KR870006126A - 산으로 양성자 첨가반응에 의해 물에 희석되는 결합제 및 그의 제법 - Google Patents

산으로 양성자 첨가반응에 의해 물에 희석되는 결합제 및 그의 제법 Download PDF

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Publication number
KR870006126A
KR870006126A KR860010385A KR860010385A KR870006126A KR 870006126 A KR870006126 A KR 870006126A KR 860010385 A KR860010385 A KR 860010385A KR 860010385 A KR860010385 A KR 860010385A KR 870006126 A KR870006126 A KR 870006126A
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South Korea
Prior art keywords
carboxyl
molecular weight
acid
binder
average
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KR860010385A
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English (en)
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KR950006258B1 (ko
Inventor
쉬베르젤 토마스
오스테르로 롤프
하르트 슈프 에베르
알렐스 클라스
Original Assignee
바트질, 라이페르트
바스프 락케 앤드 파르벤 아게
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Publication of KR870006126A publication Critical patent/KR870006126A/ko
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Publication of KR950006258B1 publication Critical patent/KR950006258B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/02—Copolymers with acrylonitrile
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C09D5/4488—Cathodic paints
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/42—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof
    • C08G59/4292—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof together with monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/56—Amines together with other curing agents
    • C08G59/58—Amines together with other curing agents with polycarboxylic acids or with anhydrides, halides, or low-molecular-weight esters thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Molecular Biology (AREA)
  • Paints Or Removers (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Epoxy Resins (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Peptides Or Proteins (AREA)

Abstract

내용 없음

Description

산으로 양성자 첨가반응에 의해 물에 희석되는 결합제 및 그의 제법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. a) a1) 분자량 500 내지 8,000을 갖는 카르복실-함유 부타디엔/아크릴로니트릴 공중합체로 구성되고, 필요하다면 a2) 상기의 a1)과 다른것으로써 분자량 90 내지 1,000을 갖는 디카르복실산과의 혼합물로써, 적절하다면 a3) 분자량 140 내지 500을 갖는 모노카르복실산으로 구성되는 카르복실-함유 성분과
    b) 상기 a)의 카르복실기의 몰당 0.7 내지 5몰의 양으로 1차 디아민 및/또는 1차/2차 아민의 반응생성물(A)와 ; 하나 또는 그 이상의 분자당 평균 1.5 내지 3.0의 에폭사이드기를 함유하고 300 내지 6,000의 평균 분자량을 갖는 에폭시수지(B) : 및 지방족 또는 시클로지방족 2차아민(C)을 반응시켜 얻어지고, 산과 더불어 양성자화되어 물에 희석되는 결합제.
  2. 제1항에 있어서, 성분(A,a1)은 공중합체분자내에 평균 1.5 내지 2.5카르복실기를 갖고, 공중합된 단위체로써 아크릴로니트릴 5 내지 45중량%를 함유하는 카르복실-함유 부타디엔/아크릴로 니트릴 공중합체임을 특징으로 하는 결합제.
  3. 제1항에 있어서, 카르복실-함유 부타디엔/아크릴로 니트릴 공중합체(A,a1)은 말단 카르복실기를 운반함을 특징으로 하는 결합제.
  4. 제1항에 있어서, 성분(A,a2)로써 사용된 디카르복실산은 이합체화된 C12-C24-지방산(이합체지방산)임을 특징으로 하는 결합제.
  5. 제1항에 있어서, 2차아민(C)는 C2내지 C18을 함유하고, 더욱더 작용기를 함유할 수 있는 디알킬아민임을 특징으로 하는 결합제.
  6. 제5항에 있어서, 2차아민(C)의 알킬사슬들은 케티민으로 전환되거나 또는 전환될 수 없는 1차아미노기를 운반함을 특징으로 하는 결합제.
  7. A) 유기용매의 존재하에 또는 부재하에
    a) a1) 분자량 500 내지 8,000을 갖는 카르복실-함유 부타디엔/아크릴로니트릴 공중합체로 구성되고, 필요하다면, a2) 상기의 a1)과 다른 것으로써 분자량 90 내지 1,000을 갖는 디카르복실산과의 혼합물로써, 적절하다면 a3) 분자량 140 내지 500을 갖는 모노카르복실산으로 구성되는 카르복실-함유 성분과 b) 상기 성분 a)의 카르복실기의 몰당 0.7 내지 5몰의 양으로 1차디아민 및/또는 1차/2차아민을 200℃ 이하에서 축합반응시키고, 이때 생성된 물은 증류제거하고, 이 축합물을 :
    B) 하나 또는 그 이상의 분자당 평균 1.5 내지 3.0의 에폭사이드기를 함유하고 300 내지 6,000의 평균분자량을 갖는 에폭시수지 및 :
    C) 지방족 또는 시클로 필요하다면, 지방족 2차아민과 40∼l80℃에서 반응시킴을 특징으로 하는 제1항에 따른 결합제의 제조방법.
  8. 교차결합제가 다가의 블록된 이소시아네이트, 아미노플라스트 또는 페놀플라스트수지, 폴리아미노메틸화된 폴리페놀, 에스테르 아미노화반응 및/또는 트랜스에스테르화반응에 의해 경화된 교차결합제 또는 요소축합물임을 특징으로 하는 제1항에 따른 피복물질.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019860010385A 1985-12-03 1986-12-03 산으로 양성자 첨가반응에 의해 물에 희석되는 결합제 및 그의 제법. KR950006258B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19853542594 DE3542594A1 (de) 1985-12-03 1985-12-03 Durch protonieren mit saeure wasserverduennbares bindemittel, dessen herstellung und verwendung
DEP3542594.6 1985-12-03

Publications (2)

Publication Number Publication Date
KR870006126A true KR870006126A (ko) 1987-07-09
KR950006258B1 KR950006258B1 (ko) 1995-06-13

Family

ID=6287403

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019860010385A KR950006258B1 (ko) 1985-12-03 1986-12-03 산으로 양성자 첨가반응에 의해 물에 희석되는 결합제 및 그의 제법.

Country Status (11)

Country Link
US (1) US4769420A (ko)
EP (1) EP0225530B1 (ko)
JP (1) JPH0765009B2 (ko)
KR (1) KR950006258B1 (ko)
CN (1) CN1012616B (ko)
AT (1) ATE63754T1 (ko)
BR (1) BR8606061A (ko)
CA (1) CA1281831C (ko)
DE (2) DE3542594A1 (ko)
ES (1) ES2022102B3 (ko)
IN (1) IN168776B (ko)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4861832A (en) * 1988-04-04 1989-08-29 Lord Corporation Flexible epoxy film from an epoxy resin reacted with a ketimine/amine terminated butadiene/acrylonitrile copolymer blend
DE3906144A1 (de) * 1989-02-28 1990-09-06 Basf Lacke & Farben Durch protonieren mit saeure wasserverduennbare polymere umsetzungsprodukte
DE3906143A1 (de) * 1989-02-28 1990-09-06 Basf Lacke & Farben Hitzehaertbares ueberzugsmittel fuer die kathodische elektrotauchlackierung
US5051209A (en) * 1990-04-27 1991-09-24 E. I. Du Pont De Nemours And Company Conductive epoxypolyamide coating composition
DE4027128A1 (de) * 1990-08-28 1992-03-05 Basf Lacke & Farben Verfahren zum grundieren oder einschichtigen lackieren von kunststoffen mit waessrigen lacken
GB2250512A (en) * 1990-12-07 1992-06-10 Leonid Alexandrovich Mirkind Composition for cathodic electrodeposition
DE4135239A1 (de) * 1991-10-25 1993-04-29 Basf Lacke & Farben Kationische harze auf basis von copolymerisaten aus butadien und acrylnitril
DE102004057651A1 (de) * 2004-11-29 2006-06-01 Tesa Ag Hitzeaktivierbares Klebeband auf der Basis von Nitrilkautschuk und Polyvinylbutyral für die Verklebung von elektronischen Bauteilen und Leiterbahnen
DE102017208511A1 (de) * 2017-05-19 2018-11-22 Henkel Ag & Co. Kgaa Polyurethan-basiertes Bindemittel-System

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE793030A (fr) * 1971-12-20 1973-04-16 Goodrich Co B F Procede pour la realisation de matieres plastiques de resine epoxy
CA1104287A (en) * 1975-07-14 1981-06-30 Goodrich (B.F.) Company (The) Reaction products of non-cycloaliphatic epoxy resins and amine-terminated liquid polymers and process for preparation thereof
US4260700A (en) * 1977-01-24 1981-04-07 The B.F. Goodrich Company Underwater curing of epoxy resin and amine-terminated liquid polymer and product thereof
US4119592A (en) * 1977-02-25 1978-10-10 The B. F. Goodrich Company Rubbery bladders from epoxy compositions
JPS555933A (en) * 1978-06-27 1980-01-17 Nippon Soda Co Ltd Cation electrodeposition coating composition
US4253930A (en) * 1979-07-16 1981-03-03 Nippon Paint Co., Ltd. Process for electrodepositing cationic compositions
DE2928769A1 (de) * 1979-07-17 1981-02-12 Nippon Paint Co Ltd Harz und dieses enthaltender elektrophoretischer anstrichstoff
US4362847A (en) * 1980-05-22 1982-12-07 Shell Oil Company Heat-curable thermosetting resin binder compositions comprising a non-acidic resinous compound, a non-acidic polyester cross-linking agent, and a transesterification catalyst
EP0055632B1 (en) * 1980-12-29 1985-09-11 Sumitomo Chemical Company, Limited Modified epoxy resin composition and process for the preparation thereof
JPS57179268A (en) * 1981-04-27 1982-11-04 Semedain Kk Epoxy resin adhesive composition
US4486571A (en) * 1983-01-05 1984-12-04 Ford Motor Company Epoxy-modified polybutadiene crosslinkable resin coating composition
DE3311514A1 (de) * 1983-03-30 1984-10-25 Basf Farben + Fasern Ag, 2000 Hamburg Herstellung von harnstoffkondensationprodukten und deren verwendung
DE3325061A1 (de) * 1983-07-12 1985-01-24 Basf Farben + Fasern Ag, 2000 Hamburg Stickstoffbasische gruppen tragendes kunstharz, dessen herstellung und verwendung

Also Published As

Publication number Publication date
ES2022102B3 (es) 1991-12-01
EP0225530A2 (de) 1987-06-16
CN1012616B (zh) 1991-05-15
KR950006258B1 (ko) 1995-06-13
JPS62174278A (ja) 1987-07-31
CN86108112A (zh) 1987-11-25
EP0225530B1 (de) 1991-05-22
DE3679388D1 (de) 1991-06-27
JPH0765009B2 (ja) 1995-07-12
ATE63754T1 (de) 1991-06-15
IN168776B (ko) 1991-06-01
BR8606061A (pt) 1987-09-15
US4769420A (en) 1988-09-06
DE3542594A1 (de) 1987-06-04
CA1281831C (en) 1991-03-19
EP0225530A3 (en) 1988-07-27

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