KR840002010A - 경화성 폴리(옥사졸리돈 및 우레탄) 조성물 및 그 제법 - Google Patents

경화성 폴리(옥사졸리돈 및 우레탄) 조성물 및 그 제법 Download PDF

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KR840002010A
KR840002010A KR1019820004516A KR820004516A KR840002010A KR 840002010 A KR840002010 A KR 840002010A KR 1019820004516 A KR1019820004516 A KR 1019820004516A KR 820004516 A KR820004516 A KR 820004516A KR 840002010 A KR840002010 A KR 840002010A
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urethane
oxazolidone
curable
composition
acid
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KR1019820004516A
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KR890003002B1 (ko
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레너드 디설보 앤터니 (외1)
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로버트 씨·술리반
스타우퍼 케미칼 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/42—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof
    • C08G59/4284—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof together with other curing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/58—Epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/58—Epoxy resins
    • C08G18/581—Reaction products of epoxy resins with less than equivalent amounts of compounds containing active hydrogen added before or during the reaction with the isocyanate component
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C08G59/12—Polycondensates containing more than one epoxy group per molecule of polycarboxylic acids with epihalohydrins or precursors thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14—Polycondensates modified by chemical after-treatment
    • C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
    • C08G59/1438—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing oxygen
    • C08G59/1455—Monocarboxylic acids, anhydrides, halides, or low-molecular-weight esters thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2120/00—Compositions for reaction injection moulding processes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Emergency Medicine (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

내용 없음

Description

경화성 폴리(옥사졸리돈 및 우레탄) 조성물 및 그 제법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (15)

  1. 폴리이소시안에이트와, 최소한 1개의 말단 에폭시 그루우프 및 최소한 1개의 비-말단 제2히드록시그루우프를 함유하는 프리폴리머를 반응시킴으로서 이루지는 옥사졸리돈 및 우레탄 결합을 함유하는 경화성 폴리(옥사졸리돈 및 우레탄) 조성물 및 그 제법.
  2. 프리폴리머는 디에폭시드와, 모노카르복실산 및 디카르복실산으로 구성된 그루우프에서 선택된 산과의 반응에 의하여 형성되는 특허청구의 범위 1기재의 경화성 폴리(옥사졸리돈 및 우레탄) 조성물 및 그 제법.
  3. 디에폭시드는 디히드릭 단핵(單核) 및 융해환페놀의 디글리시딜 에에테르, 비-융해 폴리핵 페놀의 디글리시딜 에에테르, 노볼락(novolac)수지의 디글리시딜 에에테르, 디시클로펜타디엔 디옥사이드, 비닐시클로헥산 디옥사이드, 디시클로헥실 옥사이드 카르복실실레이트 및 방향족 제1아민의 디글리시딜 유도체로 구성된 그루우프에서 선택되는 특허청구의 범위 2 기재의 경화성 폴리(옥사졸리돈 및 우레탄)조성물 및 그 제법.
  4. 모노카르복실산은 포화 모노카르복실산 및 불포화 모노카르복실산으로 구성된 그루우프에서 선택되는 특허청구의 범위 2기재의 경화성 폴리(옥사졸리돈 및 우레탄)조성물 및 그 제법.
  5. 디카르복실산은 프탈산, 이소프탈산, 테레프탈산, 아디핀산, 수산 및 호박산으로 구성된 그루우프에서 선택되는 특허청구의 범위 2기재의 경화성 폴리(옥사졸리돈 및 우레탄)조성물 및 그 제법.
  6. 폴리이소시안에이트는 방향족 폴리이소시안에이트 및 지방족 폴리이소시안에이트로 구성된 그루우프에서 선택되는 특허청구 범위 1기재의 경화성 폴리(옥사졸리돈 및 우레탄)조성물 및 그 제법.
  7. 디에폭시드는 산의 각 몰당 2몰보다 약간 많은 양으로 존개하는 특허청구의 범위 1∼6기재의 경화성 폴리(옥사졸리돈 및 우레탄)조성물 및 그 제법.
  8. 프리폴리머는 하기 구조식을 가진 특허청구의 범위 1∼6기재의 경화성 폴리(옥사졸리돈 및 우레탄)조성물 및 그 제법.
    식중, R, R1및 R2는 독자적으로 탄소원자가 공유결합될 수 있는 원자의 그루우프이며, X는 점수이고, 1 또는 2이다.
  9. 히드록시 화합물 및 에폭시 화합물로 구성되는 그루우프에서 선택된 이소시안에이트 반응성 화합물의 존재하에서 이루어지는 특허청구의 범위 1∼6기재의 경화성 폴리(옥사졸리돈 및 우레탄)조성물 및 그 제법.
  10. 우레탄 그루우프 형성에 유리한 촉매와 옥사졸리돈 그루우프 형성에 유리한 촉매로 구성된 그루우프에서 선택된 촉매 유효량을 함유하는 특허청구의 범위 1∼6기재의 경화성 폴리(옥사졸리돈 및 우레탄)조성물 및 그 제법.
  11. 옥사졸리돈 결합은 중합체등뼈에 존재하고, 에스테르 결합에 의하여 서로 분리되어 있으며, 우레탄 결합은 중합체등뼈에 인접된 촉쇄에 존재하며, 실질적으로 이소시안에이트 결합을 가지지않는 옥사졸리돈 및 우레탄 결합을 함유하는 경화성 조성물.
  12. 옥사졸리돈 대 우레탄의 분자량은 90:10∼4:96의 범위내로 이루어지는 특허청구의 범위 11기재의 경화성 조성물.
  13. 최소한 1개의 강화제를 함유하는 특허청구의 범위 11기재의 경화성 조성물.
  14. 반복 단위는 하기 구조식을 가진 특허청구의 범위 11기재의 경화성 조성물.
    식중, R, R1, R2및 R3은 탄소원자가 공유결합 될 수 있는 그루우프이며, R4-R13은 독자적으로 동일하고 또한 수소원자를 포함한다.
  15. 반응 사출성형공정에 의하여 형성되는 특허청구의 범위 11∼14 기재의 경화성 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR8204516A 1981-10-08 1982-10-07 열경화성 폴리(옥사졸리돈 및 우레탄)조성물 및 그 제법 KR890003002B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US309,732 1981-10-08
US06/309,732 US4424316A (en) 1981-10-08 1981-10-08 Compositions for forming poly(oxazolidone/urethane) thermosets and products therefrom
US309732 1981-10-08

Publications (2)

Publication Number Publication Date
KR840002010A true KR840002010A (ko) 1984-06-11
KR890003002B1 KR890003002B1 (ko) 1989-08-18

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KR8204516A KR890003002B1 (ko) 1981-10-08 1982-10-07 열경화성 폴리(옥사졸리돈 및 우레탄)조성물 및 그 제법

Country Status (10)

Country Link
US (1) US4424316A (ko)
EP (1) EP0077175B1 (ko)
JP (1) JPS5871914A (ko)
KR (1) KR890003002B1 (ko)
BR (1) BR8205890A (ko)
CA (1) CA1210889A (ko)
CS (1) CS236490B2 (ko)
DD (1) DD203055A5 (ko)
DE (1) DE3275298D1 (ko)
ES (1) ES8403954A1 (ko)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4504633A (en) * 1983-06-01 1985-03-12 Stauffer Chemical Company Modified poly(oxazolidone/urethane) compositions
FR2549277B1 (fr) * 1983-07-13 1985-10-25 Alsthom Atlantique Procede d'isolation par impregnation d'un bobinage electrique, et vernis sans solvant stabilise utilisable dans ce procede
CA1340052C (en) * 1988-03-31 1998-09-22 Narasimhan Raghupathi Chemically treated glass fibers for reinforcing thermosetting polymer matrices
DE68921092T2 (de) * 1988-05-13 1995-08-03 Nippon Paint Co Ltd Hitzehärtende Harzzusammensetzung und Herstellung von hitzebeständigen Überzügen und Gegenständen auf der Basis dieser Zusammensetzung.
US4981754A (en) * 1988-06-20 1991-01-01 Owens-Corning Fiberglas Corporation Glass fibers having a size composition containing the reaction product of an acid and/or alcohol with the terminal epoxy groups of a diglycidyl ether of a bisphenol
JPH03255122A (ja) * 1990-03-02 1991-11-14 Nippon Paint Co Ltd 熱硬化性樹脂組成物ならびに熱硬化樹脂成形物
US5138016A (en) * 1990-12-18 1992-08-11 H. B. Fuller Company Isocyanurate-free oxazolidone compound made from epoxy and a hindered isocyanate compound and a novel catalyst for their production
US5304612A (en) * 1990-12-25 1994-04-19 Teijin Limited Plural liquid pack type heat curable polyisocyanate-glycidyl acrylate compound resinous composition and process for producing shaped resin article therefrom
US5480958A (en) * 1994-09-21 1996-01-02 Air Products And Chemicals, Inc. Polyepoxide resins incorporating epoxy terminated urethanes as tougheners
DE19654149A1 (de) * 1996-12-23 1998-06-25 Basf Ag Oxazolidon- und Urethangruppen enthaltende, unter Druck stehende isocyanatterminierte Prepolymere für Einkomponenten-Schäume
US7267288B2 (en) * 2001-03-22 2007-09-11 Nevada Supply Corporation Polyurethane in intimate contact with fibrous material
US7599861B2 (en) 2006-03-02 2009-10-06 Convergys Customer Management Group, Inc. System and method for closed loop decisionmaking in an automated care system
US8379830B1 (en) 2006-05-22 2013-02-19 Convergys Customer Management Delaware Llc System and method for automated customer service with contingent live interaction
US7809663B1 (en) 2006-05-22 2010-10-05 Convergys Cmg Utah, Inc. System and method for supporting the utilization of machine language

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2830038A (en) 1957-05-07 1958-04-08 Du Pont Poly (polyalkylene ether urethane) polymers containing terminal epoxide groups
US3242108A (en) 1961-04-04 1966-03-22 Union Carbide Corp Compositions for producing polyurethane resins and resinous foams and products prepared therefrom
NL280840A (ko) 1961-07-12
US3313747A (en) 1964-10-29 1967-04-11 Baker Chem Co J T Polymers prepared from isocyanateoxazolidinones
US3373221A (en) 1964-11-04 1968-03-12 Shell Oil Co Reaction products of unsaturated esters of polyepoxides and unsaturated carboxylic acids, and polyisocyanates
US3445436A (en) 1966-06-14 1969-05-20 Tremco Mfg Co Polyurethane polyepoxides
US3761452A (en) 1968-02-16 1973-09-25 Du Pont Epoxy polyurethane prepolymer compositions which are self curing uponapplication of heat
US3484413A (en) 1968-04-29 1969-12-16 Mobay Chemical Corp Polyurethanes prepared from the cyclization product of a polyglycidyl carbamate
US3639655A (en) 1969-03-21 1972-02-01 Phillips Petroleum Co Preparation of hydroxy-substituted polyesters
JPS4940863B1 (ko) 1970-01-22 1974-11-06
DE2247696A1 (de) 1972-09-28 1974-05-02 Synthopol Chemie Dr Koch Verfahren zur herstellung von waermehaertbaren ueberzuegen
US3781235A (en) 1972-10-31 1973-12-25 Gen Electric Method for making rigid foam and compositions using such method
US4070416A (en) 1972-11-29 1978-01-24 Hitachi, Ltd. Novel thermosetting resin and a process for producing same
JPS5727894B2 (ko) * 1974-10-11 1982-06-14
FR2291996A1 (fr) * 1974-11-20 1976-06-18 Rhone Poulenc Ind Polymeres nouveaux prepares a partir de polyisocyanates et de polyepoxydes
DE2557408C2 (de) 1975-12-19 1983-08-25 Bayer Ag, 5090 Leverkusen Verfahren zur Herstellung eines in organischen Lösungsmitteln löslichen, vernetzbaren Acryloyl- und/oder Methacryloylgruppen und Carboxylgruppen enthaltenden Urethanharzes und seine Verwendung
US4066628A (en) 1976-08-02 1978-01-03 Mitsubishi Chemical Industries Ltd. Oxazolidone catalyst
US4143009A (en) 1977-03-02 1979-03-06 Frank Dewey Polyurethane-epoxy casting resin
CH624968A5 (ko) 1977-06-14 1981-08-31 Ciba Geigy Ag
US4239857A (en) 1978-06-29 1980-12-16 Union Carbide Corporation Process for producing solid or microcellular polyurethane elastomers having improved green strength

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EP0077175A3 (en) 1983-08-24
US4424316A (en) 1984-01-03
CS236490B2 (en) 1985-05-15
CA1210889A (en) 1986-09-02
DD203055A5 (de) 1983-10-12
BR8205890A (pt) 1983-09-06
EP0077175A2 (en) 1983-04-20
ES516312A0 (es) 1984-04-01
KR890003002B1 (ko) 1989-08-18
JPS5871914A (ja) 1983-04-28
EP0077175B1 (en) 1987-01-28
ES8403954A1 (es) 1984-04-01
DE3275298D1 (en) 1987-03-05

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