KR850000476A - 비이드상 폴리머 및 그의 제조법 - Google Patents

비이드상 폴리머 및 그의 제조법 Download PDF

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Publication number
KR850000476A
KR850000476A KR1019840001950A KR840001950A KR850000476A KR 850000476 A KR850000476 A KR 850000476A KR 1019840001950 A KR1019840001950 A KR 1019840001950A KR 840001950 A KR840001950 A KR 840001950A KR 850000476 A KR850000476 A KR 850000476A
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South Korea
Prior art keywords
polymer
monomer
bead
water
soluble
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KR1019840001950A
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English (en)
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KR860001409B1 (ko
Inventor
도시유끼 고바시 (외 2)
Original Assignee
와다나베 고오노스께
니혼 엑스란 고오교오 가부시끼 가이샤
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Priority claimed from JP10473583A external-priority patent/JPS59230008A/ja
Priority claimed from JP10842283A external-priority patent/JPS59232104A/ja
Application filed by 와다나베 고오노스께, 니혼 엑스란 고오교오 가부시끼 가이샤 filed Critical 와다나베 고오노스께
Publication of KR850000476A publication Critical patent/KR850000476A/ko
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Publication of KR860001409B1 publication Critical patent/KR860001409B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/20—Aqueous medium with the aid of macromolecular dispersing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F20/32—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/32—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals
    • C08F220/325—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals containing glycidyl radical, e.g. glycidyl (meth)acrylate
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

내용 없음.

Description

비이드상 폴리머 및 그의 제조법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 실시예 5에서 구하여진 용리(熔離)곡선도이다.

Claims (11)

  1. 글리시딜 아크릴레이트 또는 글리시딜메타크릴레이트 단독 또는 50중량% 이상의 상기 단량체와 잔부가 적어도 1종의 다른 단량체로 이루어진 단량체 혼합물을, 실질적으로 에틸렌계 불포화카르본산 또는 그 염으로 이루어진 단량체 단위와 에틸렌계 불포화 술폰산 또는 그 염으로 이루어진 단량체단위와를 결합 함유하는 수용성 중합체 및 유용성래디칼 중합개시제의 존재하, pH 2 내지 9에서 또한 교반속도 50 내지 500r,p,m의 조건하에서 수계 현탁중합하는 것을 특징으로 한 구상 중합체의 제조법.
  2. 제1항에 있어서, 단량체에 대하여 5중량%이상의 수용성 중합체를 사용하는 것을 특징으로한 구상중합체의 제조법.
  3. 제1항에 있어서, 중합도 500 내지 2000 또한 비누화도 85 내지 95%의 폴리비닐알코올을 존재시키는 것을 특징으로한 구상중합체의 제조법.
  4. 제1항에 있어서, 80℃ 이하의 온도조건하에서 중합하는 것을 특징으르 한 구상중합체의 제조법.
  5. 글리시 딜아클리레이트 또는 글리시딜메타클리레이트 단독 또는 50중량% 이상의 상기 단량체와 잔부가 적어도 1종의 다른 단량으로 이루어진 단량체 혼합물을 중합하여 이루어지고 또한 에폭시기의 개환에 의한 수산기가 도입되어 있고, 그리고 겔수분율이 30%이상이며 또한 용제불용성인 비이드상 폴리머.
  6. 제5항에 있어서, 폴리머의 입자경이 10μ이상인 것을 특징으로한 비이드상 폴리머.
  7. 글리시딜아클리레이트 또는 글리시딜메타클리레이트 단독 또는 50중량% 이상의 상기 단량체와 잔부가 적어도 1종의 다른 단량체로 이루어진 단량체 혼합물을, 실질적으로 에틸렌계 불포화 카르본산 또는 그 염으로 이루어진 단량체 단위와 에틸렌계 불포화 술폰산 또는 그 염으로 이루어진 단량체 단위와를 결합유함유하는 수용성 중합제 및 유용성 래디칼중합개시제의 존재하, pH 2 내지 9에서 또한 교반속도 50 내지 500r,p,m의 조건하에서 수계현탁중합한후, pH3 이하에서 또한 온도 70℃이상의 조건하에서 열처리한 것을 특징으로 한 비이드상 폴리머의 제조법.
  8. 제7항에 있어서, 단량체에 대하여 5중량% 이상의 수용성 중합체를 사용한 것을 특징으로 한 비이즈 상 폴리머의 제조법.
  9. 제7항에 있어서, 중합계에 중합도 500 내지 2000 또한 비누화도 85 내지 95%의 폴리비닐알코올을 존재시키는 것을 특징으로 한 비이드상 폴리머 제조법.
  10. 제7항에 있어서, 80℃ 이하의 온도조건하에서 중합하는 것을 특징으로 한 비이드상 폴리머 제조법.
  11. 제7항에 있어서, 0.5 내지 5시간 열처리하는 것을 특징으로 한 비이드상 폴리머 제조법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019840001950A 1983-06-10 1984-04-13 비이드상 폴리머의 제조법 KR860001409B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP10473583A JPS59230008A (ja) 1983-06-10 1983-06-10 球状重合体の製造法
JP???58-104735 1983-06-10
JP58-104735 1983-06-10
JP10842283A JPS59232104A (ja) 1983-06-15 1983-06-15 ビーズ状ポリマーの製造法
JP58-108422 1983-06-15

Publications (2)

Publication Number Publication Date
KR850000476A true KR850000476A (ko) 1985-02-27
KR860001409B1 KR860001409B1 (ko) 1986-09-23

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KR1019840001950A KR860001409B1 (ko) 1983-06-10 1984-04-13 비이드상 폴리머의 제조법

Country Status (6)

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US (1) US4794152A (ko)
KR (1) KR860001409B1 (ko)
DE (2) DE3448010A1 (ko)
FR (1) FR2568256B1 (ko)
GB (1) GB2143243B (ko)
SE (2) SE446869B (ko)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3585786D1 (de) * 1984-12-06 1992-05-07 Japan Exlan Co Ltd Polymergel und seine verwendung zur abtrennung von komponenten aus fluessigkeiten von entschwefelungs- und decyanisierungsverfahren.
WO1992001748A1 (en) * 1990-07-16 1992-02-06 Estron Chemical, Inc. Thermosetting polyester powder coating compositions containing glycidyl methacrylate copolymers as the crosslinking agent
EP0467339A1 (en) * 1990-07-18 1992-01-22 Mitsubishi Kasei Corporation Water-swellable crosslinked polymer particles and process for their production
DE69101435T2 (de) * 1991-06-19 1994-10-06 Ge Plastics Abs Europ Bv Verfahren zur Herstellung von Copolymeren mit Einheiten abgeleitet von Glycidylestern oder Glycidylethern.
JP3131955B2 (ja) * 1992-02-14 2001-02-05 日本エクスラン工業株式会社 ポリアクリロニトリル溶剤中の着色成分の除去方法
WO1997025381A1 (fr) 1996-01-12 1997-07-17 Mitsubishi Rayon Co., Ltd. Resine acrylique a groupes epoxy pour revetements en poudre et son procede de fabrication
US6967232B2 (en) * 2001-10-04 2005-11-22 Dainichiseika Color & Chemicals Mfg., Co., Ltd. High-molecular gelling agent precursor for electrolyte
US7638576B2 (en) * 2005-11-01 2009-12-29 Rohm And Haas Company Aqueous dispersion of epoxy groups-bearing multi-stage polymeric particles
WO2013147306A1 (ja) 2012-03-30 2013-10-03 積水メディカル株式会社 粒子凝集測定用ラテックス粒子
WO2014051098A1 (ja) 2012-09-27 2014-04-03 積水メディカル株式会社 粒子凝集測定用ラテックス粒子

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3639524A (en) * 1969-07-28 1972-02-01 Maurice Seiderman Hydrophilic gel polymer insoluble in water from polyvinylpyrrolidone with n-vinyl-2-pyrrolidone and methacrylic modifier
DE2306808C3 (de) * 1973-02-12 1985-05-30 Wacker-Chemie GmbH, 8000 München Copolymere auf Vinylchloridbasis
US3970633A (en) * 1973-05-16 1976-07-20 Rohm And Haas Company Thermosetting powder coatings composition
JPS5131280B2 (ko) * 1974-04-06 1976-09-06
JPS5839161B2 (ja) * 1976-08-03 1983-08-27 大日本インキ化学工業株式会社 分散樹脂組成物の製造法
JPS55118975A (en) * 1979-03-06 1980-09-12 Sumitomo Chem Co Ltd Powder coating composition
US4304701A (en) * 1979-06-01 1981-12-08 Ppg Industries, Inc. Aqueous acrylic polymer dispersions
JPS5693309A (en) * 1979-12-26 1981-07-28 Nippon Denso Co Ltd High-tension coil
EP0054249B2 (en) * 1980-12-09 1993-04-21 Toray Industries, Inc. Immunoparticles and process for preparing the same
DE3048883A1 (de) * 1980-12-23 1982-07-15 Boehringer Mannheim Gmbh, 6800 Mannheim Hydrophile latexpartikel, verfahren zu deren herstellung und deren verwendung

Also Published As

Publication number Publication date
SE8403842D0 (sv) 1984-07-24
DE3448010A1 (de) 1986-02-20
KR860001409B1 (ko) 1986-09-23
FR2568256B1 (fr) 1986-09-05
US4794152A (en) 1988-12-27
DE3427441A1 (de) 1986-02-06
GB8414602D0 (en) 1984-07-11
SE8403842L (sv) 1986-01-25
SE8504433D0 (sv) 1985-09-25
SE8504433L (sv) 1986-01-25
SE446869B (sv) 1986-10-13
GB2143243B (en) 1987-08-05
DE3427441C2 (ko) 1989-01-26
GB2143243A (en) 1985-02-06
FR2568256A1 (fr) 1986-01-31
SE446870B (sv) 1986-10-13
DE3448010C2 (ko) 1989-01-26

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