KR102590852B1 - Capsule type detergent - Google Patents

Capsule type detergent Download PDF

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KR102590852B1
KR102590852B1 KR1020230077853A KR20230077853A KR102590852B1 KR 102590852 B1 KR102590852 B1 KR 102590852B1 KR 1020230077853 A KR1020230077853 A KR 1020230077853A KR 20230077853 A KR20230077853 A KR 20230077853A KR 102590852 B1 KR102590852 B1 KR 102590852B1
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weight
parts
capsule
water
type detergent
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KR1020230077853A
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Korean (ko)
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최규태
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주식회사 블루워시
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/08Liquid soap, e.g. for dispensers; capsuled
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L29/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
    • C08L29/02Homopolymers or copolymers of unsaturated alcohols
    • C08L29/04Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/04Polyesters derived from hydroxycarboxylic acids, e.g. lactones
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/042Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
    • C11D17/043Liquid or thixotropic (gel) compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/382Vegetable products, e.g. soya meal, wood flour, sawdust
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/386Preparations containing enzymes, e.g. protease or amylase

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Dispersion Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

본 발명은 캡슐형 세제에 관한 것으로, 보다 상세하게는 세제 사용량을 줄이면서도 특히, 인체에서 배출되는 단백질이나 지방에 의해 찌든 때를 쉽게 잘 분리 분해하여 제거함으로써 세탁효과를 높이되, 옷감 손상은 최소화시킬 수 있으면서 섬유유연 특성을 더욱 증대시키고, 탈취는 물론 정전기방지 특성을 강화시킬 수 있도록 개선된 캡슐형 세제에 관한 것이다.The present invention relates to a capsule-type detergent. More specifically, the present invention relates to a capsule-type detergent. More specifically, it reduces the amount of detergent used and, in particular, easily separates and decomposes and removes stains caused by proteins or fats discharged from the human body, thereby increasing the washing effect and minimizing damage to clothes. This relates to an improved capsule-type detergent that can further increase fabric softening properties and enhance deodorizing and anti-static properties.

Description

캡슐형 세제{Capsule type detergent}Capsule type detergent

본 발명은 캡슐형 세제에 관한 것으로, 보다 상세하게는 세제 사용량을 줄이면서도 특히, 인체에서 배출되는 단백질이나 지방에 의해 찌든 때를 쉽게 잘 분리 분해하여 제거함으로써 세탁효과를 높이되, 옷감 손상은 최소화시킬 수 있으면서 섬유유연 특성을 더욱 증대시키고, 탈취는 물론 정전기방지 특성을 강화시킬 수 있도록 개선된 캡슐형 세제에 관한 것이다.The present invention relates to a capsule-type detergent. More specifically, the present invention relates to a capsule-type detergent. More specifically, it reduces the amount of detergent used and, in particular, easily separates and decomposes and removes stains caused by proteins or fats discharged from the human body, thereby increasing the washing effect and minimizing damage to clothes. This relates to an improved capsule-type detergent that can further increase fabric softening properties and enhance deodorizing and anti-static properties.

일반적으로, 세탁에 사용되는 세제는 직물의 세정을 돕기 위해 직물을 세탁할 때 첨가하는 물질이다.Generally, detergents used in laundry are substances added when washing fabrics to help clean them.

이러한 세탁 세제는 주로 분말 또는 과립 형태의 고체가 사용되고 있으며, 최근에는 액상 세제도 시판되고 있다.These laundry detergents are mainly used in the form of solid powders or granules, and recently, liquid detergents are also commercially available.

그런데, 종래 개시된 세제들은 분말, 과립, 액상을 불문하고 세정력을 높이기 위해 거품발생을 증가시키도록 거품발생제 함량을 증대시키고 있어 그만큼 세탁을 위한 물 사용량이 증가하게 되어 세탁수 낭비가 심한 단점이 있다.However, conventionally disclosed detergents, regardless of whether they are powder, granule, or liquid, increase the foaming agent content to increase foaming in order to increase cleaning power. This has the disadvantage of increasing the amount of water used for washing, resulting in significant waste of washing water. .

이를 개선하기 위해 다양한 세제 절약형 세탁볼들이 개시된 바 있다.To improve this, various detergent-saving laundry balls have been introduced.

예컨대, 은나노 코팅을 통한 항균성 강화 수준 혹은 맥반석, 제올라이트, 토르말린, 탄산칼슘 등을 세라믹볼 형태로 내장하여 원적외선 방출이나 음이온 방출에 따른 세척력 향상을 목적으로 한 것들이다.For example, these are designed to enhance antibacterial properties through silver nano coating or to improve cleaning power by emitting far-infrared rays or anions by embedding elvanite, zeolite, tourmaline, calcium carbonate, etc. in the form of ceramic balls.

하지만, 이들이 실제 인체에서 방출되는 단백질이나 지방 등이 누적된 찌든때를 쉽게 분해 제거할 수 없기 때문에 사실상 유명무실하여 소비자들로부터 외면받고 있는 것이 현실이다.However, the reality is that they are practically worthless and are being ignored by consumers because they cannot easily decompose and remove accumulated dirt such as proteins and fats released from the human body.

특히, 분말 세제의 경우, 농축된 상태이므로 과도하게 사용할 경우 환경오염의 문제가 대두되고, 세제 사용시 비산에 의한 흡입시 안전사고의 위험, 쏟아지기 쉬워 세제가 낭비되는 단점도 있다.In particular, in the case of powdered detergents, since they are in a concentrated state, environmental pollution problems arise when used excessively, there is also a risk of safety accidents when inhaled due to scattering when using detergents, and there are also disadvantages such as wasting detergent because it is easy to spill.

국내 공개특허 제10-2023-0027477호(2023.02.28.) 세척력이 우수한 캡슐세제용 조성물 및 이를 이용하여 제조한 캡슐세제Domestic Patent Publication No. 10-2023-0027477 (2023.02.28.) Composition for capsule detergent with excellent cleaning power and capsule detergent manufactured using the same

본 발명은 상술한 바와 같은 종래 기술상의 제반 문제점들을 감안하여 이를 해결하고자 창출된 것으로, 세제 사용량을 줄이면서도 특히, 인체에서 배출되는 단백질이나 지방에 의해 찌든 때를 쉽게 잘 분리 분해하여 제거함으로써 세탁효과를 높이되, 옷감 손상은 최소화시킬 수 있으면서 섬유유연 특성을 더욱 증대시키고, 탈취는 물론 정전기방지 특성을 강화시킬 수 있도록 개선된 캡슐형 세제를 제공함에 주된 목적이 있다.The present invention was created to solve the problems in the prior art as described above. It reduces the amount of detergent used and, in particular, provides a washing effect by easily separating and decomposing stains caused by proteins or fats discharged from the human body. The main purpose is to provide an improved capsule-type detergent that can minimize damage to fabric, further increase fabric softening properties, and enhance deodorizing and anti-static properties.

본 발명은 상기한 목적을 달성하기 위한 수단으로, 수용성 합성수지로 된 외피와, 상기 외피에 내장된 충전제로 이루어진 캡슐형 세제로서, 상기 충전제는 정제수 100중량부에 대해, 모노(2-프로필헵틸)에테르(Mono(2-Propylheptyl)Ether) 15중량부, 포타슘코코에이트(Potassium Cocoate) 10중량부, 라우라미도프로필하이드록시설타인(Lauramidopropyl Hydroxysultaine) 10중량부, 무환자추출물(Sapindus Mukurossi Fruit Extract) 20중량부, 복합효소 9종 각 5중량부씩 혼합되어 조성된 것을 특징으로 하는 캡슐형 세제를 제공한다.The present invention is a means to achieve the above object, and is a capsule-type detergent consisting of an outer shell made of water-soluble synthetic resin and a filler built into the outer shell, wherein the filler is mono(2-propylheptyl) based on 100 parts by weight of purified water. 15 parts by weight of ether (Mono(2-Propylheptyl)Ether), 10 parts by weight of Potassium Cocoate, 10 parts by weight of Lauramidopropyl Hydroxysultaine, 20 parts by weight of Sapindus Mukurossi Fruit Extract A capsule-type detergent is provided, characterized in that it is composed of 5 parts by weight of each of 9 types of complex enzymes.

본 발명에 따르면, 세제 사용량을 줄이면서도 특히, 인체에서 배출되는 단백질이나 지방에 의해 찌든 때를 쉽게 잘 분리 분해하여 제거함으로써 세탁효과를 높이되, 옷감 손상은 최소화시킬 수 있으면서 섬유유연 특성을 더욱 증대시키고, 탈취는 물론 정전기방지 특성을 강화시킬 수 있도록 개선된 효과를 얻을 수 있다.According to the present invention, while reducing the amount of detergent used, the washing effect is increased by easily separating and removing stains caused by proteins or fats discharged from the human body, while minimizing damage to fabric and further increasing fabric softening properties. You can achieve an improved effect by not only deodorizing but also strengthening the anti-static properties.

도 1은 본 발명에 따른 캡슐형 세제의 예시도이다.1 is an exemplary diagram of a capsule-type detergent according to the present invention.

이하에서는, 본 발명에 따른 바람직한 실시예를 보다 상세하게 설명하기로 한다.Hereinafter, preferred embodiments according to the present invention will be described in more detail.

본 발명에 따른 캡슐형 세제는 도 1의 예시와 같이, 수용성 합성수지로 된 외피(100)와, 상기 외피(100)에 내장된 충전제로 이루어진다.As shown in the example of FIG. 1, the capsule-type detergent according to the present invention consists of a shell 100 made of water-soluble synthetic resin and a filler built into the shell 100.

특히, 상기 외피(100)의 내부 공간에 채워진 충전제는 액체 또는 고체 상태의 세제, 표백제, 유연제 또는 살균제 등이 될 수 있다.In particular, the filler filled in the inner space of the outer shell 100 may be a liquid or solid detergent, bleach, softener, or disinfectant.

이렇게 구성된 본 발명에 따른 캡슐형 세제는 세탁기 내부에 세탁물과 함께 넣은 후 세탁하게 되면 외피(100)가 녹으면서 충전제가 세탁제 역할을 하여 세탁물을 세탁하게 된다.When the capsule-type detergent according to the present invention configured in this way is put into a washing machine with laundry and then washed, the outer shell 100 melts and the filler acts as a detergent to wash the laundry.

이때, 상기 외피(100)는 투명 또는 반투명하게 구성하여 내부에 충전된 세제성분들이 자체 색으로 비춰질 수 있도록 구성하면 더욱 좋다.At this time, it is better if the outer shell 100 is made transparent or translucent so that the detergent ingredients filled inside can be reflected in their own color.

이를 위해, 상기 외피(100)는 폴리비닐알콜(PolyVinyl Alcohol) 90중량%와 말레산 무수물-그라프티드 폴리락타이드(MA-g-PLA) 10중량%를 반응시켜 만든 수용성폴리머로 제조됨이 바람직하다.For this purpose, the outer shell 100 is preferably made of a water-soluble polymer made by reacting 90% by weight of polyvinyl alcohol and 10% by weight of maleic anhydride-grafted polylactide (MA-g-PLA). do.

여기에서, 상기 말레산 무수물-그라프티드 폴리락타이드(MA-g-PLA)는 반응성 상용화제이다.Here, the maleic anhydride-grafted polylactide (MA-g-PLA) is a reactive compatibilizer.

이러한 수용성폴리머는 깨지기 쉽고 물에 녹기 쉬울 뿐만 아니라, 생체적합성과 생분해성이 우수하며, 안전하고 인체 무해성을 갖기 때문에 세탁수와 함께 사용시 매우 바람직한 세제 외피로 사용될 수 있다.These water-soluble polymers are not only fragile and soluble in water, but also have excellent biocompatibility and biodegradability, and are safe and harmless to the human body, so they can be used as a very desirable detergent shell when used with washing water.

다만, 외피(100)의 모양을 다양하게 형성하기 위해 성형성을 고려하여 상기 수용성폴리머 100중량부에 대해, 폴리카프로락톤(Polycaprolactone) 10중량부를 더 혼합하여 성형할 수 있다.However, in order to form the outer shell 100 in various shapes, considering moldability, 10 parts by weight of polycaprolactone can be further mixed with 100 parts by weight of the water-soluble polymer.

이 경우, 폴리카프로락톤은 CAS No. 24980-41-4에 해당하는 물질로서, 무독성에 생체적합성, 생체 무해성이 뛰어나고 생분해성이 있으며, 약 60℃의 물에서 투명성이 증대되면서 자유로운 성형이 가능한 장점이 있다.In this case, polycaprolactone has CAS No. As a material corresponding to 24980-41-4, it is non-toxic, biocompatible, bio-harmless, biodegradable, and has the advantage of being freely moldable while increasing transparency in water at about 60°C.

한편, 상기 외피(100)에 채워지는 충전제는 복합효소 9종과 섬유유연성을 증대시키고, 탈취 및 표백과 정전방지 특성을 강화시키는 성분일 수 있다.Meanwhile, the filler filled in the outer shell 100 may be 9 types of complex enzymes and ingredients that increase fiber flexibility, deodorization, bleaching, and anti-static properties.

즉, 상기 충전제는 정제수 100중량부에 대해, 모노(2-프로필헵틸)에테르(Mono(2-Propylheptyl)Ether) 15중량부, 포타슘코코에이트(Potassium Cocoate) 10중량부, 라우라미도프로필하이드록시설타인(Lauramidopropyl Hydroxysultaine) 10중량부, 무환자추출물(Sapindus Mukurossi Fruit Extract) 20중량부, 복합효소 9종 각 5중량부씩 혼합되어 조성된다.That is, the filler is 15 parts by weight of Mono(2-Propylheptyl)Ether, 10 parts by weight of Potassium Cocoate, and lauramidopropyl hydroxyl, based on 100 parts by weight of purified water. It is composed of 10 parts by weight of Lauramidopropyl Hydroxysultaine, 20 parts by weight of Sapindus Mukurossi Fruit Extract, and 5 parts by weight of 9 types of complex enzymes.

이때, 모노(2-프로필헵틸)에테르(Mono(2-Propylheptyl)Ether)는 CAS No. 160875-66-1에 해당하는 물질로서, 분자식은 (C2H4O)nC10H22O이고, 정식명칭은 폴리에틸렌옥사이드모노-2-프로필헵틸에테르이며, 세탁시 탈취기능을 강화시키고 성분간 유화성을 증대시킨다.At this time, Mono(2-Propylheptyl)Ether is CAS No. It is a substance corresponding to 160875-66-1, the molecular formula is (C 2 H 4 O)nC 10 H 22 O, and the official name is polyethylene oxide mono-2-propylheptyl ether. It strengthens the deodorizing function during washing and prevents Increases emulsibility.

그리고, 포타슘코코에이트(Potassium Cocoate)는 섬유를 유연하게 하는 유연제로서 사용되면서 동시에, 향을 잡아 고정하는 기능과 기름 성분을 용해 제거하는 특성을 가지고 있다.In addition, Potassium Cocoate is used as a softener to soften fibers, and at the same time, it has the function of catching and fixing scents and dissolving and removing oil components.

또한, 라우라미도프로필하이드록시설타인(Lauramidopropyl Hydroxysultaine)은 충전제의 점도를 조절하면서 특히 정전기 방지 기능을 강화시켜 세탁시 세탁물에 보풀이 생기지 않도록 억제하는 장점이 있고, 분자구조식은 다음과 같다.In addition, Lauramidopropyl Hydroxysultaine has the advantage of controlling the viscosity of the filler and especially strengthening the anti-static function to prevent fluff from forming in laundry during washing. Its molecular structure is as follows.

뿐만 아니라, 무환자추출물(Sapindus Mukurossi Fruit Extract)은 무환자나무 열매에서 추출한 성분으로 사핀두스(Sapindus)라는 속명처럼 세척력이 강해 고래로부터 세척용 비누 대용으로 사용되어 왔으며, 특히 살균, 소취, 클린징 특성이 우수한 것으로 보고되어 있다. 본 발명에서는 천연 세탁 세제기능을 강화시키기 위해 첨가된다.In addition, Sapindus Mukurossi Fruit Extract is an ingredient extracted from the fruit of the Mukurossi tree, and as its genus name Sapindus suggests, it has strong cleaning power and has been used as a substitute for washing soap by whales. It has particularly excellent sterilizing, deodorizing, and cleansing properties. It is reported that In the present invention, it is added to enhance the function of natural laundry detergent.

아울러, 복합효소 9종은 공지된 시판품으로서, 프로테아제A,B, 리파아제, 셀룰라제A,B, 아밀라제, EM효소, 만나아제, 펙티나제를 말한다.In addition, the 9 types of complex enzymes are known commercial products and include protease A, B, lipase, cellulase A, B, amylase, EM enzyme, mannanase, and pectinase.

여기에서, 프로테아제는 A 단백질계를 분해, B 피지 분해 특성이 있는 것으로 땀에 의해 찌든 때까지 분해하게 된다.Here, protease decomposes protein A and sebum B, which has sebum decomposition properties and decomposes dirt accumulated by sweat.

그리고, 리파아제는 지방계를 분해하는 것으로 튀김, 기름류를 분해하며; 셀룰라제는 탈색, 변색방지, 보풀생성 방지를 위한 것이고; 아밀라제는 전분계를 분해하는 것으로 밥, 라면 등을 분해하며; EM(Effective Micro-organisms) 효소는 악취제거, 산화방지에 기여하고; 만나아제는 소스 화장품류를 분해하며; 펙티나제는 과일, 야채, 주스 등을 분해하는데 사용된다.In addition, lipase breaks down the fatty system and breaks down fried foods and oils; Cellulase is used to prevent discoloration, discoloration, and fluffing; Amylase breaks down the starch system and breaks down rice, ramen, etc.; EM (Effective Micro-organisms) enzymes contribute to removing odor and preventing oxidation; Mannanase decomposes source cosmetics; Pectinase is used to break down fruits, vegetables, juices, etc.

덧붙여, 본 발명에서는 섬유 유연효과를 높이기 위해 상기 충전제를 구성할 때 상기 정제수 100중량부에 대해, 시트르산(citric acid) 5중량부, 알파-D-글루코피라노스(α-D-glucopyranose) 10중량부, 데실글루코사이드(Decyl glucoside) 5중량부를 더 첨가할 수 있다.In addition, in the present invention, when composing the filler to increase the fabric softening effect, 5 parts by weight of citric acid and 10 parts by weight of alpha-D-glucopyranose are used for 100 parts by weight of the purified water. 5 parts by weight of decyl glucoside can be added.

이때, 시트르산은 레몬이나 밀감 따위의 과실 속에 풍부하게 들어 있는 유기산으로, 이온화되어 3가의 음이온으로 작용하는 하이드록시트라이카복실산의 한 종류이나 다른 카복실산보다는 강한 산성을 띠며, 무색무취의 고체 결정으로 물과 알코올에 잘 녹고 신맛이 있어 청량음료, 의약품의 첨가제로 쓰이며, 분자식은 C6H8O7이고, 본 발명에서는 세탁시 풀리면서 섬유 유연 효과를 증대시키기 위해 첨가된다.At this time, citric acid is an organic acid abundantly found in fruits such as lemons and tangerines. It is a type of hydroxytricarboxylic acid that ionizes and acts as a trivalent anion, but it is more acidic than other carboxylic acids and is a colorless, odorless solid crystal that dissolves in water and water. It is easily soluble in alcohol and has a sour taste, so it is used as an additive in soft drinks and medicines. Its molecular formula is C 6 H 8 O 7 , and in the present invention, it is added to increase the fabric softening effect by loosening during washing.

또한, 알파-D-글루코피라노스는 CAS No. 492-62-6에 해당하는 물질로서, 분자식은 C6H12O6이고, 세탁시 계면활성 기능을 강화시켜 섬유 유연효과를 증대시킨다. Additionally, alpha-D-glucopyranose has CAS No. It is a substance corresponding to 492-62-6, the molecular formula is C 6 H 12 O 6 , and it increases the fabric softening effect by strengthening the surface activity function during washing.

그리고, 데실글루코사이드는 CAS No. 68515-73-1에 해당하는 물질로서, 시트르산과 혼합되어 산도가 낮아지면서 세정력을 제공하여 건조시 덩어리진 먼지나 이물 발생을 억제하고 섬유를 부드럽게 하는데 기여한다.And, decylglucoside has CAS No. It is a substance corresponding to 68515-73-1. It is mixed with citric acid and provides cleaning power while lowering the acidity, suppressing the generation of lumpy dust or foreign substances during drying and contributing to softening the fiber.

덧붙여, 본 발명은 상기 충전제를 구성할 때, 상기 정제수 100중량부에 대해 향료 10중량부를 더 첨가할 수 있다.In addition, when configuring the filler of the present invention, 10 parts by weight of fragrance may be further added to 100 parts by weight of the purified water.

이 경우, 상기 향료는 미온수 100중량부에 대해, 백리향추출물(thymus quinquecostatus extract) 5중량부, 송진(Pine Sap) 5.5중량부, 글루타티온(glutathione) 5중량부를 첨가혼합하여 조성된다.In this case, the fragrance is prepared by adding and mixing 5 parts by weight of thymus quinquecostatus extract, 5.5 parts by weight of Pine Sap, and 5 parts by weight of glutathione with respect to 100 parts by weight of lukewarm water.

이 경우, 미온수는 약 30-50℃ 온도의 물이고, 백리향추출물은 향기가 백리까지 간다고 해서 붙여진 이름으로, 방향성은 물론 살균성까지 갖춘 천연 살균제로도 활용된다.In this case, lukewarm water is water with a temperature of about 30-50℃, and thyme extract is so named because its scent lasts up to thyme, and is used as a natural disinfectant with not only aromatic properties but also sterilizing properties.

또한, 송진은 청량감을 제공하는 대표적인 천연 항균제이다.Additionally, rosin is a representative natural antibacterial agent that provides a refreshing feeling.

그리고, 글루타티온(glutathione)은 글루탐산, 시스테인, 글라이신 세개의 펩티드로 구성되어 산화와 환원의 순환이 반복되면서 독성 과산화물을 제거하는 특성이 있다.Additionally, glutathione is composed of three peptides: glutamic acid, cysteine, and glycine, and has the property of removing toxic peroxides through repeated cycles of oxidation and reduction.

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이와 같은 본 발명에 따른 캡슐형 세제의 섬유 유연 효과와 탈취 및 정전기 방지 효과를 확인하기 위해 정전기 발생이 극심한 폴리에스터 90% 이상 함유 섬유를 세탁할 때 상기 캡슐형 세제를 투입한 후 세탁하였고, 건조 후 정전기 발생여부를 확인한 결과, 정전기 발생이 없었다.In order to confirm the fabric softening effect, deodorization, and static electricity prevention effect of the capsule-type detergent according to the present invention, the capsule-type detergent was added when washing fibers containing 90% or more of polyester, which generate extreme static electricity, and then washed and dried. After checking for static electricity, there was no static electricity.

또한, 섬유 유연 효과는 사람마다 느끼는 기준이 다를 수 있지만, 10명을 대상으로 테스트한 후 느낌을 확인한 결과, 섬유 유연성이 충분한 것으로 확인되었다.In addition, the standard for feeling the effect of fabric flexibility may vary from person to person, but after testing with 10 people and confirming the feeling, it was confirmed that the fabric flexibility was sufficient.

뿐만 아니라, 탈취의 경우도 주관성이 강하지만, 파인트리 향이 매우 좋다고 답한 사람이 10명중 10명이었다.In addition, although deodorization is highly subjective, 10 out of 10 people responded that the pinetree scent was very good.

아울러, 세탁시 거품성과 세탁세제 투입량을 비교 검토한 결과, 높은 거품성과 작은 세제 투입량에 효과가 있는 것으로 육안으로 확인되었다.In addition, as a result of comparing the foamability and amount of laundry detergent used during washing, it was visually confirmed that high foaming properties and small amounts of detergent were effective.

100: 외피100: outer shell

Claims (4)

수용성 합성수지로 된 외피와, 상기 외피에 내장된 충전제로 이루어진 캡슐형 세제로서, 상기 외피는 폴리비닐알콜(PolyVinyl Alcohol) 90중량%와 말레산 무수물-그라프티드 폴리락타이드(MA-g-PLA) 10중량%를 반응시켜 만든 수용성폴리머로 제조되고; 상기 충전제는 정제수 100중량부에 대해, 모노(2-프로필헵틸)에테르(Mono(2-Propylheptyl)Ether) 15중량부, 포타슘코코에이트(Potassium Cocoate) 10중량부, 라우라미도프로필하이드록시설타인(Lauramidopropyl Hydroxysultaine) 10중량부, 무환자추출물(Sapindus Mukurossi Fruit Extract) 20중량부, 복합효소 9종 각 5중량부씩 혼합되어 조성된 캡슐형 세제에 있어서;
상기 외피는 상기 수용성폴리머 100중량부에 대해, 폴리카프로락톤(Polycaprolactone) 10중량부를 더 혼합하여 성형되고;
상기 충전제를 구성할 때, 상기 정제수 100중량부에 대해 시트르산(citric acid) 5중량부, 알파-D-글루코피라노스(α-D-glucopyranose) 10중량부, 데실글루코사이드(Decyl glucoside) 5중량부 및 향료 10중량부를 더 첨가하되,
상기 향료는 미온수 100중량부에 대해, 백리향추출물(thymus quinquecostatus extract) 5중량부, 송진(Pine Sap) 5.5중량부, 글루타티온(glutathione) 5중량부를 첨가혼합하여 조성된 것을 특징으로 하는 캡슐형 세제.
It is a capsule-type detergent composed of a shell made of water-soluble synthetic resin and fillers built into the shell, and the shell is made of 90% by weight of polyvinyl alcohol and maleic anhydride-grafted polylactide (MA-g-PLA). It is manufactured from a water-soluble polymer made by reacting 10% by weight; The filler is 15 parts by weight of Mono(2-Propylheptyl)Ether, 10 parts by weight of Potassium Cocoate, and lauramidopropyl hydroxysulsteine (based on 100 parts by weight of purified water). In a capsule-type detergent composed of a mixture of 10 parts by weight of Lauramidopropyl Hydroxysultaine, 20 parts by weight of Sapindus Mukurossi Fruit Extract, and 5 parts by weight of each of 9 types of complex enzymes;
The outer shell is formed by further mixing 10 parts by weight of polycaprolactone with 100 parts by weight of the water-soluble polymer;
When composing the filler, 5 parts by weight of citric acid, 10 parts by weight of alpha-D-glucopyranose, and 5 parts by weight of Decyl glucoside are used based on 100 parts by weight of purified water. And add 10 more parts by weight of fragrance,
The fragrance is a capsule-type detergent characterized by adding and mixing 5 parts by weight of thymus quinquecostatus extract, 5.5 parts by weight of Pine Sap, and 5 parts by weight of glutathione with 100 parts by weight of lukewarm water.
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KR102647897B1 (en) * 2023-11-13 2024-03-15 주식회사 휴먼텍스 Eco-friendly fabric dyeing method

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KR101834283B1 (en) * 2011-03-31 2018-03-06 브리티시 아메리칸 토바코 (인베스트먼츠) 리미티드 Blends of a polylactic acid and a water soluble polymer
JP2018035269A (en) * 2016-08-31 2018-03-08 ライオン株式会社 Kitchen washing composition
KR20210022896A (en) * 2019-08-21 2021-03-04 (주)영진 Method for manufacturing laundry detergent composition using soapberry extract
KR20230017978A (en) * 2021-07-28 2023-02-07 박순영 Eco-friendly detergent composition for washing down products
KR20230027477A (en) 2021-08-19 2023-02-28 이난희 Capsule detergent composition with excellent cleaning effect and Capsule detergent manufactured by using the same

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KR101834283B1 (en) * 2011-03-31 2018-03-06 브리티시 아메리칸 토바코 (인베스트먼츠) 리미티드 Blends of a polylactic acid and a water soluble polymer
JP2018035269A (en) * 2016-08-31 2018-03-08 ライオン株式会社 Kitchen washing composition
KR20210022896A (en) * 2019-08-21 2021-03-04 (주)영진 Method for manufacturing laundry detergent composition using soapberry extract
KR20230017978A (en) * 2021-07-28 2023-02-07 박순영 Eco-friendly detergent composition for washing down products
KR20230027477A (en) 2021-08-19 2023-02-28 이난희 Capsule detergent composition with excellent cleaning effect and Capsule detergent manufactured by using the same

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Publication number Priority date Publication date Assignee Title
KR102647897B1 (en) * 2023-11-13 2024-03-15 주식회사 휴먼텍스 Eco-friendly fabric dyeing method

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