KR880012689A - 대전방지 및 전기전도성 중합체 조성물 - Google Patents

대전방지 및 전기전도성 중합체 조성물 Download PDF

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KR880012689A
KR880012689A KR1019880003823A KR880003823A KR880012689A KR 880012689 A KR880012689 A KR 880012689A KR 1019880003823 A KR1019880003823 A KR 1019880003823A KR 880003823 A KR880003823 A KR 880003823A KR 880012689 A KR880012689 A KR 880012689A
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composition
organic compound
electron acceptor
dichloro
component
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KR960014554B1 (ko
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핀테르 위르겐
힐티 브루노
더블유.메이어 칼
민데르 에른스트
파이페르 요세프
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아놀드 자일러, 에른스트 알테르
시바-가이기 아게
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D495/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms
    • C07D495/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
    • C07D495/06—Peri-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D517/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having selenium, tellurium, or halogen atoms as ring hetero atoms
    • C07D517/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having selenium, tellurium, or halogen atoms as ring hetero atoms in which the condensed system contains two hetero rings
    • C07D517/06—Peri-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D517/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having selenium, tellurium, or halogen atoms as ring hetero atoms
    • C07D517/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having selenium, tellurium, or halogen atoms as ring hetero atoms in which the condensed system contains two hetero rings
    • C07D517/08—Bridged systems
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/45—Heterocyclic compounds having sulfur in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/48—Selenium- or tellurium-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00—Compositions of unspecified macromolecular compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/121—Charge-transfer complexes

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  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
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  • Compositions Of Macromolecular Compounds (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Conductive Materials (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
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Abstract

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Description

대전방지 및 전기전도성 중합체 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (19)

  1. a)성분 b)에 대해 불활성인 선상, 측쇄 또는 가교 중합체와 b)하기 일반식(I) 또는 (Ia)화합물, 또는 이들의 혼합물을 포함하는 조성물 ;
    상기식에서, X는 S, Se 또는 Te이고 ; R1, R2, R3및 R4는 서로 독립적인 것으로서 수소 또는 염소이거나, 또는 R1및 R2와 R3및 R4는 함께 각각
    이거나;또는 R1, R2, R3및 R4가 각기 페닐티오, 4-메틸페닐티오, 4-메틸옥시페닐티오 또는 4-피리딜티오이고;R5, R6, R7및 R8은 서로 독립적으로 H 또는 F이거나;R5가 CH3이고 R6, R7, R8은 H이거나;R5, R6, R7및 R8이, CH3이고, R5및 R6가 CH3또는 C1이고 R7및 R8이 H이거나;R5및 R6가 H이고, R7이 -COR9이고 R8이 H 또는 -COR9이거나; 또는 R5및 R6가 H이고, R7및 R8이 함께 -CO-O-CO 또는 -CO-NR10-CO-(여기서 R9는 할로겐화물, -OH, NH2또는 알코올 또는 1급 또는 2급 아민의 라디칼이거나; 또는 R9는 -OM(M은 양이온)이고, R10및 H또는 NH2기에 의해 환원된 1급 아민의 라디칼임)이다.
  2. 제1항에 있어서, 성분b)가 중합체에 대해 0.01 내지 20중량%존재하는 조성물
  3. 제1항에 있어서, 성분b)가 테트라티오테트라센, 테트라셀래노테트라센, 2-플루오로테트라셀래노테트라센 또는 2,3-디플루오로테트라셀래노테트라센인 조성물.
  4. 제1항에 있어서, 일반식(I) 및 (Ia)화합물의 혼합물을 포함하는 조성물.
  5. 제1항에 있어서, 성분 b) 및 가용성 중합체에 대한 용매를 포함하는 조성물.
  6. 제1항에 있어서, 전자 수용체를 포함하는 조성물.
  7. 제6항에 있어서, 전자 수용체는 에너지가 공급될때 할로겐을 분리시키는 할로겐 함유 유기화합물인 조성물.
  8. 제6항에 있어서, 전자 수용체 대 성분 b)의 비가 10:1 내지 1:5인 조성물.
  9. 제7항에 있어서, 할로겐 함유 화합물이 할로겐화, 포화 또는 불포화 지방족, 지환족, 지방족-복소환, 방향족 또는 헤테로방향족 유기 화합물인 조성물.
  10. 제9항에 있어서, 유기 화합물이 염소화, 브롬화 및/또는 요오드화된 조성물.
  11. 제7항에 있어서, 할로겐화 유기화합물이 테트라브로모메탄, 브로모포름, 트리클로로브로모메탄, 헥사클로로프로렌, 헥사클로로시클로프로판, 헥사클로로시클로펜타디엔, 헥사클로로에탄, N-클로로숙신이미드, 옥타클로로프로판, n-옥타-클로로부탄, n-데카클로로부탄, 테트라브로모에탄, 헥사브로모에탄, 테트라-브로모-o-벤조퀴논, N-브로모숙신이미드, 2,4,4,6-테트라브로모-2,5-시클로헥사디엔온, 헥사브로모벤젠, 클로란일, 헥사클로로이세톤, 1,4,5,6,7,7-헥사클로로-5-노르보르넨-2,3-디카르복시산, 1,2,5,6,9,10-헥사브로모시클로도데칸, 테트라클로로에틸렌, 퍼클로로시클로펜타디엔, 퍼클로로부타디엔, 디클로로아세트알데히드 디에틸 아세탈, 1,4-디클로로-2-부텐, 1,3-디클로로-2-부텐, 3,4-디클로로-1-부텐, 테트라클로로시클로로프로펜, 1,3-디클로로아세톤, 2,3,5,6-헥사클로로-p-크실렌, 1,4-비스-(트리클로로메틸)벤젠, 1,3-디브로모프로판, 1,6-디브로모헥산, 에틸 3-클로로프로피온에이트, 3-클로로톨루엔, 메틸 2-클로로프로피온에이트, 2-클로로아크릴로니트릴,에틸 트리클로로아세테이트, 1,2,3-트리클로로프로판, 1,1,2-트리클로로에탄, 부틸 클로로포름에이트, 트리클로로에틸렌, 2,3-디클로로말레산 무수물, 1,12-디브로모도데칸,,` -디브로모-p크실렌,,`-디클로로-o-크실렌, 펜아실클로라이드 또는 브로마이드, 1,10-디브로모데칸,,`-디클로로-p-크실렌,,`디브로모-m-크실렌, 요오드아세토니트릴, 2,3-디클로로-5,6-디시아노벤조퀴논, 메틸 2,3-디클로로프로피온에이트, 1-브로모-2-클로로에탄, 1-브로모-2-클로로프로판, 2-브로모에틸클로로포름에이트, 에틸 요오드아세테이트, N-크롤로숙신이미드, N-브로모숙신이미드, N-요오도숙신이미드, N-크롤로프탈이미드, N-브로모-프탈이미드 또는 N-요오도프탈이미드 또는 그의, 혼합물인 조성물.
  12. 제7항에 있어서, 할로겐 함유 유기 화합물이 액체이며 중합체와 성분 b) 모두에 대한 용매인 조성물.
  13. 제1항에 있어서, 중합체가 열경화성 플라스틱, 열가소성 플라스틱 또는 탄성 중합체인 조성물.
  14. a)선상, 측쇄 또는 가교결합 중합체 그리고 b)제1항에 따른 일반식(I) 또는 (Ia)의 1화합물과 전자수용체로 구성된 적어도 하나의 전하-전이 착물 (CT 착물)을 포함하는 조성물.
  15. 제14항에 있어서, CT 착물이 중합체에 대해 0.01 내지 20중량% 존재한 조성물.
  16. 제12항에 있어서, 전자 수용체가 O2기체 또는 증기 형태의 할로겐화제, 할로겐 함유 유기 화합물 또는 비친핵성 음이온과 함께 산화작용을 갖는 음이온의 염인 조성물.
  17. 전자 수용체가 제1항에 따른 조성물에 작용하는 제14항의 조성물을 제조하는 방법.
  18. 제17항에 있어서, 전자 수용체가 조성물중에 존재하고 C1, Br 및/또는 I를 형성하는 유기 화합물을 가열함으로써 유리되는 염소, 브롬 및/또는 요오드인 방법.
  19. 제14항의 조성물로 부터 제조된 성형물, 필름, 필라멘트, 섬유, 피복물 또는 혼합물질.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880003823A 1987-04-03 1988-04-04 대전방지 및 도전성 중합체 조성물 KR960014554B1 (ko)

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CA1314548C (en) 1993-03-16
IL85941A (en) 1991-09-16
KR960014554B1 (ko) 1996-10-16
EP0285564B1 (de) 1992-04-15
FI95040B (fi) 1995-08-31
ES2032222T3 (es) 1993-01-16
ATE74923T1 (de) 1992-05-15
CN88101671A (zh) 1988-10-19
AU610145B2 (en) 1991-05-16
PH25647A (en) 1991-08-21
FI881495A (fi) 1988-10-04
EP0285564A1 (de) 1988-10-05
IL85941A0 (en) 1988-09-30
JPS6479263A (en) 1989-03-24
GR3004375T3 (ko) 1993-03-31
JP2577769B2 (ja) 1997-02-05
AU1403688A (en) 1988-10-06
US5009812A (en) 1991-04-23
DE3870012D1 (de) 1992-05-21
ZA882320B (en) 1988-10-03
FI881495A0 (fi) 1988-03-30
NZ224110A (en) 1989-08-29
FI95040C (fi) 1995-12-11

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