KR20230090715A - Method For Manufacturing Antibacterial Deodorizing Agent Using Natural Ingredients - Google Patents
Method For Manufacturing Antibacterial Deodorizing Agent Using Natural Ingredients Download PDFInfo
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- 239000004615 ingredient Substances 0.000 title claims abstract description 12
- 238000000034 method Methods 0.000 title claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 9
- 230000000844 anti-bacterial effect Effects 0.000 title claims description 11
- 230000001877 deodorizing effect Effects 0.000 title description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 43
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000008213 purified water Substances 0.000 claims abstract description 32
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000002781 deodorant agent Substances 0.000 claims abstract description 22
- 229920001353 Dextrin Polymers 0.000 claims abstract description 19
- 239000004375 Dextrin Substances 0.000 claims abstract description 19
- 235000019425 dextrin Nutrition 0.000 claims abstract description 19
- 238000010438 heat treatment Methods 0.000 claims abstract description 13
- 238000003756 stirring Methods 0.000 claims abstract description 12
- 238000002156 mixing Methods 0.000 claims abstract description 9
- 241000018646 Pinus brutia Species 0.000 claims abstract description 7
- 239000007787 solid Substances 0.000 claims abstract description 6
- 235000008331 Pinus X rigitaeda Nutrition 0.000 claims abstract description 5
- 235000011613 Pinus brutia Nutrition 0.000 claims abstract description 5
- 239000011347 resin Substances 0.000 claims abstract description 5
- 229920005989 resin Polymers 0.000 claims abstract description 5
- 241000209094 Oryza Species 0.000 claims description 10
- 235000007164 Oryza sativa Nutrition 0.000 claims description 10
- 235000009566 rice Nutrition 0.000 claims description 10
- 239000010902 straw Substances 0.000 claims description 10
- 239000000440 bentonite Substances 0.000 claims description 6
- 229910000278 bentonite Inorganic materials 0.000 claims description 6
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 5
- 239000003205 fragrance Substances 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 239000000171 lavandula angustifolia l. flower oil Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 239000000463 material Substances 0.000 claims 1
- 239000002244 precipitate Substances 0.000 claims 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract description 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 239000007788 liquid Substances 0.000 abstract description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract description 2
- 229910000027 potassium carbonate Inorganic materials 0.000 abstract description 2
- 235000019645 odor Nutrition 0.000 description 19
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 14
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 7
- 229910021529 ammonia Inorganic materials 0.000 description 7
- 239000007789 gas Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 5
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 4
- 238000004332 deodorization Methods 0.000 description 4
- 230000007246 mechanism Effects 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 4
- 230000009471 action Effects 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229920002774 Maltodextrin Polymers 0.000 description 2
- 239000005913 Maltodextrin Substances 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 2
- 229940035034 maltodextrin Drugs 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000001648 tannin Substances 0.000 description 2
- 229920001864 tannin Polymers 0.000 description 2
- 235000018553 tannin Nutrition 0.000 description 2
- QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003146 anticoagulant agent Substances 0.000 description 1
- 229940127219 anticoagulant drug Drugs 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
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- 239000013078 crystal Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
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- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
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- 238000006722 reduction reaction Methods 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
- A61L9/012—Deodorant compositions characterised by being in a special form, e.g. gels, emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
- A61L9/013—Deodorant compositions containing animal or plant extracts, or vegetable material
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
- A61L9/014—Deodorant compositions containing sorbent material, e.g. activated carbon
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/14—Disinfection, sterilisation or deodorisation of air using sprayed or atomised substances including air-liquid contact processes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
- A61L2209/20—Method-related aspects
- A61L2209/22—Treatment by sorption, e.g. absorption, adsorption, chemisorption, scrubbing, wet cleaning
Abstract
본 발명은 액상으로 되어 있으며 천연성분으로 구성되어 인체에 무해하며 효과가 뛰어난, 천연성분을 이용한 친환경 탈취제 제조방법에 관한 것이다. 그 구성은, 정제수를 가열하여 준비하는 제1단계; 준비된 정제수 100중량부에 대하여 20 ~ 30중량부의 에탄올을 혼합하는 제2단계; 에탄올이 혼합된 정제수 100중량부에 대하여 0.3 ~ 0.5중량부의 덱스트린을 투입하여 교반하는 제3단계; 상기 알코올이 혼합된 정제수 100중량부에 대하여 탄산칼륨 또는 탄산칼슘 중 어느 하나 이상을 8 ~ 10중량부 투입하고 교반하는 제4단계; 상기 에탄올이 혼합된 정제수 100중량부에 대하여 0.01 ~ 0.1 중량부의 구연산을 투입하고 교반하는 제5단계; 및 상기 에탄올 100중량부에 대하여 고체 상태의 송지(松脂)를 20 ~ 30중량부 투입하고, 오픈된 가열용기에 넣고 60 ~ 80℃의 온도로 가열하면서 용해시키는 제6단계를 포함하는 것을 특징으로 한다. The present invention relates to a method for manufacturing an eco-friendly deodorant using natural ingredients, which is in liquid form and composed of natural ingredients, is harmless to the human body, and has excellent effects. Its configuration includes a first step of preparing purified water by heating; A second step of mixing 20 to 30 parts by weight of ethanol with respect to 100 parts by weight of prepared purified water; A third step of adding and stirring 0.3 to 0.5 parts by weight of dextrin based on 100 parts by weight of purified water mixed with ethanol; A fourth step of adding 8 to 10 parts by weight of at least one of potassium carbonate or calcium carbonate with respect to 100 parts by weight of the alcohol-mixed purified water and stirring; A fifth step of adding and stirring 0.01 to 0.1 parts by weight of citric acid based on 100 parts by weight of the purified water mixed with ethanol; And a sixth step of adding 20 to 30 parts by weight of pine resin in a solid state with respect to 100 parts by weight of the ethanol, putting it in an open heating container and dissolving it while heating at a temperature of 60 to 80 ° C. do.
Description
본 발명은 탈취제에 관한 것으로서, 보다 구체적으로는 액상으로 되어 있으며 천연성분으로 구성되어 인체에 무해하며, 다양한 수소이온농도로 구성된 여러 종류의 악취를 제거하는데 효과가 뛰어난, 천연성분을 이용한 친환경 탈취제 제조방법에 관한 것이다.The present invention relates to a deodorant, and more specifically, to manufacture an eco-friendly deodorant using natural ingredients, which is in liquid form, is harmless to the human body as it is composed of natural ingredients, and is highly effective in removing various types of odors composed of various hydrogen ion concentrations. It's about how.
생활주변에는 많은 종류의 냄새발생요인이 있다. 향을 제외한 각종의 냄새는 실내활동에 좋지 않은 영향을 줄 수 있다. 좋지 않은 냄새들은 대부분 유기물이 부패 또는 분해하는 과정에서 발생되며, 암모니아(Ammonia), 아민(Amine)류 등 염기성 성분과 황화수소, 메르켑탄(Mercaptane) 등의 산성성분이 그 주요한 원인으로 작용한다. There are many types of odor generating factors around life. Various odors other than incense can adversely affect indoor activities. Most of the bad smells are generated in the process of decay or decomposition of organic matter, and basic components such as ammonia and amines and acidic components such as hydrogen sulfide and mercaptane act as the main causes.
악취와 같은 냄새를 저감시키는 종래 방법으로는 활성탄, 제올라이트, 실리카겔, 세라믹 등의 다공성 물질을 사용하는 물리적인 방법이 있다. 또한 악취를 일으키는 물질과 중합, 축합반응을 시키거나, 산화와 환원 반응을 유도하는 화학적 방법이 있기도 하며, 악취보다 강한 냄새를 발생하는 방향성 물질을 악취 발생원에 살포하여 악취를 느끼지 못하게 하는 마스킹 방법이 있기도 하다.Conventional methods for reducing odors such as malodor include physical methods using porous materials such as activated carbon, zeolite, silica gel, and ceramics. In addition, there are chemical methods that cause polymerization or condensation reactions with substances that cause odors, or induce oxidation and reduction reactions, and there is a masking method that prevents odors by spraying aromatic substances that generate odors stronger than odors to odor sources. there is also
그러나 위 방법들은 고가이거나, 환경 저해요소를 가지고 있거나, 가정에서의 편리한 사용을 어렵게 하는 등의 문제를 갖고 있다. However, the above methods have problems such as being expensive, having environmental hazards, or making convenient use at home difficult.
본 발명의 목적은 악취가 발생한 분무기 등을 이용하여 살포하여 냄새를 없애는 것으로서, 천연성분을 이용함으로써 인체에 해를 입히지 아니하며, 환경을 오염시키지 아니하며 항균기능을 가지면서 탈취효과가 뛰어난 친환경 액상 항균 탈취제 제조방법을 제공하는 것을 목적으로 한다. An object of the present invention is to eliminate odors by spraying using a sprayer that generates odors, and by using natural ingredients, it does not harm the human body, does not pollute the environment, and is an eco-friendly liquid antibacterial deodorant having an antibacterial function and excellent deodorizing effect. It is an object of the present invention to provide a manufacturing method.
위와 같은 목적은, 정제수를 가열하여 준비하는 제1단계; The above object is, the first step of preparing by heating the purified water;
준비된 정제수 100중량부에 대하여 20 ~ 30중량부의 에탄올을 혼합하는 제2단계;A second step of mixing 20 to 30 parts by weight of ethanol with respect to 100 parts by weight of prepared purified water;
에탄올이 혼합된 정제수 100중량부에 대하여 0.3 ~ 0.5중량부의 덱스트린을 투입하여 교반하는 제3단계; A third step of adding and stirring 0.3 to 0.5 parts by weight of dextrin based on 100 parts by weight of purified water mixed with ethanol;
상기 알코올이 혼합된 정제수 100중량부에 대하여 탄산을 8 ~ 10중량부 투입하고 교반하는 제4단계;A fourth step of adding 8 to 10 parts by weight of carbonic acid based on 100 parts by weight of the alcohol-mixed purified water and stirring;
상기 에탄올이 혼합된 정제수 100중량부에 대하여 0.01 ~ 0.1 중량부의 구연산을 투입하고 교반하는 제5단계;A fifth step of adding and stirring 0.01 to 0.1 parts by weight of citric acid based on 100 parts by weight of the purified water mixed with ethanol;
를 포함하는 것을 특징으로 하는 천연성분을 이용한 항균 탈취제 제조방법에 의해 달성된다. It is achieved by a method for producing an antibacterial deodorant using natural ingredients, characterized in that it comprises a.
여기서 상기 탄산은 탄산칼륨 또는 탄산칼슘 중 어느 하나 이상으로부터 제공하는 것일 수 있다. Here, the carbonic acid may be provided from any one or more of potassium carbonate and calcium carbonate.
본 발명의 다른 특징에 의하면, 상기 제3단계와 제4단계 사이에는 상기 에탄올 100중량부에 대하여 고체 상태의 송지(松脂)를 20 ~ 30중량부 투입하고 가열하면서 용해시키는 송지투입단계를 더 포함할 수 있다. According to another feature of the present invention, between the third step and the fourth step, 20 to 30 parts by weight of pine resin in a solid state with respect to 100 parts by weight of the ethanol is added and dissolved while heating. can do.
본 발명에 따르면, 덱스트린 등의 천연성분을 이용한 친환경 탈취제의 제조방법이 제공된다. 본 발명에 의한 탈취제는 구성성분이 모두 천연에서 채취한 것으로서 친환경제품에 해당되어 제조과정이나 사용과정에서 환경을 오염시키지 않아 유익하다. According to the present invention, a method for manufacturing an eco-friendly deodorant using natural ingredients such as dextrin is provided. The deodorant according to the present invention is useful because all components are taken from nature and are eco-friendly products so that they do not pollute the environment during manufacturing or use.
본 발명에 의한 탈취제는 pH 10.5 ~11의 염기성을 가지며 산성을 띄는 냄새 성분과의 중화작용을 통하여 악취를 효과적으로 제거할 수 있다. 또한 하이드록시기를 가지는 다염기 카복실산의 하나인 구연산(citric acid)에 의해 염기성을 띄는 악취도 제거가 가능하다. 또한 중성을 띄는 악취도 유기화합물과 계면활성제의 포집작용을 통해 제거가 가능한 구조를 가진 탈취제가 제공된다. The deodorant according to the present invention has a basicity of pH 10.5 to 11 and can effectively remove odor through neutralization with an acidic odor component. In addition, citric acid, which is one of polybasic carboxylic acids having a hydroxyl group, can remove a basic odor. In addition, a deodorant having a structure capable of removing neutral odors through the collecting action of organic compounds and surfactants is provided.
본 발명의 탈취제는 도 1 내지 도 2의 시험결과와 같이 탁월한 탈취력을 제공한다. The deodorant of the present invention provides excellent deodorizing power as shown in the test results of FIGS. 1 and 2.
도 1은 본 발명의 실시예에 의한 항균 탈취제 조성물의 시험결과를 나타낸 표로서 암모니아를 시험대상으로 한 결과를 나타낸다.
도 2는 본 발명의 실시예에 의한 항균 탈취제 조성물의 시험결과를 나타낸 표로서 황화수소를 시험대상으로 한 결과를 나타낸다. Figure 1 is a table showing the test results of the antibacterial deodorant composition according to an embodiment of the present invention, showing the results of ammonia as a test subject.
Figure 2 is a table showing the test results of the antibacterial deodorant composition according to an embodiment of the present invention, showing the results of hydrogen sulfide as a test subject.
이하, 본 발명에 의한 천연성분을 이용한 항균 탈취제의 제조방법을 단계별로 설명한다. Hereinafter, a method for preparing an antibacterial deodorant using natural ingredients according to the present invention will be described step by step.
<제1단계> <
제1단계는 정제수를 가열하여 준비하는 단계이다. 정제수는 끓는점 이상으로 30분간 가열하고 서냉시킨다. The first step is to prepare purified water by heating it. Purified water is heated above boiling point for 30 minutes and cooled slowly.
<제2단계><Step 2>
제2단계는 준비된 정제수 100중량부에 대하여 20 ~ 30중량부의 에탄올을 혼합하는 단계이다. 에탄올은 후속과정에서 첨가되는 각 물질의 용해작용을 돕기 위한 것이다. The second step is a step of mixing 20 to 30 parts by weight of ethanol with respect to 100 parts by weight of prepared purified water. Ethanol is to help dissolve each substance added in the subsequent process.
알코올은 알려진 바와 같이 살균 및 소독을 담당하며, 더 나아가 후술되는 송지 및 향료 오일을 분해하여 물에 잘 용해되도록 하는 작용을 한다. As is well known, alcohol is responsible for sterilization and disinfection, and further acts to decompose pine resin and spice oil to be described later so that they are well soluble in water.
<제3단계>;<Step 3>;
제3단계는 에탄올이 혼합된 정제수 100중량부에 대하여 0.3 ~ 0.5중량부의 덱스트린(dextrin)을 투입하여 교반하는 단계이다. 덱스트린(dextrin, 화학식 : C18H32O16)은 D-글루코스(D-glucose)에서 파생된 천연 고분자 화합물로서, 아밀레이스(amylase)와 같은 효소에 의한 전분(starch) 또는 글리코겐(glycogen)의 가수분해(hydrolysis)로 생성되는 저분자량의 다당류(polysaccharide)이다. 덱스트린 분자에는 총 68 개의 화학결합이 있으며, 이는 36 개의 비수소결합, 7 개의 단일결합, 3 개의 6원자 고리, 11 개의 수산기, 3 개의 1차 알코올, 7 개의 2차 알코올 그리고 5 개의 에테르(지방족)로 구성되어 있다.[네이버 지식백과 참조] The third step is a step of adding and stirring 0.3 to 0.5 parts by weight of dextrin based on 100 parts by weight of purified water mixed with ethanol. Dextrin (chemical formula: C 18 H 32 O 16 ) is a natural high-molecular compound derived from D-glucose. It is a low molecular weight polysaccharide produced by hydrolysis. There are a total of 68 chemical bonds in the dextrin molecule, including 36 non-hydrogen bonds, 7 single bonds, 3 six-membered rings, 11 hydroxyl groups, 3 primary alcohols, 7 secondary alcohols, and 5 ethers (aliphatic ). [Refer to Naver Knowledge Encyclopedia]
본 발명에서 덱스트린은 말토덱스트린(maltodextrin)을 이용한다. 에탄올은 덱스트린의 용해를 촉진시킨다. In the present invention, maltodextrin is used as the dextrin. Ethanol promotes the dissolution of dextrin.
말토덱스트린은 백색의 무정형 고체로서 녹말의 불완전 가수분해로 생성된 탄수화물로서 증점제, 충전제 또는 방부제의 목적으로 사용되는 물질이다. Maltodextrin is a white amorphous solid that is produced by incomplete hydrolysis of starch and is used as a thickener, filler, or preservative.
덱스트린은 점성을 부여함으로써 탈취제 분자가 냄새분자에 잘 달라붙게 한다. Dextrin provides viscosity so that deodorant molecules stick to odor molecules.
본 발명의 다른 실시예에 의하면 덱스트린은 정제수 100중량부에 분말형태의 덱스트린 0.1 ~ 0.2 중량부를 투입한 다음 70 ~ 80℃의 온도로 2 ~ 3시간 가열함으로써 정제수를 증발시켜 농도를 높이고 여기에 다시 분말형태의 덱스트린을 첨가하면서 0.3 ~ 0.5중량부로 덱스트린 함량을 맞춘다. According to another embodiment of the present invention, 0.1 to 0.2 parts by weight of dextrin in powder form is added to 100 parts by weight of purified water, and then heated at a temperature of 70 to 80 ° C for 2 to 3 hours to evaporate the purified water to increase the concentration. Adjust the dextrin content to 0.3 to 0.5 parts by weight while adding powdered dextrin.
이와 같이 덱스트린은 수용액 상태로 투입할 수 있다. 정제수에 분말 형태의 텍스트린을 조금씩 투입해가며 가열함으로써 얻은 것을 사용하는 것이 증점 효과를 높일 수 있다. In this way, dextrin can be introduced in the form of an aqueous solution. It is possible to increase the thickening effect by adding dextrin in powder form to purified water and heating it little by little.
<제4단계><
제4단계는 상기 알코올이 혼합된 정제수 100중량부에 대하여 볏짚재를 8 ~ 10중량부 투입하고 교반하는 단계이다. 이 단계는 탈취효율의 향상을 위한 것이다. The fourth step is a step of adding 8 to 10 parts by weight of rice straw ash based on 100 parts by weight of the alcohol-mixed purified water and stirring. This step is for improving deodorization efficiency.
볏짚재는 볏짚을 세척하고 건조한 뒤 연소시킨 다음 분쇄기를 이용하여 곱게 분쇄한 것을 수용액으로 만들어 사용한다. 볏짚재는 탈취제의 pH 농도의 조절을 위한 것이다. Rice straw ash is used by washing rice straw, drying it, burning it, and then finely pulverizing it using a grinder to make an aqueous solution. The rice straw ash is for adjusting the pH concentration of the deodorant.
실시예에 따라서 볏짚재는 다음과 같이 준비할 수 있다. According to the embodiment, rice straw ash can be prepared as follows.
정제수가 담긴 용기에 분말형 볏짚재를 투입한 뒤 침전 및 용해시킨 다음 침전물 또는 부유물을 걸러낸다. 이렇게 걸러낸 것을 상기 알코올이 혼합된 정제수에 투입하면서 pH 농도가 10.5 ~11이 되도록 조절한다. Powdered rice straw ash is put into a container containing purified water, precipitated and dissolved, and then sediment or suspended matter is filtered out. The filtered water is added to the purified water mixed with the alcohol while adjusting the pH concentration to 10.5 to 11.
<제5단계><Step 5>
제5단계는 상기 에탄올이 혼합된 정제수 100중량부에 대하여 0.01 ~ 0.1 중량부의 구연산(citric acid)을 투입하고 교반하는 단계이다. 구연산은 하이드록시기(R-COOH)를 가지는 다염기 카복실산의 하나로서 항응고제, 킬레이트제로 사용되며 음식의 신맛을 내기 위하여 널리 사용되는 성분이다. The fifth step is a step of adding and stirring 0.01 to 0.1 parts by weight of citric acid based on 100 parts by weight of the purified water mixed with ethanol. Citric acid is one of the polybasic carboxylic acids having a hydroxyl group (R-COOH), and is used as an anticoagulant and a chelating agent, and is a widely used ingredient to make food sour.
본 발명에서 구연산은 살균, 소독작용을 부가하기 위하여 사용된다. In the present invention, citric acid is used to add sterilization and disinfection action.
구연산은 나아가 방부제로서의 역할을 한다. Citric acid further acts as a preservative.
구연산과 함께 타닌이 같은 분량으로 첨가될 수 있다. 타닌은 탈취기능을 수행하므로 덱스트린의 기능을 보조하여 탈취효과를 배가시킨다. Tannins may be added in equal portions with citric acid. Since tannin performs a deodorizing function, it doubles the deodorizing effect by assisting the function of dextrin.
<제6단계><Stage 6>
본 발명의 실시예에 의하면 상기 제5단계 이후에 상기 에탄올 100중량부에 대하여 고체 상태의 송지(松脂)를 20 ~ 30중량부 투입하고 가열하면서 용해시키는 송지투입단계를 더 포함할 수 있다. 송지(松脂)는 항균 및 탈취작용을 향상시키며 단단한 고체 상태로 투입된다. 송지는 에탄올에 의해 용해되며 항균작용을 하게 된다. According to an embodiment of the present invention, after the fifth step, a step of adding 20 to 30 parts by weight of pine resin in a solid state with respect to 100 parts by weight of the ethanol and dissolving it while heating may be further included. Pine pine enhances antibacterial and deodorizing action and is introduced in a hard solid state. Pine pine is dissolved by ethanol and has an antibacterial effect.
이 과정에서는 60 ~ 80℃의 온도로 오픈된 가열용기에 넣고 가열한다. 이는가열과정에서 비등점이 낮은 에탄올이 증발에 의해 함량이 감소되도록 하기 위한 것이다.In this process, it is put into an open heating container at a temperature of 60 ~ 80 ℃ and heated. This is to reduce the content of ethanol having a low boiling point by evaporation during the heating process.
이하, 본 발명에 의한 탈취제의 기작 내지 반응메카니즘을 설명한다. Hereinafter, the mechanism or reaction mechanism of the deodorant according to the present invention will be described.
본 발명의 탈취제에 의하면 황화수소, 메틸메르캅탄(methyl mercaptan), 및 저급지방산과 같은 산성취는 다음과 같은 메카니즘에 의해 중화된다. According to the deodorant of the present invention, acid odors such as hydrogen sulfide, methyl mercaptan, and lower fatty acids are neutralized by the following mechanism.
황화수소(H2S)의 경우,In the case of hydrogen sulfide (H 2 S),
H2S + R=NH → R=NH2SHH 2 S + R=NH → R=NH 2 SH
메틸메르캅탄의 경우,In the case of methyl mercaptan,
CH3SH + R=NH → R=NH2SCH3 CH 3 SH + R=NH → R=NH 2 SCH 3
그리고 암모니아나 트리메틸아민 등의 알카리성취는 다음과 같은 메카니즘에 의해 중화된다. And alkali achievements such as ammonia and trimethylamine are neutralized by the following mechanism.
암모니아(NH3)의 경우,In the case of ammonia (NH 3 ),
NH3 +R-COOH → R-COONH3 NH 3 +R-COOH → R-COONH 3
트리메틸아민의 경우,For trimethylamine,
(CH3)3N + R-COOH → R-COO(CH3)3 (CH 3 ) 3 N + R-COOH → R-COO(CH 3 ) 3
그리고 수소이온농도가 중성인 중성취(예를 들어, 알데히드, 황화메틸, 또는 유지류 등)의 경우에는 유기화합물과 계면활성제의 포집작용을 통해 악취를 없애게 된다. In addition, in the case of a neutral odor having a neutral hydrogen ion concentration (eg, aldehyde, methyl sulfide, or oils and fats), the odor is eliminated through the trapping action of organic compounds and surfactants.
<제6단계><Stage 6>
제7단계는 오일 형태로 된 향료를 정제수 100중량부에 대하여 0.01~0.1중량부 더 혼합하는 단계이다. 이 향료는 라벤더 오일(twin 80)이 될 수 있다. 라벤더 오일은 천연오일이며 탈취제의 상품성을 제고하며 사용시 대상물품에 향을 부여하는 작용을 한다. 다양한 천연 오일이 대체될 수 있음은 물론이다. The seventh step is a step of further mixing 0.01 to 0.1 parts by weight of perfume in the form of oil with respect to 100 parts by weight of purified water. This fragrance can be lavender oil (twin 80). Lavender oil is a natural oil and improves the marketability of a deodorant and acts to impart a fragrance to a target product when used. Of course, various natural oils can be substituted.
<제8단계><Step 8>
제8단계는 정제수 100중량부에 대하여 벤토나이트를 5 ~ 20중량부 더 혼합하는 단계이다. 벤토나이트(bentonite)는 운모와 같은 결정구조를 하는 단사정계에 속하는 광물인 몬모릴로나이트가 주로 들어있는 점토를 말한다. 그의 색깔은 백색, 회색, 담갈색, 담녹색 등이며 주물형의 결합제, 요업원료의 혼입제, 연고의 기초제 등 다양한 분야에 사용되고 있는 것이다. 본 발명자는 이 벤토나이트가 가지는 탈취기능을 접목하여 보다 효과적이며 기능적으로 탁월한 탈취제를 제안한다. 벤토나이트의 입자는 작을수록 유익하므로 가능한 입자의 입경을 작게 하는 것이 좋다. 예를 들어 벤토나이트의 입경은 1 ~ 100㎛가 될 수 있다. The eighth step is a step of further mixing 5 to 20 parts by weight of bentonite with respect to 100 parts by weight of purified water. Bentonite refers to clay mainly containing montmorillonite, a mineral belonging to the monoclinic system having a crystal structure like mica. Its color is white, gray, light brown, light green, etc., and it is used in various fields such as a casting type binder, a mixing agent for ceramic raw materials, and a base agent for ointment. The present inventor proposes a more effective and functionally excellent deodorant by incorporating the deodorizing function of this bentonite. Since the smaller the bentonite particles are, the more beneficial it is, so it is better to make the particle diameter of the particles as small as possible. For example, the particle size of bentonite may be 1 to 100 μm.
<구체적인 실시예><Specific Example>
도 1 내지 도 2는 본 발명의 실시예에 의한 탈취제 조성물의 시험결과를 나타낸 표이다. 도 1은 암모니아(NH3 )를 시험대상으로 한 결과를 나타내며, 도 2는 황화수소(H2S)를 시험대상으로 한 결과를 나타낸다. 1 and 2 are tables showing test results of deodorant compositions according to embodiments of the present invention. Figure 1 shows the results of using ammonia (NH 3 ) as a test subject, Figure 2 shows the results of using hydrogen sulfide (H 2 S) as a test subject.
각 표에 나타난 바에 의하면 30분 경과 후에는 암모니아는 99.6%의 탈취율을 나타내며, 황화수소는 120분 경과 후에 91.8%의 탈취율을 나타낸다. 암모니아 또는 황화수소는 종래의 일반적인 탈취제로 이 정도의 탈취율을 낼 수 없다. 이하 도면의 시험성적서 상의 시험방법을 설명한다(한국건설생활환경시험연구원). As shown in each table, after 30 minutes, ammonia shows a deodorization rate of 99.6%, and hydrogen sulfide shows a deodorization rate of 91.8% after 120 minutes. Ammonia or hydrogen sulfide cannot achieve this level of deodorization with conventional general deodorizers. Hereinafter, the test method on the test report of the drawing will be described (Korea Conformity Laboratories).
<시험방법><Test method>
시험방법은 시료 150ml를 5리터 크기의 반응기에 넣고 밀봉한 다음, 시험가스의 초기농도를 50μmol/mol으로 주입하고 시험가스의 농도를 초기(0분), 30분, 60분, 120분에서 측정하고 이를 샘플농도라 하였다. 시료는 청구항 제1항의 방법으로 제작된 것이며, 각 성분비율은 기재된 범위의 중간값으로 선택하였다. The test method is to put 150ml of sample into a 5-liter reactor, seal it, inject the initial concentration of the test gas at 50 μmol/mol, and measure the concentration of the test gas at the initial (0 minute), 30 minute, 60 minute, and 120 minute And this was called the sample concentration. The sample was prepared by the method of
시험가스의 농도는 가스검지관(구KS 2218)에 의해 측정하였다. 시험중 온도는 (23.0 ± 5.0)℃, 습도는 (50 ± 15)% R.H.를 유지하였다. The concentration of the test gas was measured by a gas detection tube (formerly KS 2218). During the test, the temperature was maintained at (23.0 ± 5.0) ° C, and the humidity was maintained at (50 ± 15)% R.H.
이와 별도로 시료가 없는 상태에서 위와 같은 방식으로 시험을 진행하고 이를 blank 농도라 하였다. Separately, the test was conducted in the same manner as above in the absence of a sample, and this was referred to as the blank concentration.
각 시간대별 시험가스의 제거율은 다음 식에 의해 계산하였다. The removal rate of the test gas for each time period was calculated by the following formula.
시험가스 제거율(%) = [{(blank 농도) -(샘플농도)}/(blank 농도)] ㅧ100Test gas removal rate (%) = [{(blank concentration) - (sample concentration)}/(blank concentration)] ㅧ100
위에 설명된 구성은 본 발명의 기술적 사상에 근거한 바람직한 실시예에 지나지 아니한다. 당업자는 통상의 기술적 상식을 바탕으로 다양한 변경실시를 할 수 있을 것이지만 이는 본 발명의 보호범위에 포함될 수 있음을 주지해야 할 것이다. The configuration described above is only a preferred embodiment based on the technical idea of the present invention. Those skilled in the art will be able to make various changes based on common technical knowledge, but it should be noted that these may be included in the protection scope of the present invention.
Claims (2)
준비된 정제수 100중량부에 대하여 20 ~ 30중량부의 에탄올을 혼합하는 제2단계;
에탄올이 혼합된 정제수 100중량부에 대하여 0.3 ~ 0.5중량부의 덱스트린을 투입하여 교반하는 제3단계;
상기 알코올이 혼합된 정제수 100중량부에 대하여 볏짚을 태워서 얻은 볏짚재를 8 ~ 10중량부 투입하고 교반하는 제4단계;
상기 에탄올이 혼합된 정제수 100중량부에 대하여 0.01 ~ 0.1 중량부의 구연산을 투입하고 교반하는 제5단계; 및
상기 에탄올 100중량부에 대하여 고체 상태의 송지(松脂)를 20 ~ 30중량부 투입하고, 오픈된 가열용기에 넣고 60 ~ 80℃의 온도로 가열하면서 용해시키는 제6단계;를 포함하되;
상기 덱스트린은,
정제수 100중량부에 대하여 분말 형상의 덱스트린을 0.1~0.2중량부 투입한 뒤 70 ~80℃의 온도로 2 ~3시간 가열하고, 여기에 분말 형태의 덱스트린을 새로 투입하고 교반함으로써 얻은 수용액 상태로 투입하며;
상기 볏짚재는,
볏짚재를 세척, 건조, 연소 및 분쇄 공정을 통해 얻은 분말 형태의 것을 정제수에 투입하여 침전 및 용해시킨 뒤 침전물을 걸러낸 것을 투입하며;
pH 농도가 10.5 ~ 11이 되도록 하는 것을 특징으로 하는 천연성분을 이용한 항균 탈취제 제조방법.
A first step of preparing purified water by heating;
A second step of mixing 20 to 30 parts by weight of ethanol with respect to 100 parts by weight of prepared purified water;
A third step of adding and stirring 0.3 to 0.5 parts by weight of dextrin based on 100 parts by weight of purified water mixed with ethanol;
A fourth step of adding 8 to 10 parts by weight of rice straw ash obtained by burning rice straw with respect to 100 parts by weight of the purified water mixed with alcohol and stirring;
A fifth step of adding and stirring 0.01 to 0.1 parts by weight of citric acid based on 100 parts by weight of the purified water mixed with ethanol; and
A sixth step of adding 20 to 30 parts by weight of pine resin in a solid state with respect to 100 parts by weight of the ethanol, putting it in an open heating container and dissolving it while heating at a temperature of 60 to 80 ° C;
The dextrin,
0.1 to 0.2 parts by weight of dextrin in powder form is added to 100 parts by weight of purified water, heated at a temperature of 70 to 80 ° C for 2 to 3 hours, and dextrin in powder form is newly added and stirred to form an aqueous solution. and;
The rice straw material,
The powdered rice straw ash obtained through the washing, drying, burning and crushing process is put into purified water to precipitate and dissolve, and then the precipitate is filtered out;
Method for producing an antibacterial deodorant using natural ingredients, characterized in that the pH concentration is 10.5 to 11.
오일 형태로 된 향료를 정제수 100중량부에 대하여 0.01~0.1중량부 더 혼합하는 제6단계; 및
상기 정제수 100중량부에 대하여 벤토나이트를 5 ~ 20중량부 혼합하는 제7단계를 더 포함하되;
상기 향료는 라벤더 오일(twin 80)인 것을 특징으로 하는 천연성분을 이용한 항균 탈취제 제조방법. According to claim 1,
A sixth step of further mixing 0.01 to 0.1 parts by weight of a fragrance in oil form with respect to 100 parts by weight of purified water; and
Further comprising a seventh step of mixing 5 to 20 parts by weight of bentonite with respect to 100 parts by weight of the purified water;
The fragrance is an antibacterial deodorant manufacturing method using natural ingredients, characterized in that lavender oil (twin 80).
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