KR102366265B1 - Black Composition for inlay using paddy soil and manufacturing method thereof - Google Patents

Black Composition for inlay using paddy soil and manufacturing method thereof Download PDF

Info

Publication number
KR102366265B1
KR102366265B1 KR1020210115967A KR20210115967A KR102366265B1 KR 102366265 B1 KR102366265 B1 KR 102366265B1 KR 1020210115967 A KR1020210115967 A KR 1020210115967A KR 20210115967 A KR20210115967 A KR 20210115967A KR 102366265 B1 KR102366265 B1 KR 102366265B1
Authority
KR
South Korea
Prior art keywords
paddy soil
weight
paddy
black
soil
Prior art date
Application number
KR1020210115967A
Other languages
Korean (ko)
Inventor
박병호
Original Assignee
박병호
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 박병호 filed Critical 박병호
Priority to KR1020210115967A priority Critical patent/KR102366265B1/en
Application granted granted Critical
Publication of KR102366265B1 publication Critical patent/KR102366265B1/en

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/002Use of waste materials, e.g. slags
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/24Manufacture of porcelain or white ware
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/32Burning methods
    • C04B33/34Burning methods combined with glazing
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/4572Partial coating or impregnation of the surface of the substrate
    • C04B41/4576Inlaid coatings, i.e. resulting in a plane surface
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2203/00Production processes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Manufacturing & Machinery (AREA)
  • Adornments (AREA)

Abstract

The present invention provides a black inlay engobe composition using paddy soil. The paddy soil is subjected to a first step of collecting muddy paddy soil from paddy fields; a second step of mixing the collected paddy soil with water and then filtering foreign substances other than paddy soil using a sieve; a third step of repeating the act of separating water from the precipitated material at least three times when the paddy soil settles and sinks after wet mixing with water after performing the second step; and a fourth step of wet-mixing the remaining paddy soil with water after performing the third step to have a preset viscosity. The paddy soil contains 55.1% by weight of silicon oxide (SiO_2), 26.6% by weight of aluminum oxide (Al_2O_3), 8.94% by weight of iron oxide (Fe_2O_3), 3.14% by weight of magnesium oxide (MgO), and 3.74% by weight of potassium oxide (K_2O), based on the total weight of paddy soil. When the paddy soil is subjected to reduction calcination at 1250℃ for 5 hours in a gas kiln, black appears. A UV-vis analysis result value of a specimen is L: 29.35, a: -0.02, b: -4.43.

Description

논흙을 활용한 흑색 상감용 화장토 조성물 및 이의 제조방법{Black Composition for inlay using paddy soil and manufacturing method thereof}Black Composition for inlay using paddy soil and manufacturing method thereof

본 발명은 논흙을 활용한 흑색 상감용 화장토 조성물 및 이의 제조방법에 관한 것이다.The present invention relates to a composition for black inlay using paddy soil and a method for manufacturing the same.

이 부분에 기술된 내용은 단순히 본 발명에 대한 배경정보를 제공할 뿐 종래기술을 구성하는 것은 아니다.The content described in this section merely provides background information on the present invention and does not constitute the prior art.

상감기법은 도자기의 표면에 홈을 내고 그 홈을 상감용 조성물로 채워 독특한 문양과 패턴을 표현하기 위하여 사용될 수 있다. 종래에 사용되는 흑색 화장토는 퇴적된 황토가 검붉은색을 띄게 될 때 이를 채취하여 수비과정을 거쳐 사용하는데, 유약을 도포한 후 소성하는 과정에서 유약에 의해 분해되고 고온의 소성과정 동안 색상이 옅어지는 문제점이 있었다. 즉, 발색력이 굉장히 저하되는 문제가 있었는데 별다른 해결방법이 없어 그대로 사용하였다. 이를 보완하기 위하여 철성분이 많이 포함된 오수를 첨가해서 사용하였으나 이는 인체에 유해한 단점이 있다. 다른 보완책으로 검은색 안료를 첨가하여 사용하여 왔는데, 그 전보다 색상이 짙어지긴 하지만 보다 깊고 자연스러운 색감으로 발색이 되지 않는 한계가 있었다.The inlay technique can be used to express unique patterns and patterns by making grooves on the surface of ceramics and filling the grooves with an inlay composition. The conventionally used black crematory soil is collected when the deposited loess becomes dark red and used through a defensive process. There was a problem with losing. That is, there was a problem that the color development power was greatly reduced, but there was no specific solution, so it was used as it is. To compensate for this, sewage containing a lot of iron was added and used, but this has a disadvantage that is harmful to the human body. As another supplementary measure, black pigment has been added, and although the color is darker than before, there is a limitation in that the color cannot be developed with a deeper and more natural color.

공개된 특허 중 흑색 화장토(흑상감)에 관한 내용을 개시하는 것이 없긴 하지만 그나마 비슷한 것을 찾아보면, 종래기술인 등록특허 제10-0945787호의 갯벌흙을 이용한 유약 및 이를 이용한 흑색, 황색 반점을 갖는 도자기 제조 방법이 존재한다. 이 종래기술은 '흑색' 반점을 가지는 도자기 인 점은 개시되어 있긴 하나 상감용 화장토가 아닌 유약에 관한 것이며 유약을 전체적으로 도포하여 소성하면 도자기에 흑색 반점이 나타난다는 내용을 담고 있어 본 발명과는 다소 거리가 있다. 뿐만 아니라 소지 자체로 어두운 흑색을 발하는 것도 아닌 점에서 그 사용도가 좁은 단점이 있다.Although none of the published patents disclose the content of black emollient (black inlay), if you look for similar ones, you can find the glaze using the mud flat soil of the prior art Registration No. 10-0945787 and the manufacture of porcelain with black and yellow spots using the same There is a way. Although it is disclosed that this prior art is ceramics with 'black' spots, it relates to a glaze, not an emollient for inlay. there is a distance In addition, there is a disadvantage that the use is narrow in that the material itself does not emit a dark black color.

이에 본 발명자는 인체 무해하고 고급스럽고 깊은 흑색의 자연미를 살릴 수 있는 상감용 흑색 화장토에 대하여 연구를 거듭하였고, 철성분이 많이 포함된 논 흙을 사용하여 흑상감을 제조하는 경우 그 어떠한 첨가물을 첨가하지 않고도 유약과 반응하지 않고 고온에도 잘 견뎌 매우 자연스럽고 깊은 느낌의 흑색을 낼 수 있다는 것을 파악하였다. 기존의 흐릿하게 나오는 흑색 상감용 화장토는 퇴적되어 검붉은색을 내는 황토를 사용했으나 요즘은 이마저도 이러한 황토를 찾는 것이 매우 어려운 반면에, 논 흙은 보다 구하기가 용이하여 경제적이면서도 어떠한 첨가물 없이도 발색력이 매우 우수하다는 것을 알게 된 것이다. 이에 이를 체계적으로 정리하여 본 발명을 완성하기에 이르렀다.Accordingly, the present inventor has repeatedly researched on black emollient for inlay that is harmless to the human body and can preserve the luxurious and deep black natural beauty. It has been found that it can produce a very natural and deep black color without reacting with the glaze and withstand high temperatures well. Existing hazy black inlay soil used loess that has been deposited to give a dark red color, but it is very difficult to find such loess even these days. found out that it was excellent. Accordingly, it was systematically arranged to complete the present invention.

본 발명의 일 목적은 보다 우수한 발색력을 가지면서도 경제적인 흑색 상감용 화장토 및 이의 제조방법을 제공하는 것이다.One object of the present invention is to provide an economical black inlay emulsion and a method for manufacturing the same while having better color development.

본 발명의 일 목적을 달성하기 위해, 본 발명은, 논 흙 100중량%을 포함하는 논 흙을 활용한 흑색 상감용 화장토 조성물을 제공한다. In order to achieve one object of the present invention, the present invention provides a black inlay composition using paddy soil containing 100% by weight of paddy soil.

본 발명의 추가적인 해결수단은 아래에서 이어지는 설명에서 일부 설명될 것이고, 그 설명으로부터 부분적으로 용이하게 확인할 수 있거나, 또는 본 발명의 실시에 의해 지득될 수 있다.Additional solutions of the invention will be set forth in part in the description that follows, and may be readily ascertained in part from the description, or may be learned by practice of the invention.

전술한 일반적인 설명 및 다음의 상세한 설명 모두는 단지 예시적이고 설명을 위한 것이며 청구범위에 기재된 본 발명을 제한하지 않는다.Both the foregoing general description and the following detailed description are exemplary and explanatory only and do not limit the invention as set forth in the claims.

본 발명에 따른 흑색 상감용 화장토 조성물은 우수한 발색력을 가지므로 보다 자연스럽고 고급스러우면서도 선명한 흑색이 표현될 수 있다.Since the black inlay composition according to the present invention has excellent color development, a more natural, luxurious and clear black color can be expressed.

본 발명에 따른 흑색 상감용 화장토 조성물은 보다 그 원재료를 구하기 용이하여 경제적인 장점이 있다.The black inlay composition according to the present invention has an economic advantage because it is easier to obtain the raw material thereof.

도 1 및 2는 종래기술에 따른 상감용 화장토를 이용하여 제조한 도자기 시편이다.
도 3은 본 발명에 따른 논 흙을 활용한 상감용 화장토를 이용하여 제조한 도자기 시편이다.
1 and 2 are porcelain specimens prepared by using the inlay soil according to the prior art.
3 is a ceramic specimen prepared using paddy soil for inlay using paddy soil according to the present invention.

이하, 첨부된 도면을 참조하여 본 발명의 구체적인 실시형태에 대하여 상세하게 서술하도록 한다. Hereinafter, specific embodiments of the present invention will be described in detail with reference to the accompanying drawings.

다만, 본 발명의 구체적 일 실시 형태를 설명함에 있어, 관련된 공지 기능 또는 구성에 대한 구체적인 설명이 본 발명의 요지를 불필요하게 흐릴 수 있다고 판단되는 경우에는 그 상세한 설명을 생략한다.However, in describing a specific embodiment of the present invention, if it is determined that a detailed description of a related known function or configuration may unnecessarily obscure the gist of the present invention, the detailed description thereof will be omitted.

도 1 및 2는 종래기술에 따른 상감용 화장토를 이용하여 제조한 도자기 시편이다.1 and 2 are porcelain specimens prepared by using the inlay soil according to the prior art.

도 1에 나타난 것은 퇴적되어 검붉은색을 띄는 황토를 채취하여 수비과정을 거쳐 제조한 상감용 흑색 화장토 조성물을 이용하여 그림을 그린 후 소성한 도자기 시편이다. 도 1을 참조하면 유약과 일부 성분이 반응하는 등의 이유로 발색이 선명하지 못하고 흐릿하며, 고온의 소성 과정을 견디지 못하여 색상의 선명도가 저하되는 것을 알 수 있다. 이는 유약 조성물을 뚫고 나오는 발색력이 좋지 못한 것으로 표현될 수 있다. 이에 의해 제조된 도자기는 전체적으로 그림의 느낌이 살지 못하기 때문에 생동감을 줄 수 없고 결국 작품으로서의 사회적/경제적 가치가 낮게 평가될 수밖에 없다.What is shown in FIG. 1 is a ceramic specimen that is baked after drawing a picture using a black emollient composition for inlay prepared by collecting dark red ocher that has been deposited and subjected to a defensive process. Referring to FIG. 1 , it can be seen that the color development is not clear and hazy due to the reaction of some components with the glaze, and the color vividness is deteriorated because it cannot withstand the high-temperature firing process. This may be expressed as poor color development through the glaze composition. The pottery produced by this method cannot liven up the feeling of painting as a whole, so it cannot give vitality, and in the end, the social/economic value of the work is inevitably low.

이를 해결하기 위해 제안된 것이 도 2에 표현된 흑색 화장토 조성물이다. 이는 퇴적되어 검붉은색을 띄는 황토를 채취하여 수비과정을 거친 후 첨가물(오수 또는 흑색 물감)을 더해 제조할 수 있다. 도 2를 참조하면 기존에 비해 색상이 선명해진 것으로 보이긴 하지만, 이 경우에도 진하고 깊은 검은색이 표현되지 못하여 전체적으로 색이 바랜듯한 느낌이 든다.To solve this problem, the black emulsion composition shown in FIG. 2 is proposed. It can be manufactured by collecting loess that has been deposited and has a dark red color, going through the defense process, and then adding additives (stained water or black paint). Referring to FIG. 2 , although it seems that the color has become clearer than before, even in this case, the dark and deep black color cannot be expressed, so the overall color feels washed out.

도 3은 본 발명에 따른 논 흙을 활용한 상감용 화장토를 이용하여 제조한 도자기 시편이다.3 is a ceramic specimen prepared using paddy soil for inlay using paddy soil according to the present invention.

도 3을 참조하면 본 발명에 따른 논 흙을 활용한 흑색 상감용 화장토 조성물은 한눈에 보아도 깊고 진한 색상으로 발색되어 전체적으로 색이 바랜듯한 느낌 없이 매우 선명하게 표현된 것을 파악할 수 있다. Referring to FIG. 3 , it can be seen that the black inlay composition using paddy soil according to the present invention is expressed in a deep and dark color even at a glance, so that the color is expressed very clearly without feeling that the color as a whole is faded.

이와 같이 색상의 발색 측면에서 현저한 효과를 내는 본 발명에 따른 논 흙을 활용한 흑색 상감용 화장토 조성물은 아래의 표 1과 같이 논 흙으로 구성될 수 있다.As described above, the black inlay composition using paddy soil according to the present invention, which produces a remarkable effect in terms of color development, may be composed of paddy soil as shown in Table 1 below.

논 흙paddy soil 100100

논 흙은 논에서 채취한 후 아래와 같은 과정을 거칠 수 있다. After the paddy soil is collected from the paddy field, the following process can be performed.

먼저, 진흙상태의 논 흙을 논에서 채취하는 제1단계, 이를 물과 섞은 다음 체를 이용하여 논 흙 이외의 이물질을 걸러 주는 제2단계가 수행될 수 있다. 이 후 물과 습식혼합한 후 논 흙이 침전되어 가라앉으면 침전된 물질로부터 물을 분리해 내는(여러번 반복, 최소 3회) 제3단계 및 남아 있는 논 흙을 물과 습식혼합하여 적절한 점도를 가지도록 하는 제4단계가 수행될 수 있다.First, the first step of collecting muddy paddy soil from the paddy field, the second step of mixing it with water and filtering foreign substances other than the paddy soil using a sieve may be performed. After that, after wet mixing with water, when the paddy soil settles and sinks, the third step is to separate the water from the settled material (repeat several times, at least 3 times), and wet the remaining paddy soil with water to obtain an appropriate viscosity. A fourth step may be performed.

상기 논 흙의 구체적인 성분과 각 성분의 함량비율은 아래와 같다.The specific components of the paddy soil and the content ratio of each component are as follows.

시험예: 논 흙 성분 분석Test Example: Analysis of the composition of paddy soil

아래의 표 2는 XRF로 분석한 논 흙의 성분분석 결과표이다.Table 2 below is a table of composition analysis results of paddy soil analyzed by XRF.

성분ingredient SiO2 SiO 2 Al2O3 Al 2 O 3 Fe2O3 Fe 2 O 3 CaOCaO MgOMgO K2OK 2 O Na2ONa 2 O ZnOZnO NiONiO 기타Other 단위:wt%Unit: wt% 55.155.1 26.626.6 8.948.94 0.8580.858 3.143.14 3.743.74 0.6790.679 0.020.02 0.01200.0120 0.9110.911

기타 성분은 그 성분 함량이 작아 큰 영향을 미치지 않는 요소를 '기타'라는 하나의 카테고리로 묶은 것이다.As for other ingredients, elements that do not have a significant effect due to their small content are grouped into one category called 'Others'.

종래기술 대비하여 본 발명에 따른 논 흙은 산화규소(SiO2)와 산화알루미늄(Al2O3)이 풍부하게 함유되어 이들 요소가 유약과 같이 잘 융합되어 유약에 의해 영향을 덜 받게 하면서도 가마 고온 소성 시 발색을 하는 역할인 산화철(Fe2O3) 등에게 고온에 따른 열에너지가 덜 전달이 되도록 완충 역할을 하므로 도 3과 같이 매우 선명하면서도 깊고 고급스러운 발색이 가능하다.Compared to the prior art, the paddy soil according to the present invention contains abundant silicon oxide (SiO 2 ) and aluminum oxide (Al 2 O 3 ), so that these elements are well fused like glaze, making them less affected by the glaze and the high temperature of the kiln It serves as a buffer so that less thermal energy due to high temperature is transferred to iron oxide (Fe 2 O 3 ), which is responsible for color development during firing, so that very vivid, deep and luxurious color development is possible as shown in FIG. 3 .

아래의 표 3은 본 발명에 따른 논흙을 활용한 상감용 조성물로 그림을 그린 후 소성한 시편에 대한 UV-vis 분석을 통한 색상 분석 결과 값이다. 가스가마에서 1250℃ 5시간을 유지하는 환원 소성이 수행될 수 있다.Table 3 below shows the color analysis result values through UV-vis analysis of the calcined specimen after drawing with the composition for inlay using paddy soil according to the present invention. Reduction calcination may be performed in a gas kiln at 1250° C. for 5 hours.

색상분석color analysis L: 29.35,
a: -0.02,
b: -4.43
L: 29.35,
a: -0.02,
b: -4.43
명도(L)가 매우 낮은 것으로 진한 흑색이 발현된 것을 파악할 수 있음With very low brightness (L), it can be understood that dark black is expressed.

L은 명도, a는 Red와 Green의 정도, b는 Yellow와 Blue의 정도를 나타내는 수치다.L is the brightness, a is the degree of red and green, and b is the number that represents the degree of yellow and blue.

위의 특성을 가지는 본 발명에 따른 상감용 화장토 조성물은 도자기 표면에 그림을 그리거나, 도자기 표면에 홈을 내고 상감을 채워넣는 음각기법, 상감용 화장토를 도자기 표면에 모두 바른 후 문양부분을 파내는 투각기법 등의 다양한 표현기법을 사용할 때 유용하게 활용할 수 있다. 본 발명에 따른 흑색 상감용 화장토는 오로지 논 흙만을 활용하여 전술한 과정을 통해 제조한 것으로 어떠한 첨가물이나 추가 공정 없이도 우수한 발색력을 가지는 것이므로 미적 측면과 경제적 측면 모든 것을 일거에 해결할 수 있는 장점을 가진다.The composition for inlay according to the present invention having the above characteristics is an engraving technique that draws a picture on a ceramic surface, makes a groove on the surface of the ceramic and fills the inlay, and an openwork that digs out a pattern after applying all the inlay soil on the surface of the ceramic It can be usefully used when using various expression techniques such as techniques. The black inlay crematory soil according to the present invention is manufactured through the above-described process using only paddy soil, and has excellent color development power without any additives or additional processes.

본 실시예는 본 발명의 기술적 사상을 예시적으로 설명한 것에 불과하고, 본 발명이 속하는 기술 분야에서 통상의 지식을 가진 자라면 본 발명의 본질적인 특성에서 벗어나지 않는 범위에서 본 실시예의 다양한 수정 및 변형이 가능할 것이다. 본 실시예는 본 발명의 기술적 사상을 한정하기 위한 것이 아니라 설명하기 위한 것이고, 따라서 본 실시예에 의하여 본 발명의 권리범위가 한정되는 것은 아니다. 본 발명의 보호범위는 청구범위에 의하여 해석되어야 하며, 그와 동등하거나 균등하다고 인정되는 모든 기술적 사상은 본 발명의 권리범위에 포함되는 것으로 해석되어야 한다.This embodiment is merely illustrative of the technical idea of the present invention, and those of ordinary skill in the art to which the present invention pertains may make various modifications and variations of this embodiment without departing from the essential characteristics of the present invention. It will be possible. This embodiment is intended to explain, not to limit the technical spirit of the present invention, and therefore the scope of the present invention is not limited by the present embodiment. The scope of protection of the present invention should be construed by the claims, and all technical ideas that are equivalent to or recognized as equivalent should be construed as being included in the scope of the present invention.

Claims (4)

논 흙을 포함하는 논 흙을 활용한 흑색 상감용 화장토 조성물로서,
상기 논 흙은,
진흙상태의 논 흙을 논에서 채취하는 제1단계;
채취한 상기 논 흙을 물과 섞은 다음 체를 이용하여 논 흙 이외의 이물질을 걸러 주는 제2단계;
상기 제2단계 수행 후 물과 습식혼합한 후 상기 논 흙이 침전되어 가라앉으면 침전된 물질로부터 물을 분리해 내는 행위를 적어도 3회 반복하는 제3단계; 및
상기 제3단계 수행 후 잔여 논 흙을 물과 습식혼합하여 기 설정된 점도를 가지도록 하는 제4단계
를 거치며,
상기 논 흙은 논 흙 전체 중량을 기준으로 산화규소(SiO2) 55.1중량%, 산화알루미늄(Al2O3) 26.6중량%, 산화철(Fe2O3) 8.94중량%, 산화마그네슘(MgO) 3.14중량%, 산화칼륨(K2O) 3.74중량%를 포함하고,
가스가마에서 1250℃ 5시간을 유지하는 환원 소성을 거치는 경우 흑색이 발현되며, 시편의 UV-vis분석 결과값이 L: 29.35, a: -0.02, b: -4.43인 것
을 특징으로 하는 논 흙을 활용한 흑색 상감용 화장토 조성물.
As a black inlay composition using paddy soil including paddy soil,
The paddy soil is
A first step of collecting muddy paddy soil from paddy fields;
a second step of mixing the collected paddy soil with water and then filtering foreign substances other than paddy soil using a sieve;
a third step of repeating the act of separating water from the precipitated material at least three times when the paddy soil is precipitated and settled after wet mixing with water after performing the second step; and
A fourth step of wet-mixing the remaining paddy soil with water after performing the third step to have a preset viscosity
going through,
The paddy soil is based on the total weight of paddy soil, silicon oxide (SiO 2 ) 55.1% by weight, aluminum oxide (Al 2 O 3 ) 26.6% by weight, iron oxide (Fe 2 O 3 ) 8.94% by weight, magnesium oxide (MgO) 3.14 % by weight, including 3.74% by weight of potassium oxide (K 2 O),
If it undergoes reduction calcination at 1250℃ for 5 hours in a gas kiln, black is expressed, and the result of UV-vis analysis of the specimen is L: 29.35, a: -0.02, b: -4.43
A black inlay composition using paddy soil, characterized in that
삭제delete 삭제delete 삭제delete
KR1020210115967A 2021-08-31 2021-08-31 Black Composition for inlay using paddy soil and manufacturing method thereof KR102366265B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1020210115967A KR102366265B1 (en) 2021-08-31 2021-08-31 Black Composition for inlay using paddy soil and manufacturing method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020210115967A KR102366265B1 (en) 2021-08-31 2021-08-31 Black Composition for inlay using paddy soil and manufacturing method thereof

Publications (1)

Publication Number Publication Date
KR102366265B1 true KR102366265B1 (en) 2022-02-23

Family

ID=80495596

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020210115967A KR102366265B1 (en) 2021-08-31 2021-08-31 Black Composition for inlay using paddy soil and manufacturing method thereof

Country Status (1)

Country Link
KR (1) KR102366265B1 (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100945787B1 (en) * 2009-03-13 2010-03-05 서동규 Glaze using foreshore mud and manufacturing method of ceramics using thereof
KR20110001467A (en) * 2009-06-30 2011-01-06 주식회사 트라앤 Method for manufacturing ceramic ware clay and glaze using foreshore mud
KR20120034263A (en) * 2010-08-26 2012-04-12 이장수 Black engobe
KR101497835B1 (en) * 2013-10-21 2015-03-04 유기정 ceramics glaze using rice paddy soil and coloring method thereby

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100945787B1 (en) * 2009-03-13 2010-03-05 서동규 Glaze using foreshore mud and manufacturing method of ceramics using thereof
KR20110001467A (en) * 2009-06-30 2011-01-06 주식회사 트라앤 Method for manufacturing ceramic ware clay and glaze using foreshore mud
KR20120034263A (en) * 2010-08-26 2012-04-12 이장수 Black engobe
KR101497835B1 (en) * 2013-10-21 2015-03-04 유기정 ceramics glaze using rice paddy soil and coloring method thereby

Similar Documents

Publication Publication Date Title
CN105330158A (en) Glaze of brunet ceramic and preparation method of glaze
KR101129683B1 (en) Method for manufacturing ceramic ware clay and glaze using foreshore mud
KR20120037293A (en) Glaze composition for ceramic ware comprising ashes from the excrements of earthworm and preparation method thereof
CN112374762A (en) Moon white glaze for jun porcelain and preparation method thereof
KR102016467B1 (en) Glace Composition for Ceramic Ware Comprising Ashes from Peanut shell and Preparation Method thereof
KR20200028374A (en) Method of manufacturing Ceramic Ware by using Ashes from Leaves
KR102366265B1 (en) Black Composition for inlay using paddy soil and manufacturing method thereof
CN114149246B (en) Production method of ceramic with cosmetic clay decoration
KR20120095106A (en) Glaze composition for ceramic ware including fly ash and preparation method thereof
CN107619268A (en) Porcelain formula and production process
KR20120061546A (en) Glaze composition for ceramic ware comprising ashes from the excrements of silkworm and preparation method thereof
KR102380992B1 (en) Black Ceramic Composition Comprising with High Bending Strength Using Water treatment Sludge and Method for Preparation thereof
KR102380991B1 (en) Dark Ceramic Composition Comprising Ferrite Sludge and Water treatment Sludge and Method for Preparation thereof
KR102377457B1 (en) Buckwheat grain type crystal glaze composition and manufacturing method ceramic using thereof
KR101054253B1 (en) Method for preparing a green-ceramic pigment for reduction fire using copper oxide and a green ceramic thereof
KR19990045852A (en) Pottery manufacturing method used by loess
KR102234769B1 (en) Glace Composition for Ceramic Ware Comprising Ashes from Bean and Preparation Method thereof
KR102208096B1 (en) Buncheong Ceramic Composition and Manufacturing Method thereof
Coentro et al. White on blue: a study on underglaze-decorated ceramic tiles from 15th-16th-century Valencian and Sevillian productions
KR102076228B1 (en) White Ceramic Composition Comprising Powder from Amphibole and Manufacturing Method thereof
KR20230081495A (en) Color Substrate composition with reproducibility of Goryeo white porcelain and manufacturing method thereof
KR100688874B1 (en) Glaze Prepared with Scoria, and Method of Preparing and Using Same
KR20230031094A (en) Substrate composition with high bending strength with reproducibility of Goryeo white porcelain and manufacturing method thereof
KR102138702B1 (en) Glace Composition for Ceramic Ware Comprising Ashes from Hawthorn-like raspberry and Preparation Method thereof
KR102016470B1 (en) Glace Composition for Ceramic Ware Comprising Ashes from Corn Husk and Preparation Method thereof

Legal Events

Date Code Title Description
E701 Decision to grant or registration of patent right
GRNT Written decision to grant