KR890010168A - 비극성 용매로부터의 수은제거 방법 - Google Patents
비극성 용매로부터의 수은제거 방법 Download PDFInfo
- Publication number
- KR890010168A KR890010168A KR1019880016608A KR880016608A KR890010168A KR 890010168 A KR890010168 A KR 890010168A KR 1019880016608 A KR1019880016608 A KR 1019880016608A KR 880016608 A KR880016608 A KR 880016608A KR 890010168 A KR890010168 A KR 890010168A
- Authority
- KR
- South Korea
- Prior art keywords
- solvent
- solid adsorbent
- active
- process according
- mercury
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims 11
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 title claims 4
- 229910052753 mercury Inorganic materials 0.000 title claims 4
- 239000012454 non-polar solvent Substances 0.000 title 1
- 239000003463 adsorbent Substances 0.000 claims 5
- 239000007787 solid Substances 0.000 claims 5
- 239000002904 solvent Substances 0.000 claims 5
- 239000007789 gas Substances 0.000 claims 4
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical group C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 2
- 239000003456 ion exchange resin Substances 0.000 claims 2
- 229920003303 ion-exchange polymer Polymers 0.000 claims 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- 238000009833 condensation Methods 0.000 claims 1
- 230000005494 condensation Effects 0.000 claims 1
- 229920001577 copolymer Polymers 0.000 claims 1
- 238000004508 fractional distillation Methods 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 1
- 238000002844 melting Methods 0.000 claims 1
- 230000008018 melting Effects 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 239000003345 natural gas Substances 0.000 claims 1
- 239000003960 organic solvent Substances 0.000 claims 1
- 238000003419 tautomerization reaction Methods 0.000 claims 1
- 125000003396 thiol group Chemical group [H]S* 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/04—Processes using organic exchangers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
- C10G25/02—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/10—Working-up natural gas or synthetic natural gas
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S210/00—Liquid purification or separation
- Y10S210/902—Materials removed
- Y10S210/911—Cumulative poison
- Y10S210/912—Heavy metal
- Y10S210/914—Mercury
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Treating Waste Gases (AREA)
- Treatment Of Water By Ion Exchange (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (9)
- 용매를 활성 SH-기를 함유하고 있는 고체 흡착제와 접촉시키는 것을 특징으로 하는 비극성 유기 용매로부터 수은을 제거하는 방법.
- 제1항에 있어서, 고체 흡착제가 토토머화를 통해 활성 SH-기를 만들어 낼 수 있는 그룹을 가지고 있는 것을 특징으로 하는 방법.
- 제1항 또는 2항에 있어서, 고체 흡착제가 이온교환수지인 것을 특징으로 하는 방법.
- 제3항에 있어서, 이온교환수지가 스티렌과 활성 티올기를 함유하고 있는 디비닐벤젠의 대공성 코폴리머인 것을 특징으로 하는 방법.
- 제1항 내지 4항중 어느 한항에 있어서, 처리되는 용매가 주로 탄화수소 혼합물인 것을 특징으로 하는 방법.
- 제1항 내지 5항중 어느 한항에 있어서, 처리되는 용매가 천연개스의 부분적인 응축에 의해 얻어지는, 융점이 낮은 개스 성분이 거의 없는 개스 응축물인 것을 특징으로 하는 방법.
- 제1항 내지 6항중 어느 한항에 있어서, 수은을 함유하고 있는 용매가 30초 이상동안 고체 흡착제와 접촉되는 것을 특징으로 하는 방법.
- 제1항 내지 7항중 어느 한항에 있어서, 수은을 함유하고 있는 용매가 0-30-60℃, 바람직하기로는 0-60℃에서 고체 흡착제와 접촉되는 것을 특징으로 하는 방법.
- 개스 응축물이 제1항 내지 8항중 어느 한항에 따른 방법에 의해 전처리되는 것을 특징으로 하는 개스응축물을 분별증류하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL202485.6 | 1987-12-11 | ||
NL87202485.6 | 1987-12-11 | ||
EP87202485A EP0319615B2 (en) | 1987-12-11 | 1987-12-11 | Process for removing mercury from organic media |
Publications (2)
Publication Number | Publication Date |
---|---|
KR890010168A true KR890010168A (ko) | 1989-08-07 |
KR910007459B1 KR910007459B1 (ko) | 1991-09-26 |
Family
ID=8197720
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019880016608A KR910007459B1 (ko) | 1987-12-11 | 1988-12-12 | 비극성 용매로부터의 수은제거 방법 |
Country Status (17)
Country | Link |
---|---|
US (1) | US4950408A (ko) |
EP (1) | EP0319615B2 (ko) |
JP (1) | JP2569157B2 (ko) |
KR (1) | KR910007459B1 (ko) |
AR (1) | AR245189A1 (ko) |
AT (1) | ATE73165T1 (ko) |
AU (1) | AU607288B2 (ko) |
BR (1) | BR8806500A (ko) |
CA (1) | CA1336647C (ko) |
DE (1) | DE3777190D1 (ko) |
ES (1) | ES2032291T5 (ko) |
FI (1) | FI92218C (ko) |
GR (1) | GR3004683T3 (ko) |
NO (1) | NO172031C (ko) |
PT (1) | PT89190B (ko) |
SA (1) | SA90110004B1 (ko) |
SG (1) | SG48792G (ko) |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3934101A1 (de) * | 1989-10-12 | 1991-04-18 | Erdoelchemie Gmbh | Verfahren zur mindestens teilweisen entfernung von spurenelementen aus kohlenwasserstoffgemischen |
US5082569A (en) * | 1990-12-03 | 1992-01-21 | Uop | Removal of metals from liquefied hydrocarbons |
WO1993012201A1 (en) * | 1991-12-09 | 1993-06-24 | Dow Benelux N.V. | Process for removing mercury from organic media |
US5238488A (en) * | 1992-03-26 | 1993-08-24 | Gas Research Institute | Process and solution for transforming insoluble mercury metal into a soluble compound |
US5227463A (en) * | 1992-06-12 | 1993-07-13 | Polysar Rubber Corporation | Process for the manufacture of functionalized resins from styrene, divinyl benzene and alkane dithiol |
BE1007049A3 (nl) * | 1993-05-05 | 1995-02-28 | Dsm Nv | Werkwijze voor het verwijderen van kwik. |
US6350372B1 (en) | 1999-05-17 | 2002-02-26 | Mobil Oil Corporation | Mercury removal in petroleum crude using H2S/C |
US6537443B1 (en) * | 2000-02-24 | 2003-03-25 | Union Oil Company Of California | Process for removing mercury from liquid hydrocarbons |
US6797178B2 (en) | 2000-03-24 | 2004-09-28 | Ada Technologies, Inc. | Method for removing mercury and mercuric compounds from dental effluents |
US6475451B1 (en) | 2000-08-23 | 2002-11-05 | Gas Technology Institute | Mercury removal from gaseous process streams |
US6942840B1 (en) | 2001-09-24 | 2005-09-13 | Ada Technologies, Inc. | Method for removal and stabilization of mercury in mercury-containing gas streams |
WO2003062176A1 (en) * | 2002-01-23 | 2003-07-31 | Johnson Matthey Plc | Sulphided ion exchange resins |
US20070137097A1 (en) * | 2005-12-16 | 2007-06-21 | Michio Ikura | Production of biodiesel from triglycerides via a thermal route |
US8034246B2 (en) * | 2007-05-16 | 2011-10-11 | Exxonmobil Research & Engineering Company | Wastewater mercury removal process |
JP5443682B2 (ja) | 2007-11-05 | 2014-03-19 | 日東電工株式会社 | ヒドロキシ基又は第1級アミノ基を有する多孔質樹脂粒子とその製造方法 |
GB0816378D0 (en) * | 2008-09-08 | 2008-10-15 | Johnson Matthey Plc | Adsorbents |
JP5889060B2 (ja) * | 2011-04-04 | 2016-03-22 | アークレイ株式会社 | 金属の回収方法 |
JP5889059B2 (ja) | 2011-04-04 | 2016-03-22 | アークレイ株式会社 | 金属の回収方法 |
JP5899085B2 (ja) | 2011-09-22 | 2016-04-06 | アークレイ株式会社 | 重金属の回収方法およびそれに使用する重金属回収用試薬 |
ITMI20132023A1 (it) * | 2013-12-05 | 2015-06-06 | Dipharma Francis Srl | "metodo di purificazione di un composto chetonico" |
US10364397B2 (en) | 2017-04-18 | 2019-07-30 | King Fahd University Of Petroleum And Minerals | Mercury removal from liquid hydrocarbons by 1,4-benzenediamine alkyldiamine cross-linked polymers |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3755161A (en) * | 1970-02-05 | 1973-08-28 | Osaka Soda Co Ltd | Treatment process for removal of metals and treating agent therefor |
GB1360648A (en) * | 1970-12-23 | 1974-07-17 | Nippon Soda Co | Method of adsorbing heavy metals and compounds of heavy metals |
JPS5641673B2 (ko) * | 1972-07-04 | 1981-09-29 | ||
US3785968A (en) * | 1972-07-12 | 1974-01-15 | Mobil Oil Corp | Sorbent and process for heavy metal removal from motor fuel |
US4693731A (en) * | 1986-10-27 | 1987-09-15 | The M. W. Kellogg Company | Removal of mercury from gases |
-
1987
- 1987-12-11 ES ES87202485T patent/ES2032291T5/es not_active Expired - Lifetime
- 1987-12-11 DE DE8787202485T patent/DE3777190D1/de not_active Expired - Lifetime
- 1987-12-11 EP EP87202485A patent/EP0319615B2/en not_active Expired - Lifetime
- 1987-12-11 AT AT87202485T patent/ATE73165T1/de not_active IP Right Cessation
-
1988
- 1988-12-02 US US07/278,718 patent/US4950408A/en not_active Expired - Lifetime
- 1988-12-05 AU AU26569/88A patent/AU607288B2/en not_active Ceased
- 1988-12-07 PT PT89190A patent/PT89190B/pt not_active IP Right Cessation
- 1988-12-07 AR AR88312648A patent/AR245189A1/es active
- 1988-12-09 NO NO885475A patent/NO172031C/no not_active IP Right Cessation
- 1988-12-09 CA CA000585415A patent/CA1336647C/en not_active Expired - Fee Related
- 1988-12-09 BR BR888806500A patent/BR8806500A/pt not_active IP Right Cessation
- 1988-12-09 FI FI885734A patent/FI92218C/fi not_active IP Right Cessation
- 1988-12-12 JP JP63312142A patent/JP2569157B2/ja not_active Expired - Fee Related
- 1988-12-12 KR KR1019880016608A patent/KR910007459B1/ko not_active IP Right Cessation
-
1990
- 1990-07-23 SA SA90110004A patent/SA90110004B1/ar unknown
-
1992
- 1992-04-29 SG SG48792A patent/SG48792G/en unknown
- 1992-05-22 GR GR920401010T patent/GR3004683T3/el unknown
Also Published As
Publication number | Publication date |
---|---|
JPH02138394A (ja) | 1990-05-28 |
ES2032291T5 (es) | 1997-01-16 |
EP0319615B1 (en) | 1992-03-04 |
NO885475L (no) | 1989-06-12 |
PT89190B (pt) | 1993-06-30 |
EP0319615A1 (en) | 1989-06-14 |
US4950408A (en) | 1990-08-21 |
JP2569157B2 (ja) | 1997-01-08 |
KR910007459B1 (ko) | 1991-09-26 |
AU607288B2 (en) | 1991-02-28 |
NO885475D0 (no) | 1988-12-09 |
AR245189A1 (es) | 1993-12-30 |
EP0319615B2 (en) | 1996-09-25 |
DE3777190D1 (de) | 1992-04-09 |
NO172031B (no) | 1993-02-22 |
SA90110004B1 (ar) | 2001-11-12 |
ES2032291T3 (es) | 1993-02-01 |
FI92218C (fi) | 1994-10-10 |
PT89190A (pt) | 1989-12-29 |
AU2656988A (en) | 1989-06-15 |
CA1336647C (en) | 1995-08-15 |
ATE73165T1 (de) | 1992-03-15 |
FI92218B (fi) | 1994-06-30 |
GR3004683T3 (en) | 1993-04-28 |
NO172031C (no) | 1993-06-02 |
FI885734A0 (fi) | 1988-12-09 |
FI885734A (fi) | 1989-06-12 |
BR8806500A (pt) | 1989-08-22 |
SG48792G (en) | 1992-06-12 |
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Legal Events
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G160 | Decision to publish patent application | ||
E701 | Decision to grant or registration of patent right | ||
GRNT | Written decision to grant | ||
FPAY | Annual fee payment |
Payment date: 20040922 Year of fee payment: 14 |
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LAPS | Lapse due to unpaid annual fee |