KR20050121183A - Glove and the method - Google Patents

Glove and the method Download PDF

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Publication number
KR20050121183A
KR20050121183A KR1020050114478A KR20050114478A KR20050121183A KR 20050121183 A KR20050121183 A KR 20050121183A KR 1020050114478 A KR1020050114478 A KR 1020050114478A KR 20050114478 A KR20050114478 A KR 20050114478A KR 20050121183 A KR20050121183 A KR 20050121183A
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South Korea
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weight
coating
parts
gloves
synthetic rubber
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KR1020050114478A
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Korean (ko)
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KR100729531B1 (en
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강춘배
김진철
권태규
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강춘배
권태규
김진철
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    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D19/00—Gloves
    • A41D19/0006—Gloves made of several layers of material
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D19/00—Gloves
    • A41D19/04—Appliances for making gloves; Measuring devices for glove-making
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D2500/00—Materials for garments
    • A41D2500/50—Synthetic resins or rubbers
    • A41D2500/54—Synthetic resins or rubbers in coated form

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Gloves (AREA)

Abstract

본 발명은 특수합성고무 코팅제가 코팅된 나일론 장갑과 그 제조방법에 관한 것으로, 더욱 상세하게는 나일론 장갑의 손바닥면에 안료, 각종 촉진제, 분산제, 노화방지제, 안정제, 고무 발포제, 감열 응고제 등의 성분을 포함하는 특수합성고무제(NBR)을 형성시킴으로써, 코팅 공정과 건조 공정에 소요되는 시간을 단축시키고, 장갑의 통기성과 착용감 및 내유성을 증대시키는 고품질의 나일론 장갑과 그 제조방법에 관한 것이다.The present invention relates to a nylon glove coated with a special synthetic rubber coating agent and a method for manufacturing the same, and more particularly, a component such as pigments, various accelerators, dispersants, anti-aging agents, stabilizers, rubber foaming agents, thermal coagulants, etc. By forming a special synthetic rubber (NBR) comprising a, shortens the time required for the coating process and drying process, and relates to a high-quality nylon gloves and a manufacturing method thereof to increase the breathability and fit and oil resistance of the gloves.

본 발명에 따르면, 특수합성고무 200 중량부에 수산화칼륨(KOH) 0.15 중량부와 물 1 중량부를 유화하여 투입하고, 여기에 코팅부재 7.45 중량부와 물 7.45 중량부를 혼합하여 48시간을 볼밀한 혼합물도 투입하여 8시간동안 교반 및 숙성시킨 후, 고무 발포제와 감열 응고제를 혼합하여 1,2,3차 교반과정을 거쳐 발포시키는 코팅제 조성공정; 몰드가 삽입된 장갑을 발수제에 3~4초 동안 함침시켜 60℃에서 7~8분간 건조하는 발수 및 1차 건조공정; 건조된 장갑을 코팅제에 함침하여 코팅하는 코팅제 함침공정; 코팅제가 형성된 장갑을 60℃에서 20분간 예비건조하는 2차 건조공정; 건조된 장갑을 세척탈취조에서 15분간 세척하는 세척공정; 세척한 장갑을 다시 60℃에서 30분간 3차 건조하고, 다시 100℃에서 30분간 4차 건조하여 장갑에서 몰드를 탈착시키는 3,4차 건조공정;을 거쳐서 제조됨을 특징으로 하는 특수합성고무 코팅제가 코팅된 나일론 장갑 제조방법과 상기 제조방법을 통해 제조된 장갑이 제공된다.According to the present invention, 0.15 parts by weight of potassium hydroxide (KOH) and 1 part by weight of water are emulsified in 200 parts by weight of a special synthetic rubber, and the mixture is mixed with 7.45 parts by weight and 7.45 parts by weight of water for 48 hours. After the addition and stirring and aging for 8 hours, a coating composition for mixing the rubber blowing agent and the thermal coagulant to foam through 1,2,3rd stirring process; A water-repellent and primary drying step of impregnating a glove inserted with a mold into the water repellent for 3 to 4 seconds and drying at 60 ° C. for 7 to 8 minutes; A coating impregnation process of coating the dried gloves with the coating agent; A secondary drying step of predrying the gloves having the coating agent formed at 60 ° C. for 20 minutes; A washing step of washing the dried gloves in a washing deodorizing bath for 15 minutes; The synthetic rubber coating was washed through a third and third drying process of washing the gloves again at 60 ° C. for 30 minutes and again drying the fourth at 100 ° C. for 30 minutes to remove the mold from the gloves. Provided are a coated nylon glove manufacturing method and a glove manufactured through the method.

Description

특수합성고무 코팅제가 코팅된 나일론 장갑과 그 제조방법{Glove and the method}Nylon gloves coated with special synthetic rubber coatings and manufacturing method thereof {Glove and the method}

본 발명은 특수합성고무 코팅제가 코팅된 나일론 장갑과 그 제조방법에 관한 것으로, 더욱 상세하게는 나일론 장갑의 손바닥면에 안료, 각종 촉진제, 분산제, 노화방지제, 안정제, 고무 발포제, 감열 응고제 등의 성분을 포함하는 특수합성고무제(NBR)을 형성시킴으로써, 코팅 공정과 건조 공정에 소요되는 시간을 단축시키고, 장갑의 통기성과 착용감 및 내유성을 증대시키는 고품질의 나일론 장갑과 그 제조방법에 관한 것이다.The present invention relates to a nylon glove coated with a special synthetic rubber coating agent and a method for manufacturing the same, and more particularly, a component such as pigments, various accelerators, dispersants, anti-aging agents, stabilizers, rubber foaming agents, thermal coagulants, etc. By forming a special synthetic rubber (NBR) comprising a, shortens the time required for the coating process and drying process, and relates to a high-quality nylon gloves and a manufacturing method thereof to increase the breathability and fit and oil resistance of the gloves.

일반적으로 작업용 나일론 장갑은 미끄러움을 방지하기 위하여 손바닥면이나 손끝에 고무 코팅제를 형성하는데, 이때 고무 코팅제의 구성성분이나 함량 등의 변화에 따라 장갑의 통기성, 착용감, 내유성, 내구성 등이 확연히 달라지게 된다.In general, nylon glove for work forms a rubber coating on the palm or fingertips in order to prevent slippage. At this time, the breathability, fit, oil resistance, durability, etc. of the glove are significantly changed depending on the composition or content of the rubber coating. do.

최근 나일론 장갑에 코팅제의 접착력을 증대시키는 동시에 코팅제의 두께를 얇고 부드럽게 형성한 특허등록 제449534호 '특수합성고무 코팅제가 코팅된 나일론 작업용 장갑과 그 코팅방법'이 제시된 바 있으나, 이는 코팅공정을 이중으로 수행해야 하므로, 코팅제를 이중으로 제조해야 하는데 많은 비용이 소모되고, 작업시간이 길어진다. 뿐만 아니라 코팅제가 형성된 장갑 표면에서 기공이 형성되지 않아 땀이나 수분 배출이 어렵고, 코팅제가 뻣뻣하여 착용감이 좋지 않으며, 인장강도가 떨어지는 등 여러가지 문제가 발생하고 있는 실정이다.Recently, the patent registration No. 449534 'Nylon working gloves coated with a special synthetic rubber coating and its coating method' has been proposed to increase the adhesive strength of the coating material on the nylon gloves and to form a thin and soft coating material. Since the coating should be performed in duplicate, it is necessary to manufacture a double coating costly, and the working time is long. In addition, pores are not formed on the surface of the glove on which the coating agent is formed, so it is difficult to release sweat or moisture, and the coating agent is stiff, so that it is not comfortable to wear and the tensile strength is poor.

본 발명의 목적은 종래의 이와같은 문제점을 해소하고자 하는데 있는 것으로, 이중으로 수행하던 코팅공정을 단축하고, 건조공정에 걸리는 시간을 단축시켜 작업 효율성을 증대시킬 뿐만 아니라, 미세한 표면기공으로 인하여 땀이나 수분은 배출하고 먼지나 이물질의 유입은 방지하며, 착용감과 내유성 및 접지력을 증대시키고자 하는데 그 목적이 있다.It is an object of the present invention to solve such problems in the prior art, shorten the coating process was carried out in duplicate, shortening the time taken for the drying process to increase the work efficiency, as well as sweat due to fine surface pores It aims to discharge moisture, prevent the ingress of dust and foreign substances, and increase the fit, oil resistance and grip.

상기 목적을 달성하기 위한 수단으로, 몰드에 삽입된 내피를 발수제에 함침시켜 건조한 후, 특수합성고무제(주성분 NBR+보조성분)를 코팅하여 예비건조하고, 이를 다시 세척 탈취조에서 세척하여 1,2차에 걸쳐 건조시키는 나일론 장갑 제조공정과 상기 제조공정을 통해 제조된 장갑을 제공코자 한다.As a means for achieving the above object, the endothelial inserted into the mold is impregnated with a water repellent and dried, then coated with a special synthetic rubber (main ingredient NBR + auxiliary ingredient) and pre-dried, and washed again in a washing deodorizing tank 1,2 To provide a nylon glove manufacturing process to dry over the car and a glove manufactured through the manufacturing process.

특수합성고무를 주원료로 하는 코팅제가 형성된 통상의 나일론 장갑 제조방법에 있어서, In the conventional nylon glove manufacturing method is formed with a coating material mainly composed of special synthetic rubber,

특수합성고무 200 중량부에 수산화칼륨(KOH) 0.15 중량부와 물 1 중량부를 유화하여 투입하고, 여기에 코팅부재 7.45 중량부와 물 7.45 중량부를 혼합하여 48시간을 볼밀한 혼합물도 투입하여 8시간동안 교반 및 숙성시킨 후, 고무 발포제와 감열 응고제를 혼합하여 1,2,3차 교반과정을 거쳐 발포시키는 코팅제 조성공정;Emulsified by adding 0.15 parts by weight of potassium hydroxide (KOH) and 1 part by weight of water to 200 parts by weight of the special synthetic rubber, mixed with 7.45 parts by weight of coating member and 7.45 parts by weight of water for 48 hours in a ball mill mixture 8 hours After stirring and aging for a while, a coating composition for mixing the foaming agent and the thermal coagulant to foam through 1,2,3rd stirring process;

몰드가 삽입된 장갑을 발수제에 3~4초 동안 함침시켜 60℃에서 7~8분간 건조하는 발수 및 1차 건조공정;A water-repellent and primary drying step of impregnating a glove inserted with a mold into the water repellent for 3 to 4 seconds and drying at 60 ° C. for 7 to 8 minutes;

건조된 장갑을 코팅제에 함침하여 코팅하는 코팅제 함침공정;A coating impregnation process of coating the dried gloves with the coating agent;

코팅제가 형성된 장갑을 60℃에서 20분간 예비건조하는 2차 건조공정;A secondary drying step of predrying the gloves having the coating agent formed at 60 ° C. for 20 minutes;

건조된 장갑을 세척탈취조에서 15분간 세척하는 세척공정;A washing step of washing the dried gloves in a washing deodorizing bath for 15 minutes;

세척한 장갑을 다시 60℃에서 30분간 3차 건조하고, 다시 100℃에서 30분간 4차 건조하여 장갑에서 몰드를 탈착시키는 3,4차 건조공정;3rd and 4th drying process which wash | cleaned the glove again 3rd at 60 degreeC for 30 minutes, and then dried 4 times at 100 degreeC for 30 minutes, and detaching a mold from a glove;

을 거쳐서 제조됨을 특징으로 하는 것이다.It is characterized in that it is manufactured through.

상기에서, 코팅부재는 백색안료인 지당(TIO2) 1.5 중량부, 가황 촉진제인 콜로이드 유황(S) 2 중량부, 준촉진제인 엠젯트(MZ) 0.4 중량부, 초촉진제인 이젯트(EZ) 0.5 중량부, 중성 촉진제인 비젯트(BZ) 0.4 중량부, 분산제(D-N) 0.5 중량부, 노화방지제(K2246) 0.5 중량부, 안정제 및 비스코티 조절제인 수산화칼륨(KOH) 0.15 중량부로 조성한다.In the above, the coating member is a white pigment paper sugar (TIO 2 ) 1.5 parts by weight, vulcanization accelerator colloidal sulfur (S) 2 parts by weight, quasi-accelerator MZET (MZ) 0.4 parts by weight, super accelerators EZ (EZ) 0.5 parts by weight, 0.4 parts by weight of bizette (BZ) as a neutral accelerator, 0.5 parts by weight of dispersant (DN), 0.5 parts by weight of anti-aging agent (K2246), and 0.15 parts by weight of potassium hydroxide (KOH) as a stabilizer and a biscotti regulator.

상기에서, 발수제는 물과 질산칼슘(CA3)의 혼합물로, 물이 100 중량부일 때 질산칼슘(CA3)은 물의 5%~8%로 혼합한다.In the above, the water repellent is a mixture of water and calcium nitrate (CA 3 ), when the water is 100 parts by weight of calcium nitrate (CA 3 ) is mixed with 5% to 8% of water.

상기에서, 고무 발포제는 특수합성고무와 코팅부재 및 물로 된 전체 배합물의 0.5%를 투입한다.In the above, the rubber foaming agent is charged with 0.5% of the total blend of special synthetic rubber, coating member and water.

상기에서, 감열 응고제는 물에 2~3배 희석한 후, 특수합성고무 200 중량부에 포함되는 고형분 120 중량부의 0.5~2%를 투입한다.In the above, the thermal coagulant is diluted 2 to 3 times in water, and 0.5 to 2% by weight of 120 parts by weight of solids contained in 200 parts by weight of the special synthetic rubber.

상기에서, 코팅제 조성공정의 1차 교반시에는 500 RPM의 속도로 1시간 교반하고, 2차 교반시에는 1200 RPM의 속도로 1시간, 3차 교반시에는 250~300 RPM의 속도로 1시간 동안 안정화 교반한다.In the above, the coating composition is stirred for 1 hour at the speed of 500 RPM for the first stirring, the second stirring for 1 hour at the speed of 1200 RPM, the third stirring for 1 hour at the speed of 250 ~ 300 RPM Stir and stabilize.

이하 첨부된 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자가 본 발명의 기술적 사상을 용이하게 실시할 수 있도록 상세하게 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail so that those skilled in the art may easily implement the technical idea of the present invention.

도 1은 본 발명의 전체 공정을 도시한 블럭도, 2a,2b는 본 발명의 전체를 도시한 사시도, 도 3은 본 발명에서 코팅층을 도시한 단면도로서, 1 is a block diagram showing the overall process of the present invention, 2a, 2b is a perspective view showing the whole of the present invention, Figure 3 is a cross-sectional view showing a coating layer in the present invention,

먼저 장갑이 함침되는 코팅제 제조공정(S1)에 대해 살펴 보면,Looking first at the coating manufacturing process (S1) in which gloves are impregnated,

백색안료인 지당(TIO2) 1.5 중량부, 가황 촉진제인 콜로이드 유황(S) 2 중량부, 준촉진제인 엠젯트(MZ) 0.4 중량부, 초촉진제인 이젯트(EZ) 0.5 중량부, 중성 촉진제인 비젯트(BZ) 0.4 중량부, 분산제(D-N) 0.5 중량부, 노화방지제(K2246) 0.5 중량부, 안정제 및 비스코티 조절제인 수산화칼륨(KOH) 0.15 중량부로 조합된 코팅부재 7.45 중량부에 물 7.45 중량부를 혼합하여 48시간동안 볼밀하는데,1.5 parts by weight of TIO 2 , a white pigment, 2 parts by weight of colloidal sulfur (S), a vulcanization accelerator, 0.4 parts by weight of MZT, a semi-accelerator, 0.5 parts by weight of EZ, a super accelerator, and a neutral accelerator 0.445 parts by weight of phosphorus bizit (BZ), 0.5 parts by weight of dispersant (DN), 0.5 parts by weight of anti-aging agent (K2246), 7.45 parts by weight of a coating member combined with 0.15 parts by weight of potassium hydroxide (KOH), a stabilizer and a biscotti regulator. Mix the parts by weight and ball mill for 48 hours

상기에서 가황 촉진제는 고무에 탄성을 부여하기 위해 가황공정에 투입되어 가황속도 촉진 및 고무물성 증진에 기여하는 약품으로, 가황 촉진제의 종류는 약 30여종으로, 가황속도, 가황패턴 및 산염기 성질등에 따라 단독 또는 2종류 이상을 병용 사용한다. 본 발명에서는 콜로이드 유황(S)과 Dithiocarbamate계(EZ, MZ, BZ)를 사용하고자 한다.The vulcanization accelerator is a chemical that contributes to the vulcanization process and rubber properties by adding to the vulcanization process in order to give elasticity to the rubber, about 30 kinds of vulcanization accelerators, vulcanization rate, vulcanization pattern and acid group properties Therefore, it uses individually or in combination of 2 or more types. In the present invention, it is intended to use colloidal sulfur (S) and Dithiocarbamate system (EZ, MZ, BZ).

그 외 노화 방지제는 대기 중의 산소분자에 의한 고무의 산화를 방지·억제하기 위하여 첨가하는 것이다.Other anti-aging agents are added to prevent and inhibit oxidation of rubber by oxygen molecules in the atmosphere.

그리고 특수합성고무(NBR) 1드럼에 해당하는 200 중량부에 수산화칼륨(KOH) 0.15 중량부와 물 1 중량부를 유화하여 투입하고, 여기에 다시 상기 코팅부재와 물 혼합물 14.9 중량부나 일부인 10~12 중량부를 투입하여 48시간 동안 교반 및 숙성시키는데, 이때 수산화칼륨(KOH)은 pH를 중성에서 알칼리측으로 조절하기 위해 투입한다.In addition, 0.15 parts by weight of potassium hydroxide (KOH) and 1 part by weight of water are emulsified in 200 parts by weight of 1 part of a special synthetic rubber (NBR) drum, and the coating member and the water mixture are 14.9 parts by weight or part of 10 to 12 In parts by weight, stirring and aging for 48 hours, wherein potassium hydroxide (KOH) is added to adjust the pH from neutral to alkaline.

또한 교반 및 숙성된 특수합성고무 배합물에는 다시 상기 배합물 중량의 0.5%에 해당하는 고무 발포제(K1010)와 배합물 중량의 0.5~2%에 해당하는 감열 응고제(TPA 4380이나 TPA 4390)를 투입하여 1,2,3차 교반시키는데, 1차 교반시에는 500 RPM의 속도로 1시간, 2차 교반시에는 1200 RPM의 속도로 1시간, 3차 교반시에는 250~300 RPM의 속도로 1시간동안 안정화 교반한다.In addition, to the stirred and aged special synthetic rubber compound, a rubber foaming agent (K1010) corresponding to 0.5% of the weight of the compound and a thermal coagulant (TPA 4380 or TPA 4390) corresponding to 0.5 to 2% of the weight of the compound are added. 2nd and 3rd stirring, 1 hour at the speed of 500 RPM for the first stirring, 1 hour at the speed of 1200 RPM for the second stirring, 1 hour stabilizing stirring at the speed of 250 ~ 300 RPM for the third stirring do.

상기에서 고무 발포제를 통해 코팅제에 미세 기공이 형성되어 추후 땀이나 수분을 외부로 배출할 수 있게 된다. In the above, fine pores are formed in the coating through the rubber foaming agent so that sweat or moisture may be discharged to the outside.

그리고 감열 응고제(heat sensitizing agent)는 특수합성고무와 배합하여 어떤 특정한 온도에서 급격히 겔화를 일으키는 약제로, 본 발명에서는 이 감열 응고제의 사용으로 건조시간을 기존의 반으로 단축시킬 수 있다. 상기 감열 응고제는 물에 2~3배 희석하여 사용하는데, TPA 4380 이나 TPA 4390을 사용할 경우 특수합성고무의 저장 안정성이 우수하여 GUM-UP 발생을 방지할 수 있으며, 응고된 겔의 물성이 우수하다.The heat sensitizing agent is a drug that causes gelation rapidly at a specific temperature by combining with a special synthetic rubber. In the present invention, the drying time can be shortened by the use of the heat coagulant. The thermal coagulant is diluted 2 to 3 times with water. When TPA 4380 or TPA 4390 is used, the storage stability of the special synthetic rubber is excellent to prevent the occurrence of GUM-UP, and the physical properties of the coagulated gel are excellent. .

상기 코팅제 제조공정(S1)을 통해 제조된 코팅제는 본 발명의 장갑 이외에 신발안창, 카펫트, 소파, 장판 등의 여러가지 물품에 적용할 수도 있다.The coating agent prepared by the coating agent manufacturing process (S1) may be applied to various articles such as shoe insoles, carpets, sofas, floor coverings, in addition to the gloves of the present invention.

발수 및 1차 건조공정(S2)에서는 먼저 몰드가 삽입된 장갑을 침투방재액인 발수제에 함침시키는데, 이때 발수제는 물 100 중량부에 물의 3~5% 비율로 질산칼슘(CA3)을 혼합하여 조성하고, 조성된 발수제에 장갑을 3~4초 정도 함침시키며, 함침이 완료된 장갑은 열처리로에서 60℃에서 7~8분간 예비건조한다.The water repellency and the primary drying process (S2) sikineunde first mold is impregnated with the inserted gloves penetration emergency liquid water repellent agent, wherein the water repellent is a mixture of calcium nitrate (CA 3) to the 3-5% ratio of water to 100 parts by weight of water The gloves were impregnated for 3 to 4 seconds to the prepared water repellent, and the pre-impregnated gloves were pre-dried at 60 ° C. for 7 to 8 minutes in a heat treatment furnace.

상기 발수제를 종래에는 알콜을 사용했으나, 알콜은 용제로 특수합성고무의 고무 발포제 형성을 방해하여 건조시 발포가 소멸되는 등의 문제가 발생하므로, 본 발명에서는 고무 발포제의 형성을 방해하지 않는 물을 주 발수제로 하고, 물에 미량의 질산칼슘(CA3)을 첨가시킨 것이다.Although the water repellent is conventionally used alcohol, the alcohol is used as a solvent to prevent the rubber foaming agent of the special synthetic rubber to form a problem, such as foaming disappears during drying, in the present invention, water does not interfere with the formation of the rubber foaming agent. as the main water-repellant, and to which was added a small amount of calcium nitrate (CA 3) in water.

코팅제 함침공정(S3)에서는 코팅제 제조공정에서 만들어진 코팅제에 장갑의 손바닥면이나 손가락 부분 등에 함침시켜 코팅층(100)을 형성하는데, 본 발명은 발수제를 종래의 알콜에서 물로 형성하여 코팅제와 장갑의 밀착성을 증대시키므로 코팅공정을 2회에서 1회로 단축할 수 있다.In the coating impregnation step (S3) to form a coating layer 100 by impregnating the palm or finger portion of the glove in the coating made in the coating manufacturing process, the present invention is formed by the water repellent agent in water from the conventional alcohol to the adhesion between the coating and the glove By increasing, the coating process can be shortened from 2 to 1 times.

2차 건조공정(S4)에서는 코팅제에 함침된 장갑을 열처리로에 삽입하여 60℃에서 20분간 예비건조한다.In the second drying step (S4), the gloves impregnated with the coating agent are inserted into a heat treatment furnace and preliminarily dried at 60 ° C. for 20 minutes.

세척공정(S5)에서는 건조된 장갑을 세척탈취조에서 15분간 세척한다.In the washing step (S5), the dried gloves are washed for 15 minutes in a washing deodorization tank.

3,4차 건조공정(S6)에서는 세척한 장갑을 다시 열처리로에 삽입하여 60℃에서 30분간 3차 건조하고, 다시 100℃에서 30분간 4차 건조한다. In the 3rd and 4th drying process (S6), the washed gloves are inserted into the heat treatment furnace again and dried 3 times at 60 ° C. for 30 minutes, and again 4 times at 100 ° C. for 30 minutes.

건조가 완료되면 장갑에서 몰드를 탈착시키고, 불량 유무를 검사하여 포장하고 선적하여 마무리 한다.When drying is completed, the mold is detached from the glove, inspected for defects, packed, shipped and finished.

이상과 같은 공정을 거쳐 제조된 장갑은 도 3에 도시된 바와 같이 코팅층(100) 표면에 미세한 기공이 형성되는데, 이때 장갑 내피와 접면되는 코팅층 부분은 미세기공의 크기가 크고, 건조공정시 열에 바로 노출되는 외표면은 미세기공의 크기가 작게 형성된다. The glove manufactured through the above process is formed with fine pores on the surface of the coating layer 100, as shown in Figure 3, wherein the coating layer portion that is in contact with the glove endothelium is large in size of micropores, immediately in the heat during the drying process The exposed outer surface is formed with a small size of the micropores.

따라서 착용시 발생되는 땀이나 수분을 최대한 외부로 배출시킬 수 있는 동시에 외부의 미세 먼지나 수분 유입은 최소화시킬 수 있어 착용감이 증대되고, 인장강도도 증대된다.Therefore, the sweat or moisture generated during wearing can be discharged to the outside as much as possible, and at the same time, external fine dust or moisture can be minimized to increase the wearing comfort and the tensile strength.

그러므로 미세한 부품을 취급하거나 정밀을 요하는 작업에 용이하게 사용될 수 있고, 등산 및 낚시나 식물 경작 등 수분과 밀접한 관계가 있는 용도로도 용이하게 사용될 수 있다.Therefore, it can be easily used for handling fine parts or requiring precision work, and can also be easily used for applications that are closely related to moisture such as climbing, fishing, or plant cultivation.

이와 같이 본 발명은 촉진제, 분산제, 노화 방지제, 안정제, 발수제, 감열 응고제 등이 포함된 코팅제를 제조하여 장갑 표면에 미세기공이 있는 코팅층을 형성함으로써, 수분과 땀을 최대한 외부로 배출하고, 외부의 미세 먼지나 이물질 유입은 최소화시키며, 인장강도가 높아 사용수명이 연장된다. 뿐만 아니라, 착용감과 접지력 및 내유성이 우수하여 정밀한 작업이 요구되는 곳에 다양하게 사용될 수 있는데 그 효과가 있다.As described above, the present invention manufactures a coating agent including an accelerator, a dispersant, an anti-aging agent, a stabilizer, a water repellent, a thermal coagulant, and the like to form a coating layer having micropores on the surface of the glove, discharging moisture and sweat to the outside as much as possible, Minimize the inflow of fine dust or foreign substances and extend the service life due to high tensile strength. In addition, it is excellent in fit and grip and oil resistance can be used in a variety of places where precise work is required, there is an effect.

도 1은 본 발명의 전체 공정을 도시한 블럭도1 is a block diagram showing the overall process of the present invention.

2a,2b는 본 발명의 전체를 도시한 사시도2a and 2b are perspective views showing the whole of the present invention.

도 3은 본 발명에서 코팅층을 도시한 단면도Figure 3 is a cross-sectional view showing a coating layer in the present invention

< 도면의 주요부분에 대한 부호의 설명 ><Description of Symbols for Major Parts of Drawings>

100: 코팅층 S1: 코팅제 조성공정100: coating layer S1: coating agent composition process

S2: 발수 및 1차 건조공정 S3: 코팅제 함침공정S2: Water repellent and primary drying process S3: Coating impregnation process

S4: 2차 건조공정 S5: 세척공정S4: secondary drying process S5: washing process

S6: 3,4차 건조공정;S6: 3rd and 4th drying process;

Claims (7)

특수합성고무를 주원료로 하는 코팅제가 형성된 통상의 나일론 장갑 제조방법에 있어서, 특수합성고무 200 중량부에 수산화칼륨(KOH) 0.15 중량부와 물 1 중량부를 유화하여 투입하고, 여기에 코팅부재 7.45 중량부와 물 7.45 중량부를 혼합하여 48시간을 볼밀한 혼합물도 투입하여 8시간동안 교반 및 숙성시킨 후, 고무 발포제와 감열 응고제를 혼합하여 1,2,3차 교반과정을 거쳐 발포시키는 코팅제 조성공정; 몰드가 삽입된 장갑을 발수제에 3~4초 동안 함침시켜 60℃에서 7~8분간 건조하는 발수 및 1차 건조공정; 건조된 장갑을 코팅제에 함침하여 코팅하는 코팅제 함침공정; 코팅제가 형성된 장갑을 60℃에서 20분간 예비건조하는 2차 건조공정; 건조된 장갑을 세척탈취조에서 15분간 세척하는 세척공정; 세척한 장갑을 다시 60℃에서 30분간 3차 건조하고, 다시 100℃에서 30분간 4차 건조하여 장갑에서 몰드를 탈착시키는 3,4차 건조공정;을 거쳐서 제조됨을 특징으로 하는 특수합성고무 코팅제가 코팅된 나일론 장갑 제조방법.In a conventional nylon glove manufacturing method in which a coating material containing a special synthetic rubber is formed, 0.15 parts of potassium hydroxide (KOH) and 1 part by weight of water are emulsified in 200 parts by weight of the special synthetic rubber, and the coating member is 7.45 parts by weight. Mixing the mixture with 7.45 parts by weight of water and adding a ball mill mixture for 48 hours, stirring and aging for 8 hours, mixing the rubber foaming agent and the thermal coagulant, and foaming the mixture through 1,2,3rd stirring process; A water-repellent and primary drying step of impregnating a glove inserted with a mold into the water repellent for 3 to 4 seconds and drying at 60 ° C. for 7 to 8 minutes; A coating impregnation process of coating the dried gloves with the coating agent; A secondary drying step of predrying the gloves having the coating agent formed at 60 ° C. for 20 minutes; A washing step of washing the dried gloves in a washing deodorizing bath for 15 minutes; The synthetic rubber coating was washed through a third and third drying process of washing the gloves again at 60 ° C. for 30 minutes and again drying the fourth at 100 ° C. for 30 minutes to remove the mold from the gloves. Method of making coated nylon gloves. 제 1항에 있어서, 코팅부재는 백색안료인 지당(TIO2) 1.5 중량부, 가황 촉진제인 콜로이드 유황(S) 2 중량부, 준촉진제인 엠젯트(MZ) 0.4 중량부, 초촉진제인 이젯트(EZ) 0.5 중량부, 중성 촉진제인 비젯트(BZ) 0.4 중량부, 분산제(D-N) 0.5 중량부, 노화방지제(K2246) 0.5 중량부, 안정제 및 비스코티 조절제인 수산화칼륨(KOH) 0.15 중량부로 조성함을 특징으로 하는 특수합성고무 코팅제가 코팅된 나일론 장갑 제조방법.According to claim 1, wherein the coating member is white pigment pigment (TIO 2 ) 1.5 parts by weight, vulcanization accelerator colloidal sulfur (S) 2 parts by weight, quasi-accelerator MZET (MZ) 0.4 parts by weight, super accelerator accelerator (EZ) 0.5 parts by weight, Bizette (BZ) as a neutral accelerator, 0.4 parts by weight of dispersant (DN), 0.5 parts by weight of anti-aging agent (K2246), 0.15 parts by weight of potassium hydroxide (KOH) as a stabilizer and a biscotti regulator. Nylon glove manufacturing method coated with a special synthetic rubber coating, characterized in that. 제 1항에 있어서, 발수제는 물과 질산칼슘(CA3)의 혼합물로, 물이 100 중량부일 때 질산칼슘(CA3)은 물의 5%~8%로 혼합함을 특징으로 하는 특수합성고무 코팅제가 코팅된 나일론 장갑 제조방법.The method of claim 1, wherein the water repellent is a mixture of water and calcium nitrate (CA 3 ), when the water is 100 parts by weight of calcium nitrate (CA 3 ) is a special synthetic rubber coating, characterized in that mixing with 5% to 8% Method of manufacturing coated nylon gloves. 제 1항에 있어서, 고무 발포제는 특수합성고무와 코팅부재 및 물로 된 전체 배합물의 0.5%를 투입함을 특징으로 하는 특수합성고무 코팅제가 코팅된 나일론 장갑 제조방법.The method of claim 1, wherein the rubber foaming agent is a nylon synthetic glove coated with a special synthetic rubber coating, characterized in that 0.5% of the total formulation of the special synthetic rubber, the coating member and water. 제 1항에 있어서, 감열 응고제는 물에 2~3배 희석한 후, 특수합성고무 200 중량부에 포함되는 고형분 120 중량부의 0.5~2%를 투입함을 특징으로 하는 특수합성고무 코팅제가 코팅된 나일론 장갑 제조방법.The method of claim 1, wherein the thermal coagulant is diluted 2 to 3 times with water, and then coated with a special synthetic rubber coating, characterized in that 0.5 to 2% by weight of 120 parts by weight of solids contained in 200 parts by weight of the special synthetic rubber is added. How to make nylon gloves. 제 1항에 있어서, 코팅제 조성공정의 1차 교반시에는 500 RPM의 속도로 1시간 교반하고, 2차 교반시에는 1200 RPM의 속도로 1시간, 3차 교반시에는 250~300 RPM의 속도로 1시간 동안 안정화 교반함을 특징으로 하는 특수합성고무 코팅제가 코팅된 나일론 장갑 제조방법.The method according to claim 1, wherein the coating composition is stirred for 1 hour at a rate of 500 RPM during the first stirring of the coating composition, at a rate of 1200 RPM for the second stirring and at a speed of 250 to 300 RPM for the third stirring. Method for producing nylon gloves coated with a special synthetic rubber coating, characterized in that for 1 hour stabilization stirring. 제 1항의 기재방법으로 제조되는 것을 특징으로 하는 특수합성고무 코팅제가 코팅된 나일론 장갑.Nylon gloves coated with a special synthetic rubber coating, characterized in that the manufacturing method of claim 1.
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KR101899285B1 (en) * 2018-03-07 2018-09-14 알파장갑 주식회사 Manufacturing method of coating gloves
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KR101279108B1 (en) 2012-05-24 2013-06-26 현대글러브 주식회사 Manufacturing method of coating gloves
KR101353561B1 (en) 2012-08-13 2014-01-22 주식회사 성진나이스 Coating glove and manufacturing method thereof
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KR100476099B1 (en) 2003-11-26 2005-03-14 김덕수 Composition for coating of nylon gloves and process for preparation of the same

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KR101899285B1 (en) * 2018-03-07 2018-09-14 알파장갑 주식회사 Manufacturing method of coating gloves
KR20210119158A (en) * 2020-03-24 2021-10-05 김수환 Work gloves coated with synthetic rubber and manufacturing method thereof

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