd エネルギー線硬化樹脂組成物
US6635689B1 (en) * 2000-06-26 2003-10-21 3M Innovative Properties Company Accelerators for cationic polymerization catalyzed by iron-based catalysts
US20050059752A1 (en) 2002-07-12 2005-03-17 Rhodia Chimie Stable, cationically polymerizable/crosslinkable dental compositions having high filler contents
FR2876983B1 (fr) * 2004-10-22 2007-02-16 Eads Space Transp Sa Sa Rigidification de structures a deploiement par gonflage en particulier a usage spatial
WO2012047690A1 (en) 2010-10-05 2012-04-12 Ferro Corporation Single component, low temperature curable polymeric composition and related method
WO2022009966A1 (ja) * 2020-07-08 2022-01-13 三菱瓦斯化学株式会社 膜形成用組成物、レジスト組成物、感放射線性組成物、アモルファス膜の製造方法、レジストパターン形成方法、リソグラフィー用下層膜形成用組成物、リソグラフィー用下層膜の製造方法及び回路パターン形成方法、光学部材形成用組成物、膜形成用樹脂、レジスト樹脂、感放射線性樹脂、リソグラフィー用下層膜形成用樹脂

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US5089536A (en) * 1982-11-22 1992-02-18 Minnesota Mining And Manufacturing Company Energy polmerizable compositions containing organometallic initiators
AT384025B (de) * 1983-10-21 1987-09-25 Ciba Geigy Ag Haertbare massen, verfahren zur herstellung aktivierter haertbarer massen, verfahren zur herstellung gehaerteter massen und verwendung der haertbaren massen
US4740577A (en) * 1987-08-28 1988-04-26 Minnesota Mining And Manufacturing Company Energy polymerizable polyurethane precursors

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EP0354181A2 (de) 1990-02-07
JPH0848754A (ja) 1996-02-20
EP0354181A3 (en) 1990-08-16
CA1338945C (en) 1997-02-25
JP2547378B2 (ja) 1996-10-23
ATE117702T1 (de) 1995-02-15
JPH0269516A (ja) 1990-03-08
EP0354181B1 (de) 1995-01-25
JPH0822906B2 (ja) 1996-03-06
KR0135756B1 (ko) 1998-04-23
US5047376A (en) 1991-09-10
DE58908927D1 (de) 1995-03-09

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