KR20160012387A

KR20160012387A - Time control type modeling mask with nano-emulsions without containing powder and method for preparing the same

Info

Publication number: KR20160012387A
Application number: KR1020140093723A
Authority: KR
Inventors: 김인영; 최화숙
Original assignee: 김인영; 최화숙
Priority date: 2014-07-24
Filing date: 2014-07-24
Publication date: 2016-02-03

Abstract

The present invention relates to a modeling mask that does not use a powder, and is a modeling mask in which a nano emulsion, a time-controlled activator for controlling a curing rate, To a time-regulated modeling mask that does not use powder, and a method of manufacturing the same.
According to the present invention, the performance of the high-viscosity modeling mask is maintained even when the oil is blended without containing the powder, the hardening rate can be controlled according to the compounding concentration, no skin irritation, It is possible to complete the solid modeling base which is soft and resilient and to prevent the flow of the residue, to improve the convenience and efficiency to be freely mixed and used by predicting the desired use time, and as the efficacy effect, , A pore-reducing action, and a skin-absorbing effect of a desired ingredient are remarkably excellent, and a desired effective ingredient is freely mixed to have a cool soothing effect, a whitening clearing effect, a wrinkle improving effect, and a resilience improving effect.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention [0001] The present invention relates to a time-controlled modeling mask containing nano-emulsions and powder-free time-regulating modeling masks,

The present invention relates to a time-regulating modeling mask containing nano emulsions and powder-free, and a method of manufacturing the same. More particularly, the present invention relates to a modeling mask having a nano emulsion and a nano emulsion containing powder, Time-controlled modeling mask which does not use powder but contains nano-emulsions which are safe, such as being soft, strong, firm and firm, and free from skin troubles, .

Recently, various cosmetics have been released. Depending on their functions, they are mainly divided into basic cosmetics and color cosmetics. Especially, as the cosmetics industry develops, it is demanding specialized cosmetics that are based on basic functions and pursue more advanced effects.

The basic function of the cosmetic is to clean the skin, beautify it, moisturize it, give it a softening effect and prevent aging. Major mechanisms related to this are accelerated due to moisturizing effect that prevents moisture from being supplied to the skin or excessive evaporation of moisture from the skin, ultraviolet ray blocking action, skin protection from environmental pollution and external stimuli, stress, smoking, and eating habits And delayed aging. For this purpose, many skin cosmetic cosmetics have been developed and various cosmetics have been commercialized.

Skin has a direct connection with the external environment, and it plays an important role in protecting the human body from harmful factors that intrude into the human body. As the skin ages, the cells forming the skin are damaged due to various harmful pollutants, harmful ultraviolet rays, stress, overwork and nutritional imbalance, cell activation and proliferation are not properly performed, Aging such as acceleration, drop in elasticity and dryness of the skin occurs rapidly.

The modeling mask used to solve these problems is mainly used in the skin care room and the dermatology hospital, and it is also a product that is used in practice part of the skin care manager certification examination. Types of modeling masks are classified into special powder form masks and special formulations such as wash off cream masks, gypsum masks, and collagen masks that are washed after normal use. The wash-off type mask is not strictly included in the modeling mask range, and can be said to be close to general basic cosmetics. Mixed powder type modeling mask is a formulation in which alginic acid is mixed with talc, kaolin, titanium dioxide, diatomaceous earth, mud, loess, and various vegetable powders mixed at a certain ratio. The other gypsum mask is a formulation for applying gypsum to the skin, and the collagen mask refers to a mask that applies highly concentrated collagen to the skin.

Particularly, the modeling mask containing the powder is characterized in that the shape after the pack is hardened is formed in a soft manner. However, this modeling mask has a problem that the residual amount remains in the skin due to the presence of the powder, so that the residue remains uncomfortable and causes secondary irritation.

The modeling mask contains a filler such as alginic acid, diatomaceous earth, talc, kaolin, titanium dioxide, mud, loess and the like, and contains a gelling agent such as calcium sulfate. Modeling masks must be mixed thoroughly with water at a certain rate before use, where fine dusts can be blown into the body through the respiratory system, and if the amount of water to be incorporated is not correct, The gel was hardened before it was made to be used, and the surface of the gel was rough and lumps were formed, so that a good appearance could not be obtained. In addition, there has been a lot of inconvenience to the users, such as powdery and watery garbage and lumps. In addition, when the ratio of the amount of powder to the amount of water is not matched, it is not gelled when applied to the skin, and it is inconvenient that it does not harden and flow down. Also, the mixed powder to be mixed with the filler has disadvantages that the skin is burned up and has a stinging property, which causes side effects. Therefore, even if a large number of active ingredients are used, the use of the active ingredient may be limited and the efficacy may be deteriorated.

The prior art related to this modeling mask will be described as follows.

Korean Patent No. 10-1259150 entitled "A cosmetic composition for a peel-off type powder cosmetic pack containing alginic acid and a volcanic stone as an active ingredient (registrant, Catholic University of Industry & Academy Collaboration, Daegu Catholic University) The present invention relates to a cosmetic composition for a powder type cosmetic pack, which comprises a gelling retarder and alginic acid to inhibit the gelation of a gluronic acid monomer present in alginic acid, A neutral to weakly alkaline dispersing agent is used to aid dispersion and uniform film formation.

Korean Patent No. 10-1207556 entitled "Gel-type peel-off type pack cosmetic composition (registrant, Korea agent cosmetics) " refers to a gel-type peel-off type pack, which is a liquid form containing sodium alginate and sodium pyrophosphate Of an aqueous solution 1, a calcium sulfate and a thickening agent, in a gel form.

Korean Patent Laid-Open No. 10-2009-0006539 entitled " Disposable Modeling Pack Set (Applicant; La Chung) "discloses a disposable modeling pack set. The present invention relates to an essence bag comprising a powder bag containing powder, a mixing stick used for mixing the powder with a predetermined liquid, and a mixing container for mixing the powder with a predetermined liquid, And the user can directly and easily perform the pack operation without any time and place.

Korean Patent Laid-Open No. 10-2014-0058842 entitled "Cosmetics package (Applicant: Ha Jae Soon, Kang Cheol Joong) " provided to use plum juice and yellow clay lipstick, , A modeling mask pack powder selected from at least one of ascorbic acid, hyaluronic acid, ginkgo leaf, licorice extract, red iron oxide, fruit aroma and aroma lavender, and processed in a far infrared irradiation atmosphere under a specific condition, The retarder having a half width value in a range of less than 80 Hz can be mixed at a proper blending ratio and applied as a peel-off type.

Korean Academic Literature Korean Journal of Skin and Beauty, Vol.10, No.4, 911-919 Nov. 2012 (Main author: Song Hwa Kyung et al.) Prepared packs of distilled water, wheat flour and mulberry leaf powder to investigate the effects of natural pack and soap containing mulberry leaf powder on the skin improvement of adult men and the possibility of using mulberry leaf powder Soap was also applied to the face of the male using only soap base, glycerin, and mulberry leaf powder. In both groups, control group packs were applied to the left face, and mulberry leaves were packed to the right face. In each group, the mulberry soap and pack were applied together The skin improvement of the group was studied.

Korean Academic Literature Korean Journal of Skin and Beauty, Vol.11, No.5, 993-1000 Oct. 2013 (main author: Choi Sung-jin, etc) is a skin improvement effect of facial pack containing kaolin, adenosine and plant complex extract. The effect of moisturizing, transdermal water loss, elasticity, sebum secretion, skin texture, brightness, erythema, pigmentation, and exfoliation improvement was examined and the skin improvement effect of the facial pack was verified.

Most of these prior arts are mixed with powders and have the problems listed above. In the modeling formulation containing common emulsions, there is a problem that gelation can not be performed due to miscibility with oil. Also, there is no modeling mask containing nanoemulsions to date, and there is not yet a description of a manufacturing method which is easy to use as a time-regulating modeling mask and has superior efficacy.

In order to solve the problems of the prior art as described above, the present invention provides a nano emulsion containing a nano emulsion without using a powder as a filler in a modeling mask, so that the modeling mask can be made softer and more effective, , A modeling mask in the form of a high-viscosity jelly that does not flow when used on skin, and a method for manufacturing the same.

In addition, the present invention can include two formulations having the form of an activator capable of using a high-viscosity jelly cream and having a time-adjustable activator, and mixing the emulsion with a liquid or gel-like form And the speed can be controlled so that such a composition hardens hardly according to the mixing ratio of the activator, so that the convenience of use can be improved.

Another object of the present invention is to provide a cosmetic composition which is excellent in cooling and sedative action upon application of a skin, gives an immediate pore reduction effect, provides a moisturizing and softening effect and smoothly supplies an active ingredient,

Other objects of the present invention will become readily apparent from the following description of the embodiments.

According to an aspect of the present invention, there is provided a modeling mask which does not use a powder, wherein a modeling mask jelly cream base is mixed with a nano emulsion and the time-regulating activator for controlling a curing rate A time-controlled modeling mask containing nano emulsions and not using powder is provided.

The modeling mask jelly cream base comprises at least two of potassium alginate, 1-3% sodium alginate, and 0.1-1% agar, based on the total weight of the modeling mask jelly cream base , 0.1 to 1% by weight of sodium chloride, 0.1 to 3% by weight of tetrapotassium pyrophosphate, 0.01 to 1% by weight of calcium carbonate and 0.1 to 1% by weight of sodium carbonate, And the nano emulsion has a viscosity of 10 to 30 wt% of glycerol, 1 to 10 wt% of polyglyceryl-10 myristate, 30 to 50 wt% of polyglyceryl-10 myristate, 60% by weight of mixed oil, and 5 to 30% by weight of purified water.

The time controlled activator may comprise at least two of calcium sulfate from 0.1 to 20% by weight, magnesium sulfate from 0.1 to 20% by weight and sodium chloride from 0.01 to 5% by weight, based on the total weight of the time- , 0.01 to 3% by weight of hydroxyethyl cellulose, 0.01 to 2% by weight of methyl cellulose, and 0.01 to 1% by weight of xanthan gum.

The present invention relates to a cosmetic emulsion comprising an aqueous emulsion of a liquid or a gel in an amount of 0.1 to 1% by weight, 0.1 to 0.5% by weight of vitamin E, 0.01 to 0.1% by weight, 1 to 3% by weight of niacinamide, 2 to 7% by weight of arbutin, 0.01 to 1% by weight of EGF and 0.1 to 10% by weight of mixed fermentation extract, wherein the mixed fermentation extract contains green tea fermentation extract, The method according to any one of claims 1 to 3, wherein the extract comprises at least two selected from jujube fermentation extract, licorice fermentation extract, Angelica keiskei extract, Angelica keiskei fermentation extract, red ginseng fermentation extract, kelp fermentation extract, bank fermentation extract, pomegranate fermentation extract, Lt; / RTI >

According to another aspect of the present invention, there is provided a method of manufacturing a modeling mask that does not use a powder, comprising the steps of: mixing a modeling mask jelly cream base with a nano emulsion, a liquid or gel-like essence emulsion, , A liquid or gel-like essence emulsion and a time-regulated activator are mixed at a weight ratio of 50: 3 to 25: 1 to 20, and the mixture is gelled, so that the curing speed of the modeling is 3 to 30 minutes. There is provided a method of manufacturing a time-regulated modeling mask that does not use a powder while containing it.

Wherein the serum albumin emulsion comprises 0.1 to 1 wt% of panthenol, 0.1 to 0.5 wt% of vitamin E, 0.01 to 0.1 wt% of adenosine, 1 to 3 wt% of niacinamide, Wherein the mixed fermentation extract contains 7% by weight of arbutin, 0.01 to 1% by weight of EGF, and 0.1 to 10% by weight of mixed fermentation extract, wherein the mixed fermentation extract contains green tea fermentation extract, jujube fermentation extract, licorice fermentation extract, Extracts, red ginseng fermentation extract, tideland fermentation extract, bank fermentation extract, pomegranate fermentation extract, mugwort fermentation extract, yeast extract, and honey extract.

According to the time-regulated modeling mask containing the nano emulsion according to the present invention without using the powder and the method of manufacturing the same, the performance of the high-viscosity modeling mask can be improved while blending oil without containing the powder, , It is possible to adjust the curing speed according to the compounding concentration, and it is possible to complete the hard modeling base having no skin irritation, safety, powder residue, soft and elasticity, It is possible to improve the convenience and efficiency that can be predicted and freely combined and used, and as an efficacy effect, a soothing effect, a pore reducing effect, and a skin absorption effect of a desired ingredient are remarkably excellent, and a desired effective ingredient is freely mixed, Clearing effect, wrinkle improvement effect, and elasticity improvement effect.

1 is a flowchart illustrating a method of manufacturing a nano emulsion of a time-regulating modeling mask containing a nano-emulsion according to the present invention without using a powder,
FIG. 2 is a nano-emulsion image of a time-regulating modeling mask containing a nano emulsion according to the present invention without using a powder,
3 is a flowchart illustrating a method of manufacturing a modeling mask jelly cream base of a time-regulating modeling mask containing a nano emulsion according to the present invention and not using a powder,
FIG. 4 is a modeling mask jelly cream base image of a time-regulating modeling mask containing a nano emulsion according to the present invention without powder,
5 is a flowchart illustrating a method of manufacturing an activator of a time-regulating modeling mask containing nano-emulsions according to the present invention without powder,
6 is an activator image of a time-regulating modeling mask containing a nano emulsion according to the present invention without powder,
FIG. 7 is an image of a serum albumin of a time-regulating modeling mask containing a nano emulsion according to the present invention without using powder,
FIG. 8 is a flowchart illustrating a method of using a time-regulating modeling mask containing a nano emulsion according to the present invention,
9 is a graph showing a cooling effect and a soothing effect of a time-regulating modeling mask containing a nano emulsion according to the present invention without powder,
10 is a graph showing the improvement of the fine wrinkles of the time-regulating modeling mask containing the nano emulsion according to the present invention without using the powder,
11 is a graph showing a skin whitening effect of a time-regulating modeling mask containing a nano emulsion according to the present invention and not using a powder,
FIG. 12 is a graph showing skin elasticity effect of a time-regulating modeling mask containing nano emulsion according to the present invention and not using powder,
FIG. 13 is a graph showing an image of a nano emulsion containing 1% by weight and 10% by weight of a time-regulating modeling mask containing a nano emulsion according to the present invention,
14 is an image showing an example of using time-regulated modeling masks containing nano emulsions according to the present invention and using no powder, on the forearm using nanoemulsions differently.

The present invention is capable of various modifications and various embodiments, and specific embodiments are illustrated and described in detail in the drawings. It is to be understood, however, that the invention is not to be limited to the specific embodiments, but is to be understood to cover all modifications, equivalents, and alternatives falling within the spirit and scope of the invention, And the scope of the present invention is not limited to the following examples.

Hereinafter, embodiments according to the present invention will be described in detail with reference to the accompanying drawings, wherein like or corresponding elements are denoted by the same reference numerals, and redundant explanations thereof will be omitted.

The definitions of terms used in the present invention and major foreign words are expressed as follows to clarify the understanding. But are not limited to, glycerin, butylene glycol, titanium dioxide (TiO ₂ ), talc, kaolin, sodium chloride, sodium alginate, potassium alginate, Agar, Tetrapotassium pyrophosphate, Calcium carbonate, Sodium carbonate, Calcium sulfate, Magnesium sulfate, Hydroxyethyl cellulose ( Hydroxyethyl cellulose, methyl cellulose, xanthan gum, activator, disper mixer, homo mixer, polyglyceryl-10 myristate ), Macademia oil, Argan oil, Ester oil, Hydrocarbone oil, Silicone oil, Panthenol, Vitamin E (Vi adenine, niacinamide, arbutin, epidermal growth factor (EGF), and other terms and phrases conform to the chemical nomenclature of chemical and cosmetic products commonly referred to as tamin E, adenosine, niacinamide,

A key part of the present invention is to provide a nano emulsion in which the function of the high viscosity modeling mask is retained and the performance is improved even when the oil is blended, and it contains more than two components of potassium alginate, sodium alginate and agar, Chloride, tetrapotassium pyrophosphate, calcium carbonate, and sodium carbonate are described in more detail. Further, the present invention more specifically describes a part for providing an activator for curing rate controlling base containing calcium sulfate, magnesium sulfate and sodium chloride, and containing at least two components of hydroxyethyl cellulose, methyl cellulose and xanthan gum. In order to further enhance the efficacy, details of providing liquid and gel-like essence emples containing panthenol, vitamin E, adenosine, niacinamide, arbutin, EGF, and various plant fermentation complexes are described in detail. Further, the present invention can be achieved by specifically providing a modeling mask preparation method which is easily used by suitably compounding this composition. We will describe it in more detail in this chapter.

A time-regulating modeling mask containing a nano emulsion according to an embodiment of the present invention without using powder is a modeling mask that does not use a powder. The modeling mask includes a nano emulsion in a modeling mask jelly cream base, a time for controlling a curing rate An adjustable activator and a liquid or gel-like essence emulsion for skin improvement.

The nano emulsion is prepared by mixing glycerol with polyglyceryl-10 myristate as a solvent and mixing it with macadamia oil, argan oil, ester oil, hydrocarbon oil, silicone oil and purified water to form D phase (surfactant phase) emulsification system And the like. The nano emulsion may contain 10 to 30 wt% of glycerol, 1 to 10 wt% of polyglyceryl-10 myristate, 20 to 60 wt% of mixed oil, and 5 to 40 wt% of purified water, based on the total weight of the nano- And may have a particle size of 30 to 500 nm. The nano emulsion may contain, for example, 10 to 30 wt% of glycerol, 1 to 10 wt% of polyglyceryl-10 myristate, 30 to 60 wt% of mixed oil, 5 to 30 wt% of purified water And may have a particle size of 30 to 500 nm. The mixed oil may include all oils used in cosmetics, and may be a mixture of macadamia oil, argan oil and grapeseed oil.

The modeling mask jelly cream base may comprise 0.1 to 5% by weight of potassium alginate, 0.1 to 5% by weight, based on the total weight of the modeling mask jelly cream base, 0.01 to 3% by weight of sodium chloride, 0.01 to 5% by weight of tetrapotassium pyrophosphate, 0.01 to 2% by weight of sodium alginate, 0.01 to 2% by weight of sodium alginate, Calcium carbonate, 0.1 to 2% by weight of sodium carbonate, based on the total weight of the composition. The modeling mask jelly cream base specifically includes two or more of 1-3% by weight of potassium alginate, 1-3% by weight of sodium alginate and 0.1-1% by weight of agar, based on the total weight of the modeling mask jelly cream base , 0.1 to 1% by weight of sodium chloride, 0.1 to 3% by weight of tetrapotassium pyrophosphate, 0.01 to 1% by weight of calcium carbonate and 0.1 to 1% by weight of sodium carbonate, And has a viscosity of 7,000 to 50,000 cps.

The time-controlled activator comprises 0.01 to 3% by weight of hydroxyethylcellulose containing from 0.05 to 30% by weight of calcium sulfate, from 0.05 to 30% by weight of magnesium sulfate and from 0.01 to 5% by weight of sodium chloride, , 0.01 to 2% by weight of methylcellulose, and 0.01 to 1% by weight of xanthan gum, as an activator for controlling the curing rate. The time-regulated activator may be used alone or in combination of two or more of the above-mentioned groups in order to improve stability and performance. The time controlled activator comprises at least two of calcium sulfate 0.1 to 20% by weight, magnesium sulfate 0.1 to 20% by weight and sodium chloride 0.01 to 5% by weight, based on the total weight of the time controlled activator, 0.01 To 3% by weight of hydroxyethyl cellulose, 0.01 to 2% by weight of methylcellulose, and 0.01 to 1% by weight of xanthan gum.

The cosmetic emulsion is contained in order to further improve the performance and efficacy of the composition, wherein 0.01 to 3 wt% of panthenol, 0.01 to 5 wt% of vitamin E, 0.005 to 1 wt% of adenosine, 0.1 to 5 wt% of niacinamide, A liquid or gel-like essence emulsion containing 10% by weight of arbutin, 0.01 to 10% by weight of EGF and 0.01 to 20% by weight of various plant fermentation complexes is provided but may not be blended if necessary. Here, various kinds of plant fermentation extracts include green tea fermentation extract, jujube fermentation extract, licorice fermentation extract, angelica fermentation extract, peony fermentation extract, peony fermentation extract, red ginseng fermentation extract, kelp fermentation extract, bank fermentation extract, pomegranate fermentation extract, mugwort fermentation extract, And 0.1 to 10% by weight of the combined extracts in which two or more fermented extracts are combined. The serum albumin emulsion may contain, for example, 0.1 to 1 wt% of panthenol, 0.1 to 0.5 wt% of vitamin E, 0.01 to 0.1 wt% of adenosine, 1 to 3 wt% of niacinamide, 2 to 7 wt% Wherein the mixed fermentation extract comprises at least one selected from the group consisting of green tea fermentation extract, jujube fermentation extract, licorice fermentation extract, angelica fermentation extract, peony root fermentation extract, Red ginseng extract, red ginseng fermentation extract, tideland fermentation extract, bank fermentation extract, pomegranate fermentation extract, mugwort fermentation extract, yeast extract, and honey extract.

Since the modeling mask jelly cream base, the nano emulsion, the time-controlled activator and the essence emulsion described above can be similarly applied to the method of manufacturing the time-regulating modeling mask containing the nano emulsion according to the present invention without using the powder, The same description will be omitted in a method of manufacturing a time-regulating modeling mask containing a nano emulsion according to the present invention and using no powder.

A method of manufacturing a time-regulating modeling mask containing a nano emulsion according to an embodiment of the present invention without using powder is characterized by mixing a nano emulsion, a liquid or gel-like essence emulsion and a time-controlled activator in a modeling mask jelly cream base , Modeling mask Jelly cream base, Liquid or gel-like essence emulsion and time-controlled activator are mixed in a weight ratio of 50: 3 ~ 25: 1 ~ 20 and gelation is made so that the curing speed of modeling becomes 3 ~ 30 minutes do.

A method of preparing a time-regulated modeling mask containing a nano emulsion according to an embodiment of the present invention without powder is characterized in that the activator is varied from 3 g to 25 g based on 50 g of a high-viscosity modeling mask jelly cream base If you mix 20g of high concentrated enamel emulsion at 1g, add it in 3 minutes for 30 minutes or longer for 30 minutes. Here, the mixing procedure of the manufacturing method may be changed or may be changed according to the user's need, and the mixing ratio may be adjusted proportionally. In addition, additives such as preservatives and perfumes can be added to the whole composition for long-term storage.

A method of manufacturing a time-regulating modeling mask containing a nano emulsion according to an embodiment of the present invention and not using a powder will be described in detail as an example.

1. Manufacturing method of nano emulsion

First, we describe a method for making a nano emulsion to fit a modeling mask. Once focused on making the manufacturing process simple and easy to use. The reason is that consumers should be able to use it easily. The method of manufacturing the modeling mask can be performed by various methods, but when the composition is provided by the present invention, it is most suitable when economic efficiency and efficiency are considered. The nano emulsion should be prepared by first dissolving the surfactant in the glycerol to form the D phase (detergent) gel. Specifically, 1 to 10% by weight of polyglyceryl-10-myristate should be dissolved in 10 to 30% by weight of glycerol based on the total weight of the nano emulsion. At this time, a fatty acid ester type surfactant of 10 to 30 moles of polyethylene glycol may be used, a polyglyceryl 4 to 20 fatty acid ester may be used, and a manufacturing method considering production cost and economy may be provided. The nano emulsion is prepared by mixing 10 to 30% by weight of glycerol with 1 to 10% by weight of polyglyceryl-10 myristate with 20 to 60% by weight of mixed oil and 5 to 40% by weight of purified water, Specifically 30 to 60% by weight of mixed oil and 5 to 30% by weight of purified water may be mixed.

1, 10 to 30% by weight of glycerol and 1 to 10% by weight of polyglyceryl-10-myristate are heated to 40 to 60 ° C with respect to the total weight of the nano emulsion and dissolved therein. The mixture is agitated at 30 to 200 rpm with a paddle stirrer, and 20 to 60% by weight of the mixed oil is slowly added to disperse it. As the amount of mixed oil is increased, the viscosity of the emulsion increases, and when the oil phase is fully charged, a gel having a high viscosity is formed. This is also referred to as an oil / surfactant phase. When 5 to 40% by weight of purified water is added to the emulsion, the emulsion is converted into fine oily oil (o / w) nano emulsion and emulsions of nanoparticles can be obtained. This nano emulsion is particularly suitable for modeling masks. This result is shown in Fig. It is found that the concentration of the modeling mask is 0.5 to 20% by weight in the modeling mask, and the modeling condition is poor when the amount is larger than the concentration. As a result of measuring the particle size of the nano emulsion obtained by such a process, a fine nano emulsion of 30 to 500 nm was obtained.

2. Manufacturing method of high-viscosity modeling mask jelly cream base

A high-viscosity modeling mask jelly cream base manufacturing method is shown in Fig. In detail, the modeling mask jelly cream base comprises 0.01 to 3% by weight of sodium chloride, 0.1 to 5% by weight of potassium alginate, 0.1 to 5% by weight of sodium alginate and 0.01 to 2% A composition comprising 0.01 to 5% by weight of tetrapotassium pyrophosphate, 0.01 to 2% by weight of calcium carbonate, and 0.1 to 2% by weight of sodium carbonate. Finally, the purified water was adjusted to 100% of the weight of the modeling mask jelly cream base, and sufficiently dispersed at 200 to 4,000 rpm for 30 minutes to 2 hours using a high-speed dispenser to obtain a high-viscosity jelly form.

More specifically, the modeling mask jelly cream base is more effectively mixed with 1 to 3% by weight of potassium alginate and 1 to 3% by weight of sodium alginate based on the total weight of the modeling mask jelly cream base, And 0.1 to 1% by weight of agar can be additionally used to further enhance the function. In order to ensure this, the modeling mask jelly cream base is preferably used in an amount of 1 to 3% by weight of potassium alginate, 1 to 3% by weight of sodium alginate and 0.1 to 1% by weight of agar, based on the total weight of the modeling mask jelly cream base. Can be mixed.

A time-regulated modeling mask containing nanoemulsions and no powder is prepared by adding 0.1 to 1% by weight of sodium chloride, 0.1 to 3% by weight of tetrapotassium pyrophosphate, 0.01 to 1% by weight of calcium carbonate, and 0.1 to 1% by weight of sodium carbonate may be added to make a mixed jelly phase. 1 to 5% by weight of glycerin, 1 to 7% by weight of butylene glycol, and 0.1 to 1% by weight of a nano-emulsion of 0.5 to 20% by weight, The resultant high-viscosity jelly-cream-like product can be produced by blending the pigment-60 hydrogenated castor oil, 0.01 to 0.5% by weight of perfume, and 0.1 to 2% by weight of phenoxyethanol.

The results are shown in Fig. At this time, the viscosity should be appropriately adjusted so that it will not flow through the skin at the end and can be conveniently used. A suitable viscosity is about 7,000 to 50,000 cps, more specifically about 11,000 to 50,000 cps.

3. Manufacturing method of time-controlled activator

The preparation method for making an activator for controlling the curing rate which is a desired performance in the present invention can be explained as shown in FIG. 0.01 to 3% by weight of sodium hydrogencarbonate containing 0.01 to 3% by weight of calcium sulfate, 0.05 to 30% by weight of magnesium sulfate and 0.01 to 5% by weight of sodium chloride, based on the total weight of the time- 0.01 to 2% by weight of methylcellulose, and 0.01 to 1% by weight of xanthan gum, to prepare a composition for use as an activator for controlling the curing rate.

The time-regulated activator specifically includes two or more of 0.1 to 20% by weight of calcium sulfate, 0.11 to 20% by weight of magnesium sulfate and 0.01 to 5% by weight of sodium chloride based on the total weight of the time-regulated activator A suitable activator can be made and more precise composition is needed to make the time adjustable. More specifically, the time-regulated activator is suitably blended with 5 to 10% by weight of calcium sulfate and 5 to 10% by weight of magnesium sulfate in a ratio of 1: 1 based on the total weight of the time-regulated activator, The most suitable activator can be found when it contains 2% by weight of sodium chloride. To make this a stable formulation, it is necessary to make a stable activator when it contains at least two of 0.1-0.5% by weight of hydroxyethyl cellulose, 0.1-0.5% by weight of methylcellulose and 0.1-0.5% by weight of xanthan gum More specifically, it is possible to make a more stable activator when it contains two or more components in 0.01 to 3% by weight of hydroxyethyl cellulose, 0.01 to 2% by weight of methylcellulose and 0.01 to 1% by weight of xanthan gum . In addition, additives for time-controlled activators other than glycerin, butylene glycol, and phenoxyethanol may be further used for long-term preservation of the contents. The results for the activator are shown in Fig.

4. Manufacturing method of liquid and gel-like essence emulsion

In order to further enhance the efficacy of the modeling mask, a liquid and gel-like essence emulsion containing panthenol, vitamin E, adenosine, niacinamide, arbutin, EGF, various plant fermentation complexes and the like has been developed. This ingredient does not need to be formulated according to the needs of the user, but it can be added without any problem in preparation of the modeling mask to enhance the efficacy.

The liquid or gel-like essence emulsion may contain 0.01 to 3% by weight of panthenol, 0.01 to 5% by weight of vitamin E, 0.005 to 1% by weight of adenosine, 0.1 to 5% by weight of niacinamide, 0.1 To about 10% by weight of arbutin, about 0.01% to about 10% by weight of EGF, about 0.05% to about 10% by weight of FGF, and about 0.01% to about 20% by weight of mixed fermentation extract. More specifically, the essence emulsion comprises 0.1 to 1 wt% of panthenol, 0.1 to 0.5 wt% of vitamin E, 0.04 wt% of adenosine, 2 wt% of niacinamide, 2 to 7 wt% 0.01 to 1% by weight of EGF, 0.1 to 10% by weight of various plant fermentation complex extracts, and 0.05 to 1% by weight of FGF may be further contained. 0.01 to 3% by weight of sodium hyaruronate, 0.01 to 0.5% by weight of xanthan gum, and 0.01 to 1% by weight may be used in order to give a slight viscosity. Here, various kinds of plant fermentation extracts include green tea fermentation extract, jujube fermentation extract, licorice fermentation extract, angelica fermentation extract, peony fermentation extract, peony fermentation extract, red ginseng fermentation extract, kelp fermentation extract, bank fermentation extract, pomegranate fermentation extract, mugwort fermentation extract, The extract is a combination of two or more fermented extracts alone or in combination.

5. How to use the modeling mask

The use of the time-controlled modeling mask is shown in Fig. High-viscosity modeling when used in a single use When a mask jelly cream base is used as a reference and the activator is mixed with 3 ~ 20g in various amounts and 1 ~ 10g of the serum solution emulsion is added thereto, it is shortened within 3 to 30 minutes . In more detail, firstly, weigh 50 g of high-viscosity modeling mask jelly cream base into a bowl. Second, adjust the amount of activator to 3 ~ 20g, and add an appropriate amount according to the user's intention. Third, 5-10 g of the serum albumin is added thereto, and then the mixture is sufficiently stirred rapidly using a mixing spatula. At this time, the stirring time should be quickly and uniformly mixed until the gel is formed within 20 seconds to 1 minute. Fourth, use a blender to spread it evenly on the face or the required area. Fifth, in 3 to 30 minutes, a modeling mask is produced like a hard and tough rubber pack, and it can be confirmed through actual experiments that the effect of lowering the skin temperature during sedimentation, sedation, and pore reduction effect can be expected at the same time. This makes it possible even without the powder, and maintains a smooth and clean condition without residue on the skin.

Results of hardening time measurement according to activator control Raw material name Experiment 1 Experiment 2 Experiment 3 Experiment 4 Experiment 5 Experiment 6 Experiment 7 Modeling Mask
Jelly Cream Base 50g 50g 50g 50g 50g 50g 50g Activator 3g 5g 7g 8g 10g 15g 20g Beauty essence ampule 3g 4g 5g 5g 5g 5g 10g Curing Time 30 minutes 25 minutes 20 minutes 15 minutes 10 minutes 5 minutes 3 minutes Hardened state ○ ○ ○ ○ ○ ○ ○ Display division Good: Not satisfactory:? Bad: X

As shown in Table 1, the modeling mask base was fixed at 50 g, and the amount of the activator and the amount of the emulsion of the cosmetic solution were adjusted, and the curing rate was measured. As a result, it was found that the curing rate becomes faster as the amount of activator increases. More specifically, it is most preferable to carry out in Experimental Examples 3 to 5.

Comparative Example 1: Composition of a general powder-containing rubber pack division Raw material name COMPARATIVE EXAMPLE 1
(weight%) powder
Base Diatomaceous earth 12.0 kaoline 10.0 Talc 20.0 Titanium dioxide 10.0 Alginic acid 20.0 Calcium sulfate 20.0 Sodium pyrophosphate 8.0 sub Total 100

The composition of the powder base for a commercialized rubber pack is generally as shown in Comparative Example 1 in Table 2. [ In order to compare the performance evaluation of the present invention, the main reason is to reduce the performance error by using the same composition except for the composition used as the material. Compositions were prepared which contained the amounts indicated using diatomaceous earth, kaolin, talc, titanium dioxide, alginic acid, calcium sulfate, and potassium pyrophosphate in the powder base. In the present invention, various experiments were conducted through the composition of Comparative Example 1.

Comparative Examples 2 to 5 in Table 3 below are prescriptions for compositions capable of making rubber packs. In order to reduce errors in prescription and to make a more rational evaluation for various efficacy evaluations, the same active ingredient is added in the same amount to perform clinical evaluation.

Comparative Examples 2 to 5: Composition of powder-containing rubber pack division Raw material name Comparative Example 2 (g) Comparative Example 3 (g) Comparative Example 4 (g) Comparative Example 5 (g) Powder base COMPARATIVE EXAMPLE 1 30.0 30.0 30.0 30.0 water Purified water 60 60 60 60 Soothing soothing Example 11 5 - - - wrinkle improvement Practical Example 12 - 5 - - Whitening Example 13 - - 5 - elasticity Practical Example 14 - - - 5

In a method for producing a powder-containing rubber pack, 30 g of Comparative Example 1 was weighed into a bowl, 60 g of purified water was added thereto, and the serum albumin was added to each of Examples 11 to 14 according to a comparative example. When it is stirred sufficiently, it becomes a thick dough and if it is spread on the skin, it will be made rubber pack like rubber after about 20 ~ 30 minutes.

Examples 1 to 5

In order to develop a composition of a high-viscosity modeling mask, the compositions of the invention are clarified through Examples 1 to 5. Table 4 below shows the preparation method and composition for making the modeling mask jelly cream base in a high-viscosity jelly state.

Raw material name Example 1
(weight%) Practical Example 2
(weight%) Practical Example 3
(weight%) Practical Example 4
(weight%) Practical Example 5
(weight%) Nano emulsion 1.0 5.0 10.0 15.0 20.0 glycerin 3.0 5.0 1.0 10.0 20.0 Butylene glycol 2.0 4.0 5.0 8.0 10.0 PIGGY-60 Hydrogenated Castor Oil 0.5 0.6 0.7 0.8 1.0 Spices 0.1 0.2 0.3 0.4 0.5 Phenoxyethanol 0.8 0.8 0.8 0.8 0.8 Potassium alginate 1.0 2.0 2.5 3.0 3.0 Sodium alginate 1.0 2.0 1.5 2.0 3.0 Baby 0.1 0.2 0.3 0.5 1.0 Tetrapotassium pyrophosphate 0.1 0.3 0.6 0.8 1.0 Calcium carbonate 0.1 0.2 0.3 0.4 0.5 Sodium carbonate 0.1 0.1 0.3 0.5 0.5 Sodium chloride 0.1 0.2 0.3 0.5 1.0 Purified water 90.1 79.4 76.4 57.3 37.7 sub Total 100 100 100 100 100

As shown in Examples 1 to 5, this was accomplished by adding 1 to 20% by weight of a nano emulsion so as to make a modeling mask having a soft, milky and milky white color. Modeling masks containing oil emulsions of nanoparticles have not been developed to date and have been accomplished for the first time through the present invention. Table 4 will be described in more detail as follows. A base substrate used to develop a high quality composition of the modeling mask is a base substrate comprising 1 to 20% by weight of glycerin, 2 to 10% by weight of butylene glycol, 0.5 to 1% by weight of a Pigment-60 hydrogenated castor oil, 0.1 to 0.5% by weight of fragrance and 0.8% by weight of phenoxyethanol were used to improve the moisturizing effect by blending, and the base itself was not hardened and could be stored for a long period of time.

1 to 3% by weight of potassium alginate and 1 to 3% by weight of sodium alginate are suitable as core substrates for forming the gel of the modeling. In order to make the binding force of the modeling harder and have a time control function, % Agar was additionally used. When using this alone, the modeling mask did not come out properly due to the influence of the nano emulsion, and it was found that it has the best binding force when used in combination. This is first dispersed and dissolved, and 0.1 to 1 wt% of sodium chloride, 0.1 to 3 wt% of tetrapotassium pyrophosphate, 0.01 to 1 wt% of calcium carbonate, 0.1 to 1 wt% of sodium carbonate, 0.1 to 1 wt% Of sodium chloride, the stability was further increased when two or more components were added. This was added and sufficiently dispersed, and 0.5 to 20% by weight of nanoemulsions were added thereto to prepare a completed high-viscosity modeling mask jelly cream base. In the case of Example 2, development of the most stable and optimal modeling mask was possible.

Examples 6 to 10

To make the finished product of the time-controlled high-viscosity modeling mask, we want to clarify the composition of the invention through Examples 6-10 in Table 5 below for the development of the activator.

Raw material name Example 6
(weight%) Practical Example 7
(weight%) Example 8
(weight%) Example 9
(weight%) Example 10
(weight%) glycerin 1.0 3.0 5.0 7.0 10.0 Butylene glycol 1.0 4.0 3.0 8.0 10.0 Phenoxyethanol 0.8 0.8 0.8 0.8 0.8 Magnesium sulfate 1.0 5.0 8.0 16.0 20.0 Calcium sulfate 10.0 5.0 2.0 6.0 20.0 Sodium chloride 0.1 0.2 0.3 0.5 1.0 Hydroxyethyl cellulose 0.1 0.2 0.5 0.8 1.0 Methylcellulose 0.1 0.1 0.3 0.5 1.0 Xanthan gum 0.01 0.5 0.7 1.0 2.0 Purified water 85.89 81.2 79.4 59.4 34.2 sub Total 100 100 100 100 100

A time-controlled activator used to develop a high-quality composition of the modeling mask is 1 to 10% by weight of glycerin, 1 to 10% by weight of butylene glycol and 0.8% by weight of phenoxyethanol. The optimal activator could be made when it contained 1 to 20 wt% magnesium sulfate, 2 to 20 wt% calcium sulfate, and 0.1 to 1 wt% sodium chloride. In addition to this composition, it is also possible to use at least two of them. In particular, it is suitable to mix magnesium sulfate and calcium sulfate in a ratio of 1: 1. When 0.1 to 1% by weight of sodium chloride is contained therein, . To make this stable formulation, a stable base activator is made when it contains at least two of 0.1 to 1% by weight of hydroxyethyl cellulose, 0.1 to 1% by weight of methylcellulose and 0.01 to 2% by weight of xanthan gum. .

Examples 11 to 15

The preparation method and composition for producing the liquid and gel-like essence emulsion are described more clearly in Examples 11 to 15 shown in Table 6 below. This embodiment is a step for imparting various high-functioning effects to the modeling mask. Even if it is not particularly included, there is no problem in the basic function of the modeling mask. Since the needs of the customer have recently been demanding higher efficacy, this step is used, and the superior efficacy can be expected.

Raw material name Example 11
(weight%) Practical Example 12
(weight%) Example 13
(weight%) Practical Example 14
(weight%) Example 15
(weight%) function Soothing soothing wrinkle improvement Whitening elasticity Nutrition Plant fermented complex extract 3.0 3.0 5.0 7.0 10.0 Adenosine - 0.04 - - 0.04 Vitamin A solution - 5.0 - - 1.0 Niacinamide - - 2.0 - 2.0 Panthenol 1.0 - 2.0 1.0 5.0 Vitamin E solution 1.0 1.0 2.0 3.0 20.0 Arbutin - - 3.0 - 1.0 Polypeptide - - - 10.0 3.0 EGF solution 1.0 2.0 3.0 5.0 10.0 1,2-hexanediol 2.0 2.0 2.0 2.0 2.0 Ethylhexyl Glycerin 0.1 0.1 0.1 0.1 0.1 Purified water to 100 to 100 to 100 to 100 to 100

Examples 11 to 15 are compositions having a representative function of imparting efficacy by dividing into five functions of soothing soothing effect, wrinkle improving effect, whitening effect, elasticity effect and nutritional supply effect. Here, the mixed fermented extracts of plant fermentation complex are green tea fermentation extract, jujube fermentation extract, licorice fermentation extract, Angelica keiskei extract, angelica fermentation extract, peony fermentation extract, red ginseng fermentation extract, Yeast extract, and honey extract. In particular, the present invention relates to a plant fermented complex extract, which comprises 3 to 10% by weight of a plant fermented complex extract, 0.04% by weight of adenosine, 1 to 3% by weight of panthenol, 0.01 to 5% by weight of vitamin E, 0.1 to 5% 1 to 3% by weight of arbutin, and 1 to 10% by weight of EGF were used. 2% by weight of 1,2-hexanediol and 0.1% by weight of ethylhexyl glycerin were used to preserve the base for a long time.

Raw material name Example 16 (g) Example 17 (g) Example 18 (g) Example 19 (g) Practical Example 2 50.0 50.0 50.0 50.0 Practical Example 7 7.0 8.0 9.0 10.0 Example 11 (Soing) 5.0 - - - Example 12 (wrinkle improvement) - 5.0 - - Example 13 (whitening) - - 5.0 - Example 14 (elasticity) - - - 5.0

5. Clinical Test Results

(1) cooling soothing effect

The cooling effect and the soothing effect were evaluated for Example 16 and Comparative Example 2. In the evaluation method, the skin was exposed to sunlight, and two samples were applied to the skin with reddish erythema, and after 30 minutes, the sample was evaluated for cooling sensation and soothing state under application. The subjects were selected from seven men in their 20s and 40s. The results are shown in Fig. The cooling effect was the average result of the feeling used directly by the subject. The cooling effect was 37.7% in Example 16 and 12.3% in Comparative Example 2. The sedative effect was excellent in Example 16 (29.3%) and in Comparative Example 2 (9.5%).

(2) Wrinkle improvement effect

The effect of improving wrinkles was evaluated in Example 17 and Comparative Example 3. Seven women aged 40-60 years with wrinkles and aging were selected. The degree of improvement of wrinkles was measured after using for 30 days, using Comparative Example 3 on the left side and Example 17 on the right side once a day. The results are shown in Fig. As shown in the results, wrinkles of 11.7% in Comparative Example 3 and 27.2% in Example 17 were reduced. This difference was statistically significant at the 95% confidence interval through t-test. The reason for this is that the modeling mask of Example 17 possesses abundant moisture, and over time, the abundant moisture and active ingredients are released and absorbed into the skin, while the nano oil is absorbed into the skin to make it softer and moist .

(3) Skin whitening effect

In Example 18 and Comparative Example 4, the whitening effect was evaluated. The evaluation method was selected from 10 women and 40 men and 60 women who were blackened. The skin whitening effect was measured after using for 30 days, using Comparative Example 4 on the left side and Example 18 on the right side once per day under the same conditions. The measurement device was a skin color limiter and the brightness of the skin was measured and converted into a percentage. The result is shown in FIG. As shown in the results, the wrinkles of Comparative Example 4 and 28 were reduced by 13.9% and 28.8%, respectively. This difference was statistically significant at the 95% confidence interval through t-test. The reason for this is that the modeling mask of Example 18 is that nano emulsions are absorbed by the skin to make them more soft and moist. As shown in this result, in Example 18, the skin was significantly changed in transparency than in Comparative Example 4.

(4) Increased skin elasticity

The elasticity increase rate was evaluated for Example 19 and Comparative Example 5. The evaluation method was selected from 8 women and 40 women and men who lost blackness. On the left side, Comparative Example 5 and on the right side, Example 19 was used once a day under the same conditions, and after 30 days of use, the elasticity effect was measured. The results are shown in Fig. As shown in the results, wrinkles of 6.7% in Comparative Example 5 and 17.9% in Example 19 were reduced. This difference was statistically significant at the 95% confidence interval through t-test. As shown in this result, in Example 19, the effect of increasing elasticity was significantly higher than that in Comparative Example 5.

6. Skin use of modeling mask

In order to make the discrimination of the present invention clearer, the use of skin of a modeling mask not containing powder is referred to. 13 is a photograph showing the result of using the skin. After the modeling mask is applied to the face, it is soft and firmly hardened in the form of a mask. On the left side is a formulation containing 1% by weight of a nano emulsion, and the right side is a formulation containing 10% by weight of a nano emulsion. In both cases, the concentrated enamel emulsion contains 10 g of Example 11. As shown in the photograph of FIG. 13, an excellent modeling mask can be easily used.

Fig. 14 is a picture taken after 30 minutes using the forearm. The nano emulsion was applied to the forearm of 0.5% for (A), 1% for (B), 10% for (C) and 20% for (D). As shown in the photograph, it does not appear on the forearm, but it shows that it forms a milky white gel state from a translucent gel.

According to the time-regulating modeling mask containing the nano emulsion according to the present invention and using no powder, and a method for manufacturing the same, it is possible to manufacture a highly functional product realizing performance and efficacy in the cosmetics industry, It can be applied as a new formulation to the patch product field of the pharmaceutical industry and the like.

Although the present invention has been described with reference to the accompanying drawings, it is to be understood that various changes and modifications may be made without departing from the spirit of the invention. Therefore, the scope of the present invention should not be limited to the described embodiments, but should be determined by the scope of the appended claims and equivalents thereof.

Claims

As a modeling mask without powder,
Modeling mask A time-controlled modeling mask containing nano-emulsions and no powder, in which the jelly cream base is mixed with a nano emulsion and a time-controlled activator to control the cure rate.

The method according to claim 1,
The modeling mask jelly cream base comprises:
0.1 to 1% by weight of at least one of potassium alginate, 1 to 3% by weight of sodium alginate and 0.1 to 1% by weight of agar, based on the total weight of the modeling mask jelly cream base, Of sodium carbonate, 0.1 to 3% by weight of tetrapotassium pyrophosphate, 0.01 to 1% by weight of calcium carbonate and 0.1 to 1% by weight of sodium carbonate, and is prepared in a jelly form and has a viscosity of 7,000 to 50,000 cps , &Lt; / RTI >
The nano-
Wherein the nano emulsion comprises 10 to 30 wt% of glycerol, 1 to 10 wt% of polyglyceryl-10 myristate, 30 to 60 wt% of mixed oil, and 5 to 30 wt% of purified water, Time-regulating modeling mask containing nano emulsion but no powder.

The method according to claim 1,
The time-controlled activator comprises:
0.01 to 3 wt% of calcium sulfate, 0.1 to 20 wt% of magnesium sulfate, and 0.01 to 5 wt% of sodium chloride, based on the total weight of the time-controlled activator, Of hydroxyethyl cellulose, 0.01 to 2% by weight of methylcellulose, and 0.01 to 1% by weight of xanthan gum, wherein the powder is not powdered and contains nano emulsions.

The method according to any one of claims 1 to 3,
It contains liquid or gel-like essence emulsion for skin improvement,
The above-
0.1 to 0.5% by weight of vitamin E, 0.01 to 0.1% by weight of adenosine, 1 to 3% by weight of niacinamide, 2 to 7% by weight of arbutin , 0.01 to 1% by weight of EGF and 0.1 to 10% by weight of mixed fermentation extract, wherein the mixed fermentation extract contains green tea fermentation extract, jujube fermentation extract, licorice fermentation extract, angelica fermentation extract, A time-regulating modeling mask containing a nano emulsion and containing no powder, which comprises at least two selected from the group consisting of tungsten fermented extract, bank fermented extract, pomegranate fermented extract, mugwort fermented extract, yeast extract and honey extract.

A method of manufacturing a modeling mask that does not use powder,
Mixing the modeling mask jelly cream base, the liquid emulsion on the liquid or gel, and the time-controlled activator in a ratio of 50: 3-25 : A method of producing a time-regulating modeling mask containing nano emulsions and not using a powder, wherein the curing speed of the modeling is 3 to 30 minutes through a step of mixing and gelling at a weight ratio of 1 to 20.

The method of claim 5,
The modeling mask jelly cream base comprises:
0.1 to 1% by weight of at least one of potassium alginate, 1 to 3% by weight of sodium alginate and 0.1 to 1% by weight of agar, based on the total weight of the modeling mask jelly cream base, Of sodium carbonate, 0.1 to 3% by weight of tetrapotassium pyrophosphate, 0.01 to 1% by weight of calcium carbonate and 0.1 to 1% by weight of sodium carbonate, and is prepared in a jelly form and has a viscosity of 7,000 to 50,000 cps , &Lt; / RTI >
The nano-
Wherein the nano emulsion comprises 10 to 30 wt% of glycerol, 1 to 10 wt% of polyglyceryl-10 myristate, 30 to 60 wt% of mixed oil, and 5 to 30 wt% of purified water, A method of preparing a time - regulating modeling mask containing nano emulsion while not using powder.

The method according to claim 5 or 6,
The time-controlled activator comprises:
0.01 to 3 wt% of calcium sulfate, 0.1 to 20 wt% of magnesium sulfate, and 0.01 to 5 wt% of sodium chloride, based on the total weight of the time-controlled activator, By weight of hydroxyethyl cellulose, 0.01 to 2% by weight of methylcellulose, and 0.01 to 1% by weight of xanthan gum. .