KR20100105930A - Back sheet for module, its manufacturing method and its manufacturing apparatus thereof - Google Patents

Back sheet for module, its manufacturing method and its manufacturing apparatus thereof Download PDF

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KR20100105930A
KR20100105930A KR1020090024294A KR20090024294A KR20100105930A KR 20100105930 A KR20100105930 A KR 20100105930A KR 1020090024294 A KR1020090024294 A KR 1020090024294A KR 20090024294 A KR20090024294 A KR 20090024294A KR 20100105930 A KR20100105930 A KR 20100105930A
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South Korea
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film
silica
pet film
solar cell
back sheet
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KR1020090024294A
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Korean (ko)
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KR101022820B1 (en
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이정민
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이정민
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/048Encapsulation of modules
    • H01L31/0481Encapsulation of modules characterised by the composition of the encapsulation material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/048Encapsulation of modules
    • H01L31/049Protective back sheets
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

Abstract

PURPOSE: A back sheet for a solar cell module, a manufacturing method thereof, and a manufacturing apparatus thereof are provided to obtain high insulation by laminating a fluorine resin layer one side of a PET film and a silica film on the other side of the PET film. CONSTITUTION: A fluorine resin layer(20) is laminated on one side of a PET film(10). A silica film(30) is adhered to the other side of the PET film with adhesive. The fluorine resin layer blocks steam and provides high adhesion. The silica film includes a base film(31) and a silica deposition layer(32). The base film is polyester resin, polyolefin resin, or polyimide resin.

Description

Backsheet for module, its manufacturing method and its manufacturing apparatus

The present invention relates to a back sheet for a solar cell module, a manufacturing method, and a device thereof, wherein a PET film coated with a fluorine resin and a silica film deposited with silica are laminated on one side thereof to provide high moisture resistance and weather resistance. The present invention relates to a module backsheet, a manufacturing method and an apparatus thereof.

As global warming has emerged as a global problem, the Kyoto Protocol, signed in 1997 with a focus on developed countries (except the United States) as an effective reduction measure in 1992, reduced greenhouse gas emissions such as carbon dioxide in 1990-2012 to prevent global warming. It is supposed to reduce by more than 5% based on annual emissions by member countries.

Humanity is now paying attention to renewable energy as an alternative to overcoming the fundamental problems of fossil fuels without sacrificing the current quality of life.

Photovoltaic technology is a technology that converts solar energy into electrical energy using a medium called a solar cell module. Since there is no mechanical or chemical action in the process of converting solar energy into electrical energy, the system structure is simple and requires little maintenance. Long life, safe and environmentally friendly.

The solar cell module is composed of metal wire that electrically connects low iron tempered glass, filler (EVA), solar cell (Cell), back sheet and each cell from the solar incident surface. The back sheet has moisture and insulation blocking function penetrating from the rear of the module.

However, the existing back sheet is mostly dependent on imports, and the back barrier related technology is also very high due to the monopoly of developed countries.

Conventional solar cell module back sheet is used to form an aluminum thin film on the base film, the back sheet using the aluminum thin film as described above uses a conductive aluminum thin film, if damage to the back sheet, short circuit, etc. In order to solve the problem, the thickness of the backsheet and the solar cell itself has been increased due to the thickening of the insulating film.

In addition, a conventional solar cell module back sheet may be bonded by laminating a Tedlar film on a PET base film, but the Tedlar film and the PET base film may have peeling phenomena, which may cause various problems, such as durability. there was.

The present invention is to solve the above object, the object is to sequentially laminate a fluororesin layer, PET film, silica film, a solar cell module back sheet and a manufacturing method to provide high moisture resistance and weather resistance and its To provide a device.

Still another object of the present invention is to manufacture a back sheet by laminating a PET film having a fluorine resin layer and a silica film having a silica layer, so that the productivity and economic efficiency of the back sheet can be improved. To provide a sheet, a manufacturing method and an apparatus thereof.

Another object of the present invention is to apply a fluororesin paint and a silica (deposition) film by arranging a plurality of thermal drying chambers in succession, increasing the temperature conditions of each heating chamber step by step, then reducing the temperature and finally cooling. The present invention provides a back sheet for a solar cell module, a manufacturing method, and a device capable of increasing the adhesion by making the amount of adhesive uniform and at the same time suppressing bubbles or wrinkles on the coating film.

Another object of the present invention is to firmly attach the fluororesin and silica (deposition) film to the PET film to prevent the fluororesin and silica (deposition) film from being peeled off from the base PET film in the future use, vapor barrier, insulation, etc. Compared with existing products, it has a significantly higher durability.

Still another object of the present invention is to provide a cured film by a silane coupling agent on a silica film, to provide excellent durability and reliability, and thereby to manufacture a solar cell module backsheet that can improve the functionality of the backsheet. It is to provide a method and an apparatus thereof.

Another object of the present invention is to form a silica film by a base film having a different surface roughness, to improve the deposition efficiency of silica, and has a good winding property to perform a lamination process smoothly To provide a sheet, a manufacturing method and an apparatus thereof.

In the present invention, a fluororesin layer is laminated on one side of a PET film, and a silica film is laminated on the other side by a polyurethane adhesive.

At this time, the silica film is to be deposited on the polyester film coated with a coating liquid containing a silane coupling agent.

In addition, the silica film is laminated with a polyester film having different surface roughness.

In addition, the present invention provides a method for manufacturing a solar cell module back sheet;

A first step of manufacturing a PET film having a fluorine resin layer by coating and curing a fluororesin paint on one side of the PET film;

The urethane adhesive is applied to one side of the silica film, and the PET sheet having the fluorine resin layer is pressed and attached to the urethane adhesive coating surface by the first step to produce the solar cell module back sheet. .

Thus, in the present invention, the fluororesin layer is laminated on one side of the PET film, and the silica film is laminated on the other side, thereby providing water vapor barrier and excellent insulation.

In addition, the present invention can form a thin fluorine resin layer on one side of the PET film by the fluorine resin coating and a plurality of thermal drying chambers having different temperature conditions, and firmly integrates the PET film and the fluorine resin layer. You can.

In addition, the silica film of the present invention is to deposit a silica after applying a coating liquid containing a silane coupling agent to the base film, thereby improving the adhesion of the resulting silica deposition layer, thereby improving the durability of the backsheet You can.

In addition, the silica film of the present invention is formed by laminating polyesters having different roughnesses of the base film, thereby improving adhesion to the PET film, forming a silica deposition layer uniformly, and having excellent winding properties. It is provided with.

In addition, the present invention is to integrate the PET film and the silica film having a fluorine resin layer by a lamination method, it is possible to maximize the functionality and productivity of the solar cell module back sheet.

In addition, the present invention is to provide a thin film of the fluorine resin layer, the solar cell module back sheet has a thin film and lightweight, and the fluororesin layer and silica film is attached to both sides of the PET, respectively, thin film and excellent durability Equipped at the same time, through this has the effect of enabling an efficient design of the solar power system.

In addition, the present invention includes a fluorine resin layer and a silica deposition layer, has the adhesion and water vapor barrier properties by the fluorine resin layer, the water vapor barrier properties, durability, wear resistance, chemical resistance, heat resistance by the silica deposition layer It can be provided at the same time.

In addition, the present invention can form a back sheet by a simplified manufacturing process, it is possible to enable mass production and stable supply of solar cell back sheet that can simultaneously satisfy the functionality and cost competitiveness.

In addition, the present invention is attached to the PET film and the silica film by the urethane-based adhesive, it is sequentially passed through the heating chamber to increase the temperature and the temperature reduction heating chamber step by step, bubbles and wrinkles generated between the PET film and the silica film There are many effects, such as minimizing and increasing adhesion.

1 is an exemplary view showing a configuration according to the present invention, Figure 2 is an exemplary view showing another configuration of the base film according to the present invention, Figure 3 is a block exemplary view showing a manufacturing process of the back sheet according to the present invention. 4 is a view illustrating an embodiment of a solar cell module backsheet manufacturing apparatus according to the present invention, the solar cell module backsheet 400 according to the present invention is fluorine on one side of the PET film 10. The resin layer 20 is laminated, and the silica film 30 is integrally attached to the other side by the adhesive agent.

The fluororesin layer 20 is provided with water vapor barrier properties and excellent adhesion, and is formed by the application of a fluorine resin, and has a thickness of 5 to 30 μm. Such a thickness is intended to have a roll winding property and adhesiveness and moisture barrier property at the same time after being laminated on the PET film 10.

The silica film 30 is to deposit a silica on the base film 31 to have a silica deposition layer 32, the base film 31 is selected from polyester resin, polyolefin resin, polyimide resin One film is used, and preferably a polyester resin film is used.

In addition, the base film 31 is not particularly limited in thickness, but in consideration of the overall thickness of the solar cell module back sheet and the mechanical strength and solubility in forming the silica deposition layer, the range of 5 to 1000㎛ To be equipped.

In addition, the base film 31 is formed by laminating a polyester film having different surface roughness, as shown in FIG. That is, the base film has an upper polyester film 311 having a surface roughness Ra of 0.005 to 0.03 μm and having a silica deposition layer formed thereon, and a lower polyester film having a low crystalline surface roughness Ra of 0.040 μm or more ( 312) are stacked and formed.

The surface roughness of the upper polyester film 311 is formed by containing 50 to 1000 ppm of inert particles having an average particle diameter of 0.3 to 3.0 µm. If it contains less than 50ppm, problems may occur in roll winding property, and it is difficult to set the surface roughness to 0.03 μm or less at 1000 ppm or more.

The lower polyester film 312 is a film attached to the PET film 10, the surface roughness of the lower polyester film is formed by the inclusion of 0.05 to 3.0% by weight of inert particles having an average particle diameter of 0.3 to 3.0 ㎛.

In addition, the inert particles contained in the upper polyester film 311 and the lower polyester film 312 are silica particles, and the upper polyester film and the lower polyester film have a thickness ratio of 6-7: 4-3. It has an effect of suppressing winding property and wrinkles.

The upper polyester film 311 and the lower polyester film 312 as described above are integrated by pressure by a heating roller of a laminating device, and have a uniform silica deposition layer and excellent adhesion with a PET film. . In addition, since the formation of the base film by the lining apparatus is a known technical means, a detailed description thereof will be omitted.

The silica deposition layer 32 has a thickness of 10 to 300nm, is formed by being deposited on the base film 31 by a known technique such as vacuum deposition, CDV, ion plating, and the like.

In this case, the silica film 30 is provided with a silica deposition layer 32 by depositing silica on the base film 31 coated with a coating liquid containing a silane coupling agent. That is, according to the present invention, after the coating liquid containing the silane coupling agent is applied to the base film, a silica deposition layer is formed thereon to improve the adhesion of the silica deposition layer to the base film.

The silane coupling agent is a silane coupling agent having an acryloyl group or a methacryloyl group, and is added in an amount of about 0.2 to 45% by weight to the coating liquid.

The coating solution is composed of commercially available monomers or polymers for forming a cured coating. For example, monomers such as epoxy methacrylate, urethane methacrylate, polyester methacrylate and the like are used.

As shown in FIG. 1, the solar cell module backsheet of the present invention configured as described above is formed by adhesion of a PET film 10 having a fluorine resin layer 20 and a silica film 30. Specifically, the fluororesin layer 20, the PET film 10, the polyurethane adhesive layer 40, the base film 31, and the silica deposition layer 32 are sequentially stacked.

Figure 3 shows a block diagram showing a manufacturing method according to the present invention, the solar cell module back sheet (Back Sheet) according to the present invention is a first process for producing a PET film having a fluorine resin layer, And a second step of attaching the silica film to the PET film having the fluorine resin layer.

The first step is the first step of compounding the fluororesin chemicals,

A second step of unwinding the PET film wound on the roller and coating a fluororesin on one side of the unrolled PET film;

A third step of passing the PET film coated with the fluorocarbon resin into the thermal drying chamber;

A fourth step of cooling the PET film passing through the third step;

And a fifth step of winding the PET film cooled in the fourth step onto a roller and then aging them.

The fluorine resin coating coated in the first step has a main component and a component ratio of 40 to 50% by weight, a solvent ratio of 50 to 60%, and uses a fluorine-based solvent. The fluorine-based solvent facilitates the smoothness of the coating film, and in particular, serves to suppress pin holes occurring on the coating film. In this case, it is preferable to use a fluorine resin system of four fluorine atoms in consideration of weather resistance, curability and adhesion, such a fluorine resin system is provided with CF bond 116 ㎉ / mol, F by UV, O2, H2O It has a characteristic that no ions are generated. In addition, it means the well-known hardening | curing agent and various additives added to the said fluororesin system.

The second step is a step of coating the fluorine resin on one side of the uncoated PET film (Coating), the coating thickness of the fluorine resin coated on the PET film (Coating) is adjusted within 5 to 30㎛. In addition, it is preferable to use a three-line mash in the roll at the time of coating a fluororesin paint (Coating).

The third step is a step of passing through a plurality of thermal drying chambers arranged in succession with different temperature conditions to form a fluorine resin layer through stepwise temperature and temperature reduction of the temperature, the first chamber maintained at 70 ~ 80 ℃ And a second chamber maintained at 100 ° C., a third chamber maintained at 180 ° C., a fourth chamber maintained at 200 ° C., a fifth chamber maintained at 180 ° C., and a sixth chamber maintained at 150 ° C. And the seventh chamber maintained at 130 ° C. and the eighth chamber maintained at 90 ° C. to 100 ° C. are sequentially passed to uniformly apply the fluorine resin onto the PET film to increase adhesion.

The fourth step is to cool the PET film passed through the heat drying chamber, preferably to 35 ℃ to 75 ℃. This is to solidify the uniformly applied fluorine resin while passing through the heat-drying chamber and to maintain it in the uniform state until adhered to the PET film.

In the fifth step, the cooled PET film is wound on a roller, and then the wound PET film is aged in a aging chamber, and aged at 50 ° C. to 55 ° C. for 48 to 72 hours.

The second process is the first step of compounding a urethane two-component adhesive,

A second step of applying the urethane adhesive to one side of the silica film,

A third step of passing the urethane adhesive-coated silica film into a plurality of thermal chambers arranged in series,

A fourth step of pressing and attaching the PET film having the fluororesin layer laminated by the first process to the adhesive coating surface of the silica film having passed through the third step to form a back sheet;

And a fifth step of cooling the backsheet having passed through the fourth step.

At this time, the silica film and the PET film are wound on a roll and continuously supplied to the second process.

In addition, the second process further includes a silica film forming step of depositing silica on the base film.

In the silica film forming step, the coating solution containing the silane coupling agent is applied to the base film, and then the silica is deposited to form a silica deposition layer.

In addition, the silica film forming step may be a laminating step of pressing and laminating an upper polyester film having a surface roughness Ra of 0.005 to 0.03 μm and a lower polyester film having a low crystalline surface roughness Ra of 0.040 μm or more; , And depositing silica on the laminated upper polyester film.

The second step is to apply the adhesive to one side of the unwinding silica (deposition) film, the coating thickness of the urethane adhesive to be applied is adjusted within 3 to 5㎛.

At this time, the urethane adhesive is the ratio of the main agent and the curing agent by weight ratio of 10 to 20%, the solvent ratio is 40 to 50%. In addition, the urethane adhesive is a urethane two-component type is provided with heat resistance 130 ℃ ~ 200 ℃. In addition, the solvent in the adhesive is evaporated and removed while sequentially passing through a plurality of thermal drying chambers.

The third step is to pass the adhesive-coated film into a plurality of heating chambers arranged in series with different temperature conditions, the first chamber maintained at 75 ℃, the second chamber maintained at 80 ℃ and In order to sequentially pass through the third chamber maintained at 75 ° C., the solvent contained in the adhesive is evaporated through the stepwise temperature and temperature reduction of the temperature, and in particular, the adhesive prevents boiling and bubbles or wrinkles from occurring. Further, the main ingredient and the curing agent in the adhesive are evenly applied on the PET film to increase the adhesive force.

The fourth step is a step of attaching the PET film and the silica film integrally, and maintains the tension (tension) of the PET film unrolled so that bubbles or wrinkles do not occur between the PET film and the silica film at 10 to 20Kgf / ㎡ .

The fifth step is to cool the backsheet on which the PET film and the silica (deposition) film are laminated, and preferably, cool down to 35 ° C to 75 ° C.

The backsheet cooled as described above is aged for 48 to 72 hours at 50 ° C to 55 ° C, so that the fluororesin paint and adhesive are more firmly cured so that the PET film does not peel off from the fluororesin layer and the silica (deposition) film, respectively. do.

Figure 4 illustrates an embodiment of a solar cell module backsheet manufacturing apparatus according to the present invention, when the backsheet manufacturing apparatus by the illustrated Figure 4 as follows. In addition, this invention is not limited to the manufacturing apparatus of FIG.

The present invention is intended to include a first manufacturing device for laminating a fluororesin layer on one side of the PET film, and a second manufacturing device for attaching the PET film and silica film in which the fluorine resin layer is laminated.

The first manufacturing apparatus 100 has a fluorine resin (1) on one side of the first film unwinder 110 to unwind the wound PET film 10, and the PET film 10 unwinded from the first unwinder 110. Fluorine resin coating machine 130 for applying 120, a plurality of heat that is continuously arranged so that the adhesive-applied PET film can pass sequentially, the temperature conditions are gradually warmed up and then cooled down It includes a drying chamber 140, a cooler 150 for cooling the PET film passed through the thermal drying chamber 140, and a second winding machine 160 for winding the cooled PET film.

The second manufacturing apparatus 200 may include a third unwinder 210 for unwinding the wound silica (deposition) film 30 and a second unwinding film of the silica (deposition) film 30 unwinding from the third unwinder 210. Adhesive applicator 220 for applying the adhesive 40 on one side, the silica (deposition) film coated with the adhesive is successively arranged so as to pass sequentially, the temperature conditions are stepped up and then kept warm A plurality of thermal drying chamber 230, a fourth unwinder 240 for unwinding a PET film having a fluorine resin layer, a silica (deposition) film and the fourth unwinder having passed through the heat drying chamber 230 And a pressure roller 250 for compressing and laminating the PET film unwound at 240, a cooler 260 for cooling the laminated film, and a fifth winder 270 for winding the cooled film.

The second manufacturing apparatus 200 is preferably maintained at a line speed of 20 to 50M / minute, which is intended to promote the uniform application of the adhesive and the adhesive effect by the pressure roller.

In addition, the thermal drying chamber of the first manufacturing apparatus and the second manufacturing apparatus shown in FIG. 4 is not shown in detail, but the thermal drying chamber of the first manufacturing apparatus includes first to eighth chambers, and a second chamber. The heat drying chamber of the manufacturing apparatus consists of a first chamber to a third chamber.

The present invention is not limited to the above-described specific preferred embodiments, and various modifications can be made by any person having ordinary skill in the art without departing from the gist of the present invention claimed in the claims. Of course, such changes will fall within the scope of the claims.

1 is an exemplary view showing a configuration according to the present invention

Figure 2 is an exemplary view showing another configuration of the base film according to the present invention

Figure 3 is a block diagram showing a manufacturing process of the back sheet according to the present invention

Figure 4 is an embodiment of a solar cell module back sheet manufacturing apparatus according to the present invention

DESCRIPTION OF THE REFERENCE NUMERALS

10: PET film 20: fluororesin layer

(30): Silica Film (31): Base Film

(32): Silica Evaporation Layer 311: Upper Polyester Film

(312): Underlayer Polyester Film 400: Backsheet

(100): first manufacturing apparatus (110): first unwinding machine

120: fluorine resin (130): fluorine resin coating (Coating) machine

140: heat drying chamber 150: cooler

160: second winding machine 200: second manufacturing apparatus

210: third unwinder 220: adhesive applicator

230: heat drying chamber 240: the fourth unwinding machine

250: pressure roller 260: cooler

270: the fifth winding machine

Claims (20)

In the back sheet for a solar cell module; The back sheet is a solar cell module back sheet, characterized in that the fluororesin layer is laminated on one side of the PET film, the silica film is integrally attached to the other side by an adhesive. The method according to claim 1; The silica film is a silica sheet is deposited on the base film, the solar cell module back sheet, characterized in that it comprises a silica deposition layer. The method according to claim 2; The silica film is a silica sheet is deposited on a base film coated with a coating liquid containing a silane coupling agent to provide a silica deposition layer, characterized in that the back sheet for a solar cell module. The method according to claim 3; The silane coupling agent is a silane coupling agent having an acryloyl group or a methacryloyl group, characterized in that the solar cell module back sheet. The method according to claim 2 or 3; The base film is formed by laminating an upper polyester film having a surface roughness Ra of 0.005 to 0.03 μm and having a silica deposition layer formed thereon, and a lower polyester film having a low crystalline surface roughness Ra of 0.040 μm or more. Solar cell module back sheet. The method according to claim 5; The surface roughness of the upper polyester film is formed by containing 50 to 1000 ppm of inert particles having an average particle diameter of 0.3 to 3.0 µm, The surface roughness of the lower layer polyester film is formed by the inclusion of 0.05 to 3.0% by weight of inert particles having an average particle diameter of 0.3 to 3.0 µm. The method according to claim 6; The inert particles are solar cell module back sheet, characterized in that the silica particles. The method according to claim 5; An upper polyester film and a lower polyester film have a thickness ratio of 6 to 7: 4 to 3, wherein the back sheet for a solar cell module. The method according to claim 1; The fluorine resin layer is a solar cell module back sheet, characterized in that produced by the fluorine-based paint of four fluorine atoms. The method of claim 9; The fluororesin-based paint has a C-F bond 116 ㎉ / mol, and F ions are not generated by UV, O2, H2O. In the solar cell module backsheet manufacturing method; A first step of manufacturing a PET film having a fluorine resin layer by coating and curing a fluororesin paint on one side of the PET film; Manufacturing a back sheet for a solar cell module, comprising a second step of applying a urethane adhesive on one side of the silica film, and by pressing the PET film having a fluorine resin layer by pressing the urethane adhesive coating surface by a first step. Way. The method of claim 11; The first step is the first step of compounding the fluororesin chemicals, A second step of unwinding the PET film wound on the roller and coating a fluororesin on one side of the unrolled PET film; A third step of passing the PET film coated with the fluorocarbon resin into the thermal drying chamber; A fourth step of cooling the PET film passing through the third step; The method of manufacturing a back sheet for a solar cell module comprising a fifth step of winding the PET film cooled in the fourth step and then aging it. The method of claim 12; The third step includes a first chamber maintained at 70 to 80 ° C., a second chamber maintained at 100 ° C., a third chamber maintained at 180 ° C., a fourth chamber maintained at 200 ° C., and 180 ° C. A solar cell, which is sequentially passed through a fifth chamber to be maintained, a sixth chamber to be maintained at 150 ° C., a seventh chamber to be kept at 130 ° C., and an eighth chamber to be kept at 90 to 100 ° C. in succession. Method for manufacturing backsheet for module. The method of claim 12; The fourth step is to cool the PET film passed through the heat drying chamber to 35 ℃ to 75 ℃, In the fifth step, after the cooled PET film is wound on a roller, the wound PET film is aged at 50 ° C. to 55 ° C. in a aging room for 48 to 72 hours. The method of claim 11; The second process is the first step of compounding a urethane two-component adhesive, A second step of applying the urethane adhesive to one side of the silica film, A third step of passing the urethane adhesive coated silica film into a plurality of thermally dried chambers arranged in series; A fourth step of pressing and attaching the PET film having the fluororesin layer laminated by the first process to the adhesive coating surface of the silica film having passed through the third step to form a back sheet; And a fifth step of cooling the backsheet that has passed through the fourth step. The method of claim 15; The third step is a solar cell module backsheet manufacturing method characterized in that it passes sequentially through the first chamber maintained at 75 ℃, the second chamber maintained at 80 ℃, and the third chamber maintained at 75 ℃. . The method according to claim 11 or 15; The second process further comprises a silica film forming step of depositing silica on the base film solar cell module backsheet manufacturing method. The method of claim 17; The silica film forming step, after the coating liquid containing a silane coupling agent to the base film by coating curing, depositing silica to form a silica deposition layer, the method of manufacturing a back sheet for a solar cell module. The method of claim 17; The silica film forming step may be a laminating step of pressing and laminating an upper polyester film having a surface roughness Ra of 0.005 to 0.03 μm, and a lower polyester film having a low crystalline surface roughness Ra of 0.040 μm or more, and Method for manufacturing a back sheet for a solar cell module comprising the step of depositing a silica on the laminated upper polyester film. In the solar cell module back sheet manufacturing apparatus; Including a first manufacturing device for laminating a fluororesin layer on one side of the PET film, and a second manufacturing device for attaching the PET film and silica film laminated with the fluorine resin layer, The first manufacturing apparatus includes a first unwinding machine for unwinding the wound PET film 10, a fluorine resin coating machine for coating a fluororesin on one side of the PET film unwinding from the first unwinding machine, and an adhesive. A plurality of heat-drying chambers arranged continuously so that the applied PET film can pass sequentially, the temperature condition being gradually increased and then cooled down, a cooler for cooling the PET film passing through the heat-drying chamber, A second winding machine for winding the cooled PET film, The second manufacturing apparatus includes a third unwinder for unwinding the wound silica film, an adhesive applicator for applying an adhesive to one side of the silica (deposition) film unrolled from the third unwinder, and a silica film coated with the adhesive. A plurality of heat-drying chambers which are continuously arranged so as to pass sequentially, and whose temperature conditions are gradually increased and then reduced in temperature, a fourth unwinder for unwinding a PET film having a fluorine resin layer, and the heat-drying chamber An aspect comprising: a pressure roller for pressing and laminating the silica film passed through the PET film and the PET film unwound from the fourth unwinder, a cooler for cooling the laminated film, and a fifth winder for winding the cooled film. Back sheet manufacturing device for battery module.
KR1020090024294A 2009-03-23 2009-03-23 Back sheet for module, its manufacturing method and its manufacturing apparatus thereof KR101022820B1 (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012050316A1 (en) * 2010-10-13 2012-04-19 Kim Min-Hyuk Back sheet of a solar cell module for photovoltaic power generation
KR101156891B1 (en) * 2010-10-21 2012-06-21 도레이첨단소재 주식회사 Back sheet for a solarcell having an improved property for blocking a moisture and manufacturing method thereof
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KR101156891B1 (en) * 2010-10-21 2012-06-21 도레이첨단소재 주식회사 Back sheet for a solarcell having an improved property for blocking a moisture and manufacturing method thereof
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