KR840007436A - 수용성 금속 가공용 윤활제 조성물 - Google Patents

수용성 금속 가공용 윤활제 조성물 Download PDF

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KR840007436A
KR840007436A KR1019830005347A KR830005347A KR840007436A KR 840007436 A KR840007436 A KR 840007436A KR 1019830005347 A KR1019830005347 A KR 1019830005347A KR 830005347 A KR830005347 A KR 830005347A KR 840007436 A KR840007436 A KR 840007436A
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water
acid
salts
compound
group
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KR1019830005347A
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KR900005102B1 (ko
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히로유끼(외 5) 나가모리
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마루다 요시로 (외 1)
가오 세껭 가부시끼 가이샤
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Abstract

내용 없음.

Description

수용성 금속 가공용 윤활제 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (25)

  1. 반대음이온이 산성 인-함유 화합물 또는 붕산이며, 분자량이 1,000내지 10,000,000이고 한분자내에 적어도 하나의 염기성 또는 양이온성 질소원자를 함유하는 양이온성 또는 양성 부가 중합체, 개환 중합체, 중축합 생성물 및 천연 중합체 유도체의 염 또는 4급 암모늄 염으로 이루어진 그룹중에서 선택된 수용성 중합체 화합물의 적어도 하나로 이루어짐을 특징으로 하는 수용성 금속 가공용 윤활제 조성물.
  2. 제1항에 있어서, 반대음이온으로 작용하는 산성 인-함유 화합물이 인산, 아인산 또는 이들의 티오 화합물; 유기 하이드록시 화합물의 모노-또는 디-포스페이트, 또는 이들의 티오화합물; 다음일반식(X)의 화합물; 다음 일반식(XI)의 화합물; 탄소수 1내지 8의 알킬 그룹 또는 알릴 그룹을 함유하는 모노-또는 디-알킬티오포스폰산; 다음 일반식(XIII)의 화합물; 및 다음 일반식(XIII)의 화합물로 이루어진 그룹중에서 선택된 화합물인 수용성 금속 가공용 윤활제 조성물.
  4. 상기식에서, Ro는 탄소수 1내지 8의 알킬 그룹 또는 알릴 그룹을 나타낸다.
  5. 제1항 또는 2항에 있어서, 수용성 중합체 화합물이, 다음 일반식(I) 내지(V)의 질소-함유 단량체의 염 또는 4급 암모늄 염의 단중합체 또는 이들의 2가지 염 이상의 공중합체; 다음 일반식(I) 내지(V)의 질소-함유단량체의 염 또는 4급 암모늄 적어도 하나와, α,β-불포화 카복실산, 그의 염 및 유도체, 설폰산 그룹-함유 비닐 화합물 및 그의 염, 아크릴로니트릴, 피닐피롤리돈 및 탄소수 2내지 20의 지방족 올레핀으로 이루어진 그룹중에서 선택된 비닐 단량체 적어도 하나의 공중합체; 에틸렌이민의 개환 중합체의 염 또는 4급 암모늄 염; 지방족 디카복실산과 폴리에틸렌폴리아민 또는 디폴리옥시에틸렌알킬아민의 중축합 생성물의 염 또는 4급 암모늄 염; 디할로알칸-폴리알킬렌폴리아민의 중축합 생성물의 염 또는 4급 암모늄염; 에피할로히드린-아민 중축합 생성물의 염 또는 4급 암모늄염; 키토산의 염 또는 4급 암모늄염 및 전분 또는 셀룰로즈의 양이온화 생성물로 이루어진 그룹중에서 선택된 화합물인 수용성 금속 가공용 윤활제 조성물.
  7. 상기식에서, A는 -O- 또는 -NH-를 나타내며; n1은 1내지 3의 정수이고; R1은 H 또는 CH3를 나타내며; R2및 R3는 독립적으로 H,CH3또는 C2H5를 나타내고; 일반식(III)에서, 피리딘은 2- 또는 4-위치에서 치환되며;일반식(IV)에서, 피페리딘은 2- 또는 4-위치에서 치환된다.
  8. 제1항 내지 3항중의 어느 하나에 있어서, 수용성 중합체 화합물의 분자량이 10,000내지 1,000,000인 수용성 금속 가공용 윤활제 조성물.
  9. 제3항 또는 4항에 있어서, 질소-함유단량체와 공중합되는 α,β-불포화카복실산이 아크릴산, 메타크릴산 또는 말레산이며, 그의 염은 알칼리 금속염 또는 암모늄염이고, 그의 유도체는 알킬아미드, 알킬에스테르 또는 아크릴로니트릴인 수용성 금속가공용 윤활제 조성물.
  10. 제3항 또는 4항에 있어서, 질소-함유 단량체와 공중합되는 설폰산 그룹-함유 비닐 화합물이 비닐설폰산, 알릴설폰산, 메트알릴설폰산, 2-아크릴아미노-2-메틸프로판설폰산 또는 p-스티렌설폰산이며, 그의 염은 알칼리 금속염 또는 암모늄 염인 수용성 가공용 윤활제 조성물.
  11. 제3항 또는 4항에 있어서, 엘틸렌이민의 개환 중합체의 순환 단위가 다음 일반식(VI)로 표시되는 수용성 금속 가공용 윤활제 조성물.
  13. 상기식에서, n2는 1내지 5의 정수이며; n3는 0내지 5의 정수이다.
  14. 제3항 또는 4항에 있어서, 지방족 디카복실산과 폴리에틸렌 폴리아민의 중축합 생성물의 순환 단위가 다음 일반식(VII)로 표시되는 수용성 금속 가공용 윤활제 조성물.
  16. 상기식에서, R4는 다이머산 잔기 또는 탄소수 1내지 10의 알킬렌 그룹을 나타내며; R´는 -CH2CH2-를 나타내고; n4는 2내지 7의 정수이다.
  17. 제3항 또는 4항에 있어서, 지방족 디카복실산과 디폴리옥시에틸렌 알킬아민의 중축합 생성물의 순환 단위가 일반식(VIII)로 표시되는 수용성 금속 가공용 윤활제조성물.
  19. 상기식에서, R4는 일반식(VII)에서 정의된 바와 같으며; R5는 탄소수 1내지 8의 알킬 그룹을 나타내고; R6는 H 또는 CH3를 나타내며; n3및 n6는 1내지 10의 정수이다.
  20. 제3항 또는 4항에 있어서, 에피할로히드린-아민 중축합 생성물의 순환 단위가 다음 일반식(IX)로 표시되는 수용성 금속 가공용 윤활제 조성물.
  22. 상기식에서, R7내지 R9는 CH3또는 C2H5를 나타내고; X-는 할로겐 이온을 나타낸다.
  23. 반대음이온이 산성 인-함유 화합물 또는 붕산이며, 분자량이 1,000내지 10,000,000이고 한 분자내에 적어도 하나의 염기성 또는 양이온성 질소원자를 함유하는 양이온성 또는 양성 부가 중합체, 개환 중합체, 다축합 생성물 및 천연 중합체 유도체의 염 또는 4급 암모늄 염으로 이루어진 그룹 중에서 선택된 수용성 중합체 화합물 적어도 하나로 이루어진 수용성 금속 가공용 윤활제 조성물을 사용시에 물로 희석하여 수용액을 제조하고, 생성된 수용액을 분무 또는 침적시킴으로써 금속의 가공 부분에 공급함을 특징으로 하여, 수용성 금속가공용 윤활제 조성물을 공급하는 방법.
  24. 제11항에 있어서, 수용액 중의 수용성 중합체 화합물 농도가 100내지 500,000ppm범위인, 수용성 금속 가공용 윤활제 조성물을 공급하는 방법.
  25. ※ 참고사항:최초출원 내용에 의하여 공개하는 것임.
KR1019830005347A 1982-11-11 1983-11-11 수용성 금속 가공용 윤활제 조성물 KR900005102B1 (ko)

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WO1984004928A1 (en) * 1983-06-07 1984-12-20 Nippon Kokan Kk Composition for use in metal working
JPS59227985A (ja) * 1983-06-10 1984-12-21 Kao Corp 金属加工油組成物
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ES8605023A1 (es) 1986-04-01
IT8349306A0 (it) 1983-11-09
FR2536086A1 (ko) 1984-05-18
JPS5989396A (ja) 1984-05-23
GB8329389D0 (en) 1983-12-07
GB2131449B (en) 1986-06-04
DE3340551C2 (de) 1994-05-11
FR2536086B1 (ko) 1989-09-22
ES527148A0 (es) 1986-04-01
JPS632319B2 (ko) 1988-01-18
GR78738B (ko) 1984-10-02
DE3340551A1 (de) 1984-05-17
KR900005102B1 (ko) 1990-07-19
GB2131449A (en) 1984-06-20
IT1212898B (it) 1989-11-30
US4650595A (en) 1987-03-17

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