KR20020080054A - Wallpaper of synthetic resins and biodegradable natural materials - Google Patents

Wallpaper of synthetic resins and biodegradable natural materials Download PDF

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Publication number
KR20020080054A
KR20020080054A KR1020010019113A KR20010019113A KR20020080054A KR 20020080054 A KR20020080054 A KR 20020080054A KR 1020010019113 A KR1020010019113 A KR 1020010019113A KR 20010019113 A KR20010019113 A KR 20010019113A KR 20020080054 A KR20020080054 A KR 20020080054A
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weight
wallpaper
powder
water
agent
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KR1020010019113A
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Korean (ko)
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전효철
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주식회사 월핀
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Publication of KR20020080054A publication Critical patent/KR20020080054A/en

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    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/18—Paper- or board-based structures for surface covering
    • D21H27/20—Flexible structures being applied by the user, e.g. wallpaper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/38—Coatings with pigments characterised by the pigments
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/34—Ignifugeants
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/38—Corrosion-inhibiting agents or anti-oxidants
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H5/00—Special paper or cardboard not otherwise provided for
    • D21H5/0002—Flame-resistant papers; (complex) compositions rendering paper fire-resistant
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H5/00—Special paper or cardboard not otherwise provided for
    • D21H5/0082—Wall papers

Landscapes

  • Paper (AREA)

Abstract

PURPOSE: A wallpaper composition prepared by mixing water soluble synthetic resin, a natural material such as wood powder, rice hulls powder, etc. and a far infrared rays emitting material without the use of a plasticizer is provided which is improved in deodorizing properties, heat retaining property, moisturizing property, antimicrobial property and humidity control function. CONSTITUTION: A paste composition containing 30 to 50% by weight of soluble synthetic resin, 5 to 25% by weight of a natural material, 1 to 5% by weight of titanium dioxide, 10 to 25% by weight of calcium carbonate, 1 to 5% by weight of an aqueous foaming agent, 10 to 20% by weight of water, 0.1 to 0.5% by weight of a dispersant, 0.1 to 0.5% by weight of a defoaming agent and 1 to 5% by weight of a softening agent, and 5 to 15% by weight of a fire retardant agent is coated to a paper surface in an amount of 30 to 100g/m¬2.

Description

합성수지류와 생분해 가능한 자연소재를 혼합한 벽지{omitted}Wallpaper blended with synthetic resins and biodegradable natural materials {omitted}

본 발명은 목분( 소나무, 향나무, 잣나무, 육송, 백송등의 목제류의 목분을 칭함) 및 왕겨분, 콜크분, 건초분, 건수초분, 펄프파우다등의 생분해가 가능한 자연소재와 수용성 아크릴수지, EVA수지,PE수지 계면활성제가 포함된 EVA수지, 우레탄 계통의 수지류를 이용한 벽지에 관한 것이다.The present invention is a biodegradable natural material and water-soluble acrylic resin, such as wood flour (pine wood, juniper, pine, meat, white pine, etc.) and chaff powder, cork powder, hay powder, dried grass powder, pulp powder, It relates to an EVA resin, an EVA resin containing a PE resin surfactant, wallpaper using a urethane resin.

기존의 합성수지 벽지는 발포벽지 및 PVC 벽지 등으로 구별되고 있으며 PVC 및 가소제를 주성분으로 하여 벽지를 형성 하는데 이때 사용하는 가소제는 미국식품 의약국에서 (FDA)공식 발암물질로 규정된 물질이며, PVC 벽지 및 발포벽지에 공히 사용되는 유기용제는 대기오염 및 환경문제를 유발하는 두원인이 되고 있다.Conventional synthetic resin wallpaper is divided into foam wallpaper and PVC wallpaper, and the wallpaper is composed of PVC and plasticizer as the main ingredients.The plasticizer used at this time is a material prescribed by the US Food and Drug Administration as a (FDA) official carcinogen, and PVC wallpaper And organic solvents used in both foam wallpaper has become two causes of air pollution and environmental problems.

또한 소각시는 가소제에 의한 다이옥신이 발생한다.In case of incineration, dioxin is generated by a plasticizer.

이와같은 문제점을 해결하고져 특허등록 10-0192935번 에서는 명반석, 규각, 게르마늄, 제오라이트 등 원적외선 방사물질을 혼합하거나 특허등록 10-0237559호 에서는 황토를 이용하여 가소제의 유해성분 및 포르 말레이드 성분을 저감 하고져 하는데 PVC와 가소제가 분해되지 않은 상태에서는 저감 될 수 있다는 근거는 없는 상태이다.To solve this problem, patent registration No. 10-0192935 mixes far-infrared radiation materials such as alum, quartz, germanium, and zeolite, and patent registration No. 10-0237559 uses loess to reduce harmful and formalin components of plasticizers. There is no evidence that PVC and plasticizers can be reduced without degradation.

또한 상기 특허2건에서 사용되는 가소제 및 PVC는 전체 배합비의 주성분으로 구성되어 있기 때문에 가소제 및 PVC 특성상 통기성과 습도 조절을 할수 있는 기능성은 미지수다.In addition, since the plasticizer and PVC used in the above two patents are composed of the main components of the total blending ratio, the functionality of the breathability and humidity control in the properties of the plasticizer and PVC is unknown.

본 발명에 사용되는 합성수지류는 수용성 수지류로써 아크릴계통의 수지, EVA수지, PE 수지, 계면활성제가 포함된 EVA수지, 우레탄 계통의 수지 등은 토양 속에서 5∼7년 정도 시간이 경과되면 썩거나 자연분해되는 것으로 화공업계에서 공지된 상식이며 또한 첨가되는 목분, 왕겨분, 콜크분, 건초분, 건수초분, 펄프파우다등은 생분해가 가능한 천연소재이며,기능성을 부여하기 위해 첨가되는 황토, 일라이트, 맥반석, 옥, 숯분, 게르마늄, 세라믹, 명반석, 장석, 규각, 제오라이트 등 원적외선 방사물질을 혼합하여 제품을 형성하면 제품사용시는 항균, 보온, 보습, 원적외선 방사기능을 가지며 폐기시는 생분해를 촉진하여 환경 공해를 최소화 하고져 하는데 있다.Synthetic resins used in the present invention are water-soluble resins, such as acrylic resins, EVA resins, PE resins, EVA resins containing surfactants, urethane-based resins, etc., after 5-7 years in soil. Or powdered wood powder, chaff powder, cork powder, hay powder, dry grass powder, pulp powder, etc. are biodegradable natural materials and are added to impart functionality. When products are formed by mixing far-infrared radiation materials such as light, ganban stone, jade, charcoal powder, germanium, ceramics, alumite, feldspar, quartz, and zeolite, they have antibacterial, warm, moisturizing and far-infrared radiation in use and promote biodegradation in disposal. This is to minimize environmental pollution.

본 발명은 PVC 수지와 FDA에서 공식 발암물질로 규정한 가소제를 전혀 사용하지 않으면서 수용성 합성수지류와 천연소재인 목분, 왕겨분, 콜크분, 건초분, 건수초본, 펄프파우다등과 원적외선 방사물질을 첨가하여 탈취성, 보온성, 보습성, 항균성, 습도조절 기능을 부여한 벽지의 조성물질을 제공하고져 한다.The present invention is water-soluble synthetic resins and natural materials such as wood flour, rice husk flour, cork flour, hay flour, dried herbaceous acid, pulp powder and the like and far-infrared radiation materials without using any PVC resin and plasticizer prescribed by the FDA as a carcinogen. It should be added to provide the composition of the wallpaper to which the deodorizing, warming, moisturizing, antimicrobial, humidity control function.

본 발명의 전체적인 제조 공정을 제1도에서 공정순서의 개념을 도시하며 제조된 벽지 단면도가 제2도에 도시되고 있다.The overall manufacturing process of the present invention is shown in FIG. 2, with the cross-sectional view of the manufactured wallpaper showing the concept of the process sequence in FIG.

본 발명은 수용성 수지류에서 아크릴계통의 수지, EVA 계통의 수지, PE계통의 수지, 계면 활성제가 포함된 EVA수지, 우레탄계통의 수지중 어느 하나 또는 이들을 혼합한 수지의 30∼50중량%부, 목분, 왕겨분, 콜크분, 건초분, 건수초분, 펄프, 파우다등 천연소재중 어느하나 또는 이들을 혼합한 소재의 5∼25중량%, 티탄늄디옥사이드 1∼5중량%, 탄산칼슘 10∼25중량%, 수성발포제 1∼5중량%, 물 10∼20중량%, 분산제 0.1∼0.5중량%, 소포제 0.1∼0.5중량%, 유연제 1∼5중량%, 부토 혼합하거나 기능성을 부여하기 위해 황토, 일라이트, 맥반석, 옥, 게르마늄, 세라믹, 숯분, 명반석, 장석, 규각, 제오라이트 등 원적외선 방사물질중 어느 하나 또는 이들을 혼합한 방사물질 5∼15 중량%로 첨가된 벽지의 조성물이다.The present invention is 30 to 50% by weight of the resin of the acrylic resin, the resin of the EVA system, the resin of the PE system, the EVA resin containing a surfactant, the resin of the urethane-based resin or a mixture thereof in water-soluble resins, 5 to 25% by weight of any one of natural materials such as wood flour, chaff powder, cork powder, hay powder, dry grass powder, pulp, powder, or a mixture thereof, 1 to 5 weight percent titanium dioxide, 10 to 25 weight calcium carbonate %, 1 to 5% by weight aqueous foaming agent, 10 to 20% by weight water, 0.1 to 0.5% by weight dispersant, 0.1 to 0.5% by weight defoaming agent, 1 to 5% by weight softener, loess, illite for mixing or imparting functionality It is a composition of the wallpaper added with 5 to 15% by weight of any one of the far-infrared radiation materials such as, ganban stone, jade, germanium, ceramic, charcoal powder, alum stone, feldspar, zeolite, zeolite, or a mixture thereof.

본 발명의 조성물은 다음과 같이 제조된다.The composition of the present invention is prepared as follows.

1) 목분 ( 소나무, 향나무, 잣나무, 백송, 육송등의 목제류의 목분을 칭함) 왕겨분, 콜크분, 건초분, 건수초분, 펄프파우다 등의 천연소재를 일정한 입도로 분쇄하여 입도 분리하여 사용한다.1) Wood powder (referred to wood powder such as pine, juniper, pine, white pine, meat, etc.) Used to separate grain size by crushing natural materials such as chaff powder, cork powder, hay powder, dried grass powder, and pulp powder do.

40∼8O메쉬사이, 80∼120메쉬사이, 120∼150메쉬사이, 150∼200메쉬사이, 200메쉬 이상등으로 분리하여 어느 입도를 선택하여 사용한다.Any particle size can be selected by separating between 40 and 80 mesh, between 80 and 120 mesh, between 120 and 150 mesh, between 150 and 200 mesh, and more than 200 mesh.

이때 입자가 클수록 코팅작업은 어렵지만 질감 표현이 좋으며 입자가 작으면 코팅 작업은 좋지만 질감 표현이 반감될 수 있다.In this case, the larger the particle, the more difficult the coating work, but the texture is good, and the smaller the particle, the better the coating but the texture may be halved.

2) 황토, 일라이트, 맥반석, 옥, 게르마늄, 세라믹, 숯분, 명반석, 장석, 규각, 제오라이트 등 원적외선 방사물질은 300메쉬 이상 분쇄하여 사용하며 방사 물질은 어느 하나를 선별하여 사용할수도 있으며 또는 혼합하여 사용할 수도 있다.2) Far-infrared radiating materials such as ocher, illite, elvan, jade, germanium, ceramic, charcoal, alum, feldspar, quartz, zeolite are pulverized more than 300 mesh, and the radiating materials may be selected or used in combination. Can also be used.

상기 소재의 효능은 황토는 인체의 신진대사에 필요한 미네랄 성분이 다량 포함되어 있고 흡착성 생분해성이 강하고 현재에도 오수등의 정화에 주로 활동되고 있다, 일라이트는 점토질 연질 운모 광물이며 삼층 인편상 구조로써 물에 풀었을때는 견사 현상을 나타내는 독특한 성질이 있고, 그 주성분은 SiO2, Al2O3,K2O, FEO2등으로 구성되어 있으며 국내특허공보 제4623호 공고번호 96-12091호에 흡착 탈취제는 일라이트를 주성분으로 하고 있다.The efficacy of the material is that ocher contains a large amount of minerals necessary for the metabolism of the human body, has strong adsorptive biodegradability, and is still mainly used for purification of sewage, etc. When unwrapped in water, it has a unique property of showing silkiness, and its main component is composed of SiO 2 , Al 2 O 3 , K 2 O, FEO 2, etc., and it is adsorbed by Korean Patent Publication No. 4603 Publication No. 96-12091 Deodorant is based on illite.

맥반석은 SiO2, Al2O3, Fe2O3, CaO, M2O, K2O, Na2O, TiO2, MnO, P2O5를 주성분으로 하는 광물로써 항균작용과 원적외선 방사효능을 가지고 있다.Elvanite is a mineral composed mainly of SiO 2 , Al 2 O 3 , Fe 2 O 3 , CaO, M 2 O, K 2 O, Na 2 O, TiO 2 , MnO, P 2 O 5 . Have

이상과 같이 상기 소재등은 일반적으로 원적외선 방사물질로 검증이 가능한 소재등이다.As described above, the material is generally a material that can be verified as a far-infrared radiation material.

이상과 같이 준비된 원료를 아래의 혼합비 예로 혼합하여 사용한다.The raw materials prepared as above are mixed and used as an example of the mixing ratio below.

혼합비 예 1) 중량%임Mixing ratio example 1) Weight%

※ 상기 조성 비율은 작업 조건에 따라 변할 수 있다.※ The composition ratio may vary depending on the working conditions.

이때 상기 혼합비에서 합성수지류는 수용성 아크릴 수지, EVA수지, PE수지, 생분해성 계면 활성제가 포함된 EVA수지, 우레탄 수지등 어느 하나를 선정하여 사용할 수 있으며 혼합하여 사용할 수 도 있다.At this time, in the mixing ratio, the synthetic resin can be used by selecting any one of water-soluble acrylic resin, EVA resin, PE resin, EVA resin containing a biodegradable surfactant, urethane resin, etc., can also be mixed.

또한 천연소재류는 목분, 왕겨분, 콜크분, 건초분, 건수초분,펄프, 파우다등 어느하나를 선정하여 사용 할수도 있으며 혼합하여 사용할 수 도 있다.In addition, natural materials may be selected from wood flour, rice husk flour, cork flour, hay flour, dried grass flour, pulp, powder, etc., or may be mixed.

상기 혼합비에서 알수 있듯이 D∼G배합비는 유연성을 요구될 때 사용하며 A∼B 는 발포제 사용량이 많아서 고발포성을 요구될 때 사용한다.As can be seen from the above mixing ratio, the D to G blending ratio is used when flexibility is required, and A to B are used when a high foaming amount is required due to the high amount of blowing agent.

또한 B.D.F배합비는 기능성을 요구될 때 적용하며 원적외선 방사물질로는 황토, 일라이트, 맥반석, 옥, 숯분, 게르마늄, 세라믹, 명반석,장석, 규각, 제오라이트등 방사물질을 어느 하나를 선정하여 사용할 수도 있으며 혼합하여 사용할 수도 있다.In addition, the BDF blend ratio is applied when the functionality is required, and one of the far-infrared radiating materials can be selected by using radiating materials such as ocher, illite, ganban stone, jade, charcoal powder, germanium, ceramic, alumite, feldspar, quartz and zeolite. It can also be mixed and used.

또한 본 발명에서 벽지에 난연성을 부여하고져 할때는 일반제지공장에서 생산되는 난연처리된 원지를 사용하며 합성수지류에 불활성 기체인 불소계통의 난연제, 염소계통의 난연제, 부륨계통, 안티몬계통, 인산염계통, 지르코늄계통등의 난연제중 어느 하나 또는 혼합하여 사용하며 이때 사용량은 5∼15중량% 부로 사용한다.In addition, in the present invention, when the flame retardancy is given to the wallpaper, flame retardant raw paper produced in a general paper mill is used, and an inert gas is a fluorine-based flame retardant, chlorine-based flame retardant, burium-based, antimony-based, phosphate-based, zirconium Use one or a mixture of flame retardants such as the system, and the amount is used in 5 to 15% by weight.

이때 혼합비예는 다음과 같이 실시할수 있다.At this time, the mixing ratio can be carried out as follows.

혼합비 예2) 중량%임Mixing ratio Example 2) Weight%

※ 상기 조성비율은 작업조건에 따라 변할 수 있다.※ The composition ratio may change depending on working conditions.

상기 조성비율중 B.D.F 의 혼합비는 난연성에 기능성을 부여하고져 할 때 사용한다.The mixing ratio of B.D.F in the above composition ratio is used to impart functionality to flame retardancy.

이상의 코팅조성물을 기초로한 벽지제조 공정을 첨부도면에 의거하여 설명하면 다음과 같다.The wallpaper manufacturing process based on the coating composition described above will be described based on the accompanying drawings.

원지를 롤라에 장착한후 본 발명 혼합물이 배합된 재료가 담긴 코팅액 저장조로 통과시켜 원지 상면에 고형분 기준으로 30∼100 g/m2정도로 고루게 코팅한 후 건조시킨다.After the base paper is mounted on the roll, it is passed through a coating solution storage tank containing the blended material of the present invention and coated on the base paper with a solid content of 30 to 100 g / m 2 evenly and dried.

건조가 완료된 원지는 쿨링기에서 원지 및 수지를 냉각시켜 경화시킨다. 쿨링기를 통과한 원지는 인쇄기를 통과 하면서 인쇄층을 구성하고 40M/분의 속도로 120∼200℃로 가열단계에서 혼합액에 첨가된 수성발포제의 발포가 일어날 수 있도록 가열하며 다시 성형하고져 하는 형압단계를 통과하면서 제품의 좌,우 미미를 절단하며 일정길이 방향으로 2차 절단 작업을 한후 포장한다.The dried base paper is cured by cooling the base paper and the resin in a cooler. After passing through the cooling machine, the base paper forms a printing layer while passing through the printing machine, and at a rate of 40 M / min, a mold pressing step is performed by heating and remolding the aqueous foaming agent added to the mixed solution in a heating step so as to cause foaming of the aqueous foaming agent added to the mixed solution. As it passes, it cuts the left and right ends of the product, and after cutting the secondary in a certain length direction, it is packed.

도 1은 본 발명의 벽지 공정도1 is a wallpaper process diagram of the present invention

도 2는 본 발명의 벽지 단면도2 is a cross-sectional view of the wallpaper of the present invention

- 도면의 주요부분에 대한부호설명--Explanation of symbols on the main parts of the drawings-

도2의 1 : 원지 도2의 2 : 코팅층2: 1 base paper 2: 2 coating layer

도2의 3 : 인쇄층2 3: printed layer

..

PVC 수지와 발암물질인 가소제를 사용하지 않으면서 천연소재인 목분, 펄프파우다등을 합성 수지류와 혼합하여 생분해가 가능한 환경 친화적인 벽지를 형성 하고져 하는데 있다.Without using PVC resins and plasticizers that are carcinogens, natural wood flour and pulp powder are mixed with synthetic resins to form biodegradable environment-friendly wallpaper.

Claims (2)

원지(1)의 표면에 원료수지 100Kg기준으로 수용성 합성수지류 30∼50 중량%부, 천연소재류 5∼25 중량%부, 티탄늄 디옥사이드 1∼5중량%부, 탄산칼슘 10∼25중량%부, 수성발포제 1∼5중량%부, 물 10∼20중량%부, 분산제 0.1∼0.5중량%부, 소포제 0.1∼0.5중량%부, 유연제 1∼5중량%부 로 배합되어 죽상태의 수지(2)가 고형분 기준으로 30∼100g/m2정도 원지(1)에 코팅되거나 원적외선 방사물질이 5∼15중량%부로 첨가하여 원지에 코팅 되는 것을 특징으로 하는 천연소재를 이용한 벽지.30 to 50% by weight of water-soluble synthetic resins, 5 to 25% by weight of natural materials, 1 to 5% by weight of titanium dioxide, 10 to 25% by weight of calcium carbonate, 1 to 5% by weight of an aqueous foaming agent, 10 to 20% by weight of water, 0.1 to 0.5% by weight of a dispersant, 0.1 to 0.5% by weight of an antifoaming agent, and 1 to 5% by weight of a softening agent. 30 to 100 g / m 2 on the basis of the solid content, or wallpaper using a natural material, characterized in that the coating on the base paper by adding 5 to 15% by weight of far-infrared radiation material. 제1항에 있어서, 난연성을 부여하고져 할때는 일반원지 대신에 난연원지를 사용하며 수용성 합성수지류 30∼50 중량%부, 천연소재류 5∼25중량%부, 티탄늄 디옥사이드 1∼5중량%부, 탄산칼슘 10∼25중량%부, 수성발포제 1∼5 중량%부, 물 10∼20중량%부, 분산제 0.1∼0.5 중량%부, 소포제 0.1∼0.5중량%부, 유연제 1∼5중량%부, 난연제 5∼15중량%부로 배합되어 죽상태의 수지(2)가 고형분 기준으로 30∼100g/m2정도 원지에 코팅되거나 원적외선 방사물질이 5∼15 중량%부로 첨가하여 원지에 코팅되는 것을 특징으로 하는 천연소재를 이용한 난연벽지.A flame retardant base is used in place of general base paper to impart flame retardancy, and 30 to 50 wt% of water-soluble synthetic resins, 5 to 25 wt% of natural materials, 1 to 5 wt% of titanium dioxide, and carbonic acid. 10 to 25% by weight of calcium, 1 to 5% by weight of an aqueous foaming agent, 10 to 20% by weight of water, 0.1 to 0.5% by weight of dispersant, 0.1 to 0.5% by weight of antifoaming agent, 1 to 5% by weight of softener, flame retardant 5 to 15% by weight of the blended resin (2) on the basis of solids is coated on the base of about 30 to 100g / m 2 or far-infrared radiation material is added to 5 to 15% by weight, characterized in that the coating on the base Flame retardant wallpaper using natural materials.
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KR20030042774A (en) * 2001-11-23 2003-06-02 전효철 Non-woven fabrics and fabrics mixed with synthetic resins, water-based foaming agent and natural materials, and applied to a certain amount on top of the fiber
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