KR20070003874A - 중합체 제조방법 - Google Patents

중합체 제조방법 Download PDF

Info

Publication number: KR20070003874A
Authority: KR; South Korea
Prior art keywords: meth; acrylate; solution; acrylic acid; salt
Prior art date: 2004-01-28

Application number

KR1020067017100A

Other languages

English (en)

Korean (ko)

Inventor

토마스 다니엘

울리히 리에겔

마크 엘리어트

Original Assignee

바스프 악티엔게젤샤프트

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2004-01-28

Filing date

2005-01-18

Publication date

2007-01-05

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=34828321&utm_source=***_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=KR20070003874(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

2004-01-28 Priority claimed from DE102004004496A external-priority patent/DE102004004496A1/de

2004-11-26 Priority claimed from DE102004057280A external-priority patent/DE102004057280A1/de

2005-01-18 Application filed by 바스프 악티엔게젤샤프트 filed Critical 바스프 악티엔게젤샤프트

2007-01-05 Publication of KR20070003874A publication Critical patent/KR20070003874A/ko

Links

229920000642 polymer Polymers 0.000 title claims abstract description 33
238000004519 manufacturing process Methods 0.000 title abstract description 3
239000000178 monomer Substances 0.000 claims abstract description 40
239000007787 solid Substances 0.000 claims abstract description 35
239000007864 aqueous solution Substances 0.000 claims abstract description 22
150000001252 acrylic acid derivatives Chemical class 0.000 claims abstract description 21
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical group [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 11
239000012736 aqueous medium Substances 0.000 claims abstract description 5
238000010526 radical polymerization reaction Methods 0.000 claims abstract description 3
239000000243 solution Substances 0.000 claims description 99
NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical group OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 55
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 47
238000000034 method Methods 0.000 claims description 35
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 31
238000006116 polymerization reaction Methods 0.000 claims description 25
150000003839 salts Chemical class 0.000 claims description 12
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 11
230000002378 acidificating effect Effects 0.000 claims description 9
239000006185 dispersion Substances 0.000 claims description 8
238000001556 precipitation Methods 0.000 claims description 7
229910052783 alkali metal Inorganic materials 0.000 claims description 5
230000003472 neutralizing effect Effects 0.000 claims description 5
239000007921 spray Substances 0.000 claims description 4
150000001340 alkali metals Chemical group 0.000 claims description 3
238000004898 kneading Methods 0.000 claims description 3
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
238000010924 continuous production Methods 0.000 claims description 2
239000000539 dimer Substances 0.000 claims description 2
NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 claims description 2
239000011734 sodium Substances 0.000 claims description 2
229910052708 sodium Inorganic materials 0.000 claims description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 2
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 1
230000000379 polymerizing effect Effects 0.000 claims 1
230000001965 increasing effect Effects 0.000 abstract description 4
239000011541 reaction mixture Substances 0.000 abstract description 4
PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 description 68
229940047670 sodium acrylate Drugs 0.000 description 68
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 60
238000006386 neutralization reaction Methods 0.000 description 21
238000006243 chemical reaction Methods 0.000 description 16
238000001816 cooling Methods 0.000 description 11
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
239000000203 mixture Substances 0.000 description 9
238000003756 stirring Methods 0.000 description 9
229920005601 base polymer Polymers 0.000 description 8
239000000017 hydrogel Substances 0.000 description 8
238000002360 preparation method Methods 0.000 description 8
239000002245 particle Substances 0.000 description 7
CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 6
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
239000000499 gel Substances 0.000 description 6
-1 alkali metal salts Chemical class 0.000 description 5
239000000047 product Substances 0.000 description 5
UWFRVQVNYNPBEF-UHFFFAOYSA-N 1-(2,4-dimethylphenyl)propan-1-one Chemical compound CCC(=O)C1=CC=C(C)C=C1C UWFRVQVNYNPBEF-UHFFFAOYSA-N 0.000 description 4
239000004971 Cross linker Substances 0.000 description 4
ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 4
229940048053 acrylate Drugs 0.000 description 4
150000008044 alkali metal hydroxides Chemical class 0.000 description 4
239000003431 cross linking reagent Substances 0.000 description 4
238000001035 drying Methods 0.000 description 4
239000003112 inhibitor Substances 0.000 description 4
239000003381 stabilizer Substances 0.000 description 4
GTELLNMUWNJXMQ-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical class OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CCC(CO)(CO)CO GTELLNMUWNJXMQ-UHFFFAOYSA-N 0.000 description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
ZZAGLMPBQOKGGT-UHFFFAOYSA-N [4-[4-(4-prop-2-enoyloxybutoxy)benzoyl]oxyphenyl] 4-(4-prop-2-enoyloxybutoxy)benzoate Chemical compound C1=CC(OCCCCOC(=O)C=C)=CC=C1C(=O)OC(C=C1)=CC=C1OC(=O)C1=CC=C(OCCCCOC(=O)C=C)C=C1 ZZAGLMPBQOKGGT-UHFFFAOYSA-N 0.000 description 3
235000010323 ascorbic acid Nutrition 0.000 description 3
229960005070 ascorbic acid Drugs 0.000 description 3
239000011668 ascorbic acid Substances 0.000 description 3
150000007514 bases Chemical class 0.000 description 3
239000008367 deionised water Substances 0.000 description 3
229910021641 deionized water Inorganic materials 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
239000000463 material Substances 0.000 description 3
150000002734 metacrylic acid derivatives Chemical class 0.000 description 3
238000002156 mixing Methods 0.000 description 3
229920000058 polyacrylate Polymers 0.000 description 3
USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 3
239000002244 precipitate Substances 0.000 description 3
229910001220 stainless steel Inorganic materials 0.000 description 3
239000010935 stainless steel Substances 0.000 description 3
JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
229910052784 alkaline earth metal Inorganic materials 0.000 description 2
239000012267 brine Substances 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
229920006037 cross link polymer Polymers 0.000 description 2
125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
230000002779 inactivation Effects 0.000 description 2
239000004816 latex Substances 0.000 description 2
229920000126 latex Polymers 0.000 description 2
230000014759 maintenance of location Effects 0.000 description 2
230000002028 premature Effects 0.000 description 2
239000012266 salt solution Substances 0.000 description 2
239000012047 saturated solution Substances 0.000 description 2
239000002002 slurry Substances 0.000 description 2
NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical group [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 2
HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 2
150000005846 sugar alcohols Polymers 0.000 description 2
DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
CCHRVFZBKRIKIX-UHFFFAOYSA-N 1-nitro-3-(3-nitrophenyl)benzene Chemical compound [O-][N+](=O)C1=CC=CC(C=2C=C(C=CC=2)[N+]([O-])=O)=C1 CCHRVFZBKRIKIX-UHFFFAOYSA-N 0.000 description 1
LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 1
JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
IZXIZTKNFFYFOF-UHFFFAOYSA-N 2-Oxazolidone Chemical compound O=C1NCCO1 IZXIZTKNFFYFOF-UHFFFAOYSA-N 0.000 description 1
VAPQAGMSICPBKJ-UHFFFAOYSA-N 2-nitroacridine Chemical compound C1=CC=CC2=CC3=CC([N+](=O)[O-])=CC=C3N=C21 VAPQAGMSICPBKJ-UHFFFAOYSA-N 0.000 description 1
GOXNUYXRIQJIEF-UHFFFAOYSA-N 3-(2-hydroxyethyl)-1,3-oxazolidin-2-one Chemical compound OCCN1CCOC1=O GOXNUYXRIQJIEF-UHFFFAOYSA-N 0.000 description 1
FYRWKWGEFZTOQI-UHFFFAOYSA-N 3-prop-2-enoxy-2,2-bis(prop-2-enoxymethyl)propan-1-ol Chemical compound C=CCOCC(CO)(COCC=C)COCC=C FYRWKWGEFZTOQI-UHFFFAOYSA-N 0.000 description 1
ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 1
XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 1
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
101100067721 Caenorhabditis elegans gly-3 gene Proteins 0.000 description 1
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
239000002202 Polyethylene glycol Substances 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
NJSSICCENMLTKO-HRCBOCMUSA-N [(1r,2s,4r,5r)-3-hydroxy-4-(4-methylphenyl)sulfonyloxy-6,8-dioxabicyclo[3.2.1]octan-2-yl] 4-methylbenzenesulfonate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)O[C@H]1C(O)[C@@H](OS(=O)(=O)C=2C=CC(C)=CC=2)[C@@H]2OC[C@H]1O2 NJSSICCENMLTKO-HRCBOCMUSA-N 0.000 description 1
LWZFANDGMFTDAV-BURFUSLBSA-N [(2r)-2-[(2r,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O LWZFANDGMFTDAV-BURFUSLBSA-N 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
230000032683 aging Effects 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
LIQDVINWFSWENU-UHFFFAOYSA-K aluminum;prop-2-enoate Chemical compound [Al+3].[O-]C(=O)C=C.[O-]C(=O)C=C.[O-]C(=O)C=C LIQDVINWFSWENU-UHFFFAOYSA-K 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
WPKYZIPODULRBM-UHFFFAOYSA-N azane;prop-2-enoic acid Chemical compound N.OC(=O)C=C WPKYZIPODULRBM-UHFFFAOYSA-N 0.000 description 1
239000002585 base Substances 0.000 description 1
230000005587 bubbling Effects 0.000 description 1
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
TXTCTCUXLQYGLA-UHFFFAOYSA-L calcium;prop-2-enoate Chemical compound [Ca+2].[O-]C(=O)C=C.[O-]C(=O)C=C TXTCTCUXLQYGLA-UHFFFAOYSA-L 0.000 description 1
235000011089 carbon dioxide Nutrition 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
238000003776 cleavage reaction Methods 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
239000000110 cooling liquid Substances 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
238000004132 cross linking Methods 0.000 description 1
239000013078 crystal Substances 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 1
125000004386 diacrylate group Chemical group 0.000 description 1
238000004821 distillation Methods 0.000 description 1
230000003028 elevating effect Effects 0.000 description 1
UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
239000008394 flocculating agent Substances 0.000 description 1
238000001640 fractional crystallisation Methods 0.000 description 1
239000007789 gas Substances 0.000 description 1
150000002314 glycerols Chemical class 0.000 description 1
125000002768 hydroxyalkyl group Chemical group 0.000 description 1
239000012442 inert solvent Substances 0.000 description 1
239000003999 initiator Substances 0.000 description 1
230000000977 initiatory effect Effects 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
238000010309 melting process Methods 0.000 description 1
LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 1
ZQXSMRAEXCEDJD-UHFFFAOYSA-N n-ethenylformamide Chemical compound C=CNC=O ZQXSMRAEXCEDJD-UHFFFAOYSA-N 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
238000005191 phase separation Methods 0.000 description 1
229920001515 polyalkylene glycol Polymers 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
159000000001 potassium salts Chemical class 0.000 description 1
239000000843 powder Substances 0.000 description 1
QMYDVDBERNLWKB-UHFFFAOYSA-N propane-1,2-diol;hydrate Chemical compound O.CC(O)CO QMYDVDBERNLWKB-UHFFFAOYSA-N 0.000 description 1
235000013772 propylene glycol Nutrition 0.000 description 1
239000011833 salt mixture Substances 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
235000017557 sodium bicarbonate Nutrition 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
229940035044 sorbitan monolaurate Drugs 0.000 description 1
235000011067 sorbitan monolaureate Nutrition 0.000 description 1
238000005507 spraying Methods 0.000 description 1
230000000087 stabilizing effect Effects 0.000 description 1
238000003860 storage Methods 0.000 description 1
ULENOZATXLGIKY-UHFFFAOYSA-L strontium;prop-2-enoate Chemical compound [Sr+2].[O-]C(=O)C=C.[O-]C(=O)C=C ULENOZATXLGIKY-UHFFFAOYSA-L 0.000 description 1
229920000247 superabsorbent polymer Polymers 0.000 description 1
ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
238000010998 test method Methods 0.000 description 1
230000008646 thermal stress Effects 0.000 description 1
235000010384 tocopherol Nutrition 0.000 description 1
229960001295 tocopherol Drugs 0.000 description 1
229930003799 tocopherol Natural products 0.000 description 1
239000011732 tocopherol Substances 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
VPYJNCGUESNPMV-UHFFFAOYSA-N triallylamine Chemical compound C=CCN(CC=C)CC=C VPYJNCGUESNPMV-UHFFFAOYSA-N 0.000 description 1
238000011144 upstream manufacturing Methods 0.000 description 1
229920001567 vinyl ester resin Polymers 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
XKMZOFXGLBYJLS-UHFFFAOYSA-L zinc;prop-2-enoate Chemical compound [Zn+2].[O-]C(=O)C=C.[O-]C(=O)C=C XKMZOFXGLBYJLS-UHFFFAOYSA-L 0.000 description 1
GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/04—Acids, Metal salts or ammonium salts thereof
- C08F20/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof

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Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

KR1020067017100A 2004-01-28 2005-01-18 중합체 제조방법 KR20070003874A (ko)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
DE102004004496A DE102004004496A1 (de)	2004-01-28	2004-01-28	Verfahren zur Herstellung von Polymeren
DE102004004496.1		2004-01-28
DE102004057280A DE102004057280A1 (de)	2004-11-26	2004-11-26	Verfahren zur Herstellung von Polymeren
DE102004057280.1		2004-11-26

Publications (1)

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KR20070003874A true KR20070003874A (ko)	2007-01-05

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US (1)	US7629428B2 (de)
EP (1)	EP1711541B2 (de)
JP (1)	JP2007519790A (de)
KR (1)	KR20070003874A (de)
AT (1)	ATE521645T1 (de)
BR (1)	BRPI0507132A (de)
TW (1)	TW200602358A (de)
WO (1)	WO2005073260A1 (de)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN101031591B (zh) *	2004-09-28	2012-05-23	巴斯福股份公司	连续生产交联的粒状凝胶型聚合物的方法
DE102005042606A1 (de) *	2005-09-07	2007-03-08	Basf Ag	Neutralisationsverfahren
DE102005042604A1 (de) *	2005-09-07	2007-03-08	Basf Ag	Neutralisationsverfahren
DE102005042605A1 (de) *	2005-09-07	2007-03-08	Basf Ag	Neutralisationsverfahren
US20090239071A1 (en)	2006-07-19	2009-09-24	Uwe Stueven	Method for Producing Water-Absorbent Polymer Particles with a Higher Permeability by Polymerising Droplets of a Monomer Solution
FR2943678B1 (fr) *	2009-03-25	2011-06-03	Total Raffinage Marketing	Polymeres (meth)acryliques de bas poids moleculaire, exempts de composes soufres,metalliques et halogenes et de taux de monomeres residuels faible,leur procede de preparation et leurs utilisations
BR112012005901A2 (pt)	2009-09-16	2019-09-24	Basf Se	superabsorvente, processo para produzir um superabsorvente, artigo para absorver fluidos, e, processo para produzir artigos para absorver fluidos
WO2011032922A1 (de)	2009-09-17	2011-03-24	Basf Se	Farbstabiler superabsorber
EP2484702B2 (de)	2009-09-30	2021-11-10	Nippon Shokubai Co., Ltd.	Wasserabsorbierendes harz auf basis von polyacrylsäuresalz und verfahren zu seiner herstellung
JP5731522B2 (ja)	2010-09-30	2015-06-10	株式会社日本触媒	粒子状吸水剤及びその製造方法
US10196500B2 (en)	2012-08-27	2019-02-05	Nippon Shokubai Co., Ltd.	Particulate water absorbing agent and process for producing same
EP2905072B1 (de)	2012-10-03	2018-05-30	Nippon Shokubai Co., Ltd.	Absorptionsmittel und herstellungsverfahren dafür
JP7192791B2 (ja) *	2017-12-15	2022-12-20	日本ゼオン株式会社	全固体二次電池用バインダー組成物、全固体二次電池用スラリー組成物、全固体二次電池用機能層、および全固体二次電池
CN110512420A (zh) *	2019-09-10	2019-11-29	哈尔滨理工大学	一种纤维表面串珠状微米粒子可控生长的方法

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB1073856A (en) *	1965-07-27	1967-06-28	Distillers Co Yeast Ltd	Production of sodium acrylate
US3615627A (en) *	1968-01-22	1971-10-26	Hughes Aircraft Co	Photopolymerizable compositions and process of making same
JPS5871907A (ja) *	1981-10-26	1983-04-28	Arakawa Chem Ind Co Ltd	吸水性樹脂乾燥固体の製造方法
US4552938A (en) †	1981-10-26	1985-11-12	American Colloid Company	Process for preparing dry solid water absorbing polyacrylate resin
JPH01178509A (ja) †	1988-01-11	1989-07-14	Kazuo Saotome	吸水性樹脂の製造方法
JPH01318021A (ja) †	1988-06-17	1989-12-22	Kazuo Saotome	吸水性樹脂成形物の製造方法
CA2001397A1 (en)	1988-10-28	1990-04-28	Tadao Shimomura	Method for production of acrylate and acrylate-containing polymer
JPH0749449B2 (ja) *	1988-10-28	1995-05-31	株式会社日本触媒	アクリル酸塩およびアクリル酸塩含有重合体の製造方法
JPH03115313A (ja) †	1989-09-28	1991-05-16	Kazuo Saotome	吸水性樹脂の製造方法
JP3349768B2 (ja) *	1992-06-10	2002-11-25	株式会社日本触媒	アクリル酸塩系ポリマーの製造方法および組成物
JP3544372B2 (ja) *	1992-06-10	2004-07-21	株式会社日本触媒	アクリル酸塩系ポリマーおよびこれを用いた衛生材料
JP2995276B2 (ja) †	1993-01-18	1999-12-27	三洋化成工業株式会社	吸水性樹脂の製造法
JP2901480B2 (ja) †	1994-02-17	1999-06-07	株式会社日本触媒	吸水性樹脂およびその製造方法
DE19955861A1 (de) *	1999-11-20	2001-05-23	Basf Ag	Verfahren zur kontinuierlichen Herstellung von vernetzten feinteiligen gelförmigen Polymerisaten
JP4805490B2 (ja) *	2000-08-03	2011-11-02	株式会社日本触媒	吸水性樹脂の製造方法
EP1326898B1 (de) *	2000-10-19	2005-01-12	Basf Aktiengesellschaft	Vernetztes, wasserquellbares polymerisat und verfahren zu seiner herstellung
WO2003051940A1 (en) *	2001-12-19	2003-06-26	Nippon Shokubai Co., Ltd.	Acrylic acid composition and its production process, and process for producing water-absorbent resin using this acrylic acid composition, and water-absorbent resin
EP1527109B1 (de) *	2002-07-30	2007-09-12	Basf Aktiengesellschaft	Verfahren zur herstellung von polymeren
FR2859209B1 (fr)	2003-08-29	2007-11-30	Rhodia Chimie Sa	Copolymere a structure controlee presentant une partie amphotere ou zwitterionique
EP1558658B1 (de) *	2002-11-07	2012-12-19	Rhodia Chimie	Copolymer mit kontrollierter struktur mit einem amphoteren oder zwitterionischen teil
EP1667637A2 (de)	2003-09-29	2006-06-14	Rhodia Chimie	Wässrige zusammensetzung mit einem polyionischen dendritischen polymer und einem ionischen tensid

2005
- 2005-01-18 BR BRPI0507132-1A patent/BRPI0507132A/pt not_active IP Right Cessation
- 2005-01-18 US US10/586,203 patent/US7629428B2/en not_active Expired - Fee Related
- 2005-01-18 KR KR1020067017100A patent/KR20070003874A/ko not_active Application Discontinuation
- 2005-01-18 JP JP2006550006A patent/JP2007519790A/ja active Pending
- 2005-01-18 WO PCT/EP2005/000421 patent/WO2005073260A1/de active Application Filing
- 2005-01-18 AT AT05700996T patent/ATE521645T1/de active
- 2005-01-18 EP EP05700996.1A patent/EP1711541B2/de not_active Not-in-force
- 2005-01-26 TW TW094102234A patent/TW200602358A/zh unknown

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Publication number	Publication date
JP2007519790A (ja)	2007-07-19
EP1711541B2 (de)	2015-09-23
EP1711541B1 (de)	2011-08-24
TW200602358A (en)	2006-01-16
ATE521645T1 (de)	2011-09-15
EP1711541A1 (de)	2006-10-18
BRPI0507132A (pt)	2007-06-19
US7629428B2 (en)	2009-12-08
WO2005073260A1 (de)	2005-08-11
US20080114140A1 (en)	2008-05-15

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Publication	Publication Date	Title
US7629428B2 (en)	2009-12-08	Method for producing polymers
EP0751159B1 (de)	2000-08-30	Verfahren zur Herstellung wasserabsorbierender Harze
EP0312952B1 (de)	1994-01-19	Verfahren zur Herstellung absorbierender Polymere
US5210298A (en)	1993-05-11	Method for production of acrylate and acrylate-containing polymer
JPWO2010090324A1 (ja)	2012-08-09	ポリアクリル酸（塩）系吸水性樹脂およびその製造方法
US9273156B2 (en)	2016-03-01	Method for producing water-absorbent resin
JP3363000B2 (ja)	2003-01-07	吸水性樹脂の製造方法
EP0398653A1 (de)	1990-11-22	Herstellungsverfahren für hoch wasserabsorbierende Polymere
JP3357093B2 (ja)	2002-12-16	吸水性樹脂の製造方法
JP2006089525A (ja)	2006-04-06	吸水性樹脂粒子の製造方法
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JPH02209906A (ja)	1990-08-21	アクリル酸塩およびアクリル酸塩含有重合体の製造方法
JPH01304128A (ja)	1989-12-07	粒子径の改良された吸水性樹脂の製造法
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JPS5981319A (ja)	1984-05-11	高吸水性樹脂の製造方法
JPS63210108A (ja)	1988-08-31	高吸水性ポリマ−の製造法
JPH06329716A (ja)	1994-11-29	吸水性樹脂の後処理方法