KR102493870B1 - Functional textile fabric containing chia seed extract and manufacturing method thereof - Google Patents
Functional textile fabric containing chia seed extract and manufacturing method thereof Download PDFInfo
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- KR102493870B1 KR102493870B1 KR1020220120998A KR20220120998A KR102493870B1 KR 102493870 B1 KR102493870 B1 KR 102493870B1 KR 1020220120998 A KR1020220120998 A KR 1020220120998A KR 20220120998 A KR20220120998 A KR 20220120998A KR 102493870 B1 KR102493870 B1 KR 102493870B1
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- acid
- anhydride
- textile fabric
- polyester
- blend
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- 235000020235 chia seed Nutrition 0.000 title claims abstract description 28
- 239000004744 fabric Substances 0.000 title claims abstract description 26
- 239000004753 textile Substances 0.000 title claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 title claims description 17
- 239000000203 mixture Substances 0.000 claims abstract description 40
- 229920000728 polyester Polymers 0.000 claims abstract description 37
- 150000008064 anhydrides Chemical class 0.000 claims abstract description 20
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 17
- 229930195729 fatty acid Natural products 0.000 claims abstract description 17
- 239000000194 fatty acid Substances 0.000 claims abstract description 17
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 17
- 235000013311 vegetables Nutrition 0.000 claims abstract description 14
- 150000002460 imidazoles Chemical class 0.000 claims abstract description 13
- 239000008188 pellet Substances 0.000 claims abstract description 10
- 239000004033 plastic Substances 0.000 claims abstract description 10
- 229920003023 plastic Polymers 0.000 claims abstract description 10
- 230000000845 anti-microbial effect Effects 0.000 claims abstract description 9
- 229920005989 resin Polymers 0.000 claims abstract description 6
- 239000011347 resin Substances 0.000 claims abstract description 6
- 238000001816 cooling Methods 0.000 claims abstract description 5
- 239000000314 lubricant Substances 0.000 claims abstract description 5
- 239000007800 oxidant agent Substances 0.000 claims abstract description 5
- 238000004804 winding Methods 0.000 claims abstract description 5
- 238000001035 drying Methods 0.000 claims abstract description 3
- 239000004599 antimicrobial Substances 0.000 claims abstract 2
- 230000000844 anti-bacterial effect Effects 0.000 claims description 29
- 239000000126 substance Substances 0.000 claims description 19
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 15
- 230000005496 eutectics Effects 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 13
- WWZKQHOCKIZLMA-UHFFFAOYSA-N Caprylic acid Natural products CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 10
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 claims description 8
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 claims description 8
- -1 carboxylic acid compound Chemical class 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 7
- 150000003892 tartrate salts Chemical class 0.000 claims description 7
- 238000009472 formulation Methods 0.000 claims description 6
- 125000003158 alcohol group Chemical group 0.000 claims description 5
- 238000002844 melting Methods 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 5
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 claims description 4
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 claims description 4
- GIWQSPITLQVMSG-UHFFFAOYSA-N 1,2-dimethylimidazole Chemical compound CC1=NC=CN1C GIWQSPITLQVMSG-UHFFFAOYSA-N 0.000 claims description 4
- GYSCBCSGKXNZRH-UHFFFAOYSA-N 1-benzothiophene-2-carboxamide Chemical compound C1=CC=C2SC(C(=O)N)=CC2=C1 GYSCBCSGKXNZRH-UHFFFAOYSA-N 0.000 claims description 4
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 claims description 4
- GHVNFZFCNZKVNT-UHFFFAOYSA-N Decanoic acid Natural products CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 claims description 4
- 241000241413 Propolis Species 0.000 claims description 4
- GONOPSZTUGRENK-UHFFFAOYSA-N benzyl(trichloro)silane Chemical compound Cl[Si](Cl)(Cl)CC1=CC=CC=C1 GONOPSZTUGRENK-UHFFFAOYSA-N 0.000 claims description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 4
- 229930003935 flavonoid Natural products 0.000 claims description 4
- 150000002215 flavonoids Chemical class 0.000 claims description 4
- 235000017173 flavonoids Nutrition 0.000 claims description 4
- 229940041616 menthol Drugs 0.000 claims description 4
- DUWWHGPELOTTOE-UHFFFAOYSA-N n-(5-chloro-2,4-dimethoxyphenyl)-3-oxobutanamide Chemical compound COC1=CC(OC)=C(NC(=O)CC(C)=O)C=C1Cl DUWWHGPELOTTOE-UHFFFAOYSA-N 0.000 claims description 4
- FUZZWVXGSFPDMH-UHFFFAOYSA-N n-hexanoic acid Natural products CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims description 4
- 235000019260 propionic acid Nutrition 0.000 claims description 4
- 229940069949 propolis Drugs 0.000 claims description 4
- 239000003784 tall oil Substances 0.000 claims description 4
- 238000005406 washing Methods 0.000 claims description 4
- 238000000354 decomposition reaction Methods 0.000 claims description 3
- 238000002074 melt spinning Methods 0.000 claims description 2
- 239000000374 eutectic mixture Substances 0.000 abstract description 10
- 241000894006 Bacteria Species 0.000 abstract description 4
- 241000700605 Viruses Species 0.000 abstract description 4
- 238000002360 preparation method Methods 0.000 abstract 2
- 238000004140 cleaning Methods 0.000 abstract 1
- 230000000593 degrading effect Effects 0.000 abstract 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 8
- 229940095064 tartrate Drugs 0.000 description 7
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical class O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 6
- 239000000835 fiber Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 description 4
- 230000014509 gene expression Effects 0.000 description 4
- 230000000191 radiation effect Effects 0.000 description 4
- 229940014800 succinic anhydride Drugs 0.000 description 4
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 235000020660 omega-3 fatty acid Nutrition 0.000 description 3
- LTVUCOSIZFEASK-MPXCPUAZSA-N (3ar,4s,7r,7as)-3a-methyl-3a,4,7,7a-tetrahydro-4,7-methano-2-benzofuran-1,3-dione Chemical compound C([C@H]1C=C2)[C@H]2[C@H]2[C@]1(C)C(=O)OC2=O LTVUCOSIZFEASK-MPXCPUAZSA-N 0.000 description 2
- MUTGBJKUEZFXGO-OLQVQODUSA-N (3as,7ar)-3a,4,5,6,7,7a-hexahydro-2-benzofuran-1,3-dione Chemical compound C1CCC[C@@H]2C(=O)OC(=O)[C@@H]21 MUTGBJKUEZFXGO-OLQVQODUSA-N 0.000 description 2
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 description 2
- WQNHWIYLCRZRLR-UHFFFAOYSA-N 2-(3-hydroxy-2,5-dioxooxolan-3-yl)acetic acid Chemical class OC(=O)CC1(O)CC(=O)OC1=O WQNHWIYLCRZRLR-UHFFFAOYSA-N 0.000 description 2
- YAXXOCZAXKLLCV-UHFFFAOYSA-N 3-dodecyloxolane-2,5-dione Chemical compound CCCCCCCCCCCCC1CC(=O)OC1=O YAXXOCZAXKLLCV-UHFFFAOYSA-N 0.000 description 2
- MWSKJDNQKGCKPA-UHFFFAOYSA-N 6-methyl-3a,4,5,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1CC(C)=CC2C(=O)OC(=O)C12 MWSKJDNQKGCKPA-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 2
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229960004488 linolenic acid Drugs 0.000 description 2
- VYKXQOYUCMREIS-UHFFFAOYSA-N methylhexahydrophthalic anhydride Chemical compound C1CCCC2C(=O)OC(=O)C21C VYKXQOYUCMREIS-UHFFFAOYSA-N 0.000 description 2
- 239000005445 natural material Substances 0.000 description 2
- BSAIUMLZVGUGKX-UHFFFAOYSA-N non-2-enal Chemical compound CCCCCCC=CC=O BSAIUMLZVGUGKX-UHFFFAOYSA-N 0.000 description 2
- 230000002940 repellent Effects 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- XYHKNCXZYYTLRG-UHFFFAOYSA-N 1h-imidazole-2-carbaldehyde Chemical compound O=CC1=NC=CN1 XYHKNCXZYYTLRG-UHFFFAOYSA-N 0.000 description 1
- GWYFCOCPABKNJV-UHFFFAOYSA-M 3-Methylbutanoic acid Natural products CC(C)CC([O-])=O GWYFCOCPABKNJV-UHFFFAOYSA-M 0.000 description 1
- YSWBFLWKAIRHEI-UHFFFAOYSA-N 4,5-dimethyl-1h-imidazole Chemical compound CC=1N=CNC=1C YSWBFLWKAIRHEI-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- GWYFCOCPABKNJV-UHFFFAOYSA-N beta-methyl-butyric acid Natural products CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 description 1
- 230000017531 blood circulation Effects 0.000 description 1
- 230000036760 body temperature Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- CYQFCXCEBYINGO-IAGOWNOFSA-N delta1-THC Chemical compound C1=C(C)CC[C@H]2C(C)(C)OC3=CC(CCCCC)=CC(O)=C3[C@@H]21 CYQFCXCEBYINGO-IAGOWNOFSA-N 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 230000002503 metabolic effect Effects 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229940012843 omega-3 fatty acid Drugs 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
Images
Classifications
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/20—Fabaceae or Leguminosae [Pea or Legume family], e.g. pea, lentil, soybean, clover, acacia, honey locust, derris or millettia
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/088—Cooling filaments, threads or the like, leaving the spinnerettes
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/098—Melt spinning methods with simultaneous stretching
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
- D03D15/283—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/13—Physical properties anti-allergenic or anti-bacterial
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2501/00—Wearing apparel
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Natural Medicines & Medicinal Plants (AREA)
- Agronomy & Crop Science (AREA)
- Biotechnology (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Artificial Filaments (AREA)
Abstract
Description
본 발명은 치아씨드 추출물이 함유된 기능성 직물 원단 및 그의 제조방법에 관한 것으로서, 좀더 세부적으로 말하자면 치아씨드에서 추출한 식물성 지방산을 PET와 결합시킴으로써 화학섬유의 기능과 천연소재의 특징을 동시에 가진 피부친화 헬스케어 소재로 사용할 수 있으며, 의류의 표면에 부착되는 세균과 바이러스를 사멸시킴으로써 항균 효과를 나타낼 수 있으며, 이외에도 원적외선 방사 효과, 소취기능, 오염 방지 기능 등을 복합적으로 제공할 수 있는, 치아씨드 추출물이 함유된 기능성 직물 원단 및 그의 제조방법에 관한 것이다.The present invention relates to a functional textile fabric containing chia seed extract and a method for manufacturing the same, and more specifically, by combining vegetable fatty acids extracted from chia seeds with PET, skin-friendly health that has the function of chemical fibers and the characteristics of natural materials at the same time Chia seed extract, which can be used as a care material, can show antibacterial effects by killing bacteria and viruses attached to the surface of clothing, and can provide a far-infrared radiation effect, deodorization function, and anti-pollution function in a complex way. It relates to a functional textile fabric and a manufacturing method thereof.
폴리에스터는 대표적인 합성섬유로서 1940년대에 발명되어 2차세계대전이 끝난 이후 1950년대쯤 접어들자 대중화되기 시작했다.Polyester, as a representative synthetic fiber, was invented in the 1940s and started to become popular in the 1950s after the end of World War II.
폴리에스터는 당겼을 때의 강도가 나일론 다음으로 높은 섬유로서, 물에 젖어도 강도의 변함이 없고, 내구성도 좋아 쿠션, 방석, 침구, 커튼, 가방 등 실생활에서 사용하는 다양한 상품의 소재로 많이 사용된다. 특히, 대량생산이 가능해 상대적으로 저렴한데다 잘 구겨지지도 않고 내구성도 높아 각종 의류 소재로 많이 쓰인다. Polyester is a fiber with the second highest tensile strength after nylon. It does not change in strength even when wet and has good durability, so it is widely used as a material for various products used in real life such as cushions, cushions, bedding, curtains, and bags. do. In particular, it is relatively cheap because it can be mass-produced, and it is not wrinkled well and has high durability, so it is widely used in various clothing materials.
참고로, 폴리에스터 원사에 있어서, 탄화플루오르계 발수제로 발수처리되고 90~120℃의 저온 열처리되어 멀티 필라멘트의 발수도가 5mm 이하이고, 수축율이 2.5% 이하인 폴리에스터 원사를 제공하는 기술이 대한민국 공개특허공보 공개번호 10-2016-0079159호(공개일자 2016년 07월 16일)의 "발수 성능이 향상된 공강도 폴리에스테르 원사와 그 제조방법"에서 개시된 바 있다.For reference, in the polyester yarn, a technique for providing a polyester yarn having a water repellent treatment with a fluorocarbon water repellent and a low temperature heat treatment at 90 to 120 ° C., having a multifilament repellency of 5 mm or less and a shrinkage rate of 2.5% or less is disclosed in Korea. Patent Publication No. 10-2016-0079159 (published on July 16, 2016) has been disclosed in “Polystrength polyester yarn with improved water repellency and its manufacturing method”.
상기 공개번호 10-2016-0079159호에서 볼 수 있는 바와 같이, 최근에는 폴리에스터 원사에 특수한 처리를 하거나 다른 성분을 부가하여 제조함으로써 의류의 기능성을 다양하게 제공할 수 있는 기술들에 대한 연구가 이루어지고 있다. As can be seen in Publication No. 10-2016-0079159, research has recently been conducted on technologies that can provide various functionalities of clothing by manufacturing polyester yarns with special treatment or by adding other ingredients. are losing
본 발명의 목적은 이러한 기술적 추세에 부응하기 위한 것으로서, 치아씨드에서 추출한 식물성 지방산을 PET와 결합시킴으로써 화학섬유의 기능과 천연소재의 특징을 동시에 가진 피부친화 헬스케어 소재로 사용할 수 있는, 치아씨드 추출물이 함유된 기능성 직물 원단 및 그의 제조방법을 제공하는 데 있다. An object of the present invention is to respond to this technological trend, and by combining vegetable fatty acids extracted from chia seeds with PET, chia seed extract can be used as a skin-friendly healthcare material that has the function of a chemical fiber and the characteristics of a natural material at the same time. It is to provide a functional textile fabric containing this and a manufacturing method thereof.
본 발명의 다른 목적은, 의류의 표면에 부착되는 세균과 바이러스를 사멸시킴으로써 항균 효과를 나타낼 수 있으며, 이외에도 원적외선 방사 효과, 소취기능, 오염 방지 기능 등을 복합적으로 제공할 수 있는, 치아씨드 추출물이 함유된 기능성 직물 원단 및 그의 제조방법을 제공하는 데 있다.Another object of the present invention is to obtain a chia seed extract, which can exhibit an antibacterial effect by killing bacteria and viruses attached to the surface of clothing, and can provide a far-infrared radiation effect, a deodorant function, and an anti-fouling function in a complex manner. It is to provide a functional textile fabric and a manufacturing method thereof.
상기한 목적을 달성하기 위한 수단으로서 본 발명의 구성은, 치아씨드를 세척하여 건조시킨 후 치아씨드로부터 식물성 지방산을 추출하는 단계와, 항균성 공융 배합물을 준비하는 단계와, 무수물과 이미다졸염을 이용하여 무수물계 경화제 배합물을 제조하는 단계와, PET 수지에 상기 경화제 배합물과 함께 상용화제, 플라스틱용 활제, 플라스틱 분해용 산화제를 배합하여 PET 배합물을 준비하는 단계와, 상기 PET 배합물에 식물성 지방산과 항균성 공융 배합물을 배합하여 폴리에스터 배합물을 제조하는 단계와, 상기 폴리에스터 배합물을 이용하여 폴리에스터 펠렛을 제조하는 단계와, 상기 폴리에스터 펠렛을 용융, 압출, 냉각, 연신, 권취시킴으로써 필라멘트 폴리에스터 원사를 용융 방사하는 단계와, 상기 필라멘트 폴리에스터 원사를 이용하여 직물 원단을 제조하는 단계를 포함하여 이루어진다.As a means for achieving the above object, the configuration of the present invention includes the steps of washing and drying chia seeds and extracting vegetable fatty acids from chia seeds, preparing an antibacterial eutectic compound, and using an anhydride and an imidazole salt. preparing an anhydride-based curing agent blend, preparing a PET blend by blending a compatibilizer, a plastic lubricant, and an oxidizing agent for plastic decomposition with the curing agent blend in a PET resin, and antimicrobial eutectic with vegetable fatty acid in the PET blend Preparing a polyester blend by blending the blend, preparing polyester pellets using the polyester blend, and melting, extruding, cooling, drawing, and winding the polyester pellets to melt the filament polyester yarn. It comprises the step of spinning, and the step of manufacturing a fabric fabric using the filament polyester yarn.
본 발명의 구성은, 상기 무수물계 경화제 배합물은, 무수물 100중량부당 경화 촉진제로서 이미다졸염을 1~40중량부 비율로 배합하여 제조하면 바람직하다.In the configuration of the present invention, the anhydride-based curing agent formulation is preferably prepared by blending an imidazole salt as a curing accelerator in a proportion of 1 to 40 parts by weight per 100 parts by weight of the anhydride.
본 발명의 구성은, 상기 경화촉진제로서 이미다졸염은 1,2-디메틸-1H-이미다졸을 카르복실산 화합물과 배합하여 제조하면 바람직하다.In the configuration of the present invention, the imidazole salt as the curing accelerator is preferably prepared by blending 1,2-dimethyl-1H-imidazole with a carboxylic acid compound.
본 발명의 구성은, 상기 카르복실산 화합물은 아세트산, 프로판산, 헥산산, 2-에틸헥산산, 옥탄산, 노난산, 데칸산, 톨오일 지방산 (TOFA), 이들의 조합중에서 선택하면 바람직하다.In the configuration of the present invention, the carboxylic acid compound is preferably selected from acetic acid, propanoic acid, hexanoic acid, 2-ethylhexanoic acid, octanoic acid, nonanoic acid, decanoic acid, tall oil fatty acid (TOFA), and combinations thereof .
본 발명의 구성은, 상기 항균성 공융배합물은 알코올기를 가지는 항균물질과 주석산 염을 1~4 : 1의 몰비율로 공융배합하면 바람직하다.According to the configuration of the present invention, the antibacterial eutectic mixture is preferably eutectic mixture of an antibacterial substance having an alcohol group and a tartrate salt in a molar ratio of 1 to 4:1.
본 발명의 구성은, 상기 항균물질은, 멘톨, 프로폴리스, 및 플라보노이드의 그룹으로부터 선택되는 1가지 이상을 사용하면 바람직하다.In the configuration of the present invention, it is preferable to use at least one selected from the group of menthol, propolis, and flavonoid as the antibacterial substance.
본 발명은, 치아씨드에서 추출한 식물성 지방산을 PET와 결합시킴으로써 화학섬유의 기능과 천연소재의 특징을 동시에 가진 피부친화 헬스케어 소재로 사용할 수 있고, 의류의 표면에 부착되는 세균과 바이러스를 사멸시킴으로써 항균 효과를 나타낼 수 있으며, 이외에도 원적외선 방사 효과, 소취기능, 오염 방지 기능 등을 복합적으로 제공할 수 있는, 효과를 갖는다.The present invention can be used as a skin-friendly healthcare material that has both the function of a chemical fiber and the characteristics of a natural material by combining vegetable fatty acids extracted from chia seeds with PET, and by killing bacteria and viruses attached to the surface of clothing, it can be used as an antibacterial material. In addition, it has an effect that can provide a far-infrared radiation effect, a deodorizing function, a pollution prevention function, and the like in a complex manner.
도 1은 본 발명의 일 실시예에 따른 치아씨드 추출물이 함유된 기능성 직물 원단의 제조방법의 공정 순서도이다.1 is a process flow chart of a method for manufacturing a functional textile fabric containing a chia seed extract according to an embodiment of the present invention.
이하, 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자가 본 발명을 용이하게 실시할 수 있을 정도로 상세히 설명하기 위하여, 본 발명의 바람직한 실시예를 첨부된 도면을 참조로 하여 상세히 설명하기로 한다. 본 발명의 목적, 작용, 효과를 포함하여 기타 다른 목적들, 특징점들, 그리고 동작상의 이점들이 바람직한 실시예의 설명에 의해 보다 명확해질 것이다. Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings in order to explain the present invention in detail to the extent that those skilled in the art can easily practice the present invention. Other objects, features, and operational advantages, including the object, operation, and effect of the present invention, will become clearer from the description of the preferred embodiment.
참고로, 여기에서 개시되는 실시예는 여러가지 실시가능한 예중에서 당업자의 이해를 돕기 위하여 가장 바람직한 실시예를 선정하여 제시한 것일 뿐, 본 발명의 기술적 사상이 반드시 제시된 실시예에만 의해서 한정되거나 제한되는 것은 아니고, 본 발명의 기술적 사상을 벗어나지 않는 범위내에서 균등물 내지 대체물들을 포함하는 다양한 변화와 부가 및 변경이 가능하다.For reference, the embodiments disclosed herein are only presented by selecting the most preferred embodiments to help those skilled in the art to understand among various possible examples, and the technical idea of the present invention is not necessarily limited or limited only by the presented embodiments. Instead, various changes, additions, and modifications including equivalents or substitutes are possible within the scope of the technical spirit of the present invention.
또한, 본원의 명세서 및 청구범위에 사용된 용어나 단어의 표현은, 발명자는 그 자신의 발명을 가장 최선의 방법으로 설명하기 위해 용어의 개념을 적절하게 정의할 수 있다는 원칙에 입각하여 정의된 것으로서, 통상적이거나 사전적인 의미로만 한정해서 해석되어서는 아니되며, 본 발명의 기술적 사상에 부합하는 의미와 개념으로 해석되어야만 한다. 일예로서, 단수의 표현은 문맥상 명백하게 다르게 뜻하지 않는 한 복수의 표현을 포함하며, 방향에 관한 표현은 설명상의 편의를 위하여 도면상에 표현된 위치를 기준으로 설정한다.In addition, the expression of terms or words used in the specification and claims of the present application are defined based on the principle that the inventor can appropriately define the concept of terms in order to best explain his or her invention. , It should not be construed as limited to ordinary or dictionary meanings, but should be interpreted as meanings and concepts consistent with the technical spirit of the present invention. As an example, a singular expression includes a plurality of expressions unless the context clearly indicates otherwise, and an expression related to a direction is set based on a position shown on the drawing for convenience of explanation.
도 1에 도시되어 있는 바와 같이, 본 발명의 일실시예에 따른 치아씨드 추출물이 함유된 기능성 직물 원단의 제조방법의 구성은, 치아씨드를 세척하여 준비하는 단계(S10)와, 치아씨드로부터 식물성 지방산을 추출하는 단계(S20)와, 항균성 공융 배합물을 준비하는 단계(S30)와, 무수물과 이미다졸염을 이용하여 무수물계 경화제 배합물을 제조하는 단계(S40)와, PET 수지에 상기 경화제 배합물과 함께 상용화제, 플라스틱용 활제, 플라스틱 분해용 산화제를 배합하여 PET 배합물을 준비하는 단계(S50)와, 상기 PET 배합물에 식물성 지방산과 항균성 공융 배합물을 배합하여 폴리에스터 배합물을 제조하는 단계(S60)와, 상기 폴리에스터 배합물을 이용하여 폴리에스터 펠렛을 제조하는 단계(S70)와, 상기 폴리에스터 펠렛을 용융, 압출, 냉각, 연신, 권취시킴으로써 필라멘트 폴리에스터 원사를 용융 방사하는 단계(S80)와, 상기 필라멘트 폴리에스터 원사를 이용하여 제직 또는 편직을 함으로써 직물 원단을 제조하는 단계(S80)를 포함하여 이루어진다.As shown in FIG. 1, the method for manufacturing a functional textile fabric containing a chia seed extract according to an embodiment of the present invention includes the steps of washing and preparing chia seeds (S10), and extracting chia seeds from vegetable matter. Extracting fatty acids (S20), preparing an antibacterial eutectic compound (S30), preparing an anhydride-based curing agent blend using an anhydride and an imidazole salt (S40), and adding the curing agent blend to a PET resin. preparing a PET blend by blending a compatibilizer, a plastic lubricant, and an oxidizing agent for plastic decomposition (S50), and preparing a polyester blend by blending a vegetable fatty acid and an antibacterial eutectic blend with the PET blend (S60); , Step of preparing polyester pellets using the polyester blend (S70), melt-spinning a filament polyester yarn by melting, extruding, cooling, drawing, and winding the polyester pellets (S80), It comprises a step (S80) of manufacturing a fabric fabric by weaving or knitting using a filament polyester yarn.
상기 치아시드를 구성하는 지방중 약 77%는 오메가-3와 오메가-6로 구성되어 있으며, 오메가-3 지방산으로서 알파 리놀렌 지방산이 풍부하게 들어있다.About 77% of the fat constituting the chia seeds is composed of omega-3 and omega-6, and alpha-linolenic acid is abundantly contained as omega-3 fatty acid.
상기 항균성 공융배합물은 항균물질 및 주석산 염 분자가 갖는 전하 및 작용기, 및 분자 또는 작용기가 갖는 극성에 따라 그 공융배합물에 필요한 물질 간의 비율을 결정하였다. 이에 따라, 상기 항균성 공융배합물은 알코올기를 가지는 항균물질과 주석산 염이 1~4 : 1의 몰비율로 공융배합된다.For the antibacterial eutectic mixture, the ratio between the materials required for the eutectic mixture was determined according to the charge and functional group of the antimicrobial substance and the tartrate molecule, and the polarity of the molecule or functional group. Accordingly, in the antibacterial eutectic mixture, an antibacterial substance having an alcohol group and a tartrate are eutectic in a molar ratio of 1 to 4:1.
상기 항균물질은, 멘톨, 프로폴리스, 및 플라보노이드의 그룹으로부터 선택되는 1가지 이상을 사용할 수 있다.As the antimicrobial substance, one or more selected from the group of menthol, propolis, and flavonoids may be used.
일반적으로 사용되는 주석산은 물에 대한 용해도가 낮아 수지에 혼입할 경우 고농도로 적용되기 어려워 제형에 제한이 있다. 따라서, 주석산 염 형태로 항균물질과 이온결합을 유도하여 용해도 및 안정성을 개선할 수 있다. Tartaric acid, which is generally used, has low solubility in water and is difficult to apply at a high concentration when incorporated into a resin, thus limiting the formulation. Therefore, solubility and stability can be improved by inducing an ionic bond with an antibacterial substance in the form of a tartrate salt.
본 발명의 실시예로서, 하기 반응식에 화학식 1의 알코올기를 가지는 항균물질과 화학식 2의 주석산 염의 각 몰비율에서 이온결합을 나타내었다.As an example of the present invention, the ionic bond is shown in each molar ratio of the antibacterial substance having an alcohol group of Formula 1 and the tartrate of Formula 2 in the following reaction formula.
[화학식 1][Formula 1]
[화학식 2][Formula 2]
[반응식 1] 항균물질:주석산 염 (1:1)[Scheme 1] Antibacterial substance: Tartaric acid salt (1:1)
[반응식 2] 항균물질:주석산 염 (2:1)[Scheme 2] Antibacterial substance: Tartaric acid salt (2:1)
[반응식 3] 항균물질:주석산 염 (3:1)[Scheme 3] Antibacterial substance: Tartaric acid salt (3:1)
[반응식 4] 항균물질:주석산 염 (4:1)[Scheme 4] Antibacterial substance: Tartaric acid salt (4:1)
항균물질과 주석산 염은 특정 작용기의 부분 전하에 의한 쌍극자간 결합으로 인해 공융배합물을 형성할 수 있고, 이들의 화학 구조를 통해 상기 범위의 몰비에서 공융배합물을 형성할 수 있다.The antibacterial material and the tartrate may form a eutectic mixture due to dipole bonding due to partial charge of a specific functional group, and may form a eutectic mixture at a molar ratio within the above range through their chemical structures.
주석산 염의 몰비율이 1을 초과하면 항균물질과 이온결합을 하지 못하고 남는 주석산 염 분자들이 물에 대한 용해도를 초과하여 저온에서 석출될 수 있다.If the molar ratio of tartrate exceeds 1, remaining tartrate molecules that cannot form an ionic bond with the antibacterial substance may be precipitated at low temperatures beyond their solubility in water.
상기 무수물계 경화제 배합물은, 무수물 100중량부당 경화 촉진제로서 이미다졸염을 1~40중량부 비율로 배합하여 제조한다.The anhydride-based curing agent formulation is prepared by blending an imidazole salt as a curing accelerator in a ratio of 1 to 40 parts by weight per 100 parts by weight of the anhydride.
상기 무수물은, 폴리세바스산 및 폴리아젤라산 무수물, 메틸테트라히드로프탈산 무수물, 테트라히드로 프탈산 무수물, 메틸 나드산 무수물, 헥사히드로 프탈산 무수물 및 메틸헥사히드로 프탈산 무수물; 숙신산 무수물, 치환된 숙신산 무수물, 시트르산 무수물, 말레산 무수물, 말레산 무수물의 부가물, 도데실 숙신산 무수물, 말레산 무수물 비닐 및 말레산 무수물의 스티렌 공중합체, 다중-고리 지환족 무수물, 프탈산 무수물, 트리멜리트산 무수물과, 이들의 조합 중에서 선택된다.The anhydrides include polysebacic and polyazelaic anhydrides, methyltetrahydrophthalic anhydride, tetrahydrophthalic anhydride, methyl nadic anhydride, hexahydrophthalic anhydride and methylhexahydrophthalic anhydride; Succinic anhydride, substituted succinic anhydride, citric anhydride, maleic anhydride, adducts of maleic anhydride, dodecyl succinic anhydride, styrene copolymers of maleic anhydride vinyl and maleic anhydride, multi-ring cycloaliphatic anhydride, phthalic anhydride, trimellitic anhydride, and combinations thereof.
상기 경화촉진제로서 이미다졸염은 1,2-디메틸-1H-이미다졸을 카르복실산 화합물과 배합하여 제조된다.The imidazole salt as the curing accelerator is prepared by combining 1,2-dimethyl-1H-imidazole with a carboxylic acid compound.
상기 1,2-디메틸-1H-이미다졸은 밀도가 0.99g/cm3, 녹는점 20 ~ 40℃, 끓는점 205℃의 물성을 가지고 있기 때문에 이미다졸 염을 생성하는데 적합하다.Since the 1,2-dimethyl-1H-imidazole has physical properties of a density of 0.99 g/cm3, a melting point of 20 to 40°C, and a boiling point of 205°C, it is suitable for producing an imidazole salt.
상기 카르복실산 화합물은 아세트산, 프로판산, 헥산산, 2-에틸헥산산, 옥탄산, 노난산, 데칸산, 톨오일 지방산 (TOFA), 이들의 조합중에서 선택된다.The carboxylic acid compound is selected from acetic acid, propanoic acid, hexanoic acid, 2-ethylhexanoic acid, octanoic acid, nonanoic acid, decanoic acid, tall oil fatty acid (TOFA), and combinations thereof.
상기한 구성에 의한, 본 발명의 일실시예에 따른 치아씨드 추출물이 함유된 기능성 직물 원단 및 그의 제조방법의 작용은 다음과 같다.According to the above configuration, the function of the chia seed extract-containing functional textile fabric and its manufacturing method according to an embodiment of the present invention are as follows.
먼저, 치아씨드를 세척하여 준비한 후에(S10), 치아씨드로부터 식물성 지방산을 추출한다(S20). First, after washing and preparing the chia seeds (S10), vegetable fatty acids are extracted from the chia seeds (S20).
다음에, 멘톨, 프로폴리스, 및 플라보노이드의 그룹으로부터 선택되는 1가지 이상의, 알코올기를 가지는 항균물질과, 주석산 염을 1:1, 2:1, 3:1, 4:1의 몰비율로 공융배합하여 항균성 공융 배합물을 준비한다(S30).Next, at least one antibacterial substance having an alcohol group selected from the group of menthol, propolis, and flavonoid, and tartrate is eutectic in a molar ratio of 1: 1, 2: 1, 3: 1, 4: 1 to prepare an antibacterial eutectic compound (S30).
이어서, 폴리세바스산 및 폴리아젤라산 무수물, 메틸테트라히드로프탈산 무수물, 테트라히드로 프탈산 무수물, 메틸 나드산 무수물, 헥사히드로 프탈산 무수물 및 메틸헥사히드로 프탈산 무수물; 숙신산 무수물, 치환된 숙신산 무수물, 시트르산 무수물, 말레산 무수물, 말레산 무수물의 부가물, 도데실 숙신산 무수물, 말레산 무수물 비닐 및 말레산 무수물의 스티렌 공중합체, 다중-고리 지환족 무수물, 프탈산 무수물, 트리멜리트산 무수물과, 이들의 조합 중에서 선택되는 무수물 100중량부당 경화 촉진제로서 이미다졸염을 1~40중량부 비율로 배합하여 경화제 배합물을 제조한다(S40). then polysebacic and polyazelaic anhydrides, methyltetrahydrophthalic anhydride, tetrahydrophthalic anhydride, methyl nadic anhydride, hexahydrophthalic anhydride and methylhexahydrophthalic anhydride; Succinic anhydride, substituted succinic anhydride, citric anhydride, maleic anhydride, adducts of maleic anhydride, dodecyl succinic anhydride, maleic anhydride vinyl and styrene copolymers of maleic anhydride, multi-ring cycloaliphatic anhydride, phthalic anhydride, A curing agent formulation is prepared by mixing trimellitic anhydride and an imidazole salt as a curing accelerator in an amount of 1 to 40 parts by weight per 100 parts by weight of an anhydride selected from combinations thereof (S40).
상기 이미다졸염은, 아세트산, 프로판산, 헥산산, 2-에틸헥산산, 옥탄산, 노난산, 데칸산, 톨오일 지방산 (TOFA), 이들의 조합중에서 선택되는 카르복실산 화합물과 1,2-디메틸-1H-이미다졸을 배합한 것을 사용한다.The imidazole salt is a carboxylic acid compound selected from acetic acid, propanoic acid, hexanoic acid, 2-ethylhexanoic acid, octanoic acid, nonanoic acid, decanoic acid, tall oil fatty acid (TOFA), and combinations thereof and 1,2 - A mixture of dimethyl-1H-imidazole is used.
다음에, PET 수지에 상기 경화제 배합물과 함께 상용화제, 플라스틱용 활제, 플라스틱 분해용 산화제를 배합하여 PET 배합물을 준비한다(S50). Next, a PET compound is prepared by mixing a compatibilizing agent, a lubricant for plastic, and an oxidizing agent for decomposing plastic together with the curing agent compound in the PET resin (S50).
이어서, 상기 PET 배합물에 식물성 지방산과 항균성 공융 배합물을 배합하여 폴리에스터 배합물을 제조한다(S60). Subsequently, a polyester blend is prepared by blending a vegetable fatty acid and an antibacterial eutectic blend with the PET blend (S60).
상기 항균성 공융 배합물은 전체 폴리에스터 배합물 중량에 대하여 0.5 내지 10 중량부로 포함된다. 상기 항균성 공융배합물이 0.5 중량부 미만으로 포함할 경우에는 충분한 항균 효과를 기대할 수 없고, 10 중량부를 초과하여 포함할 경우에는 폴리에스테르 수지 안정성에 문제가 있을 수 있으므로 이를 방지하기 위한 것이다.The antimicrobial eutectic blend is included in an amount of 0.5 to 10 parts by weight based on the total weight of the polyester blend. When the antibacterial eutectic mixture is included in less than 0.5 parts by weight, sufficient antibacterial effect cannot be expected, and when it is included in more than 10 parts by weight, there may be a problem with the stability of the polyester resin. This is to prevent this.
다음에, 상기 폴리에스터 배합물을 이용하여 폴리에스터 펠렛을 제조한다(S70). Next, polyester pellets are prepared using the polyester blend (S70).
이어서, 상기 폴레에스터 펠렛을 용융, 압출, 냉각, 연신, 권취시킴으로써 필라멘트 폴리에스터 원사를 용융 방사한다(S80).Subsequently, the filament polyester yarn is melt-spun by melting, extruding, cooling, stretching, and winding the polyester pellets (S80).
다음에, 상기 필라멘트 폴리에스터 원사를 이용하여 제직을 함으로써 직물 원단을 제조한다(S90). 이 경우에, 다른 성분의 원사를 혼합할 수도 있다.Next, a fabric fabric is prepared by weaving using the filament polyester yarn (S90). In this case, yarns of different components may be mixed.
이와 같이 만들어진 직물 원단은 식물성 오메가-3인 리롤렌산이 함유되어 있어서, 생체 신진대사 활동에 도움을 주는 것으로 알려진 원적외선 방사 효과가 탁월하다. 따라서, 인체에서 발생되는 열을 흡수하여 에너지 형태로 방사함으로써 혈류량을 높여 체온을 조절시켜 신진대사를 촉진하고, 운동능력을 향상하고, 피로회복에 좋다. The textile fabric made in this way contains linolenic acid, which is a vegetable omega-3, and has an excellent far-infrared radiation effect known to help the body's metabolic activity. Therefore, by absorbing heat generated in the human body and radiating it in the form of energy, it increases blood flow and regulates body temperature to promote metabolism, improve exercise capacity, and is good for fatigue recovery.
또한, 본 발명의 직물원단은 포도상 구균과 페렴균을 99.9% 감소시키는 항균기능을 가지며, 아세트산은 97%, 암모니아는 49%, 이소길초산은 97%, 노네날가스는 73% 감소시키는 소취기능을 갖는다. 그리고, 마찰 대전압이 실크수준으로 일반 화학섬유보다 현격히 낮아서 미세먼지나 오염으로부터 비교적 우수하다. In addition, the fabric fabric of the present invention has an antibacterial function that reduces Staphylococcus aureus and pneumococci by 99.9%, acetic acid by 97%, ammonia by 49%, isovaleric acid by 97%, and nonenal gas by 73%. have In addition, the frictional electrification voltage is significantly lower than that of general chemical fibers at the level of silk, so it is relatively excellent from fine dust or contamination.
Claims (6)
항균성 공융 배합물을 준비하는 단계와,
무수물과 이미다졸염을 이용하여 무수물계 경화제 배합물을 제조하는 단계와,
PET 수지에 상기 경화제 배합물과 함께 상용화제, 플라스틱용 활제, 플라스틱 분해용 산화제를 배합하여 PET 배합물을 준비하는 단계와,
상기 PET 배합물에 식물성 지방산과 항균성 공융 배합물을 배합하여 폴리에스터 배합물을 제조하는 단계와,
상기 폴리에스터 배합물을 이용하여 폴리에스터 펠렛을 제조하는 단계와,
상기 폴리에스터 펠렛을 용융, 압출, 냉각, 연신, 권취시킴으로써 필라멘트 폴리에스터 원사를 용융 방사하는 단계와,
상기 필라멘트 폴리에스터 원사를 이용하여 원단을 제조하는 단계를 포함하며,
상기 무수물계 경화제 배합물은, 무수물 100중량부당 경화 촉진제로서 이미다졸염을 1~40중량부 비율로 배합하여 제조하는 것을 특징으로 하는 치아씨드 추출물이 함유된 기능성 직물 원단의 제조방법. Washing and drying the chia seeds and then extracting vegetable fatty acids from the chia seeds;
preparing an antimicrobial eutectic blend;
Preparing an anhydride-based curing agent formulation using an anhydride and an imidazole salt;
preparing a PET compound by mixing a compatibilizer, a plastic lubricant, and an oxidizing agent for plastic decomposition with the curing agent compound in the PET resin;
preparing a polyester blend by blending a vegetable fatty acid and an antibacterial eutectic blend with the PET blend;
Preparing polyester pellets using the polyester blend;
Melt-spinning a filament polyester yarn by melting, extruding, cooling, drawing, and winding the polyester pellets;
Including the step of manufacturing a fabric using the filament polyester yarn,
The anhydride-based curing agent formulation is a method for producing a functional textile fabric containing chia seed extract, characterized in that prepared by blending an imidazole salt as a curing accelerator per 100 parts by weight of the anhydride in a ratio of 1 to 40 parts by weight.
상기 경화촉진제로서 이미다졸염은 1,2-디메틸-1H-이미다졸을 카르복실산 화합물과 배합하여 제조하는 것을 특징으로 하는 치아씨드 추출물이 함유된 기능성 직물 원단의 제조방법. According to claim 1,
As the curing accelerator, the imidazole salt is prepared by combining 1,2-dimethyl-1H-imidazole with a carboxylic acid compound.
상기 카르복실산 화합물은 아세트산, 프로판산, 헥산산, 2-에틸헥산산, 옥탄산, 노난산, 데칸산, 톨오일 지방산 (TOFA), 이들의 조합중에서 선택하는 것을 특징으로 하는 치아씨드 추출물이 함유된 기능성 직물 원단의 제조방법. According to claim 3,
The carboxylic acid compound is a chia seed extract, characterized in that selected from acetic acid, propanoic acid, hexanoic acid, 2-ethylhexanoic acid, octanoic acid, nonanoic acid, decanoic acid, tall oil fatty acid (TOFA), and combinations thereof Manufacturing method of functional textile fabric containing
상기 항균성 공융배합물은 알코올기를 가지는 항균물질과 주석산 염을 1~4 : 1의 몰비율로 공융배합하는 것을 특징으로 하는 치아씨드 추출물이 함유된 기능성 직물 원단의 제조방법. According to claim 1,
The antimicrobial eutectic blend is a method for producing a functional textile fabric containing chia seed extract, characterized in that the eutectic blend of an antibacterial substance having an alcohol group and a tartrate salt in a molar ratio of 1 to 4: 1.
상기 항균물질은, 멘톨, 프로폴리스, 및 플라보노이드의 그룹으로부터 선택되는 1가지 이상을 사용하는 것을 특징으로 하는 치아씨드 추출물이 함유된 기능성 직물 원단의 제조방법.
According to claim 5,
The method for producing a functional textile fabric containing a chia seed extract, characterized in that the antibacterial material uses at least one selected from the group of menthol, propolis, and flavonoids.
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