KR890002008B1 - Fungicidal formulations process thereof and methods of treating fungal infections of cultivated plants - Google Patents
Fungicidal formulations process thereof and methods of treating fungal infections of cultivated plants Download PDFInfo
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- KR890002008B1 KR890002008B1 KR1019830003472A KR830003472A KR890002008B1 KR 890002008 B1 KR890002008 B1 KR 890002008B1 KR 1019830003472 A KR1019830003472 A KR 1019830003472A KR 830003472 A KR830003472 A KR 830003472A KR 890002008 B1 KR890002008 B1 KR 890002008B1
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/02—Sulfur; Selenium; Tellurium; Compounds thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
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Abstract
Description
본 발명은 살균제 조성물과 경작식물의 전염병을 치료하기 위한 방법에 관한 것이다.The present invention relates to fungicide compositions and methods for treating infectious diseases of cultivated plants.
본 발명은 유황과 다음 일반식(Ⅰ)의 피리미딘으로 이루어진 살균제 조성물을 제공한다.The present invention provides a fungicide composition consisting of sulfur and pyrimidine of the general formula (I).
(상기식에서 X는 염소 또는 불소이다)(Wherein X is chlorine or fluorine)
본 발명에서는 이 성분의 조합물이 포도, 고급과일과 야체와 같은 경작식물의 전염균을 억제하거나 처리하는데 특히 효과적임을 알았다. 이들 혼합물은 포도에서 분말상 흰곰팡이 운시눌라 네카토, 사과에서 포도 스페라 로우코트리카와 호리병박에서 에리싶 시코라세품과 스페로데카 펄리기니에 대하여 양호한 결과를 나타냄을 알 수 있다. 일반식(Ⅰ)의 화합물은 예을 들어 영국특허 제1, 218, 623호에 서술된 공지의 살균제이고, 이들의 효과는 유황의 존재에 의하여 놀랍게 개량된다.In the present invention, it has been found that the combination of these components is particularly effective in inhibiting or treating the infectious bacteria of cultivated plants such as grapes, higher fruits and vegetables. These mixtures show good results for powdery white fungus Uncinula necato in grapes, grapes Spera leukotrica in apples, and Eridae cycoracene and Sperodeca perligini in calabash. Compounds of general formula (I) are known fungicides described, for example, in British Patent Nos. 1,218 and 623, and their effects are surprisingly improved by the presence of sulfur.
또한 본 발명은 살균하는데 유효한 양의 상술한 살균제 조성물을 식물에 사용하는 식물의 전염병을 치료하는 방법을 포함한다. 조성물은 농작물 수확전에 언제든지 잎에 사용하는 것이 바람직하다. 사용량과 회수는 균질병의 심도와 농작물의 상태에 따라 좌우된다. 그러나 균을 억제하는데 필요한 처리 회수는 본 발명의 조성물 사용으로 감소시킬수 있고, 이에 따라 노임도 크게 감소 시킬 수 있다.The present invention also encompasses a method for treating an infectious disease of a plant, wherein the bactericidal composition described above is effective in sterilization. The composition is preferably used on the leaves at any time before harvesting the crop. Usage and recovery will depend on the depth of the homogeneity and the condition of the crop. However, the number of treatments required to inhibit the bacteria can be reduced by using the composition of the present invention, thereby significantly reducing the wage.
사용될 활성성분의 양에 있어서, 유황은 헥타르당 1000-5000g의 비율로 사용하고, 일반식(Ⅰ)의 화합물은 헥타르당 5-100g의 비율로 잎에 분무하여 사용하는 것이 바람직하다. 유황과 일반식(Ⅰ)의 화합물의 비율은 1 : 1 또는 10 : 1에서 100 : 1가 바람직하며, 예들 들면 10 : 1-500 : 1이나 50 : 1-500 : 1이 있다.In the amount of the active ingredient to be used, sulfur is preferably used at a rate of 1000-5000 g per hectare, and the compound of the general formula (I) is sprayed onto the leaf at a rate of 5-100 g per hectare. The ratio of sulfur and the compound of general formula (I) is preferably 1: 1 or 10: 1 to 100: 1, for example, 10: 1-500: 1 or 50: 1-500: 1.
본 발명의 조성물에서 유황성분은 일반식(Ⅰ)의 화합물과 만족스러운 조성물을 이룰 수 있는 일반적인 형태로 존재하며, 바람직하기로는 미분화된 유황 아니면 콜로이드성 유황이고, 최종 생성물의 평균 입자크기는 1-20미크론이 바람직하다. 상기 일반식(Ⅰ)에 의하여 이루어진 두활성 화합물중, X가 염소인 화합물, 페나리몰이 바람직하고, 누아리몰(X는 불소)도 동등하게 사용할 수 있다. 상술한 바와같이 두 화합물은 살균제 분야에서 공지되어 있고 다른 적합한 살균제와 사용할 수 있으며, 유황과 함께 조성물의 단일 활성성분을 사용한다.In the composition of the present invention, the sulfur component is present in a general form to form a satisfactory composition with the compound of general formula (I), preferably micronized sulfur or colloidal sulfur, and the average particle size of the final product is 1-. 20 microns is preferred. Among the two active compounds formed by the general formula (I), a compound in which X is chlorine and phenarimol are preferable, and noarimol (X is fluorine) can be used in the same manner. As mentioned above both compounds are known in the field of fungicides and can be used with other suitable fungicides, using a single active ingredient of the composition together with sulfur.
본 발명의 조성물은 통상 하나 또는 그 이상의 불활성, 식물 무독성 담체와 사용하고 또한 조성물은 다른 살균제 성분을 더 함유할 수 있다. 제조, 저장과 운송을 간편하게 하기 위하여, 상술한 사용비율을 나타내는데 필요한 정도로 물에 희석할 수 있도록 조합물을 녹축물 형태로 통상 제조한다. 이러한 농축 조성물은 불황성 식물무독성 담체와 함께 0.5-90중량%, 바람직하기로는 5-90중량%의 활성성분을 함유한다. 이러한 조성물은 통상 수화제, 분산 과립 또는 현탁액 형태로 만든다.The composition of the present invention is usually used with one or more inert, plant-free carriers and the composition may further contain other fungicide components. In order to simplify the manufacture, storage and transportation, the combination is usually prepared in the form of a green tea so that it can be diluted in water to the extent necessary to represent the above-mentioned usage rates. Such concentrated compositions contain 0.5-90% by weight, preferably 5-90% by weight of the active ingredient together with a septic non-toxic carrier. Such compositions are usually made in the form of hydrates, dispersed granules or suspensions.
농축 조성물은 일반적 분무탱크에서 사용하기전에 물 또는 다른 적합한 물질과 희석하거나 공중에서 사용하고, 이렇게 제조한 희석된 조성물은 불활성 식물 무독성 담체가 물 또는 다른 적합한 물질인 본 발명에 따른 조성물이다.The concentrated composition is usually diluted with water or other suitable material or used in the air before use in a spray tank, and the diluted composition thus prepared is a composition according to the invention wherein the inert plant non-toxic carrier is water or another suitable material.
수화제는 활성성분, 불활성 담체와 적합한 계면활성제의 잘 혼합된 혼합물이다. 불활성 담체는 예를 들면 알루미나, 아라펄자이트 점토, 몬모릴로나이트 점토, 규조토, 침전된 실리카, 카올린, 운모, 활석과 정제된 규산염으로부터 선택한다. 효과적인 계면활성제는 설폰화 리그닌, 설폰산 나프탈렌과 축합된 설폰산 나프탈렌, 알킬 석시네이트, 설폰산알킬 벤젠, 황산 알킬과 알킬 또는 아릴 개시 산화 에틸렌 부가물, 예를 들어 페놀의 산화 에틸렌 부가물과 같은 비이온 계면활성제로부터 선택할 수 있다. 수화제의 예를 들면 다음과 같은 조성물을 갖는 것이 있다.Hydrating agents are well mixed mixtures of the active ingredient, an inert carrier and a suitable surfactant. Inert carriers are selected from, for example, alumina, arapulite clay, montmorillonite clay, diatomaceous earth, precipitated silica, kaolin, mica, talc and purified silicates. Effective surfactants include sulfonated lignin, sulfonic acid naphthalene condensed with sulfonic acid naphthalene, alkyl succinates, alkyl sulphonate, alkyl sulfates and alkyl or aryl-initiated ethylene oxide adducts, for example ethylene oxide adducts of phenols. It can be selected from nonionic surfactants. Examples of the hydrating agent include those having the following composition.
수화제Hydrating agent
중량%weight%
일반식(Ⅰ)의 화합물 0.1-2.5Compound 0.1-2.5 of general formula (I)
유황 40-90Sulfur 40-90
계면활성제 4-10Surfactant 4-10
케이크 방지제 0-15Cake Inhibitor 0-15
불활성 담체 100까지Up to 100 inert carriers
현탄액은 활성성분, 계면활성제, 현탁화제와 물 또는 무수매체의 현탁액으로 이루어지고, 현탁액은 활성성분과 예를 들어 계면활성제, 현탁화제, 기포방지제부동제와 물로 이루어지고 예를 들면 다음과 같다.Suspensions consist of a suspension of the active ingredient, surfactant, suspending agent and water or anhydrous medium, and the suspension consists of the active ingredient, for example a surfactant, suspending agent, antifoaming agent and water, for example .
현탁액Suspension
중량%weight%
일반식(Ⅰ)의 화합물 0.1-2.5Compound 0.1-2.5 of general formula (I)
유황 40-80Sulfur 40-80
현탁화제 10.1-10Suspending Agent 10.1-10
계면활성제 1-5Surfactants 1-5
기포방지제 0.1-10Antifoam 0.1-10
부동제 5-20Antifreeze 5-20
물 100까지Up to 100 water
분산과립의 예를 들면 다음과 같은 조성을 갖는 것이 있다 :Examples of dispersed granules are those having the following composition:
분산과립Dispersed granule
중량%weight%
일반식(Ⅰ)의 화합물 0.1-2.5Compound 0.1-2.5 of general formula (I)
유황 40-80Sulfur 40-80
계면활성제 4-15Surfactant 4-15
케이크 방지제 0-10Cake Inhibitor 0-10
결합제 0-10Binder 0-10
붕해제 0-10Disintegrant 0-10
불활성 담체 100까지Up to 100 inert carriers
또한 본 발명은 활성성분으로 유황과 상기 일반식(Ⅰ)의 피리미딘을 갖는 수화제 조성물을 제조하는 방법을 포함하는데, 이는 활성성분을 부형체와 혼합하고 혼합물을 분쇄라여 필요한 입자크기, 바람직하기로는 평균입자크기가 1-20미크론으로 한다.The present invention also includes a method for preparing a hydrating composition having sulfur as the active ingredient and pyrimidine of the general formula (I), which is obtained by mixing the active ingredient with an excipient and grinding the mixture to obtain the required particle size, preferably The average particle size is 1-20 microns.
X가 염소인 일반식(Ⅰ)의 피리딘은 페나리몰로서 공지되어 있고 엘리 릴리와 예를들어 블로크, 리미딘과 루비간과 같은 회사에서 이용되고 있고, X가 불소인 일반식(Ⅰ)의 화합물은 누아리몰로서 공지되어 있고 예를 들어 트리미달과 트리미놀과 같은 회사에서 이용되고 있다.Pyridine of formula (I), wherein X is chlorine, is known as phenarimol and is used by Eli Lilly and companies such as Block, Limidine and Rubygan, and is a compound of formula (I) wherein X is fluorine Is known as noarimol and is used by companies such as for example trimidal and triminol.
본 발명을 실시예를 들어 설명하면 다음과 같다 :An embodiment of the present invention will be described as follows:
[실시예 1]Example 1
수화제는 다음과 같이 제조한다 :Hydrating agents are prepared as follows:
중량%weight%
페나리몰 또는 누아리몰 0.5Penarimol or Noarimol 0.5
유황 80Sulfur 80
알킬 나프탈렌 설포네이트 3Alkyl naphthalene sulfonate 3
설폰화 크래프트 설포네이트 3Sulfonated Craft Sulfonate 3
이산화 실리콘 3Silicon dioxide 3
카올린 100까지Up to 100 kaolins
활성성분을 통상의 혼합기에서 명시된 부형체와 혼합하고, 혼합물을 유체 에너지 분쇄기에서 입자크기분포가 0-10미크론이 되도록 분쇄한 다음 끝으로 혼합물을 제혼합하고 포장하기 전에 공기를 제거한다.The active ingredient is mixed with the excipients specified in a conventional mixer, the mixture is ground in a fluid energy grinder to a particle size distribution of 0-10 microns and then finally mixed with the mixture to remove air before packing.
[실시예 2]Example 2
현탁액은 다음과 같이 제조한다 :The suspension is prepared as follows:
중량%weight%
페나리몰 또는 누아리몰 0.5Penarimol or Noarimol 0.5
유황 80Sulfur 80
폴리아릴 에톡실화 포스페이트 3Polyaryl ethoxylated phosphate 3
나프탈렌 포름알데히드 축합물 3Naphthalene Formaldehyde Condensate 3
에틴렌 글리콜 5Ethylene Glycol 5
실리콘 유제 0.5Silicone Emulsion 0.5
크산탄 검 0.2Xanthan Gum 0.2
물 100까지Up to 100 water
성분(현탁화제는 제회)을 액상 부분과 혼합하고, 슬러리를 0-10미크론의 입자크기로 분쇄한다. 현탁화제와 액상 잔유물로 이루어진 겔을 제조한 다음 분쇄된 슬러리와 혼합하면 생성물을 얻는다.The ingredients (suspending agents are lumped) are mixed with the liquid portion and the slurry is ground to a particle size of 0-10 microns. A gel consisting of a suspending agent and a liquid residue is prepared and then mixed with the ground slurry to yield the product.
[실시예 3]Example 3
분산 과립 조성물은 다음과 같이 제조한다 :Dispersed granule compositions are prepared as follows:
중량%weight%
페나리몰 또는 누아리몰 1.5Penarimol or Noarimol 1.5
유황 80Sulfur 80
알킬 라우레이트 3Alkyl laurate 3
나트륨 페닐 설포네이트 5Sodium Phenyl Sulfonate 5
알긴산 5Alginic acid 5
카올린 100까지Up to 100 kaolins
성분들을 혼합하고 유체 에너지 분쇄기에서 0-10미크론의 크기로 분쇄하고 과합화 한다.The ingredients are mixed and ground to a size of 0-10 microns in a fluid energy grinder and overmixed.
[실시예 4]Example 4
본 발명 조성물의 상승작용 성질을 예를 들어 설명하면 다음과 같다.Referring to the synergistic properties of the composition of the present invention, for example.
몇해이상 페나리몰을 집중적으로 사용하여 스페로데카 펄리기니의 균주를 전개시키면 페나리몰에 민감성은 없다. 이러한 균주는 다음 온실 실험에서 사용했다.If fenarimol is used for more than a few years to develop a strain of Spherodeca peri guinea, it is not susceptible to phenarimol. This strain was used in the next greenhouse experiment.
개별 그릇에 함유되어 있고 하나의 참잎 단계에 있는 오이에 유황, 페나리몰과 유황/페나리몰 혼합물의 함수 현탁액으로 분무한다.Cucumbers contained in separate bowls and in a single leaf stage are sprayed with a hydrous suspension of sulfur, phenarimol and a sulfur / phenarimol mixture.
분무 24시간후 잎표면에서 분무액이 완전히 건조되었을 때, 잎에 스페로데카 펄리기니를 접종 시킨다. 10일 경과후 살균제 성분으로 처리하지 않은 비교식물과 비교하여 균억제 퍼센트를 측정하면 다음과 같은 결과를 얻는다.After 24 hours of spraying, when the spray is completely dry on the surface of the leaves, the leaves are inoculated with Spherodeca perrigini. After 10 days, the percentage of fungicides measured by comparison with the control plants not treated with the disinfectant component is obtained.
유황(ppm)Sulfur (ppm)
페나리몰Penari Mall
(ppm) 0 50 100(ppm) 0 50 100
0 0 16 550 0 16 55
5 45 87 935 45 87 93
공지의"콜비 방정식"(weeds, 15, 20-22(1967))에 의하여 분석하면 상기 결과는 시험조건하에서 상승작용 효과를 가짐을 명백히 입증한다.Analysis by the known "Colby equation" (weeds, 15, 20-22 (1967)) clearly demonstrates that the results have a synergistic effect under test conditions.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8221925 | 1982-07-29 | ||
| GB8221925 | 1982-07-29 |
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| JP2502971B2 (en) * | 1985-11-09 | 1996-05-29 | カシオ計算機株式会社 | Character output device |
| JPS62182978A (en) * | 1986-02-07 | 1987-08-11 | Sanyo Electric Co Ltd | Pattern enlarging method |
| WO2007140588A1 (en) * | 2006-06-02 | 2007-12-13 | Natural Ma Inc. | Pathogenic attenuation via the administration of an equilibiotic compound |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| FR1569940A (en) * | 1967-04-27 | 1969-06-06 | ||
| CS217976B2 (en) * | 1978-04-01 | 1983-02-25 | Lilly Industries Ltd | Fungicide means |
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