KR890014633A - 폴리아릴렌 티오에테르의 고결정화 성형물 - Google Patents

폴리아릴렌 티오에테르의 고결정화 성형물 Download PDF

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KR890014633A
KR890014633A KR1019880003595A KR880003595A KR890014633A KR 890014633 A KR890014633 A KR 890014633A KR 1019880003595 A KR1019880003595 A KR 1019880003595A KR 880003595 A KR880003595 A KR 880003595A KR 890014633 A KR890014633 A KR 890014633A
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polyarylene thioether
molding
crystallized
polyarylene
thioether
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KR1019880003595A
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KR910003720B1 (ko
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유끼지까 가와까미
다까오 이와사끼
젠야 시끼
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스가노 요리쓰구
구레하 가가꾸 고교 가부시끼가이샤
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
    • B29C55/005—Shaping by stretching, e.g. drawing through a die; Apparatus therefor characterised by the choice of materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C67/00—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
    • B29C67/24—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 characterised by the choice of material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C71/00—After-treatment of articles without altering their shape; Apparatus therefor
    • B29C71/0009—After-treatment of articles without altering their shape; Apparatus therefor using liquids, e.g. solvents, swelling agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C71/00—After-treatment of articles without altering their shape; Apparatus therefor
    • B29C71/0063—After-treatment of articles without altering their shape; Apparatus therefor for changing crystallisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/02—Polythioethers
    • C08G75/0204—Polyarylenethioethers
    • C08G75/025—Preparatory processes
    • C08G75/0254—Preparatory processes using metal sulfides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/02—Polythioethers
    • C08G75/0204—Polyarylenethioethers
    • C08G75/0277—Post-polymerisation treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/02—Polythioethers
    • C08G75/0204—Polyarylenethioethers
    • C08G75/0277—Post-polymerisation treatment
    • C08G75/0281—Recovery or purification
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/02—Polythioethers
    • C08G75/0204—Polyarylenethioethers
    • C08G75/0286—Chemical after-treatment
    • C08G75/029—Modification with organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/02—Chemical treatment or coating of shaped articles made of macromolecular substances with solvents, e.g. swelling agents
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/76—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from other polycondensation products
    • D01F6/765—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from other polycondensation products from polyarylene sulfides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C71/00—After-treatment of articles without altering their shape; Apparatus therefor
    • B29C71/02—Thermal after-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2081/00—Use of polymers having sulfur, with or without nitrogen, oxygen or carbon only, in the main chain, as moulding material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2381/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen, or carbon only; Polysulfones; Derivatives of such polymers
    • C08J2381/02—Polythioethers; Polythioether-ethers

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

Abstract

내용 없음.

Description

폴리아릴렌 티오에테르의 고결정화 성형물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (5)

  1. (1) 주성분으로서 70몰 %이상의 반복 단위를 갖고 수지중의 폴리아릴렌 티오에테르의 결정화도(밀도법에 의해 측정된 값을 나타냄) 15%이하를 갖는 폴리아릴렌 티오에테르 함유수지로 주로 구성되는 성형물을 적어도 1방향으로 2 내지 5배 연신시기고, (2) 사용용매의 고화점 내지 130℃에서 용해도 매개변수(SP값) 8 내지 12를 갖는 적어도 하나의 유기용매 또는 유기용매 50중량 %이상을 함유하는 혼합 용매와 연신된 성형물을 접촉시킴으로써 연신된 성형물의 폴리아릴렌 티오에테르의 결정화도 증가분이 6%이상으로 될때까지 처리된 성형물을 예비 결정화시키고, (3) 성형물의 폴리아릴렌 티오에테르 결정화도가 22%이상으로 될 때까지 예비결정화된 성형물을 140 내지 300℃에서 열처리하는 단계로 구성되는 방법에 의해 얻어진 폴리아릴렌 티오에테르의 고결정화 성형물.
  2. 제1항에 있어서, 두께가 0.01 내지 5mm인 폴리아릴렌 티오에테르의 고결정화 성형물.
  3. 제1항에 있어서, 두께 0.1mm의 쌤플 시이트로 측정할 때 상기 열처리에 의한 치수 변형률이 10%미만이고 내굽힘성(연신방향과 수직방향으로 굽힘)의 수가 1,000이상인 폴리아릴렌 티오에테르의 고결정화 성형물.
  4. 제1항에 있어서, 충전제를 거의 함유하지 않고 두께 0.1mm인 쌤플시이트로 측정할 때 평행광선에 대한 투과율 Tp가 20%이상인 폴리아릴렌 티오에테르의 고결정화 성형물.
  5. 제1항에 있어서, 상기 열처리가 응력을 가하지 않은 상태에서 실시되는 폴리아릴렌 티오에테르의 고결정화 성형물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880003595A 1987-03-30 1988-03-30 폴리아릴렌 티오에테르의 고 결정화 성형물 KR910003720B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP77022/87 1987-03-30
JP62077022A JPH0714625B2 (ja) 1987-03-30 1987-03-30 高結晶化ポリアリ−レンチオエ−テル成形物
JP87-077022 1987-03-30

Publications (2)

Publication Number Publication Date
KR890014633A true KR890014633A (ko) 1989-10-25
KR910003720B1 KR910003720B1 (ko) 1991-06-08

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ID=13622128

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KR1019880003595A KR910003720B1 (ko) 1987-03-30 1988-03-30 폴리아릴렌 티오에테르의 고 결정화 성형물

Country Status (10)

Country Link
US (1) US4810566A (ko)
EP (1) EP0285377B1 (ko)
JP (1) JPH0714625B2 (ko)
KR (1) KR910003720B1 (ko)
AT (1) ATE82547T1 (ko)
AU (1) AU585192B2 (ko)
CA (1) CA1323168C (ko)
DE (1) DE3875995T2 (ko)
ES (1) ES2045107T3 (ko)
GR (1) GR3006599T3 (ko)

Families Citing this family (12)

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Publication number Priority date Publication date Assignee Title
US5200501A (en) * 1986-11-20 1993-04-06 Kureha Kagaku Kogyo Kabushiki Kaisha Easily-slidable polyarylene thioether film and process for producing the same
JPH0747295B2 (ja) * 1986-11-20 1995-05-24 呉羽化学工業株式会社 易滑性ポリアリ−レンチオエ−テルフイルムおよびその製造法
JPH0623259B2 (ja) * 1987-02-24 1994-03-30 呉羽化学工業株式会社 ポリアリ−レンチオエ−テル成形物および用途
WO1989004058A1 (en) * 1987-10-27 1989-05-05 Mitsui Toatsu Chemicals, Incorporated Retention vessel
CA1314112C (en) * 1987-05-15 1993-03-02 Yukio Ichikawa Heat-resistant resin compositions, and heat-resistant molded or formed articles and production process thereof
JPH0234663A (ja) * 1988-07-22 1990-02-05 Diafoil Co Ltd ポリフェニレンスルフィドフィルム
US5593916A (en) * 1988-08-12 1997-01-14 Mitsui Toatsu Chemicals, Incorporated Processing of glass substrates using holding container and holding container
GB2228892A (en) * 1989-03-06 1990-09-12 Courtaulds Plc Filaments and hot gas filter
US5264176A (en) * 1990-05-22 1993-11-23 Phillips Petroleum Company Production of biaxially-oriented film from aromatic sulfide/ketone polymers
GB2285261B (en) * 1993-11-17 1997-10-08 North West Water Group Plc Enhancing membrane crystallinity
US6287693B1 (en) * 1998-02-25 2001-09-11 John Claude Savoir Stable shaped particles of crystalline organic compounds
JP2014046293A (ja) * 2012-09-03 2014-03-17 Dainippon Plastics Co Ltd ポリフェニレンサルファイド樹脂組成物からなるネット

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4286018A (en) * 1978-04-28 1981-08-25 Toray Industries, Incorporated Biaxially oriented poly-p-phenylene sulfide films
JPS5942611B2 (ja) * 1979-08-31 1984-10-16 東レ株式会社 ポリフエニレンスルフイドフイルムの製造方法
US4299951A (en) * 1980-01-29 1981-11-10 Phillips Petroleum Co. Treating shaped arylene sulfide/sulfone polymer with organic liquid at elevated temperature
JPS57121052A (en) * 1981-01-22 1982-07-28 Toray Ind Inc Polyphenylene sulfide sheet -like material
US4629778A (en) * 1982-05-20 1986-12-16 Dainippon Ink And Chemicals, Inc. Poly(p-phenylene sulfide) film and process for production thereof
JPS59184619A (ja) * 1983-04-04 1984-10-20 Toray Ind Inc ポリフエニレンスルフイド樹脂からなるシ−ト状物およびその製造方法
US4645825A (en) * 1984-08-07 1987-02-24 Bayer Aktiengesellschaft Fibres and filaments of polyarylene sulphides
EP0233494A3 (en) * 1986-01-23 1988-12-07 Kureha Kagaku Kogyo Kabushiki Kaisha Method for producing high-crystallinity polyarylene thioether formed products
JPS62242517A (ja) * 1986-04-14 1987-10-23 Kureha Chem Ind Co Ltd ポリパラフェニレンスルフィド２軸延伸フィルム及びその製造方法
JPH0747295B2 (ja) * 1986-11-20 1995-05-24 呉羽化学工業株式会社 易滑性ポリアリ−レンチオエ−テルフイルムおよびその製造法

Also Published As

Publication number Publication date
JPS63242522A (ja) 1988-10-07
CA1323168C (en) 1993-10-19
AU585192B2 (en) 1989-06-08
EP0285377B1 (en) 1992-11-19
GR3006599T3 (ko) 1993-06-30
US4810566A (en) 1989-03-07
EP0285377A2 (en) 1988-10-05
JPH0714625B2 (ja) 1995-02-22
DE3875995T2 (de) 1993-03-25
DE3875995D1 (de) 1992-12-24
AU1387288A (en) 1988-10-20
ES2045107T3 (es) 1994-01-16
KR910003720B1 (ko) 1991-06-08
EP0285377A3 (en) 1989-10-18
ATE82547T1 (de) 1992-12-15

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