KR880007124A - 액상유기반응용 형태화 제올라이트 촉매 - Google Patents

액상유기반응용 형태화 제올라이트 촉매 Download PDF

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KR880007124A
KR880007124A KR1019870015188A KR870015188A KR880007124A KR 880007124 A KR880007124 A KR 880007124A KR 1019870015188 A KR1019870015188 A KR 1019870015188A KR 870015188 A KR870015188 A KR 870015188A KR 880007124 A KR880007124 A KR 880007124A
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South Korea
Prior art keywords
zeolite
shaped
catalyst
shaped zeolite
liquid
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KR1019870015188A
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KR910000195B1 (ko
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마사오 나까노
가즈히꼬 세끼자와
도시오 히로나까
기요다까 오오야마
세이이찌 아사노
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나까다니 하루오
도오조오 가부시끼 가이샤
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Publication of KR880007124A publication Critical patent/KR880007124A/ko
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/60—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/51—Spheres
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B39/00—Halogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/10—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
    • C07C17/12—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms in the ring of aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/10—Catalytic reforming with moving catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

내용 없음.

Description

액상유기반응용 형태화 제올라이트 촉매
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (7)

  1. 실질적으로 70 내지 300μm 범위의 입경을 갖는 실질적으로 구형의 입자로 구성되며, 형태와 촉매 그램당 0.4 내지 1cc의 기공부피와 기공부피를 기준으로 1,000 내지 5,500Å의 메디안 기공직경을 갖는 세공들을 갖는 액상 유기 반응용 형태와 제올라이트 촉매.
  2. 제1항에 있어서, 적어도 20중량%의 제올라이트와 80중량%까지의 결합제로 필수적으로 구성되는 것을 특징으로 하는 형태화 제올라이트 촉매.
  3. 제1항에 있어서, 제올라이트함유 슬러리를 뜨거운 공기에 분무하여 액체 방울들을 형성하고 액체 방울들을 건조시키는 분무건조 과립화법에 의해 제조되는 것을 특징으로 하는 형태화 제올라이트 촉매.
  4. 제3항에 있어서, 제올라이트함유 슬러리는 총입자를 기준으로 10중량% 이하의 입자가 쿨러 계수법으로 측정한 바 적어도 30μm의 입경을 갖는 고체입자를 포함하고 상기 슬러리는 20 내지 60중량%의 고체 농도를 갖는 것을 특징으로 하는 형태화 제올라이트 촉매.
  5. 제1항에 있어서, 250 내지 900℃의 온도에서 소성시킨 것을 특징으로 하는 형태화 제올라이트 촉매.
  6. 제1항에 있어서, 액상 유기반응은 벤젠 및 벤젠 유도체로 구성되는 군으로부터 선택된 적어도 한 화합물의 액상 할로겐화인 것을 특징으로 하는 형태화 제올라이트.
  7. 제6항에 있어서, L형 제올라이트 또는 Y형 제올라이트로 되어 있는 것을 특징으로 하는 형태화 제올라이트.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019870015188A 1986-12-29 1987-12-29 액상유기반응용 형태화 제올라이트촉매 KR910000195B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP61310171A JPH0817944B2 (ja) 1986-12-29 1986-12-29 液相有機反応用ゼオライト触媒成形体
JP61-310171 1986-12-29

Publications (2)

Publication Number Publication Date
KR880007124A true KR880007124A (ko) 1988-08-26
KR910000195B1 KR910000195B1 (ko) 1991-01-23

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KR1019870015188A KR910000195B1 (ko) 1986-12-29 1987-12-29 액상유기반응용 형태화 제올라이트촉매

Country Status (5)

Country Link
US (1) US5001289A (ko)
EP (1) EP0273736B1 (ko)
JP (1) JPH0817944B2 (ko)
KR (1) KR910000195B1 (ko)
DE (1) DE3768460D1 (ko)

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US5120693A (en) * 1991-03-25 1992-06-09 Uop Bonded adsorbent agglomerates
EP1421044B1 (en) 2001-07-02 2007-03-07 Exxonmobil Chemical Patents Inc. Inhibiting catalyst coke formation in the manufacture of an olefin
US6872680B2 (en) 2002-03-20 2005-03-29 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst composition, its making and use in conversion processes
US7271123B2 (en) 2002-03-20 2007-09-18 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst composition, its making and use in conversion process
AU2003242429A1 (en) * 2002-05-27 2003-12-12 Toray Industries, Inc. Process for halogenation of benzene and benzene derivatives
DE602004030095D1 (de) * 2003-02-10 2010-12-30 Mitsubishi Gas Chemical Co Verfahren zur herstellung von iodverbindungen und verfahren zur herstellung von hochreiner 5-iod-2-methylbenzoesäure
FR2916654B1 (fr) * 2007-06-04 2011-04-08 Ceca Sa Agglomeres spheriques a base de zeolite(s), leur procede d'obtention et leur utilisation dans les procedes d'adsorption ou en catalyse.
WO2009073099A1 (en) * 2007-11-30 2009-06-11 Corning Incorporated Zeolite-based honeycomb body
JP5669362B2 (ja) * 2009-03-26 2015-02-12 月島機械株式会社 パラジクロロベンゼンの製造方法
JP5425503B2 (ja) * 2009-03-26 2014-02-26 月島機械株式会社 パラジクロロベンゼンの製造方法
WO2010110163A1 (ja) * 2009-03-26 2010-09-30 月島機械株式会社 パラジクロロベンゼンの製造方法
WO2011044091A2 (en) 2009-10-05 2011-04-14 Separation Design Group Llc Ultra rapid cycle portable oxygen concentrator
CN104923284B (zh) * 2014-03-18 2019-09-17 中国石油天然气股份有限公司 一种成型分子筛催化剂及其制备方法和应用
EP3436405A1 (en) * 2016-03-30 2019-02-06 Basf Se Process for the flash calcination of a zeolitic material
JP7145020B2 (ja) * 2018-09-26 2022-09-30 水澤化学工業株式会社 浄化材

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US3431218A (en) * 1966-10-26 1969-03-04 Mobil Oil Corp Conversion of clays to crystalline aluminosilicates and catalysts therefrom
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Also Published As

Publication number Publication date
DE3768460D1 (de) 1991-04-11
KR910000195B1 (ko) 1991-01-23
EP0273736B1 (en) 1991-03-06
JPS63166434A (ja) 1988-07-09
EP0273736A2 (en) 1988-07-06
JPH0817944B2 (ja) 1996-02-28
US5001289A (en) 1991-03-19
EP0273736A3 (en) 1988-09-07

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