KR101358405B1 - Functional detergent composition - Google Patents

Functional detergent composition Download PDF

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Publication number
KR101358405B1
KR101358405B1 KR1020130098881A KR20130098881A KR101358405B1 KR 101358405 B1 KR101358405 B1 KR 101358405B1 KR 1020130098881 A KR1020130098881 A KR 1020130098881A KR 20130098881 A KR20130098881 A KR 20130098881A KR 101358405 B1 KR101358405 B1 KR 101358405B1
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South Korea
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weight
detergent composition
hot water
functional
water extract
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KR1020130098881A
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Korean (ko)
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박규섭
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(주)파라스
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3945—Organic per-compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02—Inorganic compounds
    • C11D7/20—Water-insoluble oxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/26—Organic compounds containing oxygen
    • C11D7/266—Esters or carbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/40—Products in which the composition is not well defined

Abstract

The present invention provides a functional detergent composition which comprises: 10-20 wt% of composition for emitting far infrared ray and blocking ultraviolet ray including pegmatite, holmium oxide, cerium oxide, zirconium dioxide, lanthanum chloride, and yttrium oxide; 10-20 wt% of enzyme complex supplementation including protease, lipase, amylase, and cellulase; 5-15 wt% of sodium dodecyl sulfate; 20-30 wt% of sodium percarbonate; 10-20 wt% of sodium carbonate; 10-20 wt% of sodium citrate; 10-20 wt% of silicon dioxide; 3-7 wt% of tetraacetylethylenediamine (TAED); and 1-2 wt% of scent.

Description

기능성 세제조성물{FUNCTIONAL DETERGENT COMPOSITION}Functional detergent composition {FUNCTIONAL DETERGENT COMPOSITION}

본 발명은 기능성 세제조성물에 관한 것으로, 더욱 상세하게는 각종 오염물질이나 찌든 때가 용이하게 제거되는 것은 물론이거니와, 세탁 후 섬유의 유연성이 특히 강화되어지는 효과는 물론, 원적외선 방사, 자외선 차단기능 내지 산화방지효과를 제공함으로써 세탁 이후 건조시에도 세균오염방지 내지 피부보호효과도 제공하는 기능성 세제조성물에 관한 것이다.
The present invention relates to a functional detergent composition, and more particularly, it is easy to remove various contaminants and stings, and of course, the flexibility of the fiber is particularly enhanced after washing, as well as far-infrared radiation, UV blocking function and oxidation. The present invention relates to a functional detergent composition that also provides a skin protection effect to prevent bacterial contamination even after drying after washing.

일반적으로 세제는 일상생활에서 몸을 씻거나 그 밖의 섬유제품·식기·식품·금속 등 여러가지 물건들의 기름때 먼지·그을음 등을 깨끗이 씻어내기 위한 목적으로 쓰이며, 세척대상에 따라 각각 성분이 달라지므로 종류도 많다. In general, detergents are used to wash the body in daily life or to clean dust, soot, etc. from various oils such as textile products, tableware, foods, metals, and so on. many.

또한 용도는 화장용, 가정용, 공업용 세제 등으로 분류될 수 있고, 현재 세제의 주류를 이루고 있는 세제 형태는 분말상이나 액체상이다. In addition, the use can be classified into cosmetics, household, industrial detergents, etc., and the detergent forms that currently make up the mainstream of the detergent is powder or liquid form.

이러한 분말상과 액체상의 세제는 사용할 때마다 계량해야 하기 때문에 불편하고, 계량시 정량의 사용이 어렵고 쏟을 우려가 있기 때문에 세제의 낭비를 초래하기도 한다. These powdery and liquid detergents are inconvenient because they have to be weighed each time they are used, and the use of quantitative liquids is difficult and spills because of the risk of spillage.

또한, 분말상 세제의 경우에는 국내공개특허 제1999-0039213호 등에서와 같은 세제조성물이 공개되어 있지만, 이들의 계량시 분말이 비산되어 사용자에게 불쾌감을 불러일으킬 수 있다. 더욱이 세탁 후 건조과정에서 미생물 등에 의한 재오염의 우려가 높고, 자외선 차단, 피부보호효과 등 기능성 의류에 대한 수요자의 요구에 부응하지 못하는 한계가 있는 실정이다.
In addition, in the case of powdered detergents, detergent compositions such as those disclosed in Korean Patent Laid-Open Publication No. 1999-0039213 are disclosed, but powders may be scattered during the measurement thereof, which may cause discomfort to the user. In addition, there is a high risk of re-contamination by microorganisms in the drying process after washing, and there is a limit that does not meet the demand of the consumer for functional clothing, such as UV protection, skin protection effect.

이에 본 발명은 상기와 같은 문제점들을 해소하기 위해 안출된 것으로써, 각종 오염물질이나 찌든 때가 용이하게 제거되는 것은 물론이거니와, 세탁 후 섬유의 유연성이 특히 강화되어지는 효과는 물론, 원적외선 방사, 자외선 차단기능 내지 산화방지효과를 제공함으로써 세탁 이후 건조시에도 세균오염방지 내지 피부보호효과도 제공하는 기능성 세제조성물을 제공하는 것이 목적이다.
Therefore, the present invention has been devised to solve the above problems, as well as easily remove various contaminants and stings, as well as the effect of particularly strengthening the flexibility of the fiber after washing, far infrared radiation, UV protection It is an object of the present invention to provide a functional detergent composition that provides anti-bacterial contamination to skin protection effect even after drying after washing by providing a function to anti-oxidation effect.

상기한 바와 같은 본 발명의 기술적 과제는 다음과 같은 수단에 의해 달성되어진다.
The technical problem of the present invention as described above is achieved by the following means.

(1) 페그마타이트, 홀뮴옥사이드, 세륨옥사이드, 지르코늄다이옥사이드, 란타늄클로라이드, 이트륨옥사이드를 포함하는 원적외선방출 및 자외선차단용 조성물 10~20 중량%, 프로테아제, 리파아제, 아밀라아제, 및 셀룰라아제를 포함하는 복합효소제 10~20 중량%; 소듐도데실설페이트 5~15 중량%; 소듐퍼카보네이트 20~30 중량%; 소듐카보네이트 10~20 중량%; 구연산나트륨 10~20 중량%; 이산화규소 10~20 중량%; 테트라아세틸에틸렌디아민(Tetra Acetyl Ethylene Diamine(TAED)) 3~7 중량%; 및 향 1~2 중량%를 포함하는 것을 특징으로 하는 기능성 세제조성물.
(1) 10 to 20% by weight of far-infrared emission and sunscreen composition containing pegmatite, holmium oxide, cerium oxide, zirconium dioxide, lanthanum chloride, yttrium oxide, complex enzymes 10- including protease, lipase, amylase, and cellulase 20 wt%; 5-15% by weight sodium dodecyl sulfate; 20-30 wt% sodium percarbonate; 10-20% by weight sodium carbonate; 10-20% by weight sodium citrate; 10-20% by weight of silicon dioxide; 3-7 wt% Tetra Acetyl Ethylene Diamine (TAED); And 1 to 2 wt% of fragrance.

(2) 상기 (1)에 있어서,(2) In the above (1)

페그마타이트, 홀뮴옥사이드, 세륨옥사이드, 지르코늄다이옥사이드, 란타늄클로라이드, 이트륨옥사이드를 동량으로 함유한 원적외선방출 및 자외선차단용 조성물 11중량%, 프로테아제, 리파아제, 아밀라아제, 및 셀룰라아제가 동량으로 조성된 복합효소제 15 중량%, 소듐도데실설페이트 10 중량%, 소듐퍼카보네이트 24 중량%, 소듐카보네이트 14 중량%, 구연산나트륨 15 중량%, 이산화규소 15 중량%, TAED 5 중량%, 및 다우니향 1 중량%로 이루어진 것을 특징으로 하는 기능성 세제조성물.
11% by weight of the composition for far-infrared emission and sunscreen containing the same amount of pegmatite, holmium oxide, cerium oxide, zirconium dioxide, lanthanum chloride, yttrium oxide, and 15% by weight of a complex enzyme composed of the same amount of protease, lipase, amylase, and cellulase , Sodium dodecyl sulfate 10% by weight, sodium percarbonate 24% by weight, sodium carbonate 14% by weight, sodium citrate 15% by weight, silicon dioxide 15% by weight, TAED 5% by weight, and Downey flavor 1% by weight Functional detergent composition.

(3) 상기 (1)에 있어서,(3) In the above (1)

상기 세제조성물은 프로폴리스 열수추출물을 더 포함하는 것을 특징으로 하는 기능성 세제조성물.
The detergent composition is a functional detergent composition, characterized in that it further comprises a propolis hot water extract.

(4) 상기 (1)에 있어서,(4) In the above (1)

상기 세제조성물은 천년초 열수추출물을 더 포함하는 것을 특징으로 하는 하는 기능성 세제조성물.
The detergent composition is a functional detergent composition, characterized in that it further comprises a millennial hot water extract.

(5) 상기 (1)에 있어서,(5) In the above (1)

상기 세제조성물은 참당귀 열수추출물을 더 포함하는 것을 특징으로 하는 기능성 세제조성물.
The detergent composition is a functional detergent composition, characterized in that it further comprises a Angelica Angelica hot water extract.

(6) 상기 (1)에 있어서,(6) In the above (1),

상기 세제조성물은 삼채 열수추출물을 더 포함하는 것을 특징으로 하는 기능성 세제조성물.
The detergent composition is a functional detergent composition, characterized in that it further comprises three hot water extracts.

(7) 상기 (1)에 있어서,(7) In the above (1),

상기 세제조성물은 천년초 열수추출물, 참당귀 열수추출물 및 삼채열수추출물을 더 포함하는 것을 특징으로 하는 기능성 세제조성물.
The detergent composition is a functional detergent composition, characterized in that it further comprises a cheonnyeoncho hot water extract, Cangdong Angelica hot water extract and three water extract.

(8) 상기 (1)에 있어서,(8) As described in (1),

상기 세제조성물은 백금나노를 더 포함하는 것을 특징으로 하는 기능성 세제조성물.The detergent composition is a functional detergent composition, characterized in that it further comprises platinum nano.

상기한 바와 같이, 본 발명에 의하면 각종 오염물질이나 찌든 때가 용이하게 제거되는 것은 물론이거니와, 세탁 후 섬유의 유연성이 특히 강화되어지는 효과는 물론, 원적외선 방사, 자외선 차단기능 내지 산화방지효과를 제공함으로써 세탁 이후 건조시에도 세균오염방지 내지 피부보호효과도 제공하는 기능성 세제조성물을 제공한다.
As described above, according to the present invention, various contaminants and stings are easily removed, and the flexibility of the fiber after washing is particularly enhanced, and by providing far infrared radiation, UV blocking function or antioxidant effect. It provides a functional detergent composition that provides bacterial protection or skin protection even when dried after washing.

이하, 본 발명의 내용을 보다 상세하게 설명하면 다음과 같다.
Hereinafter, the contents of the present invention will be described in more detail.

본 발명에 따른 기능성 세제조성물은 페그마타이트, 홀뮴옥사이드, 세륨옥사이드, 지르코늄다이옥사이드, 란타늄클로라이드, 이트륨옥사이드를 포함하는 원적외선방출 및 자외선차단용 조성물 10~20 중량%, 프로테아제, 리파아제, 아밀라아제, 및 셀룰라아제를 포함하는 복합효소제 10~20 중량%; 소듐도데실설페이트 5~15 중량%; 소듐퍼카보네이트 20~30 중량%; 소듐카보네이트 10~20 중량%; 구연산나트륨 10~20 중량%; 이산화규소 10~20 중량%; 테트라아세틸에틸렌디아민(Tetra Acetyl Ethylene Diamine(TAED)) 3~7 중량%; 및 향 1~2 중량%를 포함한다.Functional detergent composition according to the present invention comprises 10-20% by weight of far-infrared emission and sunscreen composition containing pegmatite, holmium oxide, cerium oxide, zirconium dioxide, lanthanum chloride, yttrium oxide, protease, lipase, amylase, and cellulase 10 to 20% by weight of the complex enzyme; 5-15% by weight sodium dodecyl sulfate; 20-30 wt% sodium percarbonate; 10-20% by weight sodium carbonate; 10-20% by weight sodium citrate; 10-20% by weight of silicon dioxide; 3-7 wt% Tetra Acetyl Ethylene Diamine (TAED); And incense 1 to 2% by weight.

상기에서 페그마타이트, 홀뮴옥사이드, 세륨옥사이드, 지르코늄다이옥사이드, 란타늄클로라이드, 이트륨옥사이드는 원적외선방출 효과로 인해 세포조직 활성화, 노폐물 및 독성물질 배출, 혈액순환 촉진 체질개선, 및 살균효과 등을 제공하며, 특히 의류의 유연도를 복원시키는데 효과적이다. 또한, 동 조성물은 자외선차단 내지 산화작용 효능을 발휘하는 것으로 알려져 있어 옷을 세탁하고 건조하여 입는 것만으로도 자외선이 피부내 침투하거나 피부가 노화되는 현상을 방지해 주는 효과도 제공한다.The pegmatite, holmium oxide, cerium oxide, zirconium dioxide, lanthanum chloride, yttrium oxide provides the activation of cellular tissues, the discharge of waste and toxic substances, the improvement of blood circulation, and the sterilization effect due to the far-infrared radiation effect, especially clothing It is effective in restoring flexibility. In addition, the composition is known to exert UV-blocking or oxidizing effect, and even by washing and drying clothes, it also provides an effect of preventing ultraviolet rays from penetrating into the skin or aging the skin.

프로테아제, 리파아제, 아밀라아제, 및 셀룰라아제를 포함하는 복합효소제는 10~20 중량% 첨가하는 것에 의해, 단백질, 지방질, 음식물 유래 녹말 혹은 전분을 효과적으로 분해할 수 있다.The complex enzyme including protease, lipase, amylase, and cellulase can be effectively decomposed protein, fat, food starch or starch by adding 10 to 20% by weight.

본 발명에 따른 세제조성물은 이외에도 표백력이 우수한 소듐퍼카보네이트와 계면활성의 촉매에 유용한 소듐카보네이트, TAED, 탄산나트륨 등을 첨가하고, 의류의 유연도를 보다 강화하기 위해 구연산이 첨가된다.In addition to the detergent composition according to the present invention, sodium percarbonate excellent in bleaching power, sodium carbonate, TAED, sodium carbonate, etc., which are useful for the catalyst of surfactant activity, are added, and citric acid is added to further enhance the softness of the garment.

또한, 향을 첨가할 때 발생하는 자연증발을 막기 위하여 이산화규소를 미세과립화하여 향과 믹싱할 경우 향이 증발되는 것을 방지할 수 있다.
In addition, in order to prevent spontaneous evaporation generated when adding the fragrance, the fragrance may be prevented from evaporating when the silicon dioxide is fine granulated and mixed with the fragrance.

이러한 효과를 제공하면서 옷감의 유연성과 감촉을 저해하는 일이 없도록 하기 위해, 바람직하게는 상기 페그마타이트, 홀뮴옥사이드, 세륨옥사이드, 지르코늄다이옥사이드, 란타늄클로라이드, 및 이트륨옥사이드 각각은 동량으로 혼합되거나, 원적외선방출 및 자외선차단용 조성물의 전체 중량에 대하여, 각각 10~20 중량%의 범위내에서 혼합되어진다.
Preferably, the pegmatite, holmium oxide, cerium oxide, zirconium dioxide, lanthanum chloride, and yttrium oxide are each mixed in the same amount, or far-infrared emission, so as not to impair the flexibility and feel of the fabric while providing such an effect. It is mixed in the range of 10-20 weight% with respect to the total weight of a sunscreen composition.

본 발명에 따른 실험결과 상기 세제조성물을 세탁물에 투입하면, 각종 오염물질이나 찌든 때가 용이하게 제거되는 것은 물론이거니와, 세탁 후 섬유의 유연성이 특히 강화되어지는 효과는 물론, 원적외선 방사, 자외선 차단기능 내지 산화방지효과를 제공함으로써 세탁 이후 건조시에도 세균오염방지 내지 피부보호효과도 제공한다.
As a result of the experiment according to the present invention, if the detergent composition is put into the laundry, various contaminants or stings are easily removed, and the flexibility of the fiber is particularly enhanced after washing, as well as far infrared radiation and ultraviolet ray blocking function. Providing anti-oxidation effect also provides bacterium to skin protection effect even after drying after washing.

상기 본 발명에 따른 세제조성물에 항균활성을 강화하기 위해 백금나노 또는 프로폴리스 추출물을 0.1 내지 5 중량%의 범위내에서 포함하는 것이 바람직하다. 백금나노는 시판되는 제품(1000~2000 ppm 용액) 중 어느 하나를 선택하여 사용하면 충분하고, 프로폴리스 추출물은 항균활성 외에 피부보호활성을 강화하는 물질로 본 발명에 따른 세제조성물에 첨가하여 사용시 상승적 효과를 기대할 수 있다. 특히 백금나노는 세탁물에서 나는 냄새의 소취, 탈취에 효과적이다.
In order to enhance the antimicrobial activity in the detergent composition according to the present invention, it is preferable to include platinum nano or propolis extract within the range of 0.1 to 5% by weight. Platinum nano is sufficient to select any one of the commercially available products (1000 ~ 2000 ppm solution), Propolis extract is a substance that enhances the skin protective activity in addition to the antimicrobial activity synergistic when added to the detergent composition according to the invention You can expect the effect. Platinum nano is particularly effective in deodorizing and deodorizing laundry.

또, 상기 본 발명에 따른 세제조성물은 천년초 열수추출물, 참당귀 열수추출물, 및 삼채 열수추출물에서 선택되는 적어도 1종의 추출물을 첨가하는 것이 바람직하다. 상기 각 추출물은 가격이 저렴하면서도 쉽게 구입이 가능하고, 이들 추출물은 항산화활성이 우수하면서 섬유를 부드럽게 하고 탈취효과가 우수하다. 상기 각 추출물의 첨가량은 세제조성물의 중량대비 1~5 중량%로 첨가되는 것이 바람직하다.
In addition, the detergent composition according to the present invention, it is preferable to add at least one extract selected from hot spring extract, cheonnyeoncho hot water extract, and three hot water extract. Each of the extracts are cheap and easy to purchase, these extracts are excellent in antioxidant activity, soften the fibers and have an excellent deodorizing effect. The amount of each extract is preferably added in 1 to 5% by weight relative to the weight of the detergent composition.

상기 본 발명에 따른 기능성 세제조성물은 수용성 스틱 포장용기에 장입되어, 포장용기 채로 물에 직접 투입하여 세탁물을 세탁하도록 하는 것이 바람직하다.
The functional detergent composition according to the present invention is loaded into a water-soluble stick packaging container, it is preferable to directly put the water in the packaging container to wash the laundry.

이를 위해, 상기 본 발명에 따른 수용성 스틱 포장용기는 영상의 온도인 물속에서 빠르고 완전하게 용해될 수 있고 또한 재질 자체가 강하고 유연하며 고온 또는 저온, 다습 또는 건조한 보관상태에 있어서 끈적거림이 없는 수용성 필름이 바람직하고, 구체적으로는 폴리비닐알콜, 폴리에틸렌옥사이드, 메틸셀룰로스 등을 예로 들 수 있다.To this end, the water-soluble stick packaging container according to the present invention can be dissolved quickly and completely in water at the temperature of the image, and the material itself is strong and flexible, non-sticky water-soluble film in high or low temperature, high humidity or dry storage conditions This is preferable and specifically, polyvinyl alcohol, polyethylene oxide, methyl cellulose, etc. are mentioned.

상기 수용성 필름의 두께는 내부에 장입되는 세제조성물의 보관안정성 및 세탁시 용해성 등을 고려하여 0.01 내지 0.1 ㎜로 하는 것이 바람직하다. 상기 수용성 필름의 두께가 0.01 ㎜ 미만이면 보관 중에 공기중 수분에 의해 세정조성물이 용해될 수 있어 보관안정성이 저하되고 0.1 ㎜를 초과하면 세탁시 수중에서의 분해성이 저하되어 바람직하지 않다.
The thickness of the water-soluble film is preferably set to 0.01 to 0.1 mm in consideration of storage stability of the detergent composition to be charged therein and solubility during washing. When the thickness of the water-soluble film is less than 0.01 mm, the cleaning composition may be dissolved by moisture in the air during storage, and the storage stability is lowered. When the thickness of the water-soluble film exceeds 0.1 mm, the decomposability in water during washing is deteriorated.

본 발명의 기능성 세제조성물은 개별 단위 포장되어 통상의 1회분 세탁시 필요한 량 만큼씩 포장된 것을 사용하는 것이 바람직하다. 따라서 세탁시 적정량만을 사용할 수 있어 세제의 과사용을 방지할 수 있으므로 경제적이고, 세탁시 세탁물과 함께 직접 세탁조에 투여할 수 있어 사용하기가 편리하고 보관안정성 및 운반성 또한 우수하다.
The functional detergent composition of the present invention is preferably used individually packaged in units of the required amount for a single batch washing. Therefore, only a proper amount can be used during washing to prevent overuse of detergent, so it is economical, and can be directly administered to the washing tank together with the laundry during washing, so it is convenient to use and has excellent storage stability and transportability.

이하, 본 발명을 하기 실시예 및 실험예에 의해 보다 상세히 설명한다. 단, 하기 실시예 및 실험예는 본 발명을 예시하는 것일 뿐, 본 발명의 내용이 하기 실시예 및 실험예에 의해 한정되는 것은 아니다.
Hereinafter, the present invention will be described in more detail by the following examples and experimental examples. However, the following examples and experimental examples are illustrative of the present invention, and the content of the present invention is not limited by the following examples and experimental examples.

[실시예 1]Example 1

0.05mm 두께의 폴리비닐알콜 필름으로 이루어진 스틱형상의 포장용기내에 페그마타이트, 홀뮴옥사이드, 세륨옥사이드, 지르코늄다이옥사이드, 란타늄클로라이드, 이트륨옥사이드를 동량으로 함유한 원적외선방출 및 자외선차단용 조성물 11중량%, 프로테아제, 리파아제, 아밀라아제, 및 셀룰라아제가 동량으로 조성된 복합효소제 15 중량%, 소듐도데실설페이트 5 중량%, 소듐퍼카보네이트 24 중량%, 소듐카보네이트 14 중량%, 구연산나트륨 10 중량%, 이산화규소 15 중량%, TAED 5 중량%, 및 다우니향 1 중량%로 이루어진 세제조성물을 25g을 장입하여 일회용 수용성 스틱세제를 제조하였다.
11 wt% of far-infrared emission and sunscreen composition containing pegmatite, holmium oxide, cerium oxide, zirconium dioxide, lanthanum chloride and yttrium oxide in a stick-shaped packaging container made of 0.05 mm thick polyvinyl alcohol film, protease, 15% by weight of lipase, amylase, and cellulase in the same amount of enzyme, 5% by weight of sodium dodecyl sulfate, 24% by weight of sodium percarbonate, 14% by weight of sodium carbonate, 10% by weight of sodium citrate, 15% by weight of silicon dioxide, Disposable water-soluble stick detergent was prepared by charging 25 g of a detergent composition consisting of 5 wt% TAED and 1 wt% Downey flavor.

[실시예 2][Example 2]

0.05mm 두께의 폴리에틸렌옥사이드 필름을 사용하고, 세제조성물 100중량부에 대하여 프로폴리스 열수추출물 10 중량부를 첨가한 것을 제외하고는 실시예 1과 동일한 조건으로 일회용 수용성 스틱세제를 제조하였다.
A disposable water-soluble stick detergent was prepared under the same conditions as in Example 1 except that a polyethylene oxide film having a thickness of 0.05 mm was used and 10 parts by weight of propolis hot water extract was added to 100 parts by weight of the detergent composition.

[실시예 3][Example 3]

0.05mm 두께의 메틸 셀룰로스 필름을 사용하고, 세제조성물 100중량부에 대하여 백금나노용액(1000ppm) 5 중량부를 첨가한 것을 제외하고는 실시예 1과 동일한 조건으로 일회용 수용성 스틱세제를 제조하였다.
A disposable water-soluble stick detergent was prepared under the same conditions as in Example 1 except that a 0.05-mm-thick methyl cellulose film was added and 5 parts by weight of platinum nano-solution (1000 ppm) was added to 100 parts by weight of the detergent composition.

[실시예 4]Example 4

실시예 3에서 천년초 열수추출물을 세제조성물 100중량부에 대하여 3 중량부 더 첨가한 것을 제외하고는 실시예 1과 동일한 조건으로 일회용 수용성 스틱세제를 제조하였다.
In Example 3, a disposable water-soluble stick detergent was prepared under the same conditions as in Example 1 except that 3 parts by weight of millennial hot water extract was added to 100 parts by weight of the detergent composition.

[실시예 5][Example 5]

실시예 3에서 참당귀 열수추출물을 세제조성물 100중량부에 대하여 3 중량부 더 첨가한 것을 제외하고는 실시예 1과 동일한 조건으로 일회용 수용성 스틱세제를 제조하였다.
A disposable water-soluble stick detergent was prepared under the same conditions as in Example 1, except that 3 parts by weight of Angelica gigas hot water extract was added to 100 parts by weight of the detergent composition.

[실시예 6][Example 6]

실시예 3에서 삼채 열수추출물을 세제조성물 100중량부에 대하여 3 중량부 더 첨가한 것을 제외하고는 실시예 1과 동일한 조건으로 일회용 수용성 스틱세제를 제조하였다.
A water-soluble disposable detergent was prepared under the same conditions as in Example 1 except that 3 parts by weight of three hot water extracts were added to 100 parts by weight of the detergent composition in Example 3.

[실시예 7][Example 7]

실시예 3에서 천년초 열수추출물, 참당귀 열수추출물 및 삼채 열수추출물을 세제조성물 100중량부에 대하여 각각 1 중량부 더 첨가한 것을 제외하고는 실시예 1과 동일한 조건으로 일회용 수용성 스틱세제를 제조하였다.
In Example 3, a disposable water-soluble stick detergent was prepared under the same conditions as in Example 1, except that 1,000 parts by weight of hot water extract, Angelica gigas hot water extract, and three hot water extracts were added in an amount of 100 parts by weight of the detergent composition.

[실시예 8][Example 8]

실시예 1에서 세제조성물 100중량부에 대하여 프로폴리스 열수추출물 10 중량부를 첨가한 것을 제외하고는 실시예 1과 동일한 조건으로 일회용 수용성 스틱세제를 제조하였다.
A disposable water-soluble stick detergent was prepared under the same conditions as in Example 1 except that 10 parts by weight of propolis hot water extract was added to 100 parts by weight of the detergent composition.

[실험예 1] 세척력Experimental Example 1 Washing Power

인위적으로 더럽힌 옷을 시판 원심 세탁기를 사용하여, 물 50L, 실시예 1 내지 3의 스틱세제 1포 및 물 온도 25℃ 하에서 투입한 결과 모든 실시예에서 투입 직후 바로 포장이 용해되어 세제가 배출되었으며, 이어 10분 동안 세탁한 후, 계속하여 두 번 3분 동안 헹구었다. 세척력을 일반적인 방법에 따라 다음의 식으로 계산하고 평가했다.Artificially soiled clothes were used under a commercial centrifugal washer under 50 L of water, 1 stick detergent package of Examples 1 to 3, and 25 ° C of water temperature. It was then washed for 10 minutes and then rinsed twice for three minutes. The washing power was calculated and evaluated by the following equation according to the general method.

세척력(%)= {(Rw-Rs)/(RI-Rs) } ×100% Wash = ((Rw-Rs) / (RI-Rs)} × 100

RI은 더럽혀지지 않은 의류의 반사율, Rw는 세탁된 의류의 반사율이고 Rs는 더럽혀진 의류의 반사율이다. 540mn에서 반사율을 다중-광원 분광광도계 칼로리미터를 사용하여 측정했다. 비교예 1로는 나트륨폴리아크릴레이트 35 중량%, 비이온성계면활성제 5 중량%, 트리에탄올아민 시트레이트염 6 중량%, 프로필렌글리콜 5 중량%, 알칼라제 0.4 중량%, 물 48.6 중량%로 이루어진 통상적인 세제조성물이 이용되었다. RI is the reflectance of uncleaned clothing, Rw is the reflectance of washed clothing, and Rs is the reflectance of soiled clothing. Reflectance at 540 mn was measured using a multi-light spectrophotometer calorimeter. Comparative Example 1 is a conventional composition consisting of 35% by weight of sodium polyacrylate, 5% by weight of nonionic surfactant, 6% by weight of triethanolamine citrate salt, 5% by weight of propylene glycol, 0.4% by weight of alcalase, 48.6% by weight of water Detergent composition was used.

구분division 실시예 1Example 1 실시예 2Example 2 실시예 3Example 3 비교예 1Comparative Example 1 세척력Cleaning power ◎◎ ◎◎ ◎◎ △△

* ◎: 40% 이상의 세척력, ○: 32% 이상 40% 미만의 세척력, △: 20% 이상 32% 미만의 세척력, ×: 20% 미만의 세척력
* ◎: 40% or more washing power, ○: 32% or more washing power less than 40%, △: 20% or more washing power less than 32%, ×: cleaning power less than 20%

[실험예 2] 항균성Experimental Example 2 Antimicrobial Activity

실시예 1 내지 3의 스틱세제의 항균성을 알아보고자, 대장균(Escherichia coli ATCC 25922) 및 화농균(Staphylococcus aureus ATCC 6538)에 대한 항균시험을 공시 방법에 따라 수행하였으며, 그 결과를 하기 표 2에 나타내었다.In order to determine the antimicrobial activity of the stick detergents of Examples 1 to 3, an antibacterial test for Escherichia coli ATCC 25922 and P. aeruginosa (Staphylococcus aureus ATCC 6538) was performed according to the disclosure method, and the results are shown in Table 2 below. .

구분division 실험결과Experiment result 초기농도
(CFU/40p)Initial concentration
(CFU / 40p) 1시간후 농도
(CFU/40p)Concentration after 1 hour
(CFU / 40p) 세균감소율
(%)Bacterial reduction rate
(%) 대장균Escherichia coli 실시예 1Example 1 225225 22 99.199.1 실시예 2Example 2 224224 1One 99.699.6 실시예 3Example 3 227227 1One 99.699.6 비교예 1Comparative Example 1 226226 225225 0.40.4 화농균Pyogenic bacteria 실시예 1Example 1 354354 22 99.499.4 실시예 2Example 2 356356 1One 99.799.7 실시예 3Example 3 356356 1One 99.799.7 비교예 1Comparative Example 1 355355 353353 0.60.6

상기 실험결과, 본 발명의 실시예에 따른 스틱세제가 원적외선 방사효과로 인해 항균활성을 발휘하는 것으로 판단되었다.
As a result of the experiment, it was determined that the stick detergent according to the embodiment of the present invention exhibited antibacterial activity due to the far infrared radiation effect.

[실험예 3] 자외선 차단Experimental Example 3 UV Protection

인위적으로 더럽힌 옷을 10ㅧ10cm의 크기로 절단(실험포)한 후 표준사용량(1g/1L)으로 세탁기 표준코스로 세탁하고 자연건조한 후 실험포의 자외선 차단효과를 측정한 결과는 다음과 같다. 자외선 차단효과의 측정을 위해 퍼킨-엘머(Perkin-Elmer:Lambda15)를 사용하여 측정영역(250-450nm)을 설정한 후 투과율을 측정하였다. 측정시 공기를 대조로 하여 실험포에 자외선을 투과시켜 일정 파장-350nm에서의 투과율을 측정한 결과는 하기 표 3과 같다.Artificially soiled clothes were cut into 10 절단 10cm size (test cloth), washed with a standard use amount (1g / 1L) in a washing machine standard course, and naturally dried, and then the UV blocking effect of the test cloth was measured as follows. In order to measure the UV blocking effect, the transmittance was measured after setting the measurement area (250-450 nm) using Perkin-Elmer (Lambda 15). When measuring the transmittance at a predetermined wavelength-350nm by transmitting ultraviolet rays to the test cloth with air as a control, the results are shown in Table 3 below.

구분division 실시예 1Example 1 실시예 2Example 2 실시예 3Example 3 비교예 1Comparative Example 1 자외선 투과율UV transmittance 2727 2424 2424 5252

상기측정 결과와 같이, 본 실시예에 따른 일회용 스틱세제가 비교예 1의 일반 세제에 비하여 자외선 투과율이 약 48~52% 감소하여 본 발명이 자외선 차단효과가 우수한 것을 확인할 수 있다.
As a result of the measurement, the disposable stick detergent according to the present embodiment compared to the general detergent of Comparative Example 1, the UV transmittance is reduced by about 48 to 52% it can be confirmed that the present invention has excellent UV blocking effect.

[실험예 4] 산화방지Experimental Example 4 Antioxidation

실시예 1 내지 8의 세제조성을 대상으로 항산화 효과의 DPPH 소거능을 측정한 결과 아래 표 4에서와 같이 소거효과가 우수한 것으로 확인되어 세탁물에 적용시에 피부보호 효과가 있을 것으로 기대한다.As a result of measuring the DPPH scavenging ability of the antioxidant effect in the detergent compositions of Examples 1 to 8, it was confirmed that the scavenging effect is excellent as shown in Table 4 below, it is expected to have a skin protection effect when applied to the laundry.

구분division 소거능(%)% Scavenging power 실시예 1Example 1 42.7±1.642.7 ± 1.6 실시예 2Example 2 43.5±2.343.5 ± 2.3 실시예 3Example 3 44.1±0.744.1 ± 0.7 실시예 4Example 4 48.3±1.248.3 ± 1.2 실시예 5Example 5 49.8±3.149.8 ± 3.1 실시예 6Example 6 49.4±2.949.4 ± 2.9 실시예 7Example 7 53.5±1.053.5 ± 1.0 실시예 8Example 8 46.5±0.346.5 ± 0.3

상기와 같이, 본 발명의 바람직한 실시 예를 참조하여 설명하였지만 해당 기술 분야의 숙련된 당업자라면 하기의 특허청구범위에 기재된 본 발명의 사상 및 영역으로부터 벗어나지 않는 범위 내에서 본 발명을 다양하게 수정 및 변경시킬 수 있음을 이해할 수 있을 것이다.While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it will be understood by those skilled in the art that various changes and modifications may be made without departing from the spirit and scope of the invention as defined in the appended claims. It can be understood that

Claims (8)

페그마타이트, 홀뮴옥사이드, 세륨옥사이드, 지르코늄다이옥사이드, 란타늄클로라이드, 이트륨옥사이드를 포함하는 원적외선방출 및 자외선차단용 조성물 10~20 중량%, 프로테아제, 리파아제, 아밀라아제, 및 셀룰라아제를 포함하는 복합효소제 10~20 중량%; 소듐도데실설페이트 5~15 중량%; 소듐퍼카보네이트 20~30 중량%; 소듐카보네이트 10~20 중량%; 구연산나트륨 10~20 중량%; 이산화규소 10~20 중량%; 테트라아세틸에틸렌디아민(TAED) 3~7 중량%; 및 향 1~2 중량%를 포함하는 것을 특징으로 하는 기능성 세제조성물.10-20% by weight of far-infrared emission and sunscreen composition containing pegmatite, holmium oxide, cerium oxide, zirconium dioxide, lanthanum chloride, yttrium oxide, 10-20% by weight of a complex enzyme including protease, lipase, amylase, and cellulase ; 5-15% by weight sodium dodecyl sulfate; 20-30 wt% sodium percarbonate; 10-20% by weight sodium carbonate; 10-20% by weight sodium citrate; 10-20% by weight of silicon dioxide; 3-7 wt% tetraacetylethylenediamine (TAED); And 1 to 2 wt% of fragrance. 제 1항에 있어서,
페그마타이트, 홀뮴옥사이드, 세륨옥사이드, 지르코늄다이옥사이드, 란타늄클로라이드, 이트륨옥사이드를 동량으로 함유한 원적외선방출 및 자외선차단용 조성물 11중량%, 프로테아제, 리파아제, 아밀라아제, 및 셀룰라아제가 동량으로 조성된 복합효소제 15 중량%, 소듐도데실설페이트 5 중량%, 소듐퍼카보네이트 24 중량%, 소듐카보네이트 14 중량%, 구연산나트륨 10 중량%, 이산화규소 15 중량%, 테트라아세틸에틸렌디아민(TAED) 5 중량%, 및 다우니향 1 중량%로 이루어진 것을 특징으로 하는 기능성 세제조성물.The method of claim 1,
11% by weight of the composition for far-infrared emission and sunscreen containing the same amount of pegmatite, holmium oxide, cerium oxide, zirconium dioxide, lanthanum chloride, yttrium oxide, and 15% by weight of a complex enzyme composed of the same amount of protease, lipase, amylase, and cellulase , 5% by weight sodium dodecyl sulfate, 24% by weight sodium percarbonate, 14% by weight sodium carbonate, 10% by weight sodium citrate, 15% by weight silicon dioxide, 5% by weight tetraacetylethylenediamine (TAED), and 1% by weight downey Functional detergent composition, characterized in that consisting of. 제 1항에 있어서,
상기 세제조성물은 프로폴리스 열수추출물을 더 포함하는 것을 특징으로 하는 기능성 세제조성물.The method of claim 1,
The detergent composition is a functional detergent composition, characterized in that it further comprises a propolis hot water extract. 제 1항에 있어서,
상기 세제조성물은 천년초 열수추출물을 더 포함하는 것을 특징으로 하는 하는 기능성 세제조성물.The method of claim 1,
The detergent composition is a functional detergent composition, characterized in that it further comprises a millennial hot water extract. 제 1항에 있어서,
상기 세제조성물은 참당귀 열수추출물을 더 포함하는 것을 특징으로 하는 기능성 세제조성물.The method of claim 1,
The detergent composition is a functional detergent composition, characterized in that it further comprises a Angelica Angelica hot water extract. 제 1항에 있어서,
상기 세제조성물은 삼채 열수추출물을 더 포함하는 것을 특징으로 하는 기능성 세제조성물.The method of claim 1,
The detergent composition is a functional detergent composition, characterized in that it further comprises three hot water extracts. 제 1항에 있어서,
상기 세제조성물은 천년초 열수추출물, 참당귀 열수추출물 및 삼채열수추출물을 더 포함하는 것을 특징으로 하는 기능성 세제조성물.The method of claim 1,
The detergent composition is a functional detergent composition, characterized in that it further comprises a cheonnyeoncho hot water extract, Cangdong Angelica hot water extract and three water extract. 제 1항에 있어서,
상기 세제조성물은 백금나노를 더 포함하는 것을 특징으로 하는 기능성 세제조성물.The method of claim 1,
The detergent composition is a functional detergent composition, characterized in that it further comprises platinum nano.
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