KR20180103560A - Method of reducing residual pesticide using ultraviolet ray-C - Google Patents
Method of reducing residual pesticide using ultraviolet ray-C Download PDFInfo
- Publication number
- KR20180103560A KR20180103560A KR1020170030671A KR20170030671A KR20180103560A KR 20180103560 A KR20180103560 A KR 20180103560A KR 1020170030671 A KR1020170030671 A KR 1020170030671A KR 20170030671 A KR20170030671 A KR 20170030671A KR 20180103560 A KR20180103560 A KR 20180103560A
- Authority
- KR
- South Korea
- Prior art keywords
- limited
- quinazoline
- ultraviolet
- cisplatin
- agricultural products
- Prior art date
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- 238000000034 method Methods 0.000 title claims abstract description 22
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- A—HUMAN NECESSITIES
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Abstract
Description
본 발명은 자외선-C를 이용하는 잔류농약 저감방법에 관한 것이다.The present invention relates to a method for reducing residual pesticide using ultraviolet-C.
농약이란 농작물 재배를 위해 농경지의 토양 및 종자를 소독하거나, 작물 재배기간 중에 발생하는 병해충으로부터 농작물을 보호하고, 저장 농산물의 병해충을 방제하기 위한 목적으로 사용하는 모든 약제를 말한다. 종류에 따라 다소간 차이는 있으나 어느 정도의 독성이 있어서, 농약을 과다하게 사용하면 농작물에 약해를 일으키거나 농산물 중에 과량의 농약이 잔류하여 우리의 먹을거리를 오염시키고, 환경을 오염시키는 등의 부작용을 일으킬 가능성이 있다.Pesticides means all medicines used for the purpose of disinfecting soil and seeds of agricultural land for crop cultivation, protecting crops from pests occurring during the cultivation period, and controlling pests of stored agricultural products. There are some differences depending on the species, but they are toxic to some extent, and excessive use of pesticides can cause harm to crops or excessive pesticide residues in agricultural products, polluting our food streets and polluting the environment. There is a possibility to cause.
특히, 식품의약안전처는 농산물을 식품으로 간주하여 농산물의 농약잔류 허용기준을 설정하고 있으며, 이를 초과하는 농산물의 경우에는 시장에 출하할 수 없도록 하고 있다.In particular, the Korea Food & Drug Administration (KFDA) regards agricultural products as food products and sets limits for pesticide residues in agricultural products. In the case of agricultural products exceeding this level, it can not be shipped to the market.
그러나 일반적으로 사용되고 있는 농약 성분의 대부분은 물에 불용성이기 때문에 물로 세척하더라도 잘 제거되지 않으며, 잔류농약의 90% 이상이 껍질 부분에 존재하는 것으로 알려져 있으며, 농산물의 건조 이후에는 물을 이용한 세척과정조차도 어려운 문제점이 있다.However, since most of the commonly used pesticide ingredients are insoluble in water, they are not well removed even by washing with water, and it is known that more than 90% of pesticide residues are present in the skin. Even after washing with water, There is a difficult problem.
따라서 물을 사용하지 않으면서 처리효율이 탁월한 동시에 운영이 간편한 잔류농약 제거기술에 대한 개발이 요망되고 있는 실정이다.Therefore, there is a demand for development of a pesticide removal technology which is excellent in treatment efficiency without using water and is easy to operate.
한편, 한국등록특허 제1471854호는 비열 플라즈마를 이용한 농식품의 잔류농약성분의 분해 제거방법에 관하여 개시하고 있으며, 한국등록특허 제0486841호는 잔류농약이 존재하는 농산물 또는 물에 옥살레이트 또는 그의 유도체를 함유하는 용액을 적용한 후, 여기에 자외선을 조사하여 생성된 라디칼을 잔류농약과 반응시킴으로써 농산물 또는 물에 존재하는 잔류농약을 제거하는 방법을 개시하고 있으나, 본 발명의 자외선-C를 이용하는 잔류농약성분을 제거하는 방법에 대해서는 보고된 바 없다. On the other hand, Korean Patent No. 1471854 discloses a method for decomposing and removing residual pesticide components of agricultural products using non-thermal plasma, and Korean Patent No. 0486841 discloses a method in which oxalate or a derivative thereof is added to agricultural products or water in which pesticide residues are present And then reacting the generated radicals with ultraviolet rays to react with residual pesticides to remove agricultural chemicals or residual pesticides present in water. However, the method of removing residual agricultural chemicals Have not been reported.
본 발명은 상기와 같은 요구에 의해 도출된 것으로서, 본 발명은 잔류농약이 존재하는 농산물에 자외선-C를 조사하는 단계를 포함하는 것을 특징으로 하는 농산물 잔류농약의 저감방법을 제공하고, 본 발명의 농산물 잔류농약의 저감방법을 통해서 260개의 농약성분 중 103개의 농약성분이 완전 분해되고, 126개의 농약성분이 30% 이상 분해됨을 확인함으로써, 본 발명을 완성하였다.The present invention has been made in view of the above-mentioned needs, and it is an object of the present invention to provide a method for reducing pesticide residues of agricultural products, which comprises irradiating ultraviolet-C to agricultural products in which pesticide residues are present, Through the reduction method of agricultural chemicals residual pesticides, 103 pesticide components of 260 pesticide components were completely decomposed and 126 pesticide components were decomposed by 30% or more. Thus, the present invention was completed.
상기 목적을 달성하기 위하여, 본 발명은 잔류농약이 존재하는 농산물에 자외선-C의 조사 및 오존가스를 병용처리하는 단계를 포함하는 것을 특징으로 하는 농산물 잔류농약의 저감방법을 제공한다.In order to accomplish the above object, the present invention provides a method for reducing residual pesticide residues in agricultural products, which comprises treating ultraviolet-C irradiation and ozone gas in combination with agricultural products in which pesticide residues are present.
또한, 본 발명은 잔류농약이 존재하는 농산물에 오존가스를 공급하면서, 농산물과의 조사거리 1~100cm을 유지하면서, 30~100℃ 온도 조건으로, 자외선-C를 0.0.1~5일 동안 조사하는 단계를 포함하는 것을 특징으로 하는 농산물 잔류농약의 저감방법을 제공한다.The present invention also relates to a method for producing a pesticide, which comprises irradiating ultraviolet-C for 0.0.1 to 5 days at a temperature of 30 to 100 占 폚 while maintaining an irradiation distance of 1 to 100 cm with an agricultural product, The present invention also provides a method for reducing residual pesticide residues in agricultural products.
본 발명은 잔류농약이 존재하는 농산물에 자외선-C의 조사 및 오존가스를 병용처리하는 단계를 포함하는 것을 특징으로 하는 농산물 잔류농약의 저감방법에 관한 것이다.The present invention relates to a method for reducing pesticide residues of agricultural products, which comprises treating ultraviolet-C irradiation and ozone gas in combination with agricultural products in which pesticide residues are present.
본 발명에 따르면, 농산물에 무해하며 단시간에 간단한 방법으로 잔류농약의 양을 효과적으로 감소시킬 수 있으므로, 농산물 자체의 고유성을 유지하면서 무공해 농산물을 다량 유통시킬 수 있다.INDUSTRIAL APPLICABILITY According to the present invention, since the amount of pesticide residues can be effectively reduced in a short time in a short time without harm to agricultural products, a large amount of pollution-free agricultural products can be distributed while maintaining the uniqueness of agricultural products themselves.
도 1은 자외선-C 조사(UV), 오존가스 처리(오존) 및 자외선-C 조사+오존가스 처리(UV+오존)에 따른 이미다클로프리드 잔류량(mg/kg) 및 디페노코나졸 잔류량(mg/kg)을 확인한 그래프이다.1 shows the residual amount of imidacloprid (mg / kg) and the residual amount of diphenoconazole (mg / kg) according to ultraviolet-C irradiation (UV), ozone gas treatment (ozone) and ultraviolet-C irradiation + ozone gas treatment Respectively.
본 발명은 잔류농약이 존재하는 농산물에 자외선-C의 조사 및 오존가스를 병용처리하는 단계를 포함하는 것을 특징으로 하는 농산물 잔류농약의 저감방법에 관한 것이다.The present invention relates to a method for reducing pesticide residues of agricultural products, which comprises treating ultraviolet-C irradiation and ozone gas in combination with agricultural products in which pesticide residues are present.
상기 자외선-C를 조사하는 단계에서, 254nm 이하의 자외선-C를 조사하는 것이 바람직하며, 더 바람직하게는 170~200㎚의 자외선-C를 조사하는 것이며, 더욱더 바람직하게는 185nm의 자외선-C를 조사하는 것이지만, 이에 한정하는 것은 아니다.In the step of irradiating ultraviolet-C, it is preferable to irradiate ultraviolet-C of 254 nm or less, more preferably 170 to 200 nm of ultraviolet-C, even more preferably 185 nm of ultraviolet-C But the present invention is not limited thereto.
상기 자외선-C 조사는 100 리터(0.1m3)당 5~500W 범위의 세기로 조사하는 것이지만, 이에 한정하는 것은 아니다.The ultraviolet-C irradiation is conducted at an intensity in the range of 5 to 500 W per 100 liters (0.1 m 3 ), but is not limited thereto.
상기 자외선-C 조사는 30~100℃에서 조사하는 것이 바람직하며, 더 바람직하게는 35~60℃이며, 더욱더 바람직하게는 55℃이지만, 이에 한정하는 것은 아니다.The ultraviolet-C irradiation is preferably carried out at 30 to 100 캜, more preferably 35 to 60 캜, still more preferably 55 캜, but is not limited thereto.
상기 자외선-C 조사는 0.1~5일 동안 조사하는 것이 바람직하며, 더 바람직하게는 2일 동안 조사하는 것이 바람직하지만, 이에 한정하는 것은 아니다.The ultraviolet-C irradiation is preferably performed for 0.1 to 5 days, more preferably for 2 days, but is not limited thereto.
상기 자외선-C 조사는 농산물과의 조사거리를 1~100cm 유지하면서 조사하는 것이 바람직하며, 더 바람직하게는 농산물과의 조사거리를 5~50㎝로 유지하는 것이며, 더욱더 바람직하게는 10~30㎝로 유지하는 것이지만, 이에 한정하는 것은 아니다.The ultraviolet-C irradiation is preferably carried out while maintaining a distance of 1 to 100 cm from the agricultural product. More preferably, the irradiation distance with the agricultural product is maintained at 5 to 50 cm, more preferably 10 to 30 cm But the present invention is not limited thereto.
상기 조사된 자외선-C는 농산물의 잔류농약을 직접 분해할 뿐만 아니라 공기 중의 산소와 반응하여 오존가스를 생성하여, 상기 생성된 오존가스가 공급되는 오존가스와 더불어 잔류농약을 분해하는 것이 특징이다.The irradiated ultraviolet ray-C not only directly decomposes pesticide residues of agricultural products but also reacts with oxygen in the air to generate ozone gas, and decomposes pesticide residues together with ozone gas supplied by the generated ozone gas.
상기 농산물과의 조사거리가 1㎝ 미만인 경우에는 상기 자외선-C와 공기 중의 산소가 충분히 반응하지 못하여 오존가스의 생성이 불충분한 문제점이 있으며, 상기 농산물과의 조사거리가 100㎝를 초과하는 경우에는 상기 자외선-C가 농산물에 닿지 못하는 문제점이 있다.When the irradiation distance with the agricultural product is less than 1 cm, there is a problem that the ultraviolet ray C and oxygen in the air do not sufficiently react with each other and the generation of ozone gas is insufficient. When the irradiation distance with the agricultural product exceeds 100 cm There is a problem that the ultraviolet ray-C does not reach agricultural produce.
상기 자외선-C 조사를 0.1일 미만으로 하는 경우에는, 상기 자외선-C와 공기 중의 산소가 충분히 반응할 수 있는 시간이 부족하며, 5일을 초과하는 경우에는 잔류농약의 분해효과는 크게 강화되지 않는 반면, 비용이 증가하는 문제점이 있다.When the ultraviolet-C irradiation is performed for less than 0.1 day, the time for allowing the ultraviolet-C to react sufficiently with oxygen in the air is insufficient. If the ultraviolet-C irradiation exceeds 5 days, the decomposition effect of the residual pesticide is not greatly enhanced On the other hand, there is a problem that the cost increases.
상기 잔류농약은 살균제, 살충제, 제초제, 지베레린과 같은 식물호르몬 성분 또는 펜치온과 같은 살금제 성분인 것이 바람직하지만, 이에 한정하지 않으며, 상기 살균제의 바람직한 일례로는 아시벤졸라에스메틸, 아미설브롬, 보스칼리드, 시아조파미드, 사이프로코나졸, 디크로프루아니드, 디페노코나졸, 디메토모르프, 디니코나졸, 에타복삼, 에톡시퀸, 팜육사돈, 페나리몰, 펜헥사미드, 플루디옥소닐, 플루퀸코나졸, 헥사코나졸, 이마자릴, 이미벤코나졸, 만디프로파미드, 메파니피림, 메트코나졸, 마이클로부타닐, 누아리몰, 프로베나졸, 프로클로라즈, 프로피코나졸, 피라조포스, 피리메타닐, 시메코나졸, 지오파네이트메틸, 톨크로포스메칠, 카복심, 트리플록시스트로빈, 피콕시스트로빈, 펜티오피라드, 디에토펜카브, 플루오피코라이드, 디페노코나졸, 크레속심메틸, 사이프로코나졸, 이소프로치오란, 아족시스트로빈, 싸이프로다닐, 아메톡트라딘, 오푸레이스, 트리프루미졸, 페림존, 트리아디메폰, 펜코나졸, 펜뷰코나졸, 펜시쿠론, 프로파모카브, 페나미돈, 푸루실라졸, 테트라코나졸, 사이목사닐, 카벤다짐 및 이프로발리카브(R)으로 이루어진 군에서 선택되는 어느 하나 이상의 살균제 성분인 것이 바람직하며, 더 바람직하게는 아시벤졸라에스메틸, 아미설브롬, 보스칼리드, 시아조파미드, 사이프로코나졸, 디크로프루아니드, 디페노코나졸, 디메토모르프, 디니코나졸, 에타복삼, 에톡시퀸, 팜육사돈, 페나리몰, 펜헥사미드, 플루디옥소닐, 플루퀸코나졸, 헥사코나졸, 이마자릴, 이미벤코나졸, 만디프로파미드, 메파니피림, 메트코나졸, 마이클로부타닐, 누아리몰, 프로베나졸, 프로클로라즈, 프로피코나졸, 피라조포스, 피리메타닐, 시메코나졸, 지오파네이트메틸, 톨크로포스메칠, 카복심, 트리플록시스트로빈, 피콕시스트로빈, 펜티오피라드, 디에토펜카브, 플루오피코라이드, 디페노코나졸, 크레속심메틸, 사이프로코나졸, 이소프로치오란, 아족시스트로빈, 싸이프로다닐, 아메톡트라딘, 오푸레이스, 트리프루미졸, 페림존, 트리아디메폰 및 펜코나졸으로 이루어진 군에서 선택되는 어느 하나 이상의 살균제 성분인 것이 바람직하며, 더욱더 바람직하게는 아시벤졸라에스메틸, 아미설브롬, 보스칼리드, 시아조파미드, 사이프로코나졸, 디크로프루아니드, 디페노코나졸, 디메토모르프, 디니코나졸, 에타복삼, 에톡시퀸, 팜육사돈, 페나리몰, 펜헥사미드, 플루디옥소닐, 플루퀸코나졸, 헥사코나졸, 이마자릴, 이미벤코나졸, 만디프로파미드, 메파니피림, 메트코나졸, 마이클로부타닐, 누아리몰, 프로베나졸, 프로클로라즈, 프로피코나졸, 피라조포스, 피리메타닐, 시메코나졸, 지오파네이트메틸, 톨크로포스메칠, 카복심, 트리플록시스트로빈, 피콕시스트로빈, 펜티오피라드, 디에토펜카브, 플루오피코라이드 및 디페노코나졸으로 이루어진 군에서 선택되는 어느 하나 이상이다.The residual pesticide is preferably a fungicide such as a bactericide, a pesticide, a herbicide, a plant hormone component such as gibberellin, or a pesticide such as pliocin, but the present invention is not limited thereto, and preferable examples of the fungicide include acibenzorazmethyl, But are not limited to, sulbromine, boscalid, ciazopamid, cyproconazole, diclofuranide, difenoconazole, dimethomorph, diniconazole, etafoxam, ethoxyquin, But are not limited to, imidazolium, imidazolium, imidazolium, imidazolium, imidazolium, imidazolium, imidazolium, imidazolium, But are not limited to, prochloraz, propiconazole, pyrazofos, pyrimethanil, shimeconazole, giopanate methyl, tolcosphomethyl, carboxym, triplexystrobin, picoxystrobin, pentionopyrid, diethophenecarb, Fluoropicolide, difenoko But are not limited to, sol, crescentic methyl, ciproconazole, isoprothiolane, azoxystrobin, thiopropanyl, amethotradine, opulace, triplumizole, It is preferably one or more of the fungicide components selected from the group consisting of fosin, penicillin, propamocab, phenamidone, furosilazole, tetraconazole, sisoxanil, carbendazim, and ifflovalicab (R) , More preferably selected from the group consisting of acibenzorazmethyl, amisulbrom, boscalid, ciazopamid, cyproconazole, diclofuranid, difenoconazole, dimethomorph, diniconazole, But are not limited to, queen, palmaxadone, phenarimol, penhexamide, fluodioxonil, fluquinone, hexaconazole, imarjal, imbeconazole, mandipramide, mephanipyrim, Butanyl, norarimol, provenazoles, prochloraz, Picoxazoles, pyrazofos, pyrimethanil, shimeconazole, giopanate methyl, tolcosphomethyl, carboxymide, triplexystrobin, picoxystrobin, pentionopyrid, diethophenecarb, fluoropyrazide, Which is composed of nocodazole, nocona azole, chrysanthemum methyl, cyproconazole, isoprothiolane, azoxystrobin, thiopropanyl, amethotradine, opure, triplomizole, And more preferably at least one selected from the group consisting of acibenzolactamethyl, amisulbrom, boscalid, ciazopamid, cyproconazole, diclofuranid, difenoconazole, di But are not limited to, methotrexate, methomorph, diniconazole, etafoxam, ethoxyquin, palmaxadone, phenarimol, phenhexamide, fluodioxonil, fluquinonezole, hexaconazole, imarjal, imeneconazole, Ropamide, mepha But are not limited to, pyrimidines, pyrimidines, methiconazoles, Michaelobutanyl, Nuarimol, provenazoles, prochloraz, propiconazole, pyrazofos, pyrimethanil, shimeconazole, giopanate methyl, At least one selected from the group consisting of cyproxam, triplexistrobin, picoxystrobin, pentionopyrid, diethophenecarb, fluoropyrazide and diphenococonazole.
상기 살충제의 바람직한 일례로는 알디캅, 아미트라즈, 벤프라캅, 클로란트라닐리프롤, 클로르플루아주론, 클로르피리포스, 디디브이피, 다이아펜티유론, 디메틸빈포스, 이피엔, 에티오펜캅, 에트림포스, 페나자퀸, 페노뷰카뷰, 펜피록시메이트, 플루벤디아마이드, 플루세토설퓨론, 푸라티오카브, 헥사프루무론, 루페뉴론, 메톨카브, 메빈포스-1, 메빈포스-2, 밀베멕틴A3, 밀베멕틴A4, 펜토에이트, 포레이트, 포살론, 피리미포스메틸, 프로페노포스, 피라크로포스, 피라크로포스, 피리다벤, 피리플루퀴나존, 피로퀼론, 실라프루오펜, 스피로디크로펜, 스피로메시펜, 테플루벤주론, 티오디카브, 티아디닐, 바미도티온, 스피네토람(j), 스피네토람(L), 메씨오카브, 아세페이트, 비페나제이트, 클로펜테진, 크로마페노자이드, 페나미포스, 디메토에이트, 헥시치아족스, 폭심, 피리미디펜, 오메토에이트, 피리미카브, 이미시아포스, 메톡시페노자이드, 티아클로프리드, 클로피아니딘, 페노티오카브, 테부펜피라드, 포스티아제이트, 옥사밀, 카바릴, 테부페노자이드, 메소밀, 플루페녹수론, 풀루아크리피림, 이미다클로프리드, 디노테푸란, 피리다펜티온, 트리아조포스, 아세타미프리드 및 훼녹시카브로 이루어진 군에서 선택되는 어느 하나 이상의 살충제 성분인 것이 바람직하며, 더 바람직하게는 알디캅, 아미트라즈, 벤프라캅, 클로란트라닐리프롤, 클로르플루아주론, 클로르피리포스, 디디브이피, 다이아펜티유론, 디메틸빈포스, 이피엔, 에티오펜캅, 에트림포스, 페나자퀸, 페노뷰카뷰, 펜피록시메이트, 플루벤디아마이드, 플루세토설퓨론, 푸라티오카브, 헥사프루무론, 루페뉴론, 메톨카브, 메빈포스-1, 메빈포스-2, 밀베멕틴A3, 밀베멕틴A4, 펜토에이트, 포레이트, 포살론, 피리미포스메틸, 프로페노포스, 피라크로포스, 피라크로포스, 피리다벤, 피리플루퀴나존, 피로퀼론, 실라프루오펜, 스피로디크로펜, 스피로메시펜, 테플루벤주론, 티오디카브, 티아디닐, 바미도티온, 스피네토람(j), 스피네토람(L), 메씨오카브, 아세페이트, 비페나제이트, 클로펜테진, 크로마페노자이드, 페나미포스, 디메토에이트, 헥시치아족스, 폭심, 피리미디펜, 오메토에이트, 피리미카브, 이미시아포스, 메톡시페노자이드, 티아클로프리드, 클로피아니딘, 페노티오카브, 테부펜피라드, 포스티아제이트, 옥사밀, 카바릴, 테부페노자이드, 메소밀, 플루페녹수론 및 풀루아크리피림으로 이루어진 군에서 선택되는 어느 하나 이상의 살충제 성분인 것이 바람직하며, 더욱더 바람직하게는 알디캅, 아미트라즈, 벤프라캅, 클로란트라닐리프롤, 클로르플루아주론, 클로르피리포스, 디디브이피, 다이아펜티유론, 디메틸빈포스, 이피엔, 에티오펜캅, 에트림포스, 페나자퀸, 페노뷰카뷰, 펜피록시메이트, 플루벤디아마이드, 플루세토설퓨론, 푸라티오카브, 헥사프루무론, 루페뉴론, 메톨카브, 메빈포스-1, 메빈포스-2, 밀베멕틴A3, 밀베멕틴A4, 펜토에이트, 포레이트, 포살론, 피리미포스메틸, 프로페노포스, 피라크로포스, 피라크로포스, 피리다벤, 피리플루퀴나존, 피로퀼론, 실라프루오펜, 스피로디크로펜, 스피로메시펜, 테플루벤주론, 티오디카브, 티아디닐, 바미도티온, 스피네토람(j), 스피네토람(L), 메씨오카브, 아세페이트, 비페나제이트, 클로펜테진, 크로마페노자이드, 페나미포스, 디메토에이트, 헥시치아족스, 폭심, 피리미디펜, 오메토에이트, 피리미카브 및 이미시아포스로 이루어진 군에서 선택되는 어느 하나 이상이다.Preferable examples of the insecticide include aldicap, amitraz, benzplacup, chlorantraniliprol, chlorflualuron, chlorpyrifos, didypipif, diapthyturon, dimethylpinphos, , Methylvorf-1, Mabinfos-2, Methylpyridazinone, Methylpyridazinone, Methylpyridazinone, Pyridoxine, But are not limited to, but are not limited to, but are not limited to, but are not limited to, lactose, lactose, lactose, lactose, lactose, lactose, lactose, lactose, lactose, lactose, (J), spinetoram (L), methococarb, acetic acid, biphenate, thiadiazole, thiadiazine, thiadiene, , Clofenethene, chroma phenozide, phenamphos, dimethoate, Thiocloprid, clopyranidine, phenothiocarb, tebupenopyrid, phosphatidylglycerol, oxytetrahydropyrimidine, pyridoxal, pyrimicarb, imicaphor, methoxyphenozide, thiacloprid, , Carbaryl, tebufenozide, mesomil, flupenoxolone, fulloacrypyrim, imidacloprid, dinotefuran, pyridapention, triazopos, acetamiprid and phenoxycarb It is preferable to use any one or more insecticide components, and more preferably an insecticide component selected from the group consisting of aldicyc, amitraz, benfrapac, clorantraniliprol, chlorflualon, chlorpyrifos, Such as, but not limited to, corticosteroids, such as cortisone, cortisone, cortisone, cortisone, cortisone, cortisone, cortisone, , Mervin Force- 2, milbemectin A3, milbemectin A4, pentoate, phorate, phosalone, pyriminphosmethyl, prophenophor, pyracurphose, pyracurphos, pyridabene, pyrimidine, pyridylquinazoline, pyroquilone, (J), spinetoram (L), methococav, acetic acid, acetic acid, acetic acid, acetic acid, acetic acid, But are not limited to, phenanthrene, phenanthate, chlophene, chlophenethide, chroma phenozide, phenamphos, dimethoate, hexachiabs, pentium, pyrimidiphen, omeate, pyrimicab, imicaphor, methoxyphenozide, Which is selected from the group consisting of clavulanic acid, clavulanic acid, clavulanic acid, clavulanic acid, clavulanic acid, clavulanic acid, clavulanic acid, clavulanic acid, clavulanic acid, clavulanic acid, clavulanic acid, clavulanic acid, It is preferably one or more insecticide components, more preferably aldicyc, But are not limited to, but are not limited to, amidrazine, benzoprazole, aminotrazole, benzoprocap, chlorantraniliprol, chlorflualuron, chlorpyrifos, didypipif, Mabinfos-2, milbemectin A3, milbemectin A4, pentaerythritol, camphor, camphor, carbamate, carbamate, carbamate, But are not limited to, phthalates, phthalates, phthalimones, pyrimidoxymethyl, propenophores, pyracurphos, pyracurphos, pyridabenes, pyrifluquinazones, pyroquilones, silaproxenes, spirodiclofen, But are not limited to, benzenone, thiodicarb, thiadinyl, bamidothione, spinetoram (j), spinetoram (L), methococav, acetic acid, biphenase, clopentezin, Fenamiphos, dimethoate, hexachiabs, bovine, pyrimidifene, omeitoate, f Mika probe and is already more than one selected from the group consisting of cyano force.
상기 제초제의 바람직한 일례로는 잔류농약이 알라클로르, 카펜스트롤, 클로르설프론, 크레소딤-1, 크레소딤-2, 싸이클로설파무론, 사이할로포프뷰틸, 디티오피르, 페녹사프로프에틸, 플루미옥싸진, 할로설푸론메칠, 할록시포프, 이마조설퓨론, 메타조설푸론, 메트리부진, 몰리네이트, 니코설푸론, 옥사디아존, 페녹슐람, 펜톡사존, 피라졸산, 피리벤족심, 퀸메락, 퀴자로포프에틸, 세톡시딤, 티아조피르, 티디아주론, 치펜설푸론메칠, 아짐설프론, 시메트린, 디메타메트린, 테부트린, 파클로부트라졸, 다임론, 벤설푸론메칠, 프로메트린, 플루페나세트, 피리프탈리드, 벤조비사이클론, 테닐클로르, 에톡시설푸론, 피리미설판, 디메텐아마이드, 리누론, 메토브로무론, 나프로파마이드, 브로마실, 에스프로카브, 피페로포스, 펜트라자마이드, 터브틸라진, 디메피페레이트, 디우론, 메페나세트, 카르펜트라존에틸, 포클로로페누론, 피리부티카브, 메폴라클로르, 헥사지논 및 피리미노박메틸(E)로 이루어진 군에서 선택되는 어느 하나 이상의 제초제 성분인 것이 바람직하며, 더 바람직하게는 알라클로르, 카펜스트롤, 클로르설프론, 크레소딤-1, 크레소딤-2, 싸이클로설파무론, 사이할로포프뷰틸, 디티오피르, 페녹사프로프에틸, 플루미옥싸진, 할로설푸론메칠, 할록시포프, 이마조설퓨론, 메타조설푸론, 메트리부진, 몰리네이트, 니코설푸론, 옥사디아존, 페녹슐람, 펜톡사존, 피라졸산, 피리벤족심, 퀸메락, 퀴자로포프에틸, 세톡시딤, 티아조피르, 티디아주론, 치펜설푸론메칠, 아짐설프론, 시메트린, 디메타메트린, 테부트린, 파클로부트라졸, 다임론, 벤설푸론메칠, 프로메트린, 플루페나세트, 피리프탈리드, 벤조비사이클론, 테닐클로르, 에톡시설푸론, 피리미설판, 디메텐아마이드, 리누론, 메토브로무론, 나프로파마이드, 브로마실, 에스프로카브 및 피페로포스로 이루어진 군에서 선택되는 어느 하나 이상이고, 더욱더 바람직하게는 알라클로르, 카펜스트롤, 클로르설프론, 크레소딤-1, 크레소딤-2, 싸이클로설파무론, 사이할로포프뷰틸, 디티오피르, 페녹사프로프에틸, 플루미옥싸진, 할로설푸론메칠, 할록시포프, 이마조설퓨론, 메타조설푸론, 메트리부진, 몰리네이트, 니코설푸론, 옥사디아존, 페녹슐람, 펜톡사존, 피라졸산, 피리벤족심, 퀸메락, 퀴자로포프에틸, 세톡시딤, 티아조피르, 티디아주론, 치펜설푸론메칠, 아짐설프론, 시메트린, 디메타메트린, 테부트린, 파클로부트라졸, 다임론, 벤설푸론메칠, 프로메트린, 플루페나세트, 피리프탈리드 및 벤조비사이클론으로 이루어진 군에서 선택되는 어느 하나 이상의 제초제 성분인 것이지만, 이에 한정하는 것은 아니다.Preferable examples of the herbicide include those in which the residual pesticide is selected from the group consisting of allachlor, carpentol, chlorsulfuron, cresovid-1, cresovid-2, cyclosulfamuron, cyhalopopbutyl, dithiopyr, , Flumioxane, halosulfuron methyl, haloxifop, imazosulfuron, metazosulfuron, metribuzin, molinate, nicosulfuron, oxadiazon, phenoxalam, pentoxazin, pyrazolic acid, But are not limited to, quinolone, quinmalac, quizaropoethyl, cetoxydim, thiazopyr, thidiazuron, chipensulfuron methyl, azimulphuron, cymetryn, dimethmethrin, tebutyne, paracobutazole, But are not limited to, benzoyl perone, benzoyl perone, benzoyl perone, benzoyl perone, benzoyl perone, benzoyl perone, benzoyl perone methyl, promethrin, flupenaset, pyriphedride, benzo bicyclone, tenyl chlor, ethoxy furon, pyrimisulfan, dimethenamid, renuron, Esters, esters, piperazines, pentrazamides, terbutyrazine, di (E) selected from the group consisting of piperazine, diuron, mefenacet, carpentrazone ethyl, fluorophenolone, pyrylbuticarb, meperaclour, hexaginone, and pyriminobomethyl More preferably at least one selected from the group consisting of allachlor, carpentol, chlorsulfuron, cresodim-1, cresovidin-2, cyclosulfamuron, cialopropbutyl, dithiopyr, Wherein the compound is selected from the group consisting of haloperfurone methyl, haloperifop, imazosulfuron, metazosulfuron, methotribin, molinate, nicosulfuron, oxadiazon, phenoxhlam, pentoxazin, pyrazolan, , Quizaropo-ethyl, cetoxydim, thiazopyr, thiadiazuron, chipensulfuron methyl, azimsulfuron, cimetriin, dimethymetryne, tebutyne, parcoubutrazole, Methyl, promethrin, flupenacet, pyriphedral, benz At least one member selected from the group consisting of at least one member selected from the group consisting of at least one member selected from the group consisting of quinone cyclones, tenyl chlorides, ethoxylated furons, pyrimethyl sulphates, dimethenamides, renuron, metobromuron, naproparamide, bromacil, esprocar, More preferably at least one selected from the group consisting of allachlor, carpentol, chlorsulfuron, cresovid-1, cresovid-2, cyclosulfamuron, cyalopopbutyl, dithiopyr, , Halosulfuron methyl, haloxyphop, imazosulfuron, metazosulfuron, methotribose, molinate, nicosulfuron, oxadiazon, phenoxhlam, pentoxazin, pyrazolan, But are not limited to, benzopyran, xanthopyran, xanthopyran, xanthopyran, xanthopyran, xanthopyran, xanthopyran, ≪ RTI ID = 0.0 > promethrin, < / RTI > flupenacet, Which is selected from the group consisting of one or more cyclones, but the herbicide component, is not limited to this.
상기 농산물에 잔류하는 농약 성분의 저감방법에 있어서, 상기 잔류농약이 지베레린과 같은 식물호르몬 성분 또는 펜치온과 같은 살금제 성분인 것이 바람직하지만, 이에 한정하는 것은 아니다.In the method for reducing pesticide residues remaining in agricultural products, it is preferable that the residual pesticide is a scavenger component such as a plant hormone component such as gibberellin or pliocin, but the present invention is not limited thereto.
본 발명은 잔류농약이 존재하는 농산물에 농산물과의 조사거리 1~100㎝를 유지하면서, 30~100℃의 온도 조건으로, 자외선-C를 0.1~5일 동안 조사하는 단계를 포함하며, 상기 조사된 자외선-C는 공기 중의 산소와 반응하여 오존을 생성하는 것을 특징으로 하는 농산물 잔류농약의 저감방법에 관한 것이다.The present invention includes a step of irradiating ultraviolet-C for 0.1 to 5 days at a temperature of 30 to 100 DEG C while maintaining an irradiation distance of 1 to 100 cm with an agricultural product on agricultural products in which pesticide residues exist, And the ultraviolet ray-C reacts with oxygen in the air to generate ozone.
이하, 실시예 및 비교예를 이용하여 본 발명을 더욱 상세하게 설명하고자 한다. 이들 실시예는 오로지 본 발명을 보다 구체적으로 설명하기 위한 것으로 본 발명의 범위가 이들에 의해 제한되지 않는다는 것은 당해 기술분야에서 통상의 지식을 가진 자에게 있어 자명한 것이다. Hereinafter, the present invention will be described in more detail with reference to examples and comparative examples. It is to be understood by those skilled in the art that these embodiments are merely illustrative of the present invention and that the scope of the present invention is not limited thereto.
실시예Example 1. 자외선-C 조사 및 오존가스 병용 처리에 따른 농약의 잔류량 분석 1. Residue analysis of pesticides by ultraviolet-C irradiation and ozone gas treatment
살충제의 일종인 이미다클로프리드(imidacloprid)를 50중량%, 첨가제인 계면활성제, 경계제 및 증량제의 합계가 나머지 50 중량%가 되도록 하여, 국내산 1㎏의 고추에 처리하였다.50% by weight of imidacloprid, which is a kind of insecticide, and 50% by weight of surfactants, surfactants, boundary agents and extenders as additives, were treated with 1 kg of domestic red pepper.
또한, 살균제의 일종인 디페노코나졸(difenoconazole)를 50중량%, 첨가제인 계면활성제, 경계제, 증량제의 합계가 나머지 50 중량%가 되도록 하여, 국내산 1㎏의 고추에 처리하였다. In addition, 50 weight% of difenoconazole, a kind of fungicide, and 1 kg of domestic red pepper were treated so that the total amount of surfactant, boundary agent and extender added as additives was 50 weight%.
55℃에서 대기순환기를 통해 공기를 공급하면서, 185nm를 발생하는 25W UV-C lamp 를 0.150 m3 (150ℓ) 건조기 내에 설치하여 이미다클로프리드가 처리된 국내산 1㎏의 고추와 조사거리를 20㎝로 유지하면서, 48시간 동안 상기 이미다클로프리드 또는 디페노코나졸이 각각 처리된 고추에 조사하였다. 또한 오존가스를 일정하게 공급하였다.While at 55 ℃ supplying air through the air circulator, by installing a 25W UV-C lamp for generating a 185nm in a 0.150 m 3 (150ℓ) dryer keeping the peppers and irradiation distance yimidakeulro domestic 1㎏ the free-throw is treated with 20㎝ , And the imidacloprid or difenoconazole was irradiated to red pepper treated for 48 hours, respectively. Also, ozone gas was supplied constantly.
하기의 반응식 (1), (2) 및 (3)에 따라, 자외선-C와 대기순환기를 통해 공급된 공기 중 산소가 반응하여 오존을 생성하였다.According to the following reaction formulas (1), (2), and (3), oxygen in the air supplied through the ultraviolet ray C and the atmospheric circulator reacted to generate ozone.
(1) O2 + hυ → O(3P) + O (1D) (1) O 2 + hυ → O (3 P) + O (1 D)
(2) O2 + hυ → O(3P) + O (1D) (2) O 2 + hυ → O (3 P) + O (1 D)
(3) O(3P) + O2 → O3 (3) O ( 3 P) + O 2 ? O 3
상기 이미다클로프리드 또는 디페노코나졸이 처리된 고추에 상기 자외선-C 조사 및 공급된 오존가스를 통해 고추에 잔존하는 이미다클로프리드의 양을 확인하였다. 상기 고추는 건조실에서 55℃의 온도 조건으로 48시간 동안 건조한 후에 이미다클로프리드 또는 디페노코나졸을 처리하였다. The amount of imidacloprid remaining in the pepper was confirmed through the ultraviolet-C irradiation and the supplied ozone gas to the red pepper treated with imidacloprid or difenoconazole. The peppers were dried in a drying chamber at a temperature of 55 ° C for 48 hours and then treated with imidacloprid or difenoconazole.
(㎎/㎏)Before UV-C irradiation and ozone treatment
(Mg / kg)
(㎎/㎏)After UV-C irradiation and ozone treatment
(Mg / kg)
(Reduction, %)Reduction rate
(Reduction,%)
그 결과, 자외선-C 조사 및 오존처리를 병용함으로써 농약의 잔류량이 현저하게 감소한 것을 확인하였다(표 1 및 도 1). As a result, it was confirmed that the residual amount of pesticide was remarkably reduced by using UV-C irradiation and ozone treatment together (Table 1 and Fig. 1).
비교예Comparative Example 1. 254㎚의 자외선-C 조사 또는 오존 처리에 따른 농약의 잔류량 분석 1. Analysis of pesticide residues by ultraviolet-C irradiation or ozone treatment at 254 nm
상기 실시예 1과 동일한 조건으로 이미다클로프리드 및 디페노코나졸을 처리한 고추에 대하여, 자외선-C만을 조사하거나, 오존가스만을 처리한 후, 고추에 잔존하는 이미다클로프리드의 양을 확인하였다.The red pepper treated with imidacloprid and difenoconazole under the same conditions as in Example 1 was irradiated with only ultraviolet-C or treated with only ozone gas, and the amount of imidacloprid remaining in the red pepper was confirmed.
그 결과, 상기 254㎚의 자외선-C 조사는 잔류농약 분해에 큰 영향을 미치지 않음을 확인하였고, 오존가스 처리는 잔류농약을 저감시키기는 하였으나, 본 발명의 자외선-C 조사 및 오존가스 처리를 병용하는 것에 비해서는 그 효과가 미약하였다(도 1).As a result, it was confirmed that the ultraviolet-C irradiation at 254 nm had no significant effect on the decomposition of pesticide residues, and the ozone gas treatment reduced the residual pesticide. However, the ultraviolet-C irradiation and the ozone gas treatment (Fig. 1).
실시예Example 2. 자외선-C 조사 및 오존가스 병용처리에 따른 잔류 농약 분해효과 2. Degradation effect of residual pesticides on UV-C irradiation and ozone gas treatment
하기 표 2 내지 표 6에 기재된 각각의 농약들에 대한 자외선-C 조사 및 오존가스 병용처리에 따른 잔류 농약 분해효과를 확인하였다.The decomposition effects of residual pesticides on the respective pesticides listed in Tables 2 to 6 below were confirmed by ultraviolet-C irradiation and ozone gas combination treatment.
하기 표 2 내지 표 6에 기재된 각각의 농약들이 사용된 것을 제외하고는 상기 실시예 1과 동일한 방법으로 잔류 농약 분해효과를 확인하였다.The decomposition effect of the residual pesticides was confirmed in the same manner as in Example 1, except that the respective pesticides listed in Tables 2 to 6 were used.
하기 표 2에 기재된 농약성분들은 자외선-C의 조사 및 오존가스 병용처리 이후에, 모두 분해되어 하기 표 2에 기재된 농약성분들을 처리한 1㎏의 고추에서는 잔류 농약이 검출되지 아니하였다(표 2).The pesticide ingredients shown in Table 2 below were all decomposed after irradiation with UV-C and ozone gas treatment, and no residual pesticide was detected in 1 kg of red pepper treated with the pesticide ingredients shown in Table 2 below (Table 2) .
살충제
(41종)
Pesticide
(41 species)
살균제
(32종)
disinfectant
(32 species)
제초제
(28종)
Herbicide
(28 species)
*살금제는 조류를 치사하거나 쫓아 내기 위해 만들어진 화학물질을 의미한다.* Scrubbers are chemicals made to kill or expel algae.
하기 표 3에 기재된 살충제 기능의 농약성분들은 자외선-C 조사 및 오존가스 병용처리 후에, 완전 분해되는 것은 아니지만, 30%이상 농약 성분이 분해되었음을 확인하였다(표 3).The pesticide-functioning pesticide ingredients shown in Table 3 below were not completely decomposed after UV-C irradiation and ozone gas treatment, but 30% or more of the pesticide components were decomposed (Table 3).
하기 표 4에 기재된 살균제 기능의 농약성분들은 자외선-C 조사 및 오존처리 후에, 완전 분해는 아니지만, 30%이상 농약 성분이 분해되었음을 확인하였다(표 4).The pesticide components of the bactericidal function shown in Table 4 below were not completely decomposed after UV-C irradiation and ozone treatment, but 30% or more of the pesticide components were decomposed (Table 4).
하기 표 5에 기재된 제초제 기능의 농약성분들은 자외선-C 조사 및 오존처리 후에, 완전분해는 아니지만, 30%이상 농약 성분이 분해되었음을 확인하였다(표 5).The herbicidal pesticidal components shown in Table 5 below were not completely decomposed after UV-C irradiation and ozone treatment, but 30% or more of the pesticide components were decomposed (Table 5).
하기 표 6에 기재된 농약성분들은 자외선-C 조사 및 오존처리 후에, 30% 미만으로 농약 성분이 분해되었음을 확인하였다(표 6).The pesticide ingredients listed in Table 6 below were found to have degraded pesticide components below 30% after UV-C irradiation and ozone treatment (Table 6).
살충제
(7종)
Pesticide
(7 species)
(2종)disinfectant
(2 kinds)
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