KR20120126148A - The hairdye composition for oxidadation dyeing that including ecklonia cava extract - Google Patents
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Abstract
Description
본 발명은 감태(Ecklonia cava)에서 추출한 플로로탄닌(phlorotannin) 혼합물을 함유하는 산화염색용 염모제 조성물에 관한 것이다. The present invention relates to a hair dye composition for oxidation dye containing a mixture of phlorotannin extracted from Ecklonia cava .
일반적으로 모발 색을 변화시키기 위한 염모제는 염모 효과의 지속성에 따라 일시 염모제, 반영구 염모제, 영구 염모제로 분류된다. Generally, hair dyes for changing hair color are classified into temporary hair dyes, semi-permanent hair dyes, and permanent hair dyes according to the persistence of the hair dye effect.
이중에서 지속성이 가장 좋은 영구 염모제(산화염모제)는 통상 파라페닐렌디아민 등의 방향족 아미노 화합물로 대표되는 산화염료를 포함하는 1제와 2제의 혼합액을 도포하여 모발 내부에서 거대 염료분자가 축합 중합되므로 염모력이 높고 색의 지속력이 좋은 장점이 있다. Among them, the permanent hair dye (oxidative hair dye), which has the best persistence, is usually coated with a mixture of a first agent and a second agent containing an oxidative dye represented by an aromatic amino compound such as paraphenylenediamine. Because of the high dyeing force and the persistence of the color has the advantage.
보다 좋은 염모제 조성물을 개발하기 위한 노력이 이루어지고 있다. Efforts have been made to develop better hair dye compositions.
한국공개특허공보 10-2007-0068881 '천연 식물 소재를 이용한 염모제용 조성물'에는, 솔잎, 소나무피, 은행나무피, 두충잎, 두충열매, 창포잎, 오가피잎, 감잎, 복분자 열매, 구기자잎, 음양곽잎 등으로 부터 선택되는 어느 하나 이상의 분말, 열수추출물, 또는 알콜추출물을 유효성분으로 함유하는 염모제용 조성물에 관한 것이 공개되어 있다. Korean Patent Laid-Open Publication No. 10-2007-0068881 'The composition for hair dye using natural plant material' includes pine needles, pine bark, ginkgo bark, sesame leaf, soybean fruit, iris leaf, organ leaf, persimmon leaf, bokbunja fruit, goji berry leaf, Disclosed is a composition for hair dyes containing any one or more powders, hot water extracts, or alcohol extracts selected from Yin-Yang leaves and the like as active ingredients.
한국공개특허공보 10-2008-0070167 '감(잎) 탄닌을 함유하는 산화 염모제용 조성물'에는, 산화염료 전구체 및 커플러를 함유하는 염모제 조성물에 있어서, 감 또는 감잎에서 추출, 용해, 분리된 감잎 탄닌 또는 감잎 추출물을 함유하는 것을 특징으로 하며, 상기 감잎 탄닌은 열탕추출법 또는 오코니법(Okoni법) 또는 용매추출법에 의해 추출된 것으로, catechin, gallocatechin, proanthocyanidin group에 속하는 물질을 포함하는 축합형 탄닌의 혼합물인 것을 특징으로 하는 산화염색용 염모제 조성물에 관한 것이 공개되어 있다. Korean Laid-Open Patent Publication No. 10-2008-0070167 'The composition for oxidative hair dye containing persimmon (leaf) tannin' is a persimmon leaf tannin extracted, dissolved and separated from persimmon or persimmon leaf in a hair dye composition containing an oxidized dye precursor and a coupler. Or persimmon leaf extract, wherein the persimmon leaf tannin is extracted by boiling water extraction method or Oconi method (Okoni method) or solvent extraction method, of the condensed tannin containing a substance belonging to catechin, gallocatechin, proanthocyanidin group Disclosed is a hair dye composition for oxidation dyeing, which is a mixture.
한국공개특허공보 10-2009-0056200 '오배자 또는 한련초를 함유하는 산화염색용 염모제 조성물'에는, 산화염료 전구체, 커플러 및 알칼리제를 함유하는 제1제와 산화제를 함유하는 제2제로 구성되는 케라틴 섬유의 산화염색용 염모제 조성물에 있어서, 상기 제1제는 천연 항산화물질로서 오배자, 한련초 또는 이의 혼합물을 함유하는 것을 특징으로 하는 케라틴 섬유의 산화염색용 염모제 조성물에 관한 것이 공개되어 있다. Korean Patent Laid-Open Publication No. 10-2009-0056200 'Oxidation dye-dye composition containing a gall bladder or nasturtium' includes a keratin fiber composed of a first agent containing an oxidizing dye precursor, a coupler and an alkali agent and a second agent containing an oxidizing agent. In the hair dye composition for oxidative dyeing, the first agent is disclosed as a hair dye composition for oxidative dyeing of keratin fibers, characterized in that it contains a quintet, nasturtium or a mixture thereof as a natural antioxidant.
한편, 감태(Ecklonia cava)는 미역과에 속하는 해조류로서 제주도를 포함한 남해안 일대에 서식한다. Ecklonia cava , on the other hand, is a seaweed belonging to the seaweed family and lives in the southern coastal area including Jeju Island.
감태에는 바다식물의 폴리페놀(polyphenol)이라고 하는 플로로탄닌(phlorotannin)이 많이 함유되어 있다. Ecklonia pollen contains a lot of phlorotannin called polyphenols.
감태의 플로로탄닌은 열에 안정하며, 친수성이 강한 페놀릭 하이드록실기(phenolic hydroxyl group)를 매우 많이 가지고 있어서 고농도에서는 쉽게 겔화가 되고, 고분자 물질로서 수소 결합 및 비공유결합과 같은 결합이나 콤플렉스를 형성하는 등 다양한 반응성을 가지고 있다. Phlorotannin of Ecklonia cava is thermally stable and has a very high hydrophilic phenolic hydroxyl group, so it is easily gelled at high concentrations and forms a bond or complex such as a hydrogen bond or a non-covalent bond as a polymer material. It has various reactivity.
한편, 산화염색용 염모제 조성물에 있어서, 염색성을 향상시키고, 염색 지속성을 장기간 유지시키며, 알칼리제나 기타 다른 화학성분에 의한 모발 손상을 최소화시킬 수 있는 염모제 조성물의 개발이 필요한 실정이다. On the other hand, in the hair dye composition for oxidative dyeing, there is a need for the development of a hair dye composition which can improve dyeability, maintain dyeing duration for a long time, and minimize hair damage caused by alkali or other chemical components.
본 발명은 상기와 같은 문제점을 해결하기 위한 것으로, 염색시 산화염색용 염모제 조성물의 모발 침투력을 향상시켜 심색 염색을 가능하게 하는 데 있다.The present invention is to solve the above problems, to improve the hair penetration of the hair dye composition for oxidation dye during dyeing to enable deep color dyeing.
또한, 염색된 색상을 지속적으로 유지하고, 나아가서 염색으로 인한 모발 손상을 최소화시키며, 모발의보습 및 컨디셔닝을 향상시키는 산화염색용 염모제 조성물을 제공하는 데 그 목적이 있다. It is also an object of the present invention to provide a hair dye composition for oxidative dyeing, which continuously maintains dyed color, further minimizes hair damage due to dyeing, and improves moisturizing and conditioning of hair.
본 발명은 감태(Ecklonia cava)에서 추출한 플로로탄닌(phlorotannin) 혼합물을 함유하는 산화염색용 염모제 조성물을 제공한다.The present invention provides a hair dye composition for oxidation dyeing containing a mixture of phlorotannin extracted from Ecklonia cava .
상기 감태에서 추출한 플로로탄닌 혼합물은 열탕추출법 또는 용매추출법에 의해 추출된다. The phlorotannin mixture extracted from the Ecklonia cava is extracted by hot water extraction or solvent extraction.
상기 감태에서 추출한 플로로탄닌 혼합물은, 플로로글루시놀(phloroglucinol), 플로로탄닌A(phlorotanninA), 에콜(eckol), 디에콜(dieckol), 8,8'-비에콜(8,8'-bieckol), 플로로푸코푸코에콜A(phlorofucofucoeckolA), 6,6'-비에콜(6,6'-bieckol), 트리플로로에톨A(triphloroetholA), 플로로에콜(phloroeckol), 푸코디플로레톨E(fucodiphlorethol E), 또는 이들의 복합체의 혼합물로서 분말상 또는 용액상인 것을 사용한다. The phlorogannin mixture extracted from the Ecklonia cava is phloroglucinol, phlorotannin A, ecol, dieckol, 8,8'-bicol, 8,8'- bieckol), phlorofucofucoeckol A, 6,6'-bieckol, triploroethol A, phloroeckol, fucodifloletol As a mixture of fucodiphlorethol E, or a complex thereof, those used in powder or solution form are used.
상기 플로로탄닌 혼합물을 구성하는 성분들의 화학식을 도 1에 나타냈다. The chemical formulas of the components constituting the phlorotannin mixture are shown in FIG. 1.
한편, 감태에서 추출한 플로로탄닌 혼합물은 조성물 전체중량 대비 0.001 ~ 10 중량% 함유하는 것이 바람직하다. On the other hand, the phlorotannin mixture extracted from the Ecklonia chinensis is preferably contained 0.001 ~ 10% by weight relative to the total weight of the composition.
0.001 중량% 이하에서는 본 발명의 효과를 기대하기 어렵고, 10 중량% 이상에서는 오히려 효과가 떨어진다. If it is 0.001 weight% or less, the effect of this invention is hard to expect, but the effect falls rather than 10 weight% or more.
본 발명의 감태에서 추출한 플로로탄닌 혼합물을 함유하는 산화염색용 염모제 조성물은, 모발 내부로의 염모제 조성물의 침투를 향상시키고, 모발 내외부에 침착을 증대시켜 염색효과를 높인다. The dyeing agent composition for oxidation dyeing containing the phlorotannin mixture extracted from the Ecklonia cava of the present invention improves the penetration of the dyeing agent composition into the inside of the hair and increases the deposition inside and outside the hair to enhance the dyeing effect.
그리고 이미 발색된 모발의 색상 지속력을 향상시킨다.It also improves the color lasting of hair already developed.
또한 플로로탄닌의 수렴 및 함수 작용으로 모발의 보습력을 향상시키며, 모발의 프로테인과 결합을 형성하여 모발을 보호하는 효과를 나타낸다.In addition, the condensation and water function of phlorotannin improves the moisturizing power of the hair, and forms a bond with the protein of the hair to protect the hair.
도 1은 본 발명의 감태에서 추출한 플로로탄닌 혼합물을 구성하는 성분들의 화학식을 나타낸 도면이다.1 is a view showing the chemical formula of the components constituting the phlorotannin mixture extracted from the Ecklonia cava of the present invention.
본 발명의 감태에서 추출한 플로로탄닌 혼합물을 함유하는 산화염색용 염모제 조성물에 대하여 상세히 설명한다. The hair dye composition for oxidation dyeing containing the phlorotannin mixture extracted from the Ecklonia cava of the present invention will be described in detail.
감태에서 추출한 플로로탄닌은 열에 안정하여 열탕추출법으로 얻을 수 있으며, 다양한 용제를 이용하여 감태에서 플로로탄닌 성분을 분리, 추출, 용해할 수 있다. Phlorotannin extracted from Ecklonia cava is stable to heat and can be obtained by boiling water extraction method. It is possible to separate, extract, and dissolve phlorotannin from Ecklonia cava using various solvents.
따라서 본 발명은 특정한 추출법 및 용해법을 규정하지 않으며, 분말상으로 얻어지는 감태 플로로탄닌뿐만 아니라 증류수, 에탄올, 메탄올, 1,3-부틸렌글리콜 등과 같은 다양한 용제를 이용하여 추출해낸 용액도 사용가능하다. Therefore, the present invention does not define a specific extraction method and dissolution method, it is possible to use a solution extracted using various solvents such as distilled water, ethanol, methanol, 1,3-butylene glycol, as well as Ecklonia phlorotannin obtained in powder form.
본 발명에 따른 감태 플로로탄닌은 여러 개가 결합하여 색상을 발현 할 수 있는 구조로 전환되며, 철, 구리 등과 같은 금속과 함께 반응할 때는 섬유에 착색 및 염착성을 상승시킨다.Ecklonia phlorotannin according to the present invention is converted to a structure that can express the color by combining a plurality, and when reacted with metals such as iron, copper and the like to increase the coloring and dyeing property to the fiber.
또한, 본 발명에 따른 감태 플로로탄닌은 수산화기가 많은 phenolic condensed tannin계열로서 이온화된 말단 잔기를 많이 가지고 있다. In addition, the Ecklonia phlorotannin according to the present invention is a phenolic condensed tannin series having many hydroxyl groups and has many ionized terminal residues.
이러한 이온성 잔기들은 모발 잔기의 이온화된 잔기와 이온성 결합 및 수소 결합이 가능하며, 철, 구리 등과 같은 금속성과는 모발에서 배위결합까지 가능하다. These ionic moieties are capable of ionic bonds and hydrogen bonds with the ionized moieties of the hair moieties, and metallic properties, such as iron and copper, can be coordinated from hair to coordination.
특히 모발 단백질 중에 프로린이 풍부한 단백질(prolin rich protein)로서 콜라겐과 프로아민(proamine)은 탄닌과의 다중 결합 및 콤플렉스 형성이 가능하다. In particular, collagen and proamine as prolin rich proteins in hair proteins are capable of multiple bonds and complex formation with tannins.
이러한 탄닌의 특징은 모발에 적용될 때 알칼리에 의하여 노출된 모발 단백질의 잔기에 위치하여(blocking) 모발의 추가의 손상을 막아 주고, 더 나아가 모발 잔기와의 결합으로 모발을 강화시킬 수 있는 기능을 할 수 있다. This characteristic of tannins prevents further damage of the hair by blocking the residues of the hair proteins exposed by alkali when applied to the hair, and further function to strengthen the hair by binding to the hair residues. Can be.
이러한 기능이 산화형 염모제를 사용하면서 발생할 수 있는 다수의 두피 트러블을 예방할 수 있다. This can prevent many of the scalp problems that can occur when using oxidative hair dyes.
또한 탄닌 구조가 다수의 이온잔기를 가지는 phenolic group을 가짐으로써 함수의 능력이 뛰어나고, 모발 보습 등과 같은 역할 또한 가능하다.In addition, tannin structure has a phenolic group having a large number of ionic residues, so the function of the function is excellent, and it is also possible to play a role in moisturizing hair.
본 발명의 산화염색용 염모제 조성물은 산화염색용 염모제 조성물에 사용되는 통상적인 산화염료 전구체와 커플러를 함유한다. 산화 염료 전구체 및 커플러로는 현재 알려진 대부분의 산화 염료 중간체와 커플러를 본 발명에 사용할 수 있다. The dyeing agent composition for oxidation dyeing of the present invention contains a conventional oxidation dye precursor and coupler used in the dyeing agent composition for oxidation dyeing. As the oxidation dye precursors and couplers, most of the currently known oxidation dye intermediates and couplers can be used in the present invention.
이와 같은 산화염료 전구체로는 o-아미노페놀, p-아미노페놀, 염산톨루엔-2,5-디아민, 염산p-페닐엔디아민, 톨루엔-2,5-디아민, p-페닐렌디아민, 황산p-메칠아미노페놀, 황산o-아미노페놀, 황산p-아미노페놀, 황산톨루엔-2,5-디아민, 황산p-페닐렌디아민 등을 들 수 있으며 그 종류와 조합을 한정하지 않는다. Such oxidizing dye precursors include o-aminophenol, p-aminophenol, toluene-2,5-diamine hydrochloride, p-phenylenediamine hydrochloride, toluene-2,5-diamine, p-phenylenediamine, and sulfuric acid p- Methylaminophenol, sulfate o-aminophenol, p-aminophenol sulfate, toluene-2,5-diamine sulfate, p-phenylenediamine sulfate, and the like.
산화 염료 전구체의 배합량은 조성물 총 중량을 기준으로 0.05 ~ 5 중량 %(염으로 존재하는 경우에는 유리염기로서)인 것이 바람직하고, 더욱 바람직하게는 0.25 ~ 1.5 중량 %를 함유한다.The blending amount of the oxidizing dye precursor is preferably 0.05 to 5% by weight (as free base, if present as a salt) based on the total weight of the composition, more preferably 0.25 to 1.5% by weight.
또한, 커플러로는 2-메칠-5-하이드록시에칠아미노페놀, p-아미노-o-크레솔, m-아미노페놀, 염산 2,4-디아미노페녹시에탄올, 염산 m-페닐렌디아민, m-페닐렌디아민, N-메칠-p-페닐렌디아민, 황산p-아미노-o-크레솔, 황산4-에톡시-m-페닐렌디아민, 황산m-페닐렌디아민, a-나프톨, 레소르시놀, 2-메칠레소르시놀 등을 들 수 있으며, 그 종류와 조합은 한정하지 않는다.As couplers, 2-methyl-5-hydroxyethylaminophenol, p-amino-o-cresol, m-aminophenol, 2,4-diaminophenoxyethanol hydrochloride, m-phenylenediamine hydrochloride, m-phenylenediamine, N-methyl-p-phenylenediamine, p-amino-o-cresol sulfate, 4-ethoxy sulfate m-phenylenediamine, m-phenylenediamine sulfate, a-naphthol, les Sorcinol, 2-methyl sorbinol, etc. are mentioned, The kind and combination are not limited.
본 발명의 산화염색용 염모제 조성물에는 본 발명의 목적을 저해하지 않는 범위 내에서 통상적으로 사용되는 직접염료를 더 참가할 수 있다. In the dyeing composition for oxidation dyeing of the present invention, a direct dye commonly used within the range of not impairing the object of the present invention can be further added.
이러한 직접염료로는 아리아놀(Arianol) 염료, p-니트로-o-페닐렌디아민, 니트로-p-페닐렌디아민, 2-아미노-4-니트로페놀, 2-아미노-5-니트로페놀, 염산니트로-p-페닐렌디아민, 피크라미산, 기타 식물성 염료인 헨나(Henna) 등을 들 수 있다.Such direct dyes include arianol dye, p-nitro-o-phenylenediamine, nitro-p-phenylenediamine, 2-amino-4-nitrophenol, 2-amino-5-nitrophenol, nitro hydrochloride -p-phenylenediamine, picramimic acid, and other vegetable dyes such as Henna.
본 발명의 염모제 조성물에는 염모제에 통상적으로 사용되는 성분을 본 발명의 효과를 떨어뜨리지 않는 범위 내에서 사용할 수 있다. The hair dye composition of the present invention can be used within the range that does not impair the effects of the present invention, components commonly used in hair dyes.
예를 들면 알칼리제로서 암모니아, 모노에탄올아민 및 아미노메칠프로판올 등이 사용되며, 점증제로 비이온계면활성제나 알킬디에탄올아미드가 사용되며, 계면활성제로는 양이온, 음이온, 비이온 계면활성제가 사용된다. 또, 컨디셔닝제로 4급화 암모늄염 및 4급화 폴리머를 사용할 수 있다. For example, ammonia, monoethanolamine, aminomethylpropanol, and the like are used as the alkali agent, and nonionic surfactants or alkyldiethanolamides are used as thickeners, and cationic, anionic, and nonionic surfactants are used as surfactants. In addition, quaternary ammonium salts and quaternized polymers can be used as the conditioning agent.
이러한 염모제 조성물은 적절한 성분을 사용하며 크림타입, 겔상, 액상, 에어로졸상 등 적절한 제형으로 만들 수 있다.Such hair dye compositions can be formulated into suitable formulations using appropriate ingredients and including cream, gel, liquid, and aerosol phases.
본 발명의 염모제 조성물은 중성 내지 알칼리의 pH 범위에서 사용할 수 있으나 특히 알칼리 조건에서 효과적이다.The hair dye composition of the present invention can be used in the pH range of neutral to alkali, but is particularly effective in alkaline conditions.
본 발명에 따른 염모제 조성물의 사용방법은 다음과 같다. How to use the hair dye composition according to the present invention is as follows.
본 발명의 염모제 조성물은 사용 직전에 과산화물, 예를 들면 6% 과산화수소를 함유한 산화제와 혼합한 후 모발에 도포하고 5 ~ 20분간 처리한 후 통상의 샴푸와 물로 헹구어낸다. The hair dye composition of the present invention is mixed with an oxidizing agent containing peroxide, for example 6% hydrogen peroxide immediately before use, applied to the hair, treated for 5 to 20 minutes, and then rinsed with conventional shampoo and water.
본 발명에 따른 산화염색용 염모제 조성물은 용해, 분리, 추출된 감태 플로로탄닌을 포함한다. The dyeing agent composition for oxidation dyeing according to the present invention comprises soluble phlorotannin extracted, separated and extracted.
이러한 감태 플로로탄닌이 포함된 염모제는 염료의 모발 내부로의 침투를 향상시키고, 모발 내외부에 염료의 침착 및 착색을 증대시켜 염색효과를 상승시킨다.The hair dye containing the Ecklonia phlorotannin improves the penetration of the dye into the hair and enhances the dyeing effect by increasing the deposition and coloring of the dye inside and outside the hair.
그리고 이미 발색된 모발의 색상 지속력을 향상시킨다. It also improves the color lasting of hair already developed.
또한 탄닌의 수렴 및 함수 작용으로 모발의 프로테인과의 수소결합 및 이온결합 등과 같은 반응, 결합, 콤플렉스를 형성하여 알칼리제에 의해 손상된 모발을 보호 한다. In addition, by converging and hydrating the tannins, hairs damaged by alkaline agents are protected by forming reactions, bonds, and complexes such as hydrogen bonds and ionic bonds with the protein of the hair.
이하, 본 발명을 구체적으로 설명하기 위해 실시예를 들어 상세하게 설명하면 다음과 같다. 본 발명에 따른 실시예들은 여러 가지 다른 형태로 변형 될 수 있으며, 본 발명의 범위가 아래에서 상술하는 실시예들에 한정되는 것으로 해석되어서는 안 된다. Hereinafter, the present invention will be described in detail with reference to Examples. Embodiments according to the present invention can be modified in many different forms, the scope of the invention should not be construed as limited to the embodiments described below.
< 감태에서 플로로탄닌 혼합물의 추출 > <Extraction of Florotannin Mixture from Ecklonia>
제주 연근해 해안에서 채취한 감태를 흐르는 물에 세척하여 소금기를 제거한 후, 음지에서 5일간 건조시켰다. The Ecklonia cava collected from the coast of Jeju offshore was washed with running water to remove salt, and then dried in the shade for 5 days.
건조된 감태 100 g을 미분쇄하여 80% ethanol 2 ℓ를 이용하여 상온에서 1주일간 침출시켰다. 100 g of dried Ecklonia cava was ground and leached at room temperature for 1 week using 2 L of 80% ethanol.
추출된 용액을 여과하여 액상을 취한 다음, 감압 농축하여 13.0g의 분말을 수득하였다. The extracted solution was filtered to give a liquid phase, and then concentrated under reduced pressure to obtain 13.0 g of a powder.
수득된 분말을 다시 30% ethanol 1 ℓ를 이용하여 1일간 상온에서 침출시켰다. The obtained powder was again leached at room temperature for 1 day using 1 L of 30% ethanol.
추출된 용액을 여과하여 액상을 취한 다음, 감압 농축하여 분말상의 본 발명의 플로로탄닌 혼합물 5.2g을 얻었다.The extracted solution was filtered to give a liquid phase, and then concentrated under reduced pressure to obtain 5.2 g of the powdered phlorotannin mixture of the present invention.
< 산화염색용 염모제 조성물의 제조 ><Preparation of hair dye composition for oxidation dyeing>
아래 표 1에 나타난 성분과 함량으로(단위는 중량 %임), 정제수에 염료, 프로필렌글리콜, 아황산나트륨, EDTA.4Na, 스테아트리모늄 클로라이드, 미네랄오일, 세틸알콜, 감태 추출 플로로탄닌 혼합물, 폴리옥시 에틸렌세틸 에테르를 넣고 80 ℃까지 가온 용해 후에 혼합하여 유화하였다. According to the ingredients and contents shown in Table 1 below (unit is weight%), dye, propylene glycol, sodium sulfite, EDTA.4Na, sterimonium chloride, mineral oil, cetyl alcohol, Ecklonia cava fluorotannin mixture in purified water, Polyoxy ethylene cetyl ether was added thereto, heated to 80 ° C., dissolved, mixed and emulsified.
이어서, 40 ℃까지 냉각한 다음, 모노에탄올아민, 강암모니아수(28%) 및 조합향을 넣어 균일하게 혼합하여 산화염색용 염모제 조성물을 제조하였다.Subsequently, after cooling to 40 ° C., monoethanolamine, strong ammonia water (28%), and a combination of flavors were added and mixed uniformly to prepare a dyeing composition for oxidation dyeing.
(경질유동이소파라핀)Mineral oil
Hard Flow Isoparaffin
상기 실시예에 따라 제조된 산화염색용 염모제 조성물에 대해서 발색력, 컨디셔닝감, 경시 안정성, 물빠짐에 의한 색상 지속성을 아래와 같은 실험을 통하여 평가하였다.For the dyeing agent composition for oxidation dyeing prepared according to the above example, color development, conditioning, temporal stability, and color persistence due to water drainage were evaluated through the following experiment.
<발색력 평가><Color evaluation>
상기 비교(예1, 예2, 예3) 및 실시(예1, 예2, 예3, 예4)에 따라 제조한 산화염색용 염모제 조성물을 6% 과산화수소 용액과 1:1로 혼합한 다음, 실험용 사람 모발에 도포하고 10분 경과 후에 샴푸로 씻어내고 건조하였다.After mixing the dyeing agent composition for oxidation dyeing prepared according to the comparison (Example 1, Example 2, Example 3) and Example (Example 1, Example 2, Example 3, Example 4) with 6% hydrogen peroxide solution 1: 1, It was applied to experimental human hair, and after 10 minutes, washed with shampoo and dried.
건조 후에 모발상에서의 발색력 차이를 전문 패널 9명이 평가하여 그 결과를 표 2에 나타냈다. After drying, nine specialized panelists evaluated the difference in color development on the hair and the results are shown in Table 2.
◎ : 발색력 우수, ○ : 발색력 양호, △ : 발색력 다소 약함, X : 발색력 약함 ◎: excellent color development ability ○: good color development ability, △: color development power slightly weak, X: color development power weak
<컨디셔닝감 평가><Condition evaluation>
상기 비교예 및 실시예에 따라 제조한 산화염색용 염모제 조성물을 6% 과산화수소 용액과 1:1로 혼합한 다음, 준비된 실험용 사람 모발에 도포하고 10분 경과 후에 샴푸로 씻어내고 건조하였다. The hair dye composition for dyeing oxide prepared according to Comparative Examples and Examples was mixed 1: 1 with 6% hydrogen peroxide solution, and then applied to the prepared experimental human hair, and after 10 minutes, washed with shampoo and dried.
건조 후에 모발상에서의 컨디셔닝 차이를 전문 패널 9명이 평가하여 그 결과를 표3에 나타냈다.After drying, nine expert panelists evaluated the difference in conditioning on hair and the results are shown in Table 3.
◎ : 컨디셔닝감 매우 좋음, ○ : 컨디셔닝감 다소 좋음, - : 컨디셔닝감 보통, X : 컨디셔닝감 매우 나쁨 ◎: Very good conditioning, ○: Somewhat good,--Normal, X: Very bad
<경시 안정성 평가>Evaluation of stability over time
또한 각 비교예 및 실시예로 제조된 염모제조성물을 50 ℃ 항온기에서 2 개월간 관찰하여 고온 경시 안정성을 평가하였으며, 그 결과를 하기 표4에 정리하였다.In addition, the hair dye composition prepared in each of Comparative Examples and Examples was observed for 2 months at 50 ℃ thermostat to evaluate the stability over time at high temperature, the results are summarized in Table 4 below.
◎ : 염료석출 및 변색 없음, ○ : 변색은 없으나 염료 다소 석출 ◎: No dye precipitation or discoloration, ○: No discoloration but dye precipitation
<색상 지속성 평가><Color Persistence Assessment>
상기 실시예 및 비교예에 따라 제조한 산화염색용 염모제 조성물을 샴푸 견뢰도 테스트용 모발과 울포에 염색한 후 40 SLES 1% 수용액에 넣은 후 20분간 교반함을 4회 반복하여 샴푸 견뢰도 (물빠짐)테스트를 실시하였다.After dyeing the hair dye composition for oxidative dyeing according to the Examples and Comparative Examples to the hair and wool for the shampoo fastness test, put it in 40 SLES 1% aqueous solution and stir for 20 minutes to repeat the shampoo fastness (dripping) The test was conducted.
물빠짐 전후의 모발 색상 차이는 전문 패널 9 명이 평가하였다. Differences in hair color before and after flushing were evaluated by nine expert panelists.
울포의 색차는 색차계(KONICA MINOLTA, CHOROMA CETER CR-400)를 이용하여 색차를 측정하여 그 결과를 표 5에 나타냈다. The color difference of Wolfo was measured using a color difference meter (KONICA MINOLTA, CHOROMA CETER CR-400) and the results are shown in Table 5.
색차 측정은 각 값마다 3회 반복 측정 후 평균치를 기록하였다. The color difference measurement recorded the average value after repeated measurements three times for each value.
◎ : 물빠짐 후에도 색상 차이 적음, ○ : 색상 차이 다소 있음, ◎: even after dripping less color difference, ○: Some color difference,
△ : 색상 차이 심함, X : 색상 차이 매우 심함. △: severe color difference, X: very different color.
본 발명에 의해 염모제 조성물이 모발 내부로 침투가 향상되고, 모발 내외부에 침착 및 착색을 증대시켜 염색효과를 상승시키는 감태에서 추출한 산화염색용 염모제조성물이 제공된다. According to the present invention, there is provided a dyeing composition for oxidation dyeing, which is extracted from Ecklonia cava, in which the hair dye composition improves penetration into the hair and increases deposition and coloring inside and outside the hair to increase the dyeing effect.
또한, 이미 발색된 모발의 색상 지속력을 향상시켜 모발에서 염색 견뢰도를 증진시키며, 탄닌의 수렴 및 함수 작용으로 모발 보습력을 향상시키며, 모발의 프로테인과 결합을 형성하여 알칼리제에 의한 모발을 보호하는 산화염색용 염모제 조성물이 제공된다. In addition, it improves the color fastness of the already developed hair, improves the color fastness in the hair, improves the hair's moisturizing ability by converging and functioning tannins, and forms a bond with the protein of the hair to protect the hair by alkali chemicals. A hair dye composition is provided.
Claims (4)
감태(Ecklonia cava)에서 추출한 플로로탄닌(phlorotannin) 혼합물을 함유하는 것을 특징으로 하는 산화염색용 염모제 조성물. In the hair dye composition for oxidation dyeing,
A dyeing composition for oxidation dyeing, comprising a mixture of phlorotannin extracted from Ecklonia cava.
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| KR100933423B1 (en) * | 2008-02-04 | 2009-12-22 | 김두경 | Dyeing Method Using Ecklonia Dye for Improving Color Fastness in Galcheon, Jeju |
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| KR20190046681A (en) * | 2017-10-26 | 2019-05-07 | 주식회사 보타메디 | Compositions containing phlorotannin for cooling skin and product thereof |
| KR102672429B1 (en) * | 2023-03-17 | 2024-06-04 | 김주현 | Manufacturing method of ink composition for functional scalp coloring |
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