KR830006341A - 중합용촉매제 및 그 제조방법 - Google Patents
중합용촉매제 및 그 제조방법 Download PDFInfo
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- KR830006341A KR830006341A KR1019810001616A KR810001616A KR830006341A KR 830006341 A KR830006341 A KR 830006341A KR 1019810001616 A KR1019810001616 A KR 1019810001616A KR 810001616 A KR810001616 A KR 810001616A KR 830006341 A KR830006341 A KR 830006341A
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- Prior art keywords
- aluminum
- catalyst
- compound
- polymerization
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- 238000004519 manufacturing process Methods 0.000 title claims 10
- 239000002685 polymerization catalyst Substances 0.000 title 1
- -1 titanium halide Chemical class 0.000 claims 15
- 239000003054 catalyst Substances 0.000 claims 13
- 238000006116 polymerization reaction Methods 0.000 claims 12
- 125000004432 carbon atom Chemical group C* 0.000 claims 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 5
- 150000001875 compounds Chemical class 0.000 claims 5
- 239000010936 titanium Substances 0.000 claims 5
- 229910052719 titanium Inorganic materials 0.000 claims 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 4
- 239000007795 chemical reaction product Substances 0.000 claims 4
- 229910052739 hydrogen Inorganic materials 0.000 claims 4
- 239000001257 hydrogen Substances 0.000 claims 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims 3
- 150000002894 organic compounds Chemical class 0.000 claims 3
- 150000002902 organometallic compounds Chemical class 0.000 claims 3
- NXXYKOUNUYWIHA-UHFFFAOYSA-N 2,6-Dimethylphenol Chemical compound CC1=CC=CC(C)=C1O NXXYKOUNUYWIHA-UHFFFAOYSA-N 0.000 claims 2
- GJYCVCVHRSWLNY-UHFFFAOYSA-N 2-butylphenol Chemical compound CCCCC1=CC=CC=C1O GJYCVCVHRSWLNY-UHFFFAOYSA-N 0.000 claims 2
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 claims 2
- 241000123112 Cardium Species 0.000 claims 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 claims 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims 2
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 claims 2
- 150000001408 amides Chemical class 0.000 claims 2
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 claims 2
- MGDOJPNDRJNJBK-UHFFFAOYSA-N ethylaluminum Chemical compound [Al].C[CH2] MGDOJPNDRJNJBK-UHFFFAOYSA-N 0.000 claims 2
- 238000000227 grinding Methods 0.000 claims 2
- 229910052736 halogen Inorganic materials 0.000 claims 2
- 150000002367 halogens Chemical class 0.000 claims 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 claims 2
- 239000011777 magnesium Substances 0.000 claims 2
- 229910052749 magnesium Inorganic materials 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- 239000000203 mixture Substances 0.000 claims 2
- 150000007524 organic acids Chemical class 0.000 claims 2
- 235000005985 organic acids Nutrition 0.000 claims 2
- 239000000047 product Substances 0.000 claims 2
- 238000010298 pulverizing process Methods 0.000 claims 2
- 239000007787 solid Substances 0.000 claims 2
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims 2
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 claims 1
- NSENZNPLAVRFMJ-UHFFFAOYSA-N 2,3-dibutylphenol Chemical compound CCCCC1=CC=CC(O)=C1CCCC NSENZNPLAVRFMJ-UHFFFAOYSA-N 0.000 claims 1
- CJWNFAKWHDOUKL-UHFFFAOYSA-N 2-(2-phenylpropan-2-yl)phenol Chemical compound C=1C=CC=C(O)C=1C(C)(C)C1=CC=CC=C1 CJWNFAKWHDOUKL-UHFFFAOYSA-N 0.000 claims 1
- CMAOLVNGLTWICC-UHFFFAOYSA-N 2-fluoro-5-methylbenzonitrile Chemical compound CC1=CC=C(F)C(C#N)=C1 CMAOLVNGLTWICC-UHFFFAOYSA-N 0.000 claims 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 claims 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims 1
- OIGWAXDAPKFNCQ-UHFFFAOYSA-N 4-isopropylbenzyl alcohol Chemical compound CC(C)C1=CC=C(CO)C=C1 OIGWAXDAPKFNCQ-UHFFFAOYSA-N 0.000 claims 1
- MQWCXKGKQLNYQG-UHFFFAOYSA-N 4-methylcyclohexan-1-ol Chemical compound CC1CCC(O)CC1 MQWCXKGKQLNYQG-UHFFFAOYSA-N 0.000 claims 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims 1
- CDUJMDNHYLCBJI-UHFFFAOYSA-N C(CCC)[O-].C(CCC)[Al+2].C(CCC)[O-].C(CCC)[O-].C(CCC)[Al+2] Chemical compound C(CCC)[O-].C(CCC)[Al+2].C(CCC)[O-].C(CCC)[O-].C(CCC)[Al+2] CDUJMDNHYLCBJI-UHFFFAOYSA-N 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 claims 1
- 239000004743 Polypropylene Substances 0.000 claims 1
- 239000004793 Polystyrene Substances 0.000 claims 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- ZXRRHFSTAFVGOC-UHFFFAOYSA-N [AlH3].[K] Chemical compound [AlH3].[K] ZXRRHFSTAFVGOC-UHFFFAOYSA-N 0.000 claims 1
- JFBZPFYRPYOZCQ-UHFFFAOYSA-N [Li].[Al] Chemical compound [Li].[Al] JFBZPFYRPYOZCQ-UHFFFAOYSA-N 0.000 claims 1
- SZNWCVFYBNVQOI-UHFFFAOYSA-N [O-]CC.C(C)[Al+2].[O-]CC.[O-]CC.C(C)[Al+2] Chemical compound [O-]CC.C(C)[Al+2].[O-]CC.[O-]CC.C(C)[Al+2] SZNWCVFYBNVQOI-UHFFFAOYSA-N 0.000 claims 1
- 150000001298 alcohols Chemical class 0.000 claims 1
- 150000001299 aldehydes Chemical class 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- DNEHKUCSURWDGO-UHFFFAOYSA-N aluminum sodium Chemical compound [Na].[Al] DNEHKUCSURWDGO-UHFFFAOYSA-N 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 125000004429 atom Chemical group 0.000 claims 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims 1
- 229910052810 boron oxide Inorganic materials 0.000 claims 1
- OCFSGVNHPVWWKD-UHFFFAOYSA-N butylaluminum Chemical compound [Al].[CH2]CCC OCFSGVNHPVWWKD-UHFFFAOYSA-N 0.000 claims 1
- 229930003836 cresol Natural products 0.000 claims 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 claims 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims 1
- VJRUISVXILMZSL-UHFFFAOYSA-M dibutylalumanylium;chloride Chemical compound CCCC[Al](Cl)CCCC VJRUISVXILMZSL-UHFFFAOYSA-M 0.000 claims 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- HJXBDPDUCXORKZ-UHFFFAOYSA-N diethylalumane Chemical compound CC[AlH]CC HJXBDPDUCXORKZ-UHFFFAOYSA-N 0.000 claims 1
- JJSGABFIILQOEY-UHFFFAOYSA-M diethylalumanylium;bromide Chemical compound CC[Al](Br)CC JJSGABFIILQOEY-UHFFFAOYSA-M 0.000 claims 1
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 claims 1
- HQWPLXHWEZZGKY-UHFFFAOYSA-N diethylzinc Chemical compound CC[Zn]CC HQWPLXHWEZZGKY-UHFFFAOYSA-N 0.000 claims 1
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 claims 1
- 125000005843 halogen group Chemical group 0.000 claims 1
- 150000002430 hydrocarbons Chemical group 0.000 claims 1
- 150000003949 imides Chemical class 0.000 claims 1
- 239000003350 kerosene Substances 0.000 claims 1
- 229910052744 lithium Inorganic materials 0.000 claims 1
- 150000002681 magnesium compounds Chemical class 0.000 claims 1
- DLPASUVGCQPFFO-UHFFFAOYSA-N magnesium;ethane Chemical compound [Mg+2].[CH2-]C.[CH2-]C DLPASUVGCQPFFO-UHFFFAOYSA-N 0.000 claims 1
- YCCXQARVHOPWFJ-UHFFFAOYSA-M magnesium;ethane;chloride Chemical compound [Mg+2].[Cl-].[CH2-]C YCCXQARVHOPWFJ-UHFFFAOYSA-M 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- 238000003801 milling Methods 0.000 claims 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 claims 1
- 125000005375 organosiloxane group Chemical group 0.000 claims 1
- 230000000737 periodic effect Effects 0.000 claims 1
- 150000002989 phenols Chemical class 0.000 claims 1
- 229920001155 polypropylene Polymers 0.000 claims 1
- 229920002223 polystyrene Polymers 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 239000001294 propane Substances 0.000 claims 1
- OBRKWFIGZSMARO-UHFFFAOYSA-N propylalumane Chemical compound [AlH2]CCC OBRKWFIGZSMARO-UHFFFAOYSA-N 0.000 claims 1
- 229910052814 silicon oxide Inorganic materials 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 150000003573 thiols Chemical class 0.000 claims 1
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 claims 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (12)
- 본문에 상술한 바와 같이, (a) 유기알루미늄 함유성분 및 (b) 할로겐화 티타늄 함유성분으로 이루어지며, 상기 할로겐화 티타늄함유성분은 (i) 할로겐화마그네슘 화합물을 활성수소함유 유기화합물과 공분쇄함에 의하여 공분쇄된 생성물을 생성화고, (ii) 상기 공분쇄된 생성물을 주기표의 그루우프 I~Ⅱ의 금속중의 유기금속화합물과 반응함에 의하여 반응생성물을 생성하여, (iii) 반응생성물과 첫번째의 할로겐화티타늄호합물 및 여전자체의 혼합물과의 공분쇄에 의하여 고체반응생성물을 생성하고, (iv) 고체반응생성물을 둘째번의 할로겐화티타늄 화합물과 반응시킴으로써 이루어지는 중합용 촉매제 및 그 제조방법.
- 공분쇄단계(i)는 유효량의 유기 또는 무기분쇄조제의 존재하에서 수행되는 특허청구의 범위 1기재의 중합용 촉매제 및 그 제조방법.
- 분쇄조제는 헥산, 헵탄, 등유, 폴리스티렌, 폴리프로필렌, 산화붕소, 산화실리콘 및 유기실록산으로 구성되는 그루우프에서 선택되는 특허청구의 범위 1기재의 중합용 촉매제 및 그 제조방법.
- 할로겐함유 마그네슘 화합물은 이 염화마그네슘(MgCl2)인 특허청구의 범위 1기재의 중합용 촉매제 및 그 제조방법.
- 활성수소함유 화합물은 알코올, 페놀, 티올, 제1 및 제2아민, 알데히드, 유기산, 아미드, 아미드 및 유기산의 이미드로 구성된 그루우프에서 선택되는 특허청구의 범위 1기재의 중합용 촉매제 및 그 제조방법.
- 활성수소함유유기 화합물은 알코올 또는 페놀인 특허청구의 범위 1기재의 중합용 촉매제 및 그 제조방법.
- 활성수소함유유기화합물은 메탄올, 에탄올, 프로판을, 부탄올, 펜탄올, 헥산올, 2-에틸-헥산올, 에틸렌 글리코올 모노메틸렌에에테르, 시클로헥산올, 메틸시클로헥산올, 벤질 알코올, 펜에틸알코올, 큐밀 알코올, 페놀, 크레졸 2,6-디메틸페놀, 부틸페놀, 옥틸페놀, 논일페놀, 디부틸페놀, 큐밀 페놀 및 나프톨로 구성되는 그루우프에서 선택되는 특허청구의 범위 1기재의 중합용 촉매제 및 그 제조방법.
- 유기 금속화합물은(1)하기 구조식[I]의 유기알루미늄화합물과 (2) 구조식[Ⅱ]의 알루미늄 복합알킬화합물과 (3) 구조식 [Ⅲ]의 화합물로 구성된 그루우프에서 선택되는 특허청구의 범위 1기재의 중합용 촉매제 및 그 제조방법.R1mAl(OR2)nHpXq[I]식중, R1및 R2는 서로 동일하거나 또는 다르며, 그리고 1~15개의 탄소원자를 함유하는 탄화수소기, 바람직하게는 1~8개의 탄소원자를 함유하는 알킬 그루우프 또는 알릴치환분을 나타내고, X는 할로겐원자를 나타내며, m+n+p+q=3이라는 조건하에서, m은 0 이상이나 3이하(0〈m3)이고, n은 최소한 0 이나 3이하(0n〈3)이며, p는 최소한 0이나 3이하(0n〈3)이고, 그리고 q는 최소한 0이나 3이하(0q〈3)이다.식중, R3는 상기 정의된 R1과 동일하며, M1은 리듐, 나트륨 또는 칼륨을 나타낸다.식중, R1은 상기 정의된 R1과 동일하며, R4는 R1과 동일하거나, 또는 할로겐원자를 나타내고, 그리고 M2는 마그네슘, 아연 또는 카듐을 나타낸다.
- 유기금속화합물은 트리에틸알루미늄, 트리부틸알루미늄, 에틸 알루미늄 세스퀴에톡시드, 부틸 알루미늄 세스퀴부톡시드, 디에틸 알루미늄 클로라이드, 디부틸 알루미늄 클로라이드 및 디에틸 알루미늄 브로마이드, 에틸 알루미늄 세스퀴클로라이드, 부틸 알루미늄 세스퀴클로라이드, 에틸 알루미늄 세스퀴브로마이드, 에틸 알라미늄 디클로라이드, 디에틸 알루미늄 하이드라이드, 에틸 알루미늄 디하이드라이드, 프로필 알루미늄 디하이드라이드, 에틸 알루미늄 에톡시클로라이드, 부틸 알루미늄 부톡시클로라이드, 에틸 알루미늄에톡시 브로마이드, LiALH4, 리튬 알루미늄 테트라에틸, [LiAL(C2H5)4] 소듐 알루미늄 테트라부틸, 포타슘 알루미늄 테트라에틸, 디에틸 마그네슘, 디에틸아연, 디에틸 카듐 및 에틸마그네슘 클로라이드로 구성된 구루우프에서 선택되는 특허청구의 범위 1기재의 중합용 촉매제 및 그 제조방법.
- 첫번째 및 둘째번의 할로겐화 티타늄화합물은 티타늄 클로라이드물질 및 티타늄 테트라클로라이드로 구성되는 그루우프에서 독자적으로 선택되는 특허청구의 범위 1기재의 중합용 촉매제 및 그 제조방법.
- 여전자체는 18개이하의 탄소원자를 함유하는 지방족 카르복실산 에스테르, 18개 이하의 탄소원자를 함유하는 할로겐화 지방족 카르복실산에스테르, 12개 이하의 탄소원자를 함유하는 알리시클릭카르복실산 에스테르 및 20개 이하의 탄소원자를 함유하는 방향족 카르복실산 에스테르로 구성된 그루우프에서 선택되는 유기산 에스테르인 특허청구의 범위 1기재의 중합용 촉매제 및 그 제조방법.
- 복합체는 TiCl4. 에틸벤조에이트 복합체인 특허청구의 범위 1기재의 중합용 촉매제 및 그 제조방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US148,078 | 1980-05-12 | ||
| US148078 | 1980-05-12 | ||
| US06/148,078 US4312782A (en) | 1980-05-12 | 1980-05-12 | Titanium halide catalyst for polymerization |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR830006341A true KR830006341A (ko) | 1983-09-24 |
| KR840000465B1 KR840000465B1 (ko) | 1984-04-09 |
Family
ID=22524166
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019810001616A KR840000465B1 (ko) | 1980-05-01 | 1981-05-02 | 중합용 할로겐화 티타늄 함유 촉매제 |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US4312782A (ko) |
| EP (1) | EP0040711B1 (ko) |
| JP (1) | JPS575702A (ko) |
| KR (1) | KR840000465B1 (ko) |
| AT (1) | ATE4811T1 (ko) |
| AU (1) | AU542843B2 (ko) |
| BR (1) | BR8102915A (ko) |
| CA (1) | CA1158633A (ko) |
| CS (1) | CS228906B2 (ko) |
| DD (1) | DD158551A5 (ko) |
| DE (1) | DE3161012D1 (ko) |
| ES (1) | ES502136A0 (ko) |
| NO (1) | NO811596L (ko) |
| PT (1) | PT72997B (ko) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110256012A (zh) * | 2019-06-25 | 2019-09-20 | 成都建工赛利混凝土有限公司 | 一种新型环保掺合料混凝土及其制备工艺 |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4680350A (en) * | 1981-09-10 | 1987-07-14 | Stauffer Chemical Company | Purified catalyst support |
| US4382019A (en) * | 1981-09-10 | 1983-05-03 | Stauffer Chemical Company | Purified catalyst support |
| IT1190682B (it) * | 1982-02-12 | 1988-02-24 | Montedison Spa | Catalizzatori per la polimerizzazione di olefine |
| EP0095290B1 (en) * | 1982-05-14 | 1986-09-10 | Amoco Corporation | Retreating comminuted olefin polymerization catalyst with a titanium (iv) compound and an ester |
| US4431572A (en) * | 1982-05-14 | 1984-02-14 | Standard Oil Company (Indiana) | Retreating comminuted olefin polymerization catalyst with a titanium (IV) compound, a chlorocarbon and an ester |
| US4431571A (en) * | 1982-05-14 | 1984-02-14 | Standard Oil Company (Indiana) | Retreating comminuted olefin polymerization catalyst with a titanium(IV) compound, a haloalkylchlorosilane and an ester |
| US4431570A (en) * | 1982-05-14 | 1984-02-14 | Standard Oil Company (Indiana) | Retreating comminuted olefin polymerization catalyst with a titanium (IV) compound and an ester |
| US4450242A (en) * | 1982-08-09 | 1984-05-22 | Stauffer Chemical Company | Catalyst for polymerizing olefins |
| US4563437A (en) * | 1984-08-30 | 1986-01-07 | Toho Titanium Co., Ltd. | Process for preparation of catalytic components for polymerization of α-olefins |
| US5039342A (en) * | 1988-11-10 | 1991-08-13 | Herman Mark | Modified asphalt cement compositions and methods of producing the same |
| US6015768A (en) * | 1998-04-22 | 2000-01-18 | Ray; Sabyasachi Sinha | Process for preparation of a heterogeneous catalyst useful for preparation of super high molecular weight polymers of alpha-olefin |
| US6586543B1 (en) * | 1999-09-01 | 2003-07-01 | Degussa Ag | Process for the preparation of substantially amorphous poly-α-olefins |
| KR100702435B1 (ko) * | 2004-11-03 | 2007-04-03 | 주식회사 엘지화학 | 고활성 마그네슘 담지 촉매 및 이를 이용한 폴리올레핀의제조방법 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE765033R (fr) * | 1970-04-06 | 1971-09-30 | Inst Francais Du Petrole | Nouveau procede d'hydrogenation et catalyseurs d'hydrogenation correspondants |
| JPS4933957B1 (ko) * | 1970-12-25 | 1974-09-11 | ||
| US4107413A (en) * | 1971-06-25 | 1978-08-15 | Montedison S.P.A. | Process for the stereoregular polymerization of alpha olefins |
| US4071674A (en) * | 1972-09-14 | 1978-01-31 | Mitsui Petrochemical Industries Ltd. | Process for polymerization or copolymerization of olefin and catalyst compositions used therefor |
| US4076924A (en) * | 1974-09-03 | 1978-02-28 | Mitsui Petrochemical Industries Ltd. | Process for polymerization or copolymerizing olefins containing at least 3 carbon atoms |
| JPS5218784A (en) * | 1975-08-05 | 1977-02-12 | Nippon Oil Co Ltd | Process for preparing polyolefins |
| JPS52104593A (en) * | 1976-03-01 | 1977-09-02 | Mitsui Petrochem Ind Ltd | Polymerization of olefins |
| IT1068112B (it) * | 1976-08-09 | 1985-03-21 | Montedison Spa | Componenti di catalizzatori per la polimerizzazione delle alfa olefine e catalizzatori da essi ottenuti |
| JPS591407B2 (ja) * | 1977-03-04 | 1984-01-12 | 三井化学株式会社 | チタン触媒成分の製造方法 |
-
1980
- 1980-05-12 US US06/148,078 patent/US4312782A/en not_active Expired - Lifetime
-
1981
- 1981-04-23 AU AU69749/81A patent/AU542843B2/en not_active Expired - Fee Related
- 1981-04-29 DE DE8181103239T patent/DE3161012D1/de not_active Expired
- 1981-04-29 EP EP81103239A patent/EP0040711B1/en not_active Expired
- 1981-04-29 AT AT81103239T patent/ATE4811T1/de not_active IP Right Cessation
- 1981-05-02 KR KR1019810001616A patent/KR840000465B1/ko active
- 1981-05-08 JP JP6926181A patent/JPS575702A/ja active Pending
- 1981-05-08 PT PT72997A patent/PT72997B/pt unknown
- 1981-05-11 CA CA000377298A patent/CA1158633A/en not_active Expired
- 1981-05-11 NO NO811596A patent/NO811596L/no unknown
- 1981-05-11 BR BR8102915A patent/BR8102915A/pt unknown
- 1981-05-12 DD DD81229886A patent/DD158551A5/de unknown
- 1981-05-12 ES ES502136A patent/ES502136A0/es active Granted
- 1981-05-12 CS CS813485A patent/CS228906B2/cs unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110256012A (zh) * | 2019-06-25 | 2019-09-20 | 成都建工赛利混凝土有限公司 | 一种新型环保掺合料混凝土及其制备工艺 |
Also Published As
| Publication number | Publication date |
|---|---|
| NO811596L (no) | 1981-11-13 |
| JPS575702A (en) | 1982-01-12 |
| EP0040711B1 (en) | 1983-09-28 |
| ATE4811T1 (de) | 1983-10-15 |
| AU542843B2 (en) | 1985-03-21 |
| CS228906B2 (en) | 1984-05-14 |
| KR840000465B1 (ko) | 1984-04-09 |
| DD158551A5 (de) | 1983-01-19 |
| AU6974981A (en) | 1981-11-19 |
| CA1158633A (en) | 1983-12-13 |
| US4312782A (en) | 1982-01-26 |
| ES8203637A1 (es) | 1982-04-01 |
| DE3161012D1 (en) | 1983-11-03 |
| BR8102915A (pt) | 1982-02-02 |
| PT72997B (en) | 1982-07-01 |
| PT72997A (en) | 1981-06-01 |
| ES502136A0 (es) | 1982-04-01 |
| EP0040711A1 (en) | 1981-12-02 |
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