KR20010091023A - Silver particle-containing nonwoven - Google Patents

Silver particle-containing nonwoven Download PDF

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Publication number
KR20010091023A
KR20010091023A KR1020010014307A KR20010014307A KR20010091023A KR 20010091023 A KR20010091023 A KR 20010091023A KR 1020010014307 A KR1020010014307 A KR 1020010014307A KR 20010014307 A KR20010014307 A KR 20010014307A KR 20010091023 A KR20010091023 A KR 20010091023A
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South Korea
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silver
nonwoven fabric
woven fabric
silver particle
silver particles
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KR1020010014307A
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Korean (ko)
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안정오
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안정오
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Priority to KR1020010014307A priority Critical patent/KR20010091023A/en
Publication of KR20010091023A publication Critical patent/KR20010091023A/en

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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/06—Inorganic compounds or elements
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/13—Physical properties anti-allergenic or anti-bacterial
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00—Wearing apparel
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2509/00—Medical; Hygiene
    • D10B2509/02—Bandages, dressings or absorbent pads
    • D10B2509/026—Absorbent pads; Tampons; Laundry; Towels

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Absorbent Articles And Supports Therefor (AREA)

Abstract

PURPOSE: A non-woven fabric containing silver particle is provided, which has bactericidal effect, disinfecting effect and excellent antibacterial property and is useful for a diaper, a hygienic band, a wrapping paper of tea and clothes. CONSTITUTION: The non-woven fabric(1) is characterized by containing 0.0005-0.015μm of the silver particle(2) having at least 5ppm of concentration. The non-woven fabric is obtained by: when the non-woven fabric is produced, mixing the silver particle with the polymer, followed by spinning; spraying the silver particle on the non-woven fabric, followed by air-drying; or settling the non-woven fabric into silver solution, followed by air-drying.

Description

은입자 함유 부직포{.}Silver Particle-containing Nonwovens {.}

본 발명은 은입자 함유 부직포에 관한 것으로 더욱 상세하게는 기저귀, 생리대, 차류 포장용지 및 의복에 사용하는 부직포에 살균, 소독능이 있는 은입자를 함유시켜 제조한 항균성 부직포에 관한 것이다.The present invention relates to a silver particle-containing nonwoven fabric, and more particularly, to an antimicrobial nonwoven fabric prepared by containing silver particles having sterilization and disinfection ability in nonwoven fabrics used in diapers, sanitary napkins, tea packaging papers and clothing.

은(銀)은 콜로이드실버로 인체에 무해하고 무중독, 무내성으로 일반약품과는 달리 부작용이 전혀 없으면서 강력한 자연위생,살균소독 및 여드름, 부스럼, 뾰루지, 습진, 무좀 등의 피부트러블을 개선하여 피부를 보호하고 피부세포를 재생시키는 효과가 있는 것으로 알려져 있다.Silver is a colloidal silver that is harmless to the human body and is nontoxic and non-tolerant, and has no side effects unlike other general medicines.It has strong natural hygiene, disinfectant disinfection and skin problems such as acne, swelling, rashes, eczema and athlete's foot. It is known to protect skin and regenerate skin cells.

한편, 각종 항균 및 방취성 화합물을 함유하는 항균성 섬유는 이미 공지되어 있다. 그러나 항균화합물과 섬유와의 결합이 불완전하기 때문에 세탁, 가열 또는 자외선 조사 등에 의하여 항균 화합물은 탈리되거나 변질되어 인체나 자연환경에유해한 물질을 발생시키는 경우가 많았다. 예를 들면, 방향족 할로겐 계통의 트리클로산을 사용한 제품은 고온가열 또는장시간의 자외선 조사에 의해 다이옥신과 같은 독성물질을 발생하여 유해하며, 항균성 제올라이트나 이산화규소 등의 무기항균제는 변색되거나 인체에 유해한 금속을 발생하므로 안전성에 문제가 있고 옥타데실디메틸(3-트리메톡실프로필)암모니움 클로라이드, 벤조알코니움 클로라이드, 세틸 디메틸 벤질암모니움 클로라이드 등의 제4급 암모늄염계, 구아니딘계,페놀계 등의 유기 항균제는 피부표면의 미생물과의 평형이 무너져 무해한 균이 병원균으로 작용하거나 병원균의 침투 기회를 제공할 수 있고, 인체의 민감한 부위에 피부질환을 유발하는 등의 폐단이 있었다.On the other hand, antimicrobial fibers containing various antibacterial and deodorant compounds are already known. However, due to the incomplete coupling of the antimicrobial compound and the fiber, the antimicrobial compound was desorbed or deteriorated due to washing, heating or UV irradiation, which in turn caused harmful substances to the human body or the natural environment. For example, products using aromatic halogen-based triclosan are harmful because they generate toxic substances such as dioxin by high temperature heating or ultraviolet irradiation for a long time. This is a safety problem, and quaternary ammonium salts such as octadecyldimethyl (3-trimethoxylpropyl) ammonium chloride, benzoalkonium chloride, cetyl dimethyl benzyl ammonium chloride, guanidine, phenol, etc. The antimicrobial agent has a balance between microorganisms on the surface of the skin, which can cause harmless bacteria to act as pathogens or provide opportunities for invading pathogens, and cause skin diseases in sensitive areas of the human body.

상기와 같은 문제점에 의해 인체에 무해한 은분말을 함유하는 부직포가 실험적으로 제조되었으나 미세한 굵기의 섬유조직을 갖는 은분말 함유 부직포는 제조할 수 없었다.Due to the above problems, a nonwoven fabric containing silver powder, which is harmless to the human body, has been experimentally produced, but a silver powder-containing nonwoven fabric having a fine thickness fiber structure could not be manufactured.

본 발명자는 상기와 같은 점에 착안하여 살균소독 작용이 있고 인체에 무해한 은입자를 이온화상태로 합성수지 제조시폴리머 중에 혼합시켜 방사하거나 제조가 완료된 합성수지에 도포하여 부착시킴으로써 항균성이 있는 부직포를 제조하여본 발명을 완성하였으며 상기 제조된 부직포는 기저귀, 위생대, 차류 포장용지, 의복 등에 사용될 경우 유용하다.The present inventors pay attention to the above point to produce antimicrobial nonwoven fabrics by disinfecting and disinfecting silver particles which are harmless to the human body by mixing them in a polymer during the production of synthetic resins and spinning them or by applying them to the finished synthetic resins. The nonwoven fabric produced is useful when used in diapers, sanitary napkins, tea packaging, clothing, and the like.

따라서, 본 발명의 목적은 0.0005 ~ 0.015 ㎛ 크기의 은입자를 5ppm 이상 함유하는 항균성 부직포를 제공함에 있다.Accordingly, it is an object of the present invention to provide an antimicrobial nonwoven fabric containing at least 5 ppm of silver particles having a size of 0.0005 to 0.015 μm.

본 발명의 상기 목적은 0.0005∼0.015 ㎛ 크기의 은입자를 합성수지 재질의 부직포 제조시 그 폴리머 중에 혼합한 후 방사하거나 제조가 완료된 합성수지 재질의 부직포 표면에 은입자를 스프레이하거나 침적한 후 송풍건조시켜 상기 은입자가5ppm 이상 함유된 부직포를 제조함으로써 달성하였다.The object of the present invention is to mix the silver particles of 0.0005 ~ 0.015 ㎛ size in the polymer when manufacturing the non-woven fabric of synthetic resin spinning or spraying or depositing the silver particles on the surface of the non-woven fabric of the synthetic resin material is completed by blowing and drying This was achieved by producing a nonwoven fabric containing 5 ppm or more of silver particles.

도 1은 본 발명 은입자 함유 부직포의 사시도를 나타낸다.BRIEF DESCRIPTION OF THE DRAWINGS The perspective view of the silver particle containing nonwoven fabric of this invention is shown.

* 도면의 주요부분에 대한 부호설명 ** Explanation of Signs of Major Parts of Drawings *

1 : 부직포 2 : 은입자1: nonwoven fabric 2: silver particles

이하, 본 발명의 은입자 함유 부직포를 도면에 의거하여 상세히 설명하나 본 발명의 권리범위는 이에 한정되지 않으며 본 발명의 기술적 사상의 범위내에서 혼합, 제조방법, 재료 등은 얼마든지 치환 또는 변형이 가능하다는 것이 당업자에게 명백히 이해될 것이고 이 또한 본 발명의 권리범위에 속함은 물론이다.Hereinafter, the silver particle-containing nonwoven fabric of the present invention will be described in detail with reference to the drawings. However, the scope of the present invention is not limited thereto, and any mixing, manufacturing method, material, or the like may be substituted or modified within the scope of the technical idea of the present invention. It will be apparent to those skilled in the art that this is possible and this also belongs to the scope of the present invention.

도 1에 도시한 바와 같이 본 발명 은입자 함유 부직포는 합성수지 재질의 부직포(1)에 은입자(2)를 함유시켰다. 은입자는 은이온을 함유하는 은용액을 부직포제조시 폴리머 중에 혼합시킨 후 방사하거나 은이온 함유 은용액을 제조가 완료된부직포에 스프레이 하였다. 도 1은 제조가 완료된 부직포에 은이온을 함유한 은용액을 스프레이 처리한 경우로 부직포 표면에 은입자가 존재하지만 부직포 제조시 폴리머 중에 혼합시킨 후 방사한 경우는 부직포 섬유조직 내부에 까지 은입자가 존재한다.As shown in FIG. 1, the silver particle-containing nonwoven fabric of the present invention contained silver particles 2 in a nonwoven fabric 1 made of a synthetic resin material. The silver particles were mixed with silver ions containing silver ions in the polymer during manufacture of the nonwoven fabric and then spun, or the silver ions containing silver ions were sprayed onto the finished nonwoven fabric. 1 is a case in which a silver solution containing silver ions is sprayed on a finished nonwoven fabric, but silver particles are present on the surface of the nonwoven fabric. exist.

상기와 같이 제조된 부직포는 용도에 따른 기저귀, 생리대, 차류 포장용지에 사용되고, 의복에 사용될 경우 은이온은 피부에 친화적인 음이온이 되어 친화적 성질을 나타냄으로써 알레르기 등 민감 피부에도 안전할 뿐만 아니라 은이 갖는 살균, 소독효과를 나타낸다.The nonwoven fabric prepared as described above is used for diapers, sanitary napkins and tea packaging papers according to the use, and when used in clothing, silver ions become anions that are friendly to the skin and exhibit friendly properties. Sterilization and disinfection effect.

이하, 실시예를 들어 은입자 함유 부직포 제조를 구체적으로 설명하고자 한다.Hereinafter, the production of silver particles-containing nonwoven fabrics will be described in detail.

차류 포장용지의 재료는 마닐라삼 섬유와 열정성 섬유로 이는 은이온과 친화성이 있다. 따라서, 상기 액체 상태의 마닐라삼 섬유와 열정성 섬유를 혼합한 후 혼합된 폴리머에 0.0005㎛ 크기의 은입자가 7ppm 함유되도록 은용액을 첨가한 후잘 섞이도록 혼합 교반한 다음 방사하고 수분은 건조시켜 제거하였다.Tea packaging materials are manila hemp fiber and passionate fiber which are compatible with silver ions. Therefore, after mixing the liquid manila hemp fiber and passionate fiber, a silver solution is added to the mixed polymer to contain 7 ppm of silver particles having a size of 0.0005 μm, followed by mixing and stirring to mix well, spinning, and drying to remove moisture. It was.

의복용 부직포 원자재인 합성수지는 은이온과 친화성이 없으므로 먼저 부직포를 통상의 방법으로 제조한 후 0.0005㎛ 크기의 은입자가 함유된 10ppm 농도의 은용액을 부직포 표면에 스프레이하거나 은용액에 부직포를 침적한 후 송풍건조시켰다.Synthetic resin, which is a raw material of garment nonwoven fabric, is not compatible with silver ions. First, nonwoven fabric is manufactured by conventional method, and then 10ppm silver solution containing 0.0005㎛ size silver particles is sprayed on the surface of nonwoven fabric or nonwoven fabric is deposited on silver solution. After air drying.

이상 설명한 바와 같이, 본 발명의 은입자 함유 부직포는 은이 갖는 본래의 살균, 소독 등에 의해 기저귀, 생리대, 차류포장용지, 의복 등에 사용되어 우수한 항균성을 나타내는 뛰어난 효과가 있으므로 섬유산업상 매우 유용한 발명인 것이다.As described above, the silver particle-containing nonwoven fabric of the present invention is used in diapers, sanitary napkins, tea packaging papers, clothing, etc. by the original sterilization, disinfection, and the like of silver, and thus is an extremely useful invention in the textile industry.

Claims (2)

0.0005 ∼ 0.015㎛ 크기의 은입자(2)를 5ppm 이상의 농도로 부직포(2)에 함유시킨 은입자 함유 부직포.A silver particle-containing nonwoven fabric comprising silver particles (2) having a size of 0.0005 to 0.015 µm in the nonwoven fabric (2) at a concentration of 5 ppm or more. 제조가 완료된 합성수지 재질의 부직포 표면에 은입자를 스프레이하거나 침적한 후 송풍건조시켜 상기 은입자를 함유시킨 은입자 부직포.A silver particle nonwoven fabric containing the silver particles by spray-drying or depositing silver particles on the surface of the synthetic resin nonwoven fabric which has been manufactured.
KR1020010014307A 2001-03-20 2001-03-20 Silver particle-containing nonwoven KR20010091023A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20040016758A (en) * 2002-08-19 2004-02-25 최명부 The magative ion antibvacterial nonwoven fabrics
WO2003080911A3 (en) * 2002-03-27 2004-03-18 Cc Technology Invest Co Ltd Antimicrobial yarn having nanosilver particles and methods for manufacturing the same
KR100423806B1 (en) * 2001-08-07 2004-03-22 휴먼사이언스테크놀러지(주) Method for a manufacturing of vagina sanitary goods
KR100473777B1 (en) * 2001-12-13 2005-03-08 주식회사 트리코유니온 Preparation methods of resin compositions containing silver particles of nano size
US20130319599A1 (en) * 2012-06-05 2013-12-05 GM Global Technology Operations LLC Non-woven polymer fiber mat for use in a lithium ion battery electrochemical cell

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH042877A (en) * 1989-12-27 1992-01-07 Nichibi:Kk Antibacterial fiber and production thereof
JPH0760032A (en) * 1993-08-27 1995-03-07 Nippon Sheet Glass Co Ltd Antibacterial filter paper
JPH08325915A (en) * 1995-03-23 1996-12-10 Idemitsu Petrochem Co Ltd Nonwoven fabric, its laminate and production of nonwoven fabric
JPH09143850A (en) * 1995-11-22 1997-06-03 Habitsukusu Kk Highly water-absorbing/antibacterial sheet
KR200186177Y1 (en) * 1999-12-30 2000-06-15 안정오 Sanitary panties
KR20010000100U (en) * 1999-06-02 2001-01-05 안정오 Aaaaa

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH042877A (en) * 1989-12-27 1992-01-07 Nichibi:Kk Antibacterial fiber and production thereof
JPH0760032A (en) * 1993-08-27 1995-03-07 Nippon Sheet Glass Co Ltd Antibacterial filter paper
JPH08325915A (en) * 1995-03-23 1996-12-10 Idemitsu Petrochem Co Ltd Nonwoven fabric, its laminate and production of nonwoven fabric
JPH09143850A (en) * 1995-11-22 1997-06-03 Habitsukusu Kk Highly water-absorbing/antibacterial sheet
KR20010000100U (en) * 1999-06-02 2001-01-05 안정오 Aaaaa
KR200186177Y1 (en) * 1999-12-30 2000-06-15 안정오 Sanitary panties

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100423806B1 (en) * 2001-08-07 2004-03-22 휴먼사이언스테크놀러지(주) Method for a manufacturing of vagina sanitary goods
KR100473777B1 (en) * 2001-12-13 2005-03-08 주식회사 트리코유니온 Preparation methods of resin compositions containing silver particles of nano size
WO2003080911A3 (en) * 2002-03-27 2004-03-18 Cc Technology Invest Co Ltd Antimicrobial yarn having nanosilver particles and methods for manufacturing the same
US6979491B2 (en) 2002-03-27 2005-12-27 Cc Technology Investment Co., Ltd. Antimicrobial yarn having nanosilver particles and methods for manufacturing the same
KR20040016758A (en) * 2002-08-19 2004-02-25 최명부 The magative ion antibvacterial nonwoven fabrics
US20130319599A1 (en) * 2012-06-05 2013-12-05 GM Global Technology Operations LLC Non-woven polymer fiber mat for use in a lithium ion battery electrochemical cell
US9346066B2 (en) * 2012-06-05 2016-05-24 GM Global Technology Operations LLC Non-woven polymer fiber mat for use in a lithium ion battery electrochemical cell

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