KR102350438B1 - Granular pesticide composition and manufacturing method thereof - Google Patents

Granular pesticide composition and manufacturing method thereof Download PDF

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KR102350438B1
KR102350438B1 KR1020187030037A KR20187030037A KR102350438B1 KR 102350438 B1 KR102350438 B1 KR 102350438B1 KR 1020187030037 A KR1020187030037 A KR 1020187030037A KR 20187030037 A KR20187030037 A KR 20187030037A KR 102350438 B1 KR102350438 B1 KR 102350438B1
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granular
particle nuclei
outer layer
particle
parts
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KR20180128934A (en
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료 타나카
토시노부 야마자키
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구미아이 가가쿠 고교 가부시키가이샤
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/12—Powders or granules
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/26—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
    • A01N37/24—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides containing at least one oxygen or sulfur atom being directly attached to the same aromatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/14—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N2300/00—Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48

Abstract

본 발명은 3-(3,4-다이클로로아이소티아졸-5-일메톡시)-1,2-벤조티아졸-1,1-다이옥사이드의 보존 안정성이 우수한, 농원예상 유용한 입상 농약조성물 및 이의 제조 방법에 관한 것이다. 입자 핵과, 상기 입자 핵을 피복하는 외부층을 갖는 입상 농약조성물로서, 상기 입자 핵이 3-(3,4-다이클로로아이소티아졸-5-일메톡시)-1,2-벤조티아졸-1,1-다이옥사이드를 함유하고, 또한, 상기 외층부가, 상온에서 결정화되지 않는 당류인 액당을 함유하여 이루어진 입상 농약조성물이다. 또한, 상기 입상 농약조성물의 제조 방법에 있어서, 상기 화합물을 포함하는 입자 핵을 제조하는 공정, 및 상기 공정에서 얻어진 입자 핵의 표면을, 상온에서 결정화되지 않는 당류인 액당을 함유하는 액상물로 피복하여, 상기 입자 핵의 표면에 외층부를 형성시키는 공정을 포함하는 것을 특징으로 하는 입상 농약조성물의 제조방법이다.The present invention is 3-(3,4-dichloroisothiazol-5-ylmethoxy)-1,2-benzothiazole-1,1-dioxide excellent in storage stability, useful agricultural and horticultural granular agrochemical composition and preparation thereof it's about how A granular pesticide composition having particle nuclei and an outer layer covering the particle nuclei, wherein the particle nuclei are 3-(3,4-dichloroisothiazol-5-ylmethoxy)-1,2-benzothiazole-1 ,1-dioxide, and the outer layer portion is a granular pesticide composition comprising liquid sugar, which is a saccharide that does not crystallize at room temperature. Further, in the method for producing the granular agrochemical composition, in the step of producing particle nuclei containing the compound, and the surface of the particle nuclei obtained in the above step, the surface of the particle nuclei is coated with a liquid containing liquid sugar, which is a saccharide that does not crystallize at room temperature Thus, it is a method for producing a granular agrochemical composition comprising the step of forming an outer layer portion on the surface of the particle nucleus.

Description

입상 농약조성물 및 이의 제조방법Granular pesticide composition and manufacturing method thereof

본 발명은, 3-(3,4-다이클로로아이소티아졸-5-일메톡시)-1,2-벤조티아졸-1,1-다이옥사이드를 함유하는 농원예상 유용한 입상 농약조성물 및 이의 제조방법에 관한 것이다. 특히, 상기 화합물의 보존 안정성이 우수한, 농원예상 유용한 입상 농약조성물 및 이의 제조방법에 관한 것이다.The present invention relates to a useful agricultural and horticultural granular agrochemical composition containing 3-(3,4-dichloroisothiazol-5-ylmethoxy)-1,2-benzothiazole-1,1-dioxide and a method for preparing the same it's about In particular, it relates to a granular agrochemical composition having excellent storage stability of the compound, useful for agricultural and horticultural purposes, and a method for preparing the same.

현재, 농약제제의 형태로서는, 분제(粉劑), 입제(粒劑), 수화제, 과립수화제, 유동가능(flowable)제, 액제, 유제 등의 제형이 알려져 있다. 그 중에서, 입제는 농약제제를 직접 살포하는 제형이며, 논에서의 수면 시용(施用)이나 육종상자 처리, 밭의 토양 혼합 등의 형태로 사용된다. 농약 처리 작업이 간편하고, 살포용의 물을 필요로 하지 않고, 분립(粉立)에 의한 농약 활성성분의 비산의 우려도 없기 때문에, 일본에서 주류의 제형으로 되고 있다.Currently, as a form of agrochemical formulations, formulations such as powders, granules, wettable powders, wettable granules, flowable agents, liquids, and emulsions are known. Among them, granules are formulations that directly spray pesticides, and are used in the form of surface application in paddy fields, breeding box treatment, and soil mixing in fields. Since the pesticide treatment operation is simple, there is no need for water for spraying, and there is no fear of scattering of the pesticide active ingredient due to granulation, it has become a mainstream formulation in Japan.

입제로 사용되는 입상 농약조성물의 일반적인 형태는, 농약 활성성분과 점토와 탄산 칼슘 등의 고체 담체 등을 혼합하여, 상기한 바와 같이 얻어진 혼합물에 물을 넣어 반죽하고, 소정의 구멍직경을 갖는 다이(die)를 이용하여 압출 조립한 후, 건조하여 제조된 입상물이다. 이러한 입상물에서는, 농약 활성성분과 환경 중의 수분의 접촉이 제한되기 때문에, 농약 활성성분의 용출 거동은, 보다 점진적으로 방출되는 경향의 것으로 되어, 효과의 지속성이 요구되는 농약 활성성분에 적합하다. 또한, 다른 양태로서, 광물질 등을 해쇄 또는 조립함으로써 얻은 적당한 입도를 갖는 입자 핵의 표층에 바인더를 이용하여 농약 활성성분을 피복한 입상물인 입상 농약조성물도 알려져 있다. 이러한 입상물에서는, 농약 활성성분이 환경 중의 수분과 직접 접촉하기 때문에, 농약 활성성분을 보다 빨리 용출시킬 수 있어, 속효성이 요구되는 농약 활성성분에 적합하다. 더욱이, 전자의 입상물을 입자 핵으로 한 후자의 입상물의 형태도 있을 수 있다. 당업자는, 배합하는 농약 활성성분에 요구되는 용출 패턴에 따라서, 각각에 적합한 입제의 형태를 선택하고, 구분할 수 있다.The general form of the granular pesticide composition used as granules is to mix the active ingredient of the pesticide with a solid carrier such as clay and calcium carbonate, add water to the obtained mixture as described above, knead the mixture, and knead the mixture with a die having a predetermined hole diameter ( It is a granular material manufactured by extrusion granulation using a die) and then drying. In such a granular material, since the contact between the agrochemical active ingredient and moisture in the environment is limited, the dissolution behavior of the agrochemical active ingredient tends to be more gradual, and is suitable for an agrochemical active ingredient that requires continuity of effect. As another aspect, there is also known a granular agrochemical composition, which is a granular material obtained by pulverizing or granulating a mineral or the like, and coated with an agrochemical active ingredient using a binder on the surface layer of particle nuclei having an appropriate particle size. In such a granular material, since the agrochemical active ingredient is in direct contact with moisture in the environment, the agrochemical active ingredient can be eluted more quickly, which is suitable for an agrochemical active ingredient requiring fast-acting properties. Furthermore, there may be a form of the latter granular material in which the former granular material is the particle nucleus. A person skilled in the art can select and classify the form of granules suitable for each according to the dissolution pattern required for the agrochemical active ingredient to be blended.

한편, 농약 제제에 있어서의 농원예상의 방제 대상으로는, 병해 이외에 해충, 잡초가 있으며, 그 전부에 대응할 필요가 있지만, 병해 방제 활성성분은 병해 방제에 특화되어 있으며, 통상, 해충이나 잡초에는 충분한 방제 활성을 나타내지 않는다. 마찬가지로, 해충 방제 활성성분과 잡초 방제 활성성분으로 해도, 각각 해충 방제나 잡초 방제에 특화된 것이다. 따라서, 현대의 농업에서는, 병해 방제에는 병해 방제 활성성분을, 해충 방제에는 해충 방제 활성성분을, 잡초 방제에는 잡초 방제 활성성분을 각각 이용하여 농경지 등의 관리가 행해지고 있다. 또한 각각의 병해 방제 활성성분에는 효과적인 병해와 효과적이지 않은 병해가 존재한다. 농경지 등에 발생하는 다수의 방제 대상에 대응하기 위해서, 스펙트럼이 다른 다수의 병해 방제 활성성분이 개발되어 있다. 해충 방제 활성성분과 잡초 방제 활성성분에 있어서도 마찬가지 사정이다. 이러한 배경에서, 최근에는 복수의 입제를 사용 시 혼합하여 사용하거나, 단일의 농약 입제에 복수의 농약 활성성분을 배합한 혼합 농약 입제를 이용하는 것도 행해지고 있다.On the other hand, there are pests and weeds in addition to pests and weeds as the target of agricultural and horticultural control in the pesticide formulation, and it is necessary to respond to all of them, but the disease control active ingredient is specialized in disease control, and usually sufficient for pests and weeds It does not show control activity. Similarly, even with the pest control active ingredient and the weed control active ingredient, they are specialized in pest control and weed control, respectively. Accordingly, in modern agriculture, pest control active ingredients are used for disease control, pest control active ingredients are used for pest control, and weed control active ingredients are used for weed control, respectively, and farmland is managed. In addition, effective diseases and ineffective diseases exist in each disease control active ingredient. In order to respond to a large number of control targets occurring in agricultural land, etc., a large number of disease control active ingredients with different spectrums have been developed. The same is true for the pest control active ingredient and the weed control active ingredient. Against this background, recently, it is also practiced to use a mixture of a plurality of granules when using them, or to use a mixed pesticide granules in which a plurality of pesticide active ingredients are blended into a single pesticide granules.

3-(3,4-다이클로로아이소티아졸-5-일메톡시)-1,2-벤조티아졸-1,1-다이옥사이드(이하, 본 명세서에 있어서 상기 물질을 가리켜 「화합물 A」라 칭함)는 공지의 농원예용 식물 병해 방제 활성성분으로서, 벼 도열병, 밀병, 오이 병, 오이 탄저병 등의 식물 병해에 대해서 현저한 효과를 나타내는 것이 특허 문헌 1에 개시되어 있다. 이 화합물 A는 농작물 등의 생육에 필요한 오랜 기간에 걸쳐서 식물 병해를 방제하고, 또한 예방하는 것도 기대하는 것이기 때문에, 화합물 A를 입제로 조제하는 경우의 형태로서는, 화합물 A를 고체 담체 등과 함께 입자 내에 반죽(kneaded)한 조립물로 하는 것이 바람직하다 3-(3,4-dichloroisothiazol-5-ylmethoxy)-1,2-benzothiazole-1,1-dioxide (hereinafter referred to as “Compound A” in the present specification) is a known active ingredient for controlling plant diseases for agricultural and horticultural use, and it is disclosed in Patent Document 1 that exhibits a remarkable effect on plant diseases such as rice blast disease, wheat disease, cucumber disease, and cucumber anthrax. Since this compound A is also expected to control and prevent plant diseases over a long period of time necessary for the growth of crops, etc. It is preferable to use a kneaded granulated product.

그러나, 화합물 A는 화학적으로 다소 불안정한 화합물이며, 다양한 화학 물질과의 공존 하에서 불필요하게 분해가 촉진될 수 있기 때문에, 입상 농약조성물 중에 있어서의 화합물 A의 보존 안정성의 향상이 요구되고 있었다. 특히, 화합물 A와 다른 농약 활성성분을 병용하는 혼합 농약 입제에 있어서는, 의도적으로 여러 화학 물질이 공존하기 때문에, 화합물 A의 분해가 더욱 촉진되어, 보다 불리한 장해가 될 경우가 있으며, 이들 화학 물질의 영향을 받지 않고 화합물 A의 보존 안정성이 우수한 입상 농약조성물을 개발하는 것은 어려웠다.However, since compound A is a chemically somewhat unstable compound and decomposition may be promoted unnecessarily in the coexistence of various chemical substances, improvement of storage stability of compound A in a granular agrochemical composition has been desired. In particular, in mixed pesticide granules in which Compound A and other agrochemical active ingredients are used in combination, since several chemical substances coexist intentionally, the decomposition of Compound A is further accelerated, which may cause a more unfavorable obstacle, It has been difficult to develop a granular agrochemical composition which is not affected and has excellent storage stability of Compound A.

특허문헌 1: 국제공개 제2007/129454호Patent Document 1: International Publication No. 2007/129454

따라서, 본 발명의 목적은, 3-(3,4-다이클로로아이소티아졸-5-일메톡시)-1,2-벤조티아졸-1,1-다이옥사이드의 보존 안정성이 우수한, 농원예상 유용한 입상 농약조성물 및 이의 제조 방법을 제공하는 것이다.Therefore, it is an object of the present invention, 3-(3,4-dichloroisothiazol-5-ylmethoxy)-1,2-benzothiazole-1,1-dioxide excellent in storage stability, agricultural and horticultural useful granular To provide an agrochemical composition and a method for manufacturing the same.

본 발명자들은, 3-(3,4-다이클로로아이소티아졸-5-일메톡시)-1,2-벤조티아졸-1,1-다이옥사이드의 보존 안정성이 우수한 입상 농약조성물을 개발하기 위해 열심히 검토한 결과, 상기 화합물을 입자 핵에 함유시켜, 그 입자 핵의 표면에 상온(常溫)에서 결정화되지 않는 당류를 이용하여 형성한 외층부를 갖는 입상 농약조성물이 상기 과제를 해결하는 것을 발견하여, 본 발명을 완성하기에 이르렀다.The present inventors studied hard to develop a granular agrochemical composition with excellent storage stability of 3-(3,4-dichloroisothiazol-5-ylmethoxy)-1,2-benzothiazole-1,1-dioxide As a result, it has been found that a granular agrochemical composition having an outer layer formed by containing the compound in particle nuclei and using saccharides that do not crystallize at room temperature on the surface of the particle nuclei solves the above problems, and the present invention came to complete.

즉, 본 발명은, 다음과 같은 내용의 것이다.That is, the present invention has the following contents.

[1] 입자 핵과, 상기 입자 핵을 피복하는 외층부를 갖는 입상 농약조성물로서, 상기 입자 핵이 3-(3,4-다이클로로아이소티아졸-5-일메톡시)-1,2-벤조티아졸-1,1-다이옥사이드를 함유하며, 상기 외층부가 상온에서 결정화되지 않는 당류인 액당을 함유하여 이루어진, 입상 농약조성물.[1] A granular pesticide composition having particle nuclei and an outer layer covering the particle nuclei, wherein the particle nuclei are 3-(3,4-dichloroisothiazol-5-ylmethoxy)-1,2-benzothiazole A granular pesticide composition containing -1,1-dioxide, and the outer layer contains liquid sugar, which is a saccharide that does not crystallize at room temperature.

[2] 상기 입자 핵이 압출 조립법에 의해 얻어진 조립물인, 상기 1항에 기재된 입상 농약조성물.[2] The granular agrochemical composition according to item 1, wherein the particle nuclei are a granulated product obtained by an extrusion granulation method.

[3] 상기 액당이 환원당을 함유하는 전화형 액당인, 상기 1 또는 2항에 기재된 입상 농약조성물.[3] The granular agrochemical composition according to item 1 or 2, wherein the liquid sugar is an inversion liquid sugar containing a reducing sugar.

[4] 상기 액당의 함유량이 입상 농약조성물 전체에 대해서 0.5 내지 5질량%인, 상기 1 내지 3항 중 어느 한 항에 기재된 입상 농약조성물.[4] The granular pesticide composition according to any one of items 1 to 3, wherein the content of the liquid sugar is 0.5 to 5% by mass relative to the total amount of the granular pesticide composition.

[5] 추가로 농약 활성성분을 상기 외층부에 담지하여 이루어진, 상기 1 내지 4항 중 어느 한 항에 기재된 입상 농약조성물.[5] The granular agrochemical composition according to any one of items 1 to 4, wherein an agrochemical active ingredient is further supported on the outer layer portion.

[6] 상기 입자 핵이 대략 원기둥형이며, 그 단면 원 직경이 0.3 내지 1.7㎜인, 상기 1 내지 5항 중 어느 한 항에 기재된 입상 농약조성물.[6] The granular agrochemical composition according to any one of items 1 to 5, wherein the particle nuclei have a substantially cylindrical shape and a cross-sectional circle diameter of 0.3 to 1.7 mm.

[7] 상기 1 내지 6항 중 어느 한 항에 기재된 입상 농약조성물의 제조 방법에 있어서, 3-(3,4-다이클로로아이소티아졸-5-일메톡시)-1,2-벤조티아졸-1,1-다이옥사이드를 함유하는 입자 핵을 제조하는 공정, 및 상기 공정에서 얻은 입자 핵의 표면을, 상온에서 결정화되지 않는 당류인 액당을 함유하는 액상물로 피복하여, 상기 입자 핵의 표면에 외층부를 형성시키는 공정을 포함하는 것을 특징으로 하는 입상 농약조성물의 제조방법.[7] In the method for producing the granular agrochemical composition according to any one of items 1 to 6, 3-(3,4-dichloroisothiazol-5-ylmethoxy)-1,2-benzothiazole- A process for producing particle nuclei containing 1,1-dioxide, and coating the surface of the particle nuclei obtained in the above process with a liquid containing liquid sugar, which is a saccharide that does not crystallize at room temperature, to form an outer layer on the surface of the particle nuclei A method for producing a granular agrochemical composition comprising the step of forming a part.

[8] 상기 외층부를 형성시키는 공정 후에, 농약 활성성분을 상기 외층 부에 담지시키는 공정을 더 포함하는, 상기 7항에 기재된 입상 농약조성물의 제조방법.[8] The method for producing a granular agricultural chemical composition according to item 7, further comprising, after the step of forming the outer layer portion, a step of supporting an agrochemical active ingredient on the outer layer portion.

본 발명에 의하면, 3-(3,4-다이클로로아이소티아졸-5-일메톡시)-1,2-벤조티아졸-1,1-다이옥사이드의 보존 안정성이 우수한, 농원예상 유용한 입상 농약조성물 및 이의 제조방법을 제공할 수 있다.According to the present invention, 3-(3,4-dichloroisothiazol-5-ylmethoxy)-1,2-benzothiazole-1,1-dioxide has excellent storage stability, useful agricultural and horticultural granular pesticide composition and A manufacturing method thereof can be provided.

본 발명의 입상 농약조성물은, 입자 핵과, 상기 입자 핵을 피복하는 외층부를 갖는 입상 농약조성물로서, 상기 입자 핵이 3-(3,4-다이클로로아이소티아졸-5-일메톡시)-1,2-벤조티아졸-1,1-다이옥사이드를 함유하며, 또한, 상기 외층부가 실온에서 결정화되지 않는 당류인 액당을 함유하여 이루어진 것이다. 본 발명의 입상 농약조성물은, 액당을 함유하는 외층부의 존재에 의해, 상기 화합물의 분해를 억제하여, 보존 안정성이 우수하다. 또한, 본 발명의 입상 농약조성물은, 다른 농약 활성성분과의 혼합 농약 입제로서 이용하는 경우에도, 상기 화합물 A의 보존 안정성을 손상시키지 않고 사용할 수 있다. 종전의 입상 농약조성물에서는, 화합물 A를 함유하여 이루어지는 입자 핵에 관용의 바인더를 이용하여 다른 농약 활성성분을 피복하여도, 화합물 A와 다른 농약 활성성분의 접촉 기회가 비교적 적음에도 불구하고, 화합물 A의 보존 안정성이 전부 악화되고 있었다.The granular agrochemical composition of the present invention is a granular agrochemical composition having particle nuclei and an outer layer covering the particle nuclei, wherein the particle nuclei are 3-(3,4-dichloroisothiazol-5-ylmethoxy)-1, It contains 2-benzothiazole-1,1-dioxide, and the outer layer contains liquid sugar, which is a saccharide that does not crystallize at room temperature. The granular agricultural chemical composition of this invention suppresses decomposition|disassembly of the said compound by presence of the outer layer part containing liquid sugar, and is excellent in storage stability. Further, the granular agrochemical composition of the present invention can be used without impairing the storage stability of the compound A even when used as a mixed agrochemical granule with other agrochemical active ingredients. In the conventional granular agrochemical composition, even when the particle nuclei containing the compound A are coated with another agrochemical active ingredient using a conventional binder, although the chance of contact between the compound A and the other agrochemical active ingredient is relatively small, the compound A The storage stability of all was deteriorated.

본 발명의 입상 농약조성물은, 화합물 A를 입자 핵에 함유시키는 것이 중요하다. 화합물 A의 함유량은 특별히 한정되지 않지만, 입상 농약조성물 전체에 대해 0.1 내지 8질량%가 바람직하고, 더욱 바람직하게는 0.2 내지 4질량%이다.It is important for the granular agrochemical composition of the present invention to contain the compound A in particle nuclei. Although content of compound A is not specifically limited, 0.1-8 mass % is preferable with respect to the whole granular agricultural chemical composition, More preferably, it is 0.2-4 mass %.

화합물 A를 함유하는 입자 핵, 예를 들면, 화합물 A를 미분형상의 고체 담체와의 혼합물로 하고, 상기 혼합물을 교반 혼합 조립법, 전동 조립법, 압출 조립법, 파쇄 조립법, 유동층 조립법, 압축 조립법, 진공 건조 조립법 등의 공지의 조립 방법에 의해 조립물로 함으로써 제조된다.The particle nuclei containing compound A, for example, compound A, are mixed with a fine powder solid carrier, and the mixture is stirred and mixed granulation method, rolling granulation method, extrusion granulation method, crushing granulation method, fluidized bed granulation method, compression granulation method, vacuum drying It is manufactured by making it into a granulated material by well-known granulation methods, such as a granulation method.

상기 미분형상의 고체 담체의 구체적인 예로는, 벤토나이트, 점토, 카올린, 세리사이트, 활석, 산성 백토, 경석, 제올라이트, 질석, 펄라이트, 탄산 칼슘, 규사 등을 들 수 있다. 이들은 1종을 단독으로 또는 2종 이상을 조합하여 임의로 사용해도 된다.Specific examples of the fine powder solid carrier include bentonite, clay, kaolin, sericite, talc, acid clay, pumice stone, zeolite, vermiculite, perlite, calcium carbonate, and silica sand. These may be used individually by 1 type or in combination of 2 or more type.

상기 입자 핵의 조립방법은, 특별히 한정되는 것은 아니지만, 입자 핵의 외부층에 농약 활성성분을 담지시키는 경우에는, 각각의 입자 핵에 있어서 담지 가능한 농약 활성성분을 결정하는 입자 핵 표면적의 변동이 적은, 즉, 입도분포가 좁은 조립물을 수율 양호하게 얻을 수 있는 조립방법이 바람직하다. 이 목적에 적합한 방법으로서 특히 압출 조립법이 바람직하며, 압출 조립법에 의해 얻어진 조립물을 입자 핵으로서 이용하는 것이 바람직하다.The method for assembling the particle nuclei is not particularly limited, but when the agrochemical active ingredient is supported on the outer layer of the particle nuclei, there is little variation in the particle nuclei surface area, which determines the agrochemical active ingredient that can be supported in each particle nuclei. That is, a granulation method capable of obtaining a granulated product having a narrow particle size distribution with good yield is preferable. As a method suitable for this purpose, an extrusion granulation method is particularly preferable, and it is preferable to use the granulated product obtained by the extrusion granulation method as particle nuclei.

입자의 핵의 형상은, 특별히 한정되지 않지만, 농약입제로서 적당한 입도를 갖는 입상물이 바람직하며, 보다 구체적으로는, 0.1 내지 30㎜의 대략 구형상물이나, 체적 구형상에 상당하며 지름 0.1 내지 30㎜인 부정형물이나, 직경 0.1 내지 5㎜, 길이 1 내지 30㎜, 애스펙트비(길이/직경) 1 내지 10인 대략 원기둥 형상물 등이 적합하게 사용가능하다. 그 중에서도, 직경 0.3 내지 1.7㎜, 길이 0.3 내지 10.2㎜, 애스펙트비 1 내지 6인 대략 원기둥 형상물이 바람직하며, 직경 0.5 내지 1.5㎜, 길이 0.5 내지 7.5㎜, 애스펙트비 1 내지 5인 대략 원기둥 형상물이 보다 바람직하며, 직경 0.8 내지 1.2㎜, 길이 0.8 내지 4.8㎜, 애스펙트비 1 내지 4인 대략 원기둥 형상물이 한층 바람직하다.The shape of the nucleus of the particle is not particularly limited, but a granular material having a suitable particle size as an agrochemical granule is preferable, and more specifically, a substantially spherical material of 0.1 to 30 mm, or a volume spherical shape, and a diameter of 0.1 to 30 mm, a substantially cylindrical object having a diameter of 0.1 to 5 mm, a length of 1 to 30 mm, and an aspect ratio (length/diameter) of 1 to 10, and the like can be suitably used. Among them, a substantially cylindrical article having a diameter of 0.3 to 1.7 mm, a length of 0.3 to 10.2 mm, and an aspect ratio of 1 to 6 is preferable, and a substantially cylindrical article having a diameter of 0.5 to 1.5 mm, a length of 0.5 to 7.5 mm, and an aspect ratio of 1 to 5 is preferred. More preferably, a substantially cylindrical article having a diameter of 0.8 to 1.2 mm, a length of 0.8 to 4.8 mm, and an aspect ratio of 1 to 4 is still more preferable.

상기 입자 핵은 필요에 따라서 계면 활성제, 결합제, 윤활제, 착색제 등의 보조 성분을 함유시킬 수도 있다. 또한 본 발명의 입상 농약조성물에는, 필요에 따라서, 화합물 A의 안정성을 해치지 않는 한, 상기 입자 핵 내에 약해경감제나 왁스 류, 수지류, 소수성 물질 등의 용출제어제를 함유시켜도 된다.The particle nuclei may contain auxiliary components such as surfactants, binders, lubricants, and colorants as needed. In addition, the granular agrochemical composition of the present invention may contain, if necessary, a dissolution control agent such as a weakening agent, waxes, resins, and hydrophobic substances in the particle nuclei, as long as the stability of Compound A is not impaired.

상기 계면 활성제로는 알킬황산에스터염류, 아릴설폰산염류, 폴리옥시에틸렌글리콜에터류, 다가알코올에스터류, 다이알킬설포숙신산염류, 폴리카복실산류, 폴리옥시에틸렌노닐페닐에터, 리그닌설폰산나트륨 등을 들 수 있다. 이들은 1 종을 단독으로 또는 2종 이상을 조합하여 임의로 사용해도 된다.Examples of the surfactant include alkyl sulfate salts, aryl sulfonates, polyoxyethylene glycol ethers, polyhydric alcohol esters, dialkyl sulfosuccinates, polycarboxylic acids, polyoxyethylene nonylphenyl ether, sodium lignin sulfonate, etc. can be heard These may be used individually by 1 type or in combination of 2 or more type.

상기 결합제로는, 전분, 알긴산, 글리세린, 폴리비닐피롤리돈, 폴리우레탄, 폴리에틸렌글리콜, 폴리프로필렌글리콜, 폴리부텐, 폴리비닐알코올, 아라비아검, 유동파라핀, 에틸셀룰로스, 폴리비닐아세테이트 등을 들 수 있다. 이들은 1 종을 단독 또는 2종 이상을 조합하여 임의로 사용해도 된다.Examples of the binder include starch, alginic acid, glycerin, polyvinylpyrrolidone, polyurethane, polyethylene glycol, polypropylene glycol, polybutene, polyvinyl alcohol, gum arabic, liquid paraffin, ethyl cellulose, polyvinyl acetate, and the like. have. These may be used arbitrarily individually by 1 type or in combination of 2 or more type.

상기 윤활제로는, 스테아르산칼슘, 탤크, 실리카 등을 들 수 있다. 이들은 1 종을 단독으로 또는 2종 이상을 조합하여 임의로 사용해도 된다.Calcium stearate, talc, silica, etc. are mentioned as said lubricant. These may be used individually by 1 type or in combination of 2 or more type.

상기 착색제로는, 염료나 안료 등을 들 수 있다. 이들은 1종을 단독으로 또는 2종 이상을 조합하여 임의로 사용해도 된다.Dyes, pigments, etc. are mentioned as said coloring agent. These may be used individually by 1 type or in combination of 2 or more type.

상기 약해경감제로는, 베녹사콜(benoxacor), 푸릴라졸(furilazole), 다이클롤미드(dichlormid), 다이시클로논(dicyclonone), DKA-24(N1,N2-다이알릴-N2-다이클로로아세틸글리신아마이드), AD-67(4-다이클로로아세틸-1-옥사-4-아자스피로[4.5]데칸), PPG-1292(2,2-다이클로로-N-(1,3-다이옥산-2-일메틸)-N-(2-프로페닐)아세트 아마이드), R-29148(3-다이클로로아세틸-2, 2, 5-트라이메틸-1,3-옥사졸리진), 클로퀸트세트-멕실(cloquintcet-mexyl), 나프탈산 무수물(1,8-Naphthalic Anhydride), 메펜필-다이에틸(mefenpyr-diethyl), 메펜필(mefenpyr), 메펜필에틸(mefenpyr-ethyl), 펜클로라졸-O-에틸(fenchlorazole-O-ethyl), 펜클로림(fenclorim), MG-191(2-다이클로로메틸-2-메틸-1,3-다이옥산), 시오메트리닐( cyometrinil), 플루라졸(flurazole), 플룩소페님(fluxofenim), 아이속사디펜(isoxadifen), 아이속사디펜-에틸(isoxadifen-ethyl), MON4660(코드 번호), 옥사베트리닐(oxabetrinil), 시프로설파마이드(cyprosulfamide), 저급 알킬 치환벤조산, TI-35(코드 번호) 또는 N-(2-메톡시벤조일)-4-[(메틸아미노카보닐)아미노]벤젠설폰아마이드(화학명, CAS 등록번호: 129531-12-0) 등을 들 수 있다. 이들은 1종을 단독으로 또는 2종 이상을 조합하여 사용할 수 있다.Examples of the pain relievers include benoxacor, furilazole, dichlormid, dicyclonone, DKA-24 (N1,N2-diallyl-N2-dichloroacetyl). Glycinamide), AD-67 (4-dichloroacetyl-1-oxa-4-azaspiro [4.5] decane), PPG-1292 (2,2-dichloro-N- (1,3-dioxane-2- ylmethyl) -N- (2-propenyl) acetamide), R-29148 (3-dichloroacetyl-2, 2, 5-trimethyl-1,3-oxazolizine), cloquintset-mexyl ( cloquintcet-mexyl), naphthalic anhydride (1,8-Naphthalic Anhydride), mefenpyr-diethyl, mefenpyr, mefenpyr-ethyl, phenchlorazole-O-ethyl (fenchlorazole-O-ethyl), fenclorim, MG-191 (2-dichloromethyl-2-methyl-1,3-dioxane), cyometrinil, flurazole, Fluxofenim, isoxadifen, isoxadifen-ethyl, MON4660 (code number), oxabetrinil, cyprosulfamide, lower alkyl Substituted benzoic acid, TI-35 (code number) or N-(2-methoxybenzoyl)-4-[(methylaminocarbonyl)amino]benzenesulfonamide (chemical name, CAS registration number: 129531-12-0), etc. can be heard These can be used individually by 1 type or in combination of 2 or more type.

본 발명의 입상 농약조성물은, 화합물 A를 함유하는 상기 입자 핵을 피복하는 외층부에, 실온에서 결정화되지 않는 당류인 액당을 함유시키는 것도 중요하다. 여기에서 액당으로는, 일반적으로 당밀이라 불리는 것이다. 상기 액당의 종류로서, 설탕의 제조 공정에서 생성되는 사탕수수 당밀, 사탕무 당밀, 정제당최종당밀, 얼음 당밀과 환원당을 함유하는 전화당, 예를 들면 자당을 포도당과 과당으로 가수 분해한 전화당 및 자당 등의 비환원당과 함께 전화당을 포함한 것 등이 열거되는 바, 환원당을 함유하는 전화당, 즉, 환원당을 함유하는 전화형 액당이 바람직하다. 전화형 액당 중에서도, 환원당분을 20% 이상 함유하는 것이 바람직하고, 더욱 바람직한 것은 환원당분을 40% 이상 함유한 것이며, 환원당분을 약 50%, 구체적으로는 45 내지 54% 함유하는 액당이 특히 바람직하다.It is also important for the granular agrochemical composition of the present invention to contain liquid sugar, which is a saccharide that does not crystallize at room temperature, in the outer layer covering the particle nuclei containing the compound A. As the liquid sugar here, what is generally called molasses. As the type of liquid sugar, sugar cane molasses, sugar beet molasses, refined sugar final molasses, ice molasses and invert sugar containing reducing sugar, for example, invert sugar produced by hydrolysis of sucrose into glucose and fructose, and sucrose Since those containing invert sugar together with non-reducing sugars such as eg are listed, invert sugar containing reducing sugar, that is, inverted liquid sugar containing reducing sugar is preferable. Among the inverted liquid sugars, it is preferable to contain 20% or more of reducing sugars, more preferably 40% or more of reduced sugars, and liquid sugars containing about 50%, specifically 45 to 54% of reduced sugars are particularly preferable. do.

상기 액당의 함유량은 특별히 한정되지 않고, 입자 핵에 담지시키는 농약 활성 성분의 양에 의한 것도 있지만, 바람직하게는 입상 농약조성물 전체에 대해서 0.5 내지 5질량%이며, 더욱 바람직하게는 0.8 내지 2질량%이다. 이 액당의 함유량이 부족하면, 화합물 A의 보존 안정성을 해칠 우려와, 혼합 농약입제로서 사용할 경우에 농약 활성성분을 입자 핵 외층부에 담지하는 작용이 불충분해질 우려가 있다. 한편, 액당의 함유량이 과다하면 입상 농약조성물의 고결이 우려된다.The content of the liquid sugar is not particularly limited, and may depend on the amount of the agrochemical active ingredient supported on the particle nuclei, but is preferably 0.5 to 5% by mass, more preferably 0.8 to 2% by mass, based on the entire granular agrochemical composition. to be. If the content of this liquid sugar is insufficient, there is a risk of impairing the storage stability of Compound A, and an insufficient action of supporting the agrochemical active ingredient on the outer layer of particle nuclei when used as a mixed agrochemical granule. On the other hand, when the content of the liquid sugar is excessive, there is concern about caking of the granular agricultural chemical composition.

본 발명의 입상 농약조성물에 있어서, 액당을 함유하는 외층부를 형성하는 방법은 특별히 한정되지 않지만, 전형적으로는, 먼저 입자 핵을 콘크리트 믹서, 나우타 믹서 등의 통상의 혼합기를 이용하여 혼합하면서, 여기에 액당을 함유하는 액상물을 투입하여 입자 핵의 표층을 피복하는 방법을 들 수 있다. 본 발명의 입상 농약조성물을 혼합 농약 입제로서 사용하는 경우에는, 다음 농약 활성성분을 투입하여, 입자 핵 외층부에 담지시키면 된다.In the granular agrochemical composition of the present invention, the method of forming the outer layer portion containing liquid sugar is not particularly limited, but typically, the particle nuclei are first mixed using a conventional mixer such as a concrete mixer or Nauta mixer, A method of coating the surface layer of particle nuclei by injecting a liquid substance containing liquid sugar is exemplified. When the granular pesticide composition of the present invention is used as a mixed pesticide granule, the following pesticide active ingredient may be added and supported on the outer layer of the particle nucleus.

그런데, 상기 액당은, 일반적으로 상온에서 꿀 형상의 점성 액체이기 때문에, 이 액당을 함유하는 액상물을 입자 핵의 표층에 피복하는 공정에서 어려운 경우가 있다. 이 점을 해결하는 수단으로서는, 액상물을 가온하여 액당의 점성을 저하시키는 방법과, 액당에 물 등의 용매를 소량 첨가하여 액당의 점성을 저하시키는 방법 등을 들 수 있다. 액당에 물을 첨가하여 액상물로 하는 경우, 물 첨가량은 특별히 한정되지 않지만, 액상물 전량에 대하여 30질량% 정도까지로 하는 것이 적당하다. 물이 과잉, 즉, 희박한 액상물 조성으로 하면, 유효량의 액당으로 입자 핵을 피복하기 위해 다량의 액상물을 첨가할 필요가 생겨, 과잉의 물에 의해 젖은 입자 핵 끼리 응집해 버려서, 본 발명의 입상 농약조성물을 혼합 농약 입제로 사용하기 위해서는 외층부에 농약 활성성분을 담지시키는 경우, 농약 활성성분을 담지시키는 공정에서 지장을 초래할 경우가 있다.However, since the liquid sugar is generally a honey-like viscous liquid at room temperature, it may be difficult in the process of coating the liquid sugar containing the liquid sugar on the surface layer of particle nuclei. As a means to solve this problem, a method of reducing the viscosity of liquid sugar by heating a liquid substance, a method of reducing the viscosity of liquid sugar by adding a small amount of a solvent such as water to the liquid sugar, etc. are mentioned. When water is added to liquid sugar to make it a liquid product, the amount of water added is not particularly limited, but it is appropriate to set it to about 30% by mass based on the total amount of the liquid product. If the composition of the liquid substance is excessive, that is, thin, it is necessary to add a large amount of liquid substance to cover the particle nuclei with an effective amount of liquid sugar, and the wet particle nuclei agglomerate with the excess water, so that the present invention In order to use the granular agrochemical composition as a mixed pesticide granules, when the agrochemical active ingredient is supported on the outer layer, it may cause trouble in the process of supporting the agrochemical active ingredient.

본 발명의 입상 농약조성물에 있어서는, 추가로 농약 활성성분을 상기 외층부에 담지시킴으로써 함유시킬 수 있다. 농약 활성성분은 1종만을 외층부에 담지시키는 것도 가능하며, 2종 이상을 동시에 담지시키는 것도 가능하다. 농약 활성성분을 액당의 접착력에 의해 입자 핵의 외층부에 담지시킬 수 있다.In the granular agrochemical composition of the present invention, it can be contained by further supporting the agrochemical active ingredient on the outer layer portion. It is also possible to support only one kind of agrochemical active ingredient on the outer layer, and it is also possible to support two or more kinds at the same time. The agrochemical active ingredient can be supported on the outer layer of the particle nucleus by the adhesive force of the liquid sugar.

상기 외층부에 담지시키는 농약 활성성분이 상온에서 고체인 경우에는, 보통 50㎛ 이하, 바람직하게는 10㎛ 이하의 입자 크기로 미분쇄하여, 분체로서 이용하는 것이 바람직하다. 또한, 이 분체는 실리카, 규조토, 규사 등의 분쇄 조제, 리그닌 설폰산염, 아릴설폰산염, 알킬 황산염 등의 계면 활성제, 벤토나이트, 점토, 탄산 칼슘 등의 고체 담체, 알칼리 금속염, 알칼리 토류금속염, 에폭시화 유지류 등의 안정화제, 상기 예시한 약해경감제 등의 보조제를 함유 할 수 있다.When the agrochemical active ingredient supported on the outer layer is solid at room temperature, it is preferable to use it as a powder by finely pulverizing it to a particle size of usually 50 μm or less, preferably 10 μm or less. In addition, this powder is a grinding aid such as silica, diatomaceous earth, silica sand, surfactants such as lignin sulfonates, aryl sulfonates, alkyl sulfates, solid carriers such as bentonite, clay, calcium carbonate, alkali metal salts, alkaline earth metal salts, epoxidation Stabilizers such as oils and fats, and auxiliary agents such as the above exemplified medicines may be contained.

외층부에 담지시키는 농약 활성성분을 미분쇄하는 수단으로서는 공지의 분쇄 장치를 임의로 사용할 수 있으며, 구체적으로는 충격식 분쇄기, 기류식 분쇄기, 습식 분쇄기 등을 사용할 수 있지만, 특별히 한정되지 않는다. 또한, 상기 미분쇄 시, 농약 활성성분만으로 분쇄시켜도 되고, 필요에 따라 미리 상기 보조제와 혼합하여, 함께 분쇄시켜도 된다.As a means for finely pulverizing the agrochemical active ingredient supported on the outer layer, a known pulverizing device can be arbitrarily used, and specifically, an impact pulverizer, an airflow pulverizer, a wet pulverizer, etc. can be used, but is not particularly limited. In addition, at the time of the pulverization, it may be pulverized only with the agrochemical active ingredient, or if necessary, it may be pre-mixed with the auxiliary agent and pulverized together.

외층부에 담지시키는 농약 활성성분이 상온에서 액체인 경우에는, 액체 상태에서, 상기 외층부에 담지시켜도 되고, 미리 실리카, 규산염, 목분, 미결정 셀룰로스 등의 흡유성 미분에 흡착시켜 분말을 제조하고, 상기 상온에서 고체 농약 활성성분과 마찬가지로 취급할 수 있다.When the agrochemical active ingredient to be supported on the outer layer is liquid at room temperature, it may be supported on the outer layer in a liquid state, and adsorbed to oil-absorbing fine powder such as silica, silicate, wood flour, microcrystalline cellulose in advance to prepare a powder, It can be handled like a solid pesticide active ingredient at the above room temperature.

외층부에 담지시킬 수 있는 농약 활성성분의 함유량도 한정되는 것은 아니지만, 입상 농약조성물 전체에 대해서, 농약 활성성분으로서 2종 이상인 경우에는, 그 합계는, 통상 0.05 내지 5질량%, 바람직하게는 0.1 내지 4질량%, 더욱 바람직하게는 0.5 내지 3질량%이다.The content of the agrochemical active ingredient that can be supported on the outer layer is also not limited, but in the case of two or more kinds of the agrochemical active ingredient with respect to the whole granular agrochemical composition, the total is usually 0.05 to 5% by mass, preferably 0.1 It is -4 mass %, More preferably, it is 0.5-3 mass %.

또한 농약 활성성분은, 화합물 A의 안정성을 해치지 않는 한에서, 입자 핵 내에 1종 또는 2종 이상을 함유할 수도 있지만, 일반적으로, 입자 핵에 함유시킨 농약 활성성분의 용출 속도는 비교적 완만한 것으로 될 것으로 추측된다. 본 발명의 입상 농약조성물에 속효성인 약효 발현을 기대할 농약 활성성분을 함유시키고자 할 경우에는, 입자 핵 외층부에 담지시키는 설계를 선택하는 것이 합리적이다.In addition, the agrochemical active ingredient may contain one or two or more types in the particle nucleus as long as the stability of the compound A is not impaired. In general, the dissolution rate of the agrochemical active ingredient contained in the particle nucleus is relatively slow. it is assumed to be When the granular agrochemical composition of the present invention is intended to contain an agrochemical active ingredient, which is expected to exhibit a short-acting drug, it is reasonable to select a design in which the particle is supported on the outer layer of the nucleus.

본 발명의 입상 농약조성물에 있어서, 입자 핵에 함유 또는 외층부에 담지시킬 수 있는 농약 활성성분으로서는, 예들 들면, 하기에 열거한 것을 들 수 있지만, 특별히 한정되는 것은 아니다.In the granular agrochemical composition of the present invention, examples of the agrochemical active ingredient that can be contained in the particle nuclei or supported on the outer layer include those listed below, but are not particularly limited.

[제초 활성성분][herbicide active ingredient]

아이옥시닐(ioxynil), 아클로니펜(aclonifen), 아크롤레인(acrolein), 아자페니딘(azafenidin), 아시플루오르펜(acifluorfen)(나트륨 등과의 염을 포함함), 아짐설푸론(azimsulfuron), 아술람(asulam), 아세토클로르(acetochlor), 아트라진(atrazine), 아닐로포스(anilofos), 아미카바존(amicarbazone), 아미도설푸론(amidosulfuron), 아미트롤(amitrole), 아미노사이클로피라클로르(aminocyclopyrachlor), 아미노피랄리드(aminopyralid), 아미프로포스·메틸(amiprofos-methyl), 아메트린(ametryn), 알라클로르(alachlor), 알록시딤(alloxydim), 아이소우론(isouron), 아이소옥사클로르톨(isoxachlortole), 아이소옥사플루톨(isoxaflutole), 아이소옥사벤(isoxaben), 아이소프로투론(isoproturon), 이프펜카바존(ipfencarbazone), 이마자퀸(imazaquin), 이마자픽(imazapic)(아민 등과의 염을 포함함), 이마자필(imazapyr)(아이소프로필 아민 등의 염을 포함함), 이마자메타벤즈-메틸(imazamethabenz-methyl), 이마자목스(imazamox), 이마제타피르(imazethapyr), 이마조설푸론(imazosulfuron), 인다지플람(indaziflam), 인다노판(indanofan), 에글리나진·에틸(eglinazine-ethyl), 에스프로카브(esprocarb), 에타메트설푸론·메틸(ethametsulfuron-methyl), 에탈플루랄린(ethalfluralin), 에티디무론(ethidimuron), 에톡시설푸론(ethoxysulfuron), 에톡시펜·에틸(ethoxyfen-ethyl), 에토푸메세이트(ethofumesate), 에토벤자니드(etobenzanid), 엔도탈다이나트륨(endothal-disodium), 옥사다이아존(oxadiazon), 옥사다이아르길(oxadiargyl), 옥사지클로메폰(oxaziclomefone), 옥사설푸론(oxasulfuron) 옥시플루오르펜(oxyfluorfen), 오리잘린(oryzalin), 오쏘설파무론(orthosulfamuron), 오르벤카브(orbencarb), 올레산(oleicacid), 카펜스트롤(cafenstrole), 카펜트라존·에틸(carfentrazone-ethyl), 카부틸레이트(karbutilate), 카베타마이드(carbetamide), 퀴잘로포프·에틸(quizalofop-ethyl), 퀴잘로포프·P·에틸(quizalofop-P-ethyl), 퀴잘로포프·P·테푸릴(quizalofop-P-tefuryl), 퀴노클라민(quinoclamine), 퀸클로락(quinclorac), 퀸메락(quinmerac), 쿠밀루론(cumyluron), 클라사이포스(clacyfos), 글라이포세이트(glyphosate)(나트륨, 칼륨, 암모늄, 아민, 프로필아민, 아이소프로필아민, 다이메틸아민 또는 트라이메시움의 등의 염을 포함함), 글루포시네이트(glufosinate)(아민 또는 나트륨 등의 염을 포함함), 글루포시네이트·P·나트륨염(glufosinate-P-sodium), 클레토딤(clethodim), 클로디나포프·프로파길(clodinafop-propargyl), 클로피랄리드(clopyralid), 클로마존(clomazone), 클로메톡시펜(chlomethoxyfen), 클로메프로프(clomeprop,), 클로란설람·메틸(cloransulam-methyl), 클로람벤(chloramben), 클로리다존(chloridazon), 클로리무론·에틸(chlorimuron-ethyl), 클로르설푸론(chlorsulfuron), 클로르탈·다이메틸(chlorthal-dimethyl), 클로르티아미드(chlorthiamid), 클로르프탈림(chlorphthalim), 클로르플루레놀·메틸(chlorflurenol-methyl), 클로르프로팜(chlorpropham), 클로르브로무론(chlorbromuron), 클로록수론(chloroxuron), 클로로톨루론(chlorotoluron), 케토스피라독스(ketospiradox) (나트륨, 칼슘 또는 암모니아 등의 염을 포함한다.), 사플루페나실(saflufenacil), 살멘틴(sarmentine), 사이아나진(cyanazine), 사이아나마이드(cyanamide), 다이우론(diuron), 다이에타틸·에틸(diethatyl-ethyl), 다이캄바(dicamba)(아민, 다이에틸아민, 아이소프로필아민, 다이글리콜아민, 나트륨 또는 리튬 등의 염을 포함함), 사이클로에이트(cycloate), 사이클록시딤(cycloxydim), 다이클로설람(diclosulam), 사이클로설파무론(cyclosulfamuron), 사이클로피리모레이트(cyclopyrimorate), 다이클로베닐(dichlobenil), 다이클로포프·P·메틸(diclofop-P-methyl), 다이클로포프·메틸(diclofop-methyl), 다이클로르프로프(dichlorprop), 다이클로르프로프-P(dichlorprop-P), 다이쿼트(diquat), 다이티오필(dithiopyr), 시두론(siduron), 다이니트라민(dinitramine), 시니돈·에틸(cinidon-ethyl), 시노설푸론(cinosulfuron), 디노세브(dinoseb), 다이노테르브(dinoterb), 사이할로포프·부틸(cyhalofop-butyl), 다이펜아미드(diphenamid), 다이펜조쿼트(difenzoquat), 다이플루페니칸(diflufenican), 다이플루펜조필(diflufenzopyr), 시마진(simazine), 다이메타클로르(dimethachlor), 다이메타메트린(dimethametryn), 다이메텐아미드(dimethenamid), 다이메텐아미드·P(dimethenamid-P), 시메트린(simetryn), 다이메피페레이트(dimepiperate), 다이메푸론(dimefuron), 신메틸린(cinmethylin), 스웨프(swep), 설코트라이온(sulcotrione), 설펜트라존(sulfentrazone), 설포세이트(sulfosate), 설포설푸론(sulfosulfuron), 설포메투론·메틸(sulfometuron-methyl), 세톡시딤(sethoxydim), 테르바실(terbacil), 다이무론(daimuron), 탁스토민 A(thaxtomin A), 달라폰(dalapon), 티아조필(thiazopyr), 티아페나실(tiafenacil), 티엔카바존(thiencarbazone)(나트륨염, 메틸에스터 등을 포함함), 티오카바질(tiocarbazil), 티오벤카브(thiobencarb), 티다이아지민(thidiazimin), 티펜설푸론-메틸(thifensulfuron-methyl), 데스메디팜(desmedipham), 데스메트린(desmetryne), 테닐클로르(thenylchlor), 테부탐(tebutam), 테부티우론(tebuthiuron), 테프랄록시딤(tepraloxydim), 테푸릴트라이온(tefuryltrione), 템보트라이온(tembotrione), 테르부틸라진(terbuthylazine), 테르부트린(terbutryn), 테르부메톤(terbumeton), 토프라메존(topramezone), 트랄콕시딤(tralkoxydim), 트라이아지플람(triaziflam), 트라이아설푸론(triasulfuron), 트라이아파몬(triafamone), 트라이알레이트(tri-allate), 트라이에타진(trietazine), 트라이클로필(triclopyr), 트라이클로필-부토틸(triclopyr-butotyl), 트라이플루디목사진(trifludimoxazin), 트라이토설푸론(tritosulfuron), 트라이플루설푸론·메틸(triflusulfuron-methyl), 트라이플루랄린(trifluralin), 트라이플록시설푸론나트륨염(trifloxysulfuron-sodium), 트라이베누론·메틸(tribenuron-methyl), 톨피랄레이트(tolpyralate), 납탈람(naptalam)(나트륨 등과의 염을 포함함), 나프로아닐라이드(naproanilide), 나프로파마이드(napropamide), 나프로파마이드-M(napropamide-M), 니코설퓨론(nicosulfuron), 네부론(neburon), 노르플루라존(norflurazon), 베르놀레이트(vernolate), 파라쿼트(paraquat), 할라욱시펜－벤질(halauxifen-benzyl), 할라욱시펜-메틸(halauxifen-methyl), 할록시포프(haloxyfop), 할록시포프·P(haloxyfop-P), 할록시포프-에토틸(haloxyfop-etotyl), 할로사펜(halosafen), 할로설푸론·메틸(halosulfuron-methyl), 피클로람(picloram), 피콜리나펜(picolinafen), 바이사이클로피론(bicyclopyrone), 바이스피리박·나트륨염(bispyribac-sodium), 피녹사덴(pinoxaden), 바이페녹스(bifenox), 피페로포스(piperophos), 피라클로닐(pyraclonil), 피라설포톨(pyrasulfotole), 피라족시펜(pyrazoxyfen), 피라조설푸론·에틸(pyrazosulfuron-ethyl), 피라졸리네이트(pyrazolynate), 바이라나포스(bilanafos), 피라플루펜·에틸(pyraflufen-ethyl), 피리다폴(pyridafol), 피리티오박·나트륨염(pyrithiobac-sodium), 피리데이트(pyridate), 피리프탈리드(pyriftalid), 피리부티카브(pyributicarb), 피리벤족심(pyribenzoxim), 피리미설판(pyrimisulfan), 피리미노박·메틸(pyriminobac-methyl), 피록사설폰(pyroxasulfone), 피록사설람(pyroxsulam), 페니소팜(phenisopham), 페누론(fenuron), 페녹사설폰(fenoxasulfone), 페녹사프롭(fenoxaprop)（메틸, 에틸, 아이소프로필에스터를 포함한다), 페녹사프롭·P(fenoxaprop-P)(메틸, 에틸, 아이소프로필에스터를 포함한다), 펜퀴노트라이온(fenquinotrione), 펜티아프로프·에틸(fenthiaprop-ethyl), 펜트라자마이드(fentrazamide), 펜메디팜(phenmedipham), 포람설푸론(foramsulfuron), 부타클로르(butachlor), 부타페나실(butafenacil), 부타미포스(butamifos), 부틸레이트(butylate), 부텐아클로르(butenachlor), 부트랄린(butralin), 부트록시딤(butroxydim), 플라자설푸론(flazasulfuron), 플람프롭(flamprop)(메틸, 에틸, 아이소프로필 에스터를 포함함), 플람프로프·M(flamprop-M)(메틸, 에틸 및 아이소프로필 에스터를 포함함), 프리미설푸론·메틸(primisulfuron-methyl), 플루아지포프·부틸(fluazifop-butyl), 플루아지포프·P·부틸(fluazifop-P-butyl), 플루아졸레이트(fluazolate), 플루오메투론(fluometuron), 플루오로글리코펜·에틸(fluoroglycofen-ethyl), 플루카바존·나트륨염(flucarbazone-sodium), 플루클로랄린(fluchloralin), 플루세토설푸론(flucetosulfuron), 플루티아세트·메틸(fluthiacet-methyl), 플루필설푸론·메틸·나트륨염(flupyrsulfuron-methyl-sodium), 플루페나세트(flufenacet), 플루펜필·에틸(flufenpyr-ethyl), 플루프로파네이트(flupropanate), 플루폭삼(flupoxame), 플루미옥사진(flumioxazin), 플루미클로락·펜틸(flumiclorac-pentyl), 플루메트설람(flumetsulam), 플루리돈(fluridone), 플루르타몬(flurtamone), 플루록시필(fluroxypyr), 플루로클로리돈(flurochloridone), 프레틸라클로르(pretilachlor), 프로카바존·나트륨염(procarbazone-sodium), 프로다이아민(prodiamine), 프로설퓨론(prosulfuron), 프로설포카브(prosulfocarb), 프로파퀴자포프(propaquizafop), 프로파클로르(propachlor), 프로파진(propazine), 프로파닐(propanil), 프로피자마이드(propyzamide), 프로피소클로르(propisochlor), 프로피리설푸론(propyrisulfuron), 프로팜(propham), 프로플루아졸(profluazol), 프로폭시카바존·나트륨염(propoxycarbazone-sodium), 프로폭시딤(profoxydim), 브로마실(bromacil), 브롬피라존(brompyrazon), 프로메트린(prometryn), 프로메톤(prometon), 브로목시닐(bromoxynil)(부티르산, 옥탄산, 또는 헵탄산 등의 에스터체를 포함함), 브로모페녹심(bromofenoxim), 브로모부타이드(bromobutide), 플로라설람(florasulam), 플로필락시펜(florpyrauxifen), 헥사지논(hexazinone), 페톡사미드(pethoxamid), 베나졸린(benazolin), 페녹스설람(penoxsulam), 헵타말록실로글루칸(heptamaloxyloglucan), 베플루부타미드(beflubutamid), 페불레이트(pebulate), 펠랄르곤산(pelargonicacid), 벤카바존(bencarbazone), 펜디메탈린(pendimethalin), 벤즈펜디존(benzfendizone), 벤설라이드(bensulide), 벤설푸론·메틸(bensulfuron-methyl), 벤조바이사이클론(benzobicyclon), 벤조페납(benzofenap,), 벤타존(bentazone), 펜타노클로르(pentanochlor), 펜톡사존(pentoxazone), 벤플루랄린(benfluralin), 벤푸레세이트(benfuresate), 포사민(fosamine), 포메사펜(fomesafen), 포람설푸론(foramsulfuron), 메코프로프(mecoprop)(나트륨, 칼륨, 아이소프로필아민, 트라이에탄올아민, 다이메틸아민등의 염을 포함함), 메코프로프·P·칼륨염(mecoprop-P-potassium), 메소설푸론·메틸(mesosulfuron-methyl), 메소트라이온(mesotrione), 메타자클로르(metazachlor), 메타조설푸론(metazosulfuron), 메타벤즈티아주론(methabenzthiazuron), 메타미트론(metamitron), 메타미포프(metamifop), DSMA(메탄아르손 2나트륨), 메티오졸린 (methiozolin), 메틸디무론(methyldymuron), 메톡수론(metoxuron), 메토설람(metosulam), 메트설푸론·메틸(metsulfuron-methyl), 메토브로무론(metobromuron), 메토벤주론(metobenzuron), 메톨라클로르(metolachlor), 메트라이부진(metribuzin), 메페나세트(mefenacet), 모노설푸론(monosulfuron)(메틸, 에틸, 아이소프로필에스터를 포함한다), 모놀리누론(monolinuron), 몰리네이트(molinate), 아이오도설푸론(iodosulfuron), 아이오도설푸론·메틸·나트륨염(iodosulfulon-methyl-sodium), 이오펜설푸론(iofensulfuron), 이오펜설푸론·나트륨염(iofensulfuron-sodium), 락토펜(lactofen), 란코트리온(lancotrione), 리누론(linuron), 림설퓨론(rimsulfuron), 레나실(lenacil), TCA(2, 2, 2-트라이클로로아세트산) (나트륨, 칼슘 또는 암모니아 등의 염을 포함한다), 2,3,6-TBA(2,3,6-트라이클로로벤조산), 2,4,5-T(2,4,5-트라이클로로페녹시아세트산), 2,4-D(2,4-다이클로로페녹시아세트산)(아민, 다이에틸아민, 트라이에탄올아민, 아이소프로필아민, 나트륨 또는 리튬 등의 염을 포함함), ACN(2-아미노-3-클로로-1, 4-나프톡시논), MCPA(2-메틸-4-클로로페녹시아세트산), MCPB(2-메틸-4-클로로페녹시부티르산)(나트륨염, 에틸 에스터 등을 포함함), 2,4-DB(4-(2,4-다이클로로페녹시)부티르산, DNOC(4,6-다이니트로-o-크레졸)（아민 또는 나트륨 등의 염을 포함한다), AE-F-150944(코드번호), HW-02(코드번호), IR-6396(코드번호), MCPA-티오에틸(MCPA-thioethyl), SYP-298(코드 번호), SYP-300(코드 번호), EPTC(S-에틸다이프로필티오카밤산염), S-메톨라클로르(S-metolachlor).ioxynil, aclonifen, acrolein, azafenidin, acifluorfen (including salts with sodium, etc.), azimsulfuron, azimsulfuron Sulam, acetochlor, atrazine, anilofos, amicarbazone, amidosulfuron, amitrole, aminocyclopyrachlor , aminopyralid, amiprofos-methyl, amethrin, alachlor, alloxydim, isouron, isoxachlortole ), isoxaflutole, isoxaben, isoproturon, ipfencarbazone, imazaquin, imazapic (including salts with amines, etc.) ), imazapyr (including salts such as isopropyl amine), imazamethabenz-methyl, imazamox, imazethapyr, imazasulfuron ( imazosulfuron), indaziflam, indanofan, eglinazine-ethyl, esprocarb, etametsulfuron-methyl, etalfluralin ( ethalfluralin), ethidimuron, ethoxysulfuron, ethoxyfen-ethyl, etofumesate, etobenzanid, endothal-disodium ), oxadiazone azon), oxadiargyl, oxaziclomefone, oxasulfuron, oxyfluorfen, oryzalin, orthosulfamuron, orbencarb ), oleic acid, carfenstrole, carfentrazone-ethyl, carbutilate, carbetamide, quizalofop-ethyl, Quizalofop-P-ethyl, quizalofop-P-tefuryl, quinoclamine, quinclorac, quinmerac , including salts of cumyluron, clacyfos, glyphosate (sodium, potassium, ammonium, amine, propylamine, isopropylamine, dimethylamine or trimesium, etc.) ), glufosinate (including amines or salts such as sodium), glufosinate P sodium salt (glufosinate-P-sodium), clethodim, clodinafop -propargyl), clopyralid, clomazone, chlomethoxyfen, clomeprop, cloransulam-methyl, chloramben , chloridazon, chlorimuron-ethyl, chlorsulfuron, chlorthal-dimethyl, chlorthiamide, chlorphthalim , chlorflurenol methyl (chlorflurenol-methyl), chlorpropham, chlorinol chlorbromuron, chloroxuron, chlorotoluron, ketospiradox (including salts such as sodium, calcium or ammonia), saflufenacil, sal sarmentine, cyanazine, cyanamide, diuron, diethatyl-ethyl, dicamba (amine, diethylamine, isopropyl) amines, diglycolamine, salts such as sodium or lithium), cycloate, cyclooxydim, diclosulam, cyclosulfamuron, cyclopyrimorate ), diclovenil (dichlobenil), diclofop P methyl (diclofop-P-methyl), diclofop methyl (diclofop-methyl), dichlorprop (dichlorprop), dichlorprop-P ( dichlorprop-P), diquat, dithiopyr, siduron, dinitramine, cinidon-ethyl, cinosulfuron, dinoceb (dinoseb), dinoterb (dinoterb), cyhalofop-butyl, diphenamide (diphenamid), difenzoquat, diflufenican (diflufenican), diflufenzofil ( diflufenzopyr), simazine, dimethachlor, dimethametryn, dimethenamid, dimethenamid-P, simetryn, di Dimepiperate, dimefuron, cinmethylin, s swep, sulcotrione, sulfentrazone, sulfosate, sulfosulfuron, sulfometuron-methyl, sethoxydim, terbacil, daimuron, thaxtomin A, dalapon, thiazopyr, tiafenacil, thiencarbazone (sodium salt, methyl ester, etc.), tiocarbazil, thiobencarb, thidiazimin, thifensulfuron-methyl, desmedipham, desmethrin (desmetryne), tenylchlor, tebutam, tebuthiuron, tepraloxydim, tefuryltrione, tembotrione, terbutylazine ( terbutylazine), terbutryn, terbumeton, topramezone, tralkoxydim, triaziflam, triasulfuron, triaphamon ( triafamone), tri-allate, trietazine, triclopyr, triclopyr-butotyl, trifludimoxazin, tritosulfuron (tritosulfuron), triflusulfuron-methyl, trifluralin, trifloxysulfuron-sodium, tribenuron-methyl, tolpyralate ( tolpyralate), lead naptalam (including salts with sodium, etc.), naproanilide, napropamide, napropamide-M, nicosulfuron, yes neburon, norflurazon, vernolate, paraquat, halauxifen-benzyl, halauxifen-methyl, haloxy haloxyfop, haloxyfop-P, haloxyfop-etotyl, halosafen, halosulfuron-methyl, picloram ), picolinafen, bicyclopyrone, bispyribac-sodium, pinoxaden, bifenox, piperophos, pyraclo pyraclonil, pyrasulfotole, pyrazoxyfen, pyrazosulfuron-ethyl, pyrazolynate, bilanafos, pyraflufen ethyl (pyraflufen-ethyl), pyridafol, pyrithiobac-sodium, pyridate, pyriftalid, pyributicarb, pyribenzoxim ), pyrimisulfan, pyriminobac-methyl, pyroxasulfone, pyroxsulam, phenisopham, fenuron, phenoxasulfone ( fenoxasulfone), fenoxaprop (including methyl, ethyl, and isopropyl esters), fenoxa Prop P (fenoxaprop-P) (including methyl, ethyl, isopropyl ester), phenquinotrione (fenquinotrione), fenthiaprop ethyl (fenthiaprop-ethyl), fentrazamide (fentrazamide), fenmedipam ( phenmedipham), foramsulfuron, butachlor, butafenacil, butamifos, butylate, butenachlor, butralin, butralin butroxydim, flazasulfuron, flamprop (including methyl, ethyl, and isopropyl esters), flamprop-M (including methyl, ethyl and isopropyl esters) including), primisulfuron-methyl, fluazifop-butyl, fluazifop-P-butyl, fluazolate, fluume Fluometuron, fluoroglycofen-ethyl, flucarbazone-sodium, fluchloralin, flucetosulfuron, fluthiacet methyl ( fluthiacet-methyl, flupyrsulfuron-methyl-sodium, flufenacet, flufenpyr-ethyl, flupropanate, flupoxame ), flumioxazin, flumiclorac-pentyl, flumetsulam, fluridone, flurtamone, fluroxypyr, flu Flurochloridone, pretilachlor, procarba Zone sodium salt (procarbazone-sodium), prodiamine (prodiamine), prosulfuron (prosulfuron), prosulfocarb (prosulfocarb), propaquizafop (propaquizafop), propachlor, propazine ( propazine), propanil, propyzamide, propisochlor, propyrisulfuron, propham, profluazol, propoxycarbazone sodium salt (propoxycarbazone-sodium), propoxydim (profoxydim), bromacil (bromacil), brompyrazon (brompyrazon), prometryn (prometryn), prometon (prometon), bromoxynil (butyric acid, octanoic acid, or esters such as heptanoic acid), bromofenoxim, bromobutide, florasulam, florpyrauxifen, hexazinone, phenol Toxamide, benazolin, penoxsulam, heptamaloxyloglucan, beflubutamid, pebulate, pelargonic acid, bencarba bencarbazone, pendimethalin, benzfendizone, benzulide, bensulfuron-methyl, benzobicyclon, benzofenap, benta Bentazone, pentanochlor, pentoxazone, benfluralin, benfuresate, fosamine, fomesafen, foramsulfuron (fo ramsulfuron), mecoprop (including salts of sodium, potassium, isopropylamine, triethanolamine, dimethylamine, etc.), mecoprop-P-potassium, mecoprop-P-potassium novelfuron methyl (mesosulfuron-methyl), mesotrione (mesotrione), metazachlor, metazosulfuron (metazosulfuron), metabenzthiazuron (methabenzthiazuron), metamitron (metamitron), metamifop ( metamifop), DSMA (methanearsone disodium), methiozolin, methyldymuron, metoxuron, methosulfuron, metsulfuron-methyl, Metobromuron, metobenzuron, metolachlor, metribuzin, mefenacet, monosulfuron (methyl, ethyl, isopropyl ester) including), monolinuron, molinate, iodosulfuron, iodosulfulon-methyl-sodium salt (iodosulfulon-methyl-sodium), iofensulfuron, iofensulfuron Furon sodium salt (iofensulfuron-sodium), lactofen (lactofen), lancotrione (lancotrione), linuron (linuron), rimsulfuron (rimsulfuron), lenacil (lenacil), TCA (2, 2, 2-tri chloroacetic acid) (including salts such as sodium, calcium or ammonia), 2,3,6-TBA (2,3,6-trichlorobenzoic acid), 2,4,5-T (2,4,5- trichlorophenoxyacetic acid), 2,4-D (2,4-dichlorophenoxyacetic acid) (including salts of amine, diethylamine, triethanolamine, isopropylamine, sodium or lithium, etc.), ACN (2-amino-3-chloro-1 , 4-naphthoxynone), MCPA (2-methyl-4-chlorophenoxyacetic acid), MCPB (2-methyl-4-chlorophenoxybutyric acid) (including sodium salt, ethyl ester, etc.), 2,4 -DB (4- (2,4-dichlorophenoxy) butyric acid, DNOC (4,6-dinitro-o-cresol) (including salts such as amines or sodium), AE-F-150944 (code number) ), HW-02 (code number), IR-6396 (code number), MCPA-thioethyl (MCPA-thioethyl), SYP-298 (code number), SYP-300 (code number), EPTC (S-ethyl die propylthiocarbamate), S-metolachlor.

[살충 활성성분][Insecticide active ingredient]

아크리나트린(acrinathrin), 아자디라크틴(azadirachtin), 아자메티포스(azamethiphos), 아진포스·에틸(azinphos-ethyl), 아진포스·메틸(azinphos-methyl), 아세퀴노실(acequinocyl), 아세타미프리드(acetamiprid), 아세토프롤(acetoprole), 아세페이트(acephate), 아조사이클로틴(azocyclotin), 아바멕틴(abamectin), 아피도피로펜(afidopyropen), 아폭소레이나(afoxolaner), 아미도플루메트(amidoflumet), 아미트라즈(amitraz), 알라니카브(alanycarb), 알디카브(aldicarb), 알독시카브(aldoxycarb), 알레트린(allethrin)(이의 d-시스-트랜스-체 및 d-트랜스-체를 포함함), 이사조포스(isazophos), 아사미도포스(isamidofos), 이소카보포스(isocarbophos), 이속사티온(isoxathion), 이소펜포스·메틸(isofenphos-methyl), 이소프로카브(isoprocarb), 이베멕틴(ivermectin), 이미시아포스(imicyafos), 이미다클로프리드(imidacloprid), 이미프로트린(imiprothrin), 인독사카브(indoxacarb), 에스펜발레레이트(esfenvalerate), 에티오펜카브(ethiofencarb), 에티온(ethion), 에티프롤(ethiprole), 에틸렌 다이브로마이드(ethylene dibromide), 에톡사졸(etoxazole), 에토펜프록스(etofenrpox), 에토프로포스(ethoprophos), 에트림포스(etrimfos), 에마멕틴 벤조에이트(emamectin benzoate), 엔도설판(endosulfan), 엠펜트린(empenthrin), 옥사밀(oxamyl), 옥시데메톤·메틸(oxydemeton-methyl), 옥시데프로포스(oxydeprofos), 오메토에이트(omethoate), 카두사포스(cadusafos), 카파-테플루트린(kappa-tefluthrin), 카파-바이펜트린(kappa-bifenthrin), 카란진(karanjin), 카탑(cartap), 카바릴(carbaryl), 카보설판(carbosulfan), 카보푸란(carbofuran), 감마-BHC(ga㎜a-BHC), 자일릴카브(xylylcarb), 퀴날포스(quinalphos), 키노프렌(kinoprene), 키노메티오나트(chinomethionat), 쿠마포스(coumaphos), 크리오라이트(cryolite), 클로티아니딘(clothianidin), 클로펜테진(clofentezine), 크로마페노자이드(chromafenozide), 클로란트라닐리프롤(chlorantraniliprole), 클로르에톡시포스(chlorethoxyfos), 클로르덴(chlordane), 클로로피크린(chloropicrin), 클로르피리포스(chlorpyrifos), 클로르피리포스·메틸(chlorpyrifos-methyl), 클로르페나필(chlorfenapyr), 클로르펜빈포스(chlorfenvinphos), 클로르플루아주론(chlorfluazuron), 클로르메포스(chlormephos), 클로로프랄레트린(chloroprallethrin), 사이아노포스(cyanophos), 다이아펜티우론(diafenthiuron), 다이아미다포스(diamidafos), 사이안트라닐리프롤(cyantraniliprole), 디에노클로르(dienochlor), 시에노피라펜(cyenopyrafen), 다이옥사벤조포스(dioxabenzofos), 다이오페놀란(diofenolan), 사이클라닐리프롤(cyclaniliprole), 다이크로토포스(dicrotophos), 다이클로펜티온(dichlofenthion), 사이클로프로트린(cycloprothrin), 다이클로르보스(dichlorvos), 다이클로로메조티아즈(dicoloromezotiaz), 1,3-다이클로로프로펜(1,3-dichloropropene), 다이코폴(dicofol), 다이사이클라닐(dicyclanil), 다이설포톤(disulfoton), 다이노테푸란(dinotefuran), 다이노부톤(dinobuton), 사이할로다이아마이드(cyhalodiamide), 사이할로트린(cyhalothrin)(감마체 및 람다체를 포함함), 사이페노트린(cyphenothrin)((1R)-트랜스-체를 포함함), 사이플루트린(cyfluthrin)(베타-체를 포함함), 다이플루벤주론(diflubenzuron), 사이플루메토펜(cyflumetofen), 다이플로비다진(diflovidazin), 사이헥사틴(cyhexatin), 사이퍼메트린(cypermethrin)(알파-체, 베타-체, 세타-체 및 제타-체를 포함함), 다이메틸빈포스(dimethylvinphos), 다이메플루트린(dimefluthrin), 다이메토에이트(dimethoate), 실라플루오펜(silafluofen), 사이로마진(cyromazine), 스핀토람(spinetoram), 스피노사드(spinosad), 스피로다이클로펜(spirodiclofen), 스피로테트라마트(spirotetramat), 스피로메시펜(spiromesifen), 설코푸론·나트륨염(sulcofuron-sodium), 설플루라미드(sulfluramid), 설폭사플로르(sulfoxaflor), 설포텝(sulfotep), 다이아지논(diazinon), 티아클로프리드(thiacloprid), 티아메톡삼(thiamethoxam), 티옥사자펜(tioxazafen), 티오다이카브(thiodicarb), 티오사이클람(thiocyclam), 티오설탭(thiosultap), 티오나진(thionazin), 티오파녹스(thiofanox), 티오메톤(thiometon), 테트라클로르빈포스(tetrachlorvinphos), 테트라디폰(tetradifon), 테트라닐리프롤(tetraniliprole), 테트라메틸플루트린(tetramethylfluthrin), 테트라메트린(tetramethrin), 테부피림포스(tebupirimfos), 테부페노자이드(tebufenozide), 테부펜피라드(tebufenpyrad), 테플루트린(tefluthrin), 테플루벤주론(teflubenzuron), 데메톤·S·메틸(demeton-S-methyl), 테메포스(temephos), 델타메트린(deltamethrin), 테르부포스(terbufos), 트랄로메트린(tralomethrin), 트랜스플루트린(transfluthrin), 트라이아자메이트(triazamate), 트라이아조포스(triazophos), 트라이클로르폰(trichlorfon), 트라이플루무론(triflumuron), 트라이플루메조피림(triflumezopyrim), 트라이메타카브(trimethacarb), 톨펜피라드(tolfenpyrad), 날레드(naled), 니텐피람(nitenpyram), 노발루론(novaluron), 노비플루무론(noviflumuron), 베르티실륨 레카니이(Verticillium lecanii), 하이드로프렌(hydroprene), 파스퇴리아페네트랜스포자(Pasteuriapenetrans), 바미도티온(vamidothion), 파라티온(parathion), 파라티온-메틸(parathion-methyl), 할펜프록스(halfenprox), 할로페노자이드(halofenozide), 바이오알레트린(bioallethrin), 바이오알레트린 S-사이클로펜테닐(bioallethrin S-cyclopentenyl), 바이오레스메트린(bioresmethrin), 비스트라이플루론(bistrifluron), 하이드라메틸논(hydramethylnon), 비페나제이트(bifenazate), 비펜트린(bifenthrin), 피플루부마이드(pyflubumide), 피페로닐 부톡사이드(piperonyl butoxide), 피메트로진(pymetrozine), 피라클로포스(pyraclofos), 피라플루프롤(pyrafluprole), 피리다펜티온(pyridaphenthion), 피리다벤(pyridaben), 피리달릴(pyridalyl), 피리플루퀴나존(pyrifluquinazon), 피리프롤(pyriprole), 피리프록시펜(pyriproxyfen), 피리미카브(pirimicarb), 피리미디펜(pyrimidifen), 피리미노스트로빈(pyriminostrobin), 피리미포스·메틸(pirimiphos-methyl), 피레트린(pyrethrine), 팜푸르(famphur), 피프로닐(fipronil), 페나자퀸(fenazaquin), 페나미포스(fenamiphos), 페니트로티온(fenitrothion), 페녹시카브(fenoxycarb), 페노티오카브(fenothiocarb), 페노트린(phenothrin)((1R)-트랜스-체를 포함함), 페노부카브(fenobucarb), 펜티온(fenthion), 펜토에이트(phenthoate), 펜발레레이트(fenvalerate), 펜피록시메이트(fenpyroximate), 펜부타틴 옥사이드(fenbutatin oxide), 펜프로파트린(fenpropathrin), 포노포스(fonofos), 플루오린화설푸릴(sulfuryl fluoride), 부토카복심(butocarboxim), 부톡시카복심(butoxycarboxim), 부프로페진(buprofezin), 푸라티오카브(furathiocarb), 프랄레트린(prallethrin), 플루아크리피림(fluacrypyrim), 플루아자인도리진(fluazaindolizine), 플루아주론(fluazuron), 플루엔설폰(fluensulfone), 플루오로아세트산나트륨염(sodium fluoroacetate), 플럭사메타미드(fluxametamide), 플루사이클록수론(flucycloxuron), 플루사이트리네이트(flucythrinate), 플루설파마이드(flusulfamide), 플루발리네이트(fluvalinate)[타우-체를 포함함], 플루피라디푸론(flupyradifurone), 플루피라조포스(flupyrazofos), 플루피프롤(flufiprole), 플루페네림(flufenerim), 플루페녹시스트로빈(flufenoxystrobin), 플루페녹수론(flufenoxuron), 플루헥사폰(fluhexafon), 플루벤다이아마이드(flubendiamide), 플루메트린(flumethrin), 프로트라이펜부트(protrifenbute), 프로티오포스(prothiofos), 프로트라이펜부트(protrifenbute), 플로니카미드(flonicamid), 프로파포스(propaphos), 프로파르가이트(propargite), 프로페노포스(profenofos), 브로플라닐라이드(broflanilide), 프로플루트린(profluthrin), 프로페탐포스(propetamphos), 프로폭수르(propoxur), 플로메토퀸(flometoquin), 브로모프로필레이트(bromopropylate), 헥시티아족스(hexythiazox), 헥사플루무론(hexaflumuron), 패실로마이세스 테누이페스(Paecilomyces tenuipes), 패실로마이세스 푸모소로세우스(Paecilomyces fumosoroceus), 헵타플루트린(heptafluthrin), 헵테노포스(heptenophos), 퍼메트린(permethrin), 벤클로티아즈(benclothiaz), 벤설탭(bensultap), 벤족시메이트(benzoximate), 벤다이오카브(bendiocarb), 벤푸라카브(benfuracarb), 뷰베리아·테넬라(Beauveria tenella), 뷰베리아·바시아나(Beauveria bassiana), 뷰베리아 브롱니아르티이(Beauveria brongniartii), 폭심(phoxim), 포살론(phosalone), 포스티아제이트(fosthiazate), 포스티에탄(fosthietan), 포스파미돈(phosphamidon), 포스메트(phosmet), 폴리낙틴스(polynactins), 포메타네이트(formetanate), 포레이트(phorate), 말라티온(malathion), 밀베멕틴(milbemectin), 메카밤(mecarbam), 메설펜포스(mesulfenfos), 메토프렌(methoprene), 메토밀(methomyl), 메타플루미존(metaflumizone), 메타미도포스(methamidophos), 메탐(metham), 메티오카브(methiocarb), 메티다티온(methidathion), 메틸 아이소티오사이아네이트(methyl isothiocyanate), 메틸 브로마이드(methyl bromide), 메톡시클로르(methoxychlor), 메톡시페노자이드(methoxyfenozide), 메토트린(methothrin), 메토플루트린(metofluthrin), 엡실론－메토플루트린(epsilon-metofluthrin), 메톨카브(metolcarb), 메빈포스(mevinphos), 메펠플루트린(meperfluthrin), 모나크로스포륨 피마토파굼(Monacrosporium phymatophagum), 모노크로토포스(monocrotophos), 몸플루로트린(momfluorothrin), 엡실론－몸플루오로트린(epsilon-momfluorothrin), 리틀루어-A(litlure-A), 리틀루어-B(litlure-B), 인화알루미늄(aluminium phosphide), 인화아연(zinc phosphide), 포스핀(phosphine), 루페누론(lufenuron), 레스칼루어(rescalure), 레스메트린(resmethrin), 레피멕틴(lepimectin), 로테논(rotenone), 펜부타주석 옥사이드(fenbutatin oxide), 사이안화칼슘(calcium cyanide), 황산니코틴(nicotinesulfate), (Z)-11-테트라데세닐=아세테이트, (Z)-11-헥사데세날, (Z)-11-헥세데세닐=아세테이트, (Z)-9,12-테트라데카다이엔일=아세테이트, (Z)-9-테트라데센-1-올, (Z,E)-9,11-테트라데카다이엔일=아세테이트, (Z,E)-9,12-테트라데카다이엔일=아세테이트, 바실러스·포필리애(Bacillus popilliae), 바실러스·서브틸리스(Bacillus subtillis), 바실러스·스패리쿠스(Bacillus sphaericus), 바실러스·투린지엔시스·아종·아이자와이(Bacillus thuringiensis subsp. Aizawai), 바실러스·투린지엔시스·아종·이스라엘렌시스(Bacillus thuringiensis subsp. Israelensis), 바실러스·트린지엔시스·아종·쿠르스타키(Bacillus thuringiensis subsp. Kurstaki), 바실러스·투린지엔시스·아종·테네브리오니스(Bacillus thuringiensis subsp. Tenebrionis), Bt 단백질(Cry1Ab, Cry1Ac, Cry1Fa, Cry2Ab, mCry3A, Cry3Ab, Cry3Bb, Cry34/35Ab1), CL900167(코드 번호), DCIP(비스-(2-클로로-1-메틸에틸)에터), DDT(1,1,1-트라이클로로-2,2-비스(4-클로로페닐)에탄), DEP(다이메틸-2,2,2-트라이클로로-1-하이드록시에틸포스포네이트), DNOC(4,6-다이나이트로-o-크레졸), DSP(O,O-다이에틸-O-[4-다이메틸설파모일]페닐)포스포티오에이트), EPN(O-에틸-O-4-(나이트로페닐)페닐포스포노티오에이트), 핵다각체 바이러스 포매체, NA-85(코드 번호), NA-89(코드 번호), NC-515(코드 번호), RU15525(코드 번호), ZDI-2501(코드 번호), XMC, Z-13-에이코센-10-온, ZXI8901(코드 번호), ME5382.acrinathrin, azadirachtin, azamethiphos, azinphos-ethyl, azinphos-methyl, acequinocyl, acetonitrile acetamiprid, acetoprole, acephate, azocyclotin, abamectin, afidopyropen, afoxolaner, amidoflumet (amidoflumet), amitraz, alanycarb, aldicarb, aldoxycarb, allethrin (its d-cis-trans-form and d-trans- including sieve), isazophos, asamidofos, isocarbophos, isoxathion, isofenphos-methyl, isoprocarb ), ivermectin, imicyafos, imidacloprid, imiprothrin, indoxacarb, esfenvalerate, ethiofencarb, Ethion, ethiprole, ethylene dibromide, etoxazole, etofenrpox, ethoprophos, etrimfos, emamectin benzo Eate (emamectin benzoate), endosulfan (endosulfan), empenthrin (empenthrin), oxamyl (oxamyl), oxydemeton methyl (oxydemeton-methyl), oxydeprofos (oxydeprofos), omethoate (omethoate), cadusafos, kapha-te kappa-tefluthrin, kappa-bifenthrin, karanjin, cartap, carbaryl, carbosulfan, carbofuran, gamma-BHC (gamma-BHC), xylylcarb, quinalphos, kinoprene, chinomethionat, coumaphos, cryolite, clothiani Dean (clothianidin), clofentezine, chromafenozide, chlorantraniliprole, chlorethoxyfos, chlordane, chloropicrin, chlor chlorpyrifos, chlorpyrifos-methyl, chlorfenapyr, chlorfenvinphos, chlorfluazuron, chlormephos, chloropraletrine (chloroprallethrin), cyanophos, diafenthiuron, diamidafos, cyantraniliprole, dienochlor, cyenopyrafen, Dioxabenzofos, diofenolan, cyclaniliprole, dicrotophos, diclofenthion, cycloprothrin, dichlorvos ( dichlorvos), dichloromezotiaz (dicoloromezotiaz), 1,3-dichloropropene (1,3-dichloropropene), dicopol (dicofol), dicyclanyl (dicyc) lanil), disulfoton, dinotefuran, dinobuton, cyhalodiamide, cyhalothrin (including gamma and lambda forms), cyphenothrin (including (1R)-trans-isomer), cyfluthrin (including beta-isomer), diflubenzuron, cyflumetofen , diflovidazin, cyhexatin, cypermethrin (including alpha-form, beta-form, theta-form and zeta-form), dimethylvinphos, Dimefluthrin, dimethoate, silafluofen, cyromazine, spintoram, spinosad, spirodiclofen, spirotetra Spirotetramat, spiromesifen, sulcofuron-sodium, sulfluramid, sulfoxaflor, sulfotep, diazinon, Thiacloprid, thiamethoxam, thioxazafen, thiodicarb, thiocyclam, thiosultap, thionazin, thiophanox (thiofanox), thiometon, tetrachlorvinphos, tetradifon, tetraniliprole, tetramethylfluthrin, tetramethrin, tebupyrim Fos (tebupirimfos), tebufenozide (tebufenoz) ide), tebufenpyrad, tefluthrin, teflubenzuron, demeton S methyl, temephos, deltamethrin ), terbufos, tralomethrin, transfluthrin, triazamate, triazophos, trichlorfon, triflumuron , triflumezopyrim, trimethacarb, tolfenpyrad, naled, nitenpyram, novaluron, noviflumuron, verr Verticillium lecanii , hydroprene, Pasteuriapenetrans, vamidothion, parathion, parathion-methyl, halfenprox ), halofenozide, bioallethrin, bioallethrin S-cyclopentenyl, bioresmethrin, bistrifluron, hydra Methylnon, bifenazate, bifenthrin, pyflubumide, piperonyl butoxide, pymetrozine, pyraclofos ), pyrafluprole, pyridaphenthion, pyridaben, pyridalyl, pyrifluquinazone zon), pyriprole, pyriproxyfen, pyrimicarb, pyrimidifen, pyriminostrobin, pyrimiphos-methyl, pyrethrine, famphur, fipronil, fenazaquin, fenamiphos, fenitrothion, fenoxycarb, phenothiocarb ( fenothiocarb), phenothrin (including (1R)-trans-forms), fenobucarb, fenthion, phenthoate, fenvalerate, fenpyroxy Mate, fenpyroximate, fenbutatin oxide, fenpropathrin, fonofos, sulfuryl fluoride, butocarboxim, butoxycarboxim , buprofezin, furathiocarb, prallethrin, fluacrypyrim, fluazaindolizine, fluazuron, fluensulfone ), sodium fluoroacetate, fluxametamide, flucycloxuron, flucythrinate, flusulfamide, fluvalinate [ including tau-che], flupyradifurone, flupyrazofos, flufiprole, flufenerim, flufenoxystrobin, flufenox Flufenoxuron, fluhexafon, flubendiamide, flumethrin, protrifenbute, prothiofos, protrifenbute, flu nicamide, propaphos, propargite, profenofos, broflanilide, profluthrin, propetamphos, pro Poxur (propoxur), flometoquin (flometoquin), bromopropylate (bromopropylate), hexythiazox (hexythiazox), hexaflumuron (hexaflumuron), Paecilomyces tenuipes ( Paecilomyces tenuipes ) Paecilomyces fumosoroceus , heptafluthrin, heptenophos, permethrin, benclothiaz, bensultap, benzoximate ), bendiocarb, benfuracarb, Beauveria tenella, Beauveria bassiana, Beauveria brongniartii, phoxim ), phosalone, fosthiazate, fosthietan, phosphamidon, phosmet, polynactins, formetanate, phorate, malathion, milbemectin, mecarbam, mesulfenfos, methoprene, metho Wheat (methomyl), metaflumizone (metaflumizone), metamidophos (methamidophos), metham (metham), methiocarb (methiocarb), methidathion (methidathion), methyl isothiocyanate (methyl isothiocyanate), methyl methyl bromide, methoxychlor, methoxyfenozide, methothrin, metofluthrin, epsilon-metofluthrin, methol Cobb (metolcarb), mebin Force (mevinphos), mepel flute Lin (meperfluthrin), a trim (momfluorothrin), epsilon spokes volume Pima topa gum (Monacrosporium phymatophagum), monochrome topos (monocrotophos), the body flu as the monarch - a body-fluoro Epsilon-momfluorothrin, litlure-A, litlure-B, aluminum phosphide, zinc phosphide, phosphine, lufenuron ( lufenuron, rescalure, resmethrin, lepimectin, rotenone, fenbutatin oxide, calcium cyanide, nicotinesulfate ), (Z)-11-tetradecenyl=acetate, (Z)-11-hexadecenal, (Z)-11-hexedenyl=acetate, (Z)-9,12-tetradecadienyl= Acetate, (Z)-9-tetradecen-1-ol, (Z,E)-9,11-tetradecadienyl=acetate, (Z,E)-9,12-tetradecadienyl=acetate , Bacillus popilliae ( Bacillus popilliae ), Bacillus subtilis ( Bacillus subtillis ), Bacillus spiricus ( Bacillus sphaericus), Bacillus thuringiensis subspecies, Aizawa ( Bacillus thuringiensis subsp. Aizawai ), Bacillus thuringiensis subspecies Israelensis ( Bacillus thuringiensis subsp. Israelensi s), Bacillus thuringiensis subsp. Kurstaki ( Bacillus thuringiensis subsp. Kurstaki ), Bacillus thuringiensis subsp. Bacillus thuringiensis subsp. Tenebrionis , Bt protein (Cry1Ab, Cry1Ac, Cry1Fa, Cry2Ab, mCry3A, Cry3Ab, Cry3Bb, Cry34/35Ab1), CL900167 (code number), DC-1-methyl (bis- (2-chloro) ethyl) ether), DDT (1,1,1-trichloro-2,2-bis (4-chlorophenyl) ethane), DEP (dimethyl-2,2,2-trichloro-1-hydroxyethylphos phonate), DNOC (4,6-dinitro- o -cresol), DSP (O,O-diethyl-O-[4-dimethylsulfamoyl]phenyl)phosphothioate), EPN (O- Ethyl-O-4- (nitrophenyl) phenylphosphonothioate), polyhedral virus carrier, NA-85 (code number), NA-89 (code number), NC-515 (code number), RU15525 ( Code No.), ZDI-2501 (Code No.), XMC, Z-13-Eikosen-10-On, ZXI8901 (Code No.), ME5382.

［살균활성성분］[bactericidal active ingredient]

아자코나졸(azaconazole), 아시벤졸라·S·메틸(acibenzolar-S-methyl), 아족시스트로빈(azoxystrobin), 아닐라진(anilazine), 아미설브롬(amisulbrom), 아메톡트라딘(ametoctradin), 알디몰프(aldimorph), 아이소티아닐(isotianil), 아이소피라잠(isopyrazam), 아이소페타미드(isofetamid), 아이소프로티올란(isoprothiolane), 이프코나졸(ipconazole), 이프펜트리플루코나졸(ipfentrifluconazole), 이프로디온(iprodione), 이프로발리카브(iprovalicarb), 이프로벤포스(iprobenfos), 이마잘릴(imazalil), 이미녹타딘-트라이알베실레이트(iminoctadine-trialbesilate), 이미녹타딘트라이아세테이트(iminoctadine-triacetate), 이미벤코나졸(imibenconazole), 에디펜포스(edifenphos), 에타코나졸(etaconazole), 에타복삼(ethaboxam), 에티리몰(ethirimol), 에톡시퀸(ethoxyquin), 에트리디아졸(etridiazole), 에네스트로부린(enestroburin), 에녹사스트로빈(enoxastrobin), 에폭시코나졸(epoxiconazole), 오가닉 오일(organic oil), 옥사딕실(oxadixyl), 옥사진일라졸(oxazinylazole), 옥사티아피프롤린(oxathiapiprolin), 옥시카복신(oxycarboxin), 옥신-구리(oxine-copper), 옥시테트라사이클린(oxytetracycline), 옥스포코나졸-푸말산염(oxpoconazole-fumarate), 옥솔린산(oxolinic acid), 다이옥탄산구리(copper dioctanoate), 옥틸리논(octhilinone), 오푸라세(ofurace), 오리사스트로빈(orysastrobin), o-페닐페놀(o-phenylphenol), 카스가마이신(kasugamycin), 캅타폴(captafol), 카프로파미드(carpropamid), 카벤다짐(carbendazim), 카복신(carboxin), 카르본(carvone), 퀴녹시펜(quinoxyfen), 퀴노푸멜린(quinofumelin), 키노메티오나트(chinomethionat), 캅탄(captan), 퀸코나졸(quinconazole), 퀸토젠(quintozene), 구아자틴(guazatine), 쿠프라넵(cufraneb), 쿠목시스트로빈(coumoxystrobin), 크레속심·메틸(kresoxim-methyl), 클로질라콘(clozylacon), 클로졸리네이트(chlozolinate), 클로로탈로닐(chlorothalonil), 클로로넵(chloroneb), 시아조파마이드(cyazofamid), 다이에토펜카브(diethofencarb), 다이클로시메트(diclocymet), 다이클로플루아니드(dichlofluanid), 다이클로메진(diclomezine), 다이클로란(dicloran), 다이클로로펜(dichlorophen), 다이티아논(dithianon), 다이니코나졸(diniconazole), 다이니코나졸·M(diniconazole-M), 지넵(zineb), 디노캅(dinocap), 다이피메티트론(dipymetitrone), 다이페닐아민(diphenylamine), 다이페노코나졸(difenoconazole), 시플루페나미드(cyflufenamid), 디플루메토림(diflumetorim), 시프로코나졸(cyproconazole), 시프로디닐(cyprodinil), 시메코나졸(simeconazole), 다이메티리몰(dimethirimol), 다이메틸 다이설파이드(dimethyl disulfide), 다이메토몰프(dimethomorph), 시목사닐(cymoxanil), 다이목시스트로빈(dimoxystrobin), 지람(ziram), 실티오팜(silthiofam), 스트렙토마이신(streptomycin), 스피록사민(spiroxamine), 세닥산(sedaxane), 족사마이드(zoxamide), 다조메트(dazomet), 티아디닐(tiadinil), 티아벤다졸(thiabendazole), 티람(thiram), 티오파네이트(thiophanate), 티오페네이트-메틸(thiophanate-methyl), 티플루자마이드(thifluzamide), 테크나젠(tecnazene), 테클로프탈람(tecloftalam), 테트라코나졸(tetraconazole), 데바카브(debacarb), 테부코나졸(tebuconazole), 테부플로퀸(tebufloquin), 터비나핀(terbinafine), 도딘(dodine), 도데몰프(dodemorph), 트라이아디메놀(triadimenol), 트라이아디메폰(triadimefon), 트라이아족사이드(triazoxide), 트라이클라마이드(trichlamide), 트라이클로피리카브(triclopyricarb), 트라이사이클라졸(tricyclazole), 트라이티코나졸(triticonazole), 트라이데몰프(tridemorph), 트라이플루미졸(triflumizole), 트라이플록시스트로빈(trifloxystrobin), 트라이포린(triforine), 톨릴플루아니드(tolylfluanid), 톨클로포스·메틸(tolclofos-methyl), 톨니파나이드(tolnifanide), 톨프로카브(tolprocarb), 나밤(nabam), 나타마이신(natamycin), 나프티핀(naftifine), 니트라피린(nitrapyrin), 니트로탈·아이소프로필(nitrothal-isopropyl), 누아리몰(nuarimol), 노닐 페놀 설폰산 구리(copper nonyl phenol sulphonate), 바실러스·서브틸리스(Bacillus subtilis)(균주: QST 713), 발리다마이신(validamycin), 발리페날레이트(valifenalate), 피카부트라족스(picarbutrazox), 빅사펜(bixafen), 피콕시스트로빈(picoxystrobin), 피디플루메토펜(pydiflumetofen), 비텔타놀(bitertanol), 비나파크릴(binapacryl), 바이페닐(biphenyl), 피페랄린(piperalin), 히멕사졸(hymexazol), 피라옥시스트로빈(pyraoxystrobin), 피라클로스트로빈(pyraclostrobin), 피라지플루미드(pyraziflumid), 피라조포스(pyrazophos), 피라메토스트로빈(pyrametostrobin), 피리오페논(pyriofenone), 피리속사졸(pyrisoxazole), 피리페녹스(pyrifenox), 피리부티카브(pyributicarb), 피리벤카브(pyribencarb), 피리메타닐(pyrimethanil), 피로퀼론(pyroquilon), 빈클로졸린(vinclozolin), 퍼밤(ferbam), 파목사돈(famoxadone), 페나진 옥사이드(phenazine oxide), 페나미돈(fenamidone), 페나민스트로빈(fenaminstrobin), 페나리몰(fenarimol), 페녹사닐(fenoxanil), 페림존(ferimzone), 펜피클로닐(fenpiclonil), 펜피콕사미드(fenpicoxamid), 펜피라자민(fenpyrazamine), 펜부코나졸(fenbuconazole), 펜푸람(fenfuram), 펜프로피딘(fenpropidin), 펜프로피모프(fenpropimorph), 펜헥사미드(fenhexamid), 폴페트(folpet), 프탈라이드(phthalide), 부피리메이트(bupirimate), 부페리다졸(fuberidazole), 블라스티시딘-S(blasticidin-S), 푸라메트필(furametpyr), 푸랄락실(furalaxyl), 푸란카복실산(furancarboxylic acid), 플루아지난(fluazinam), 플루이다필(fluindapyr), 플루옥사스트로빈(fluoxastrobin), 플루오피콜라이드(fluopicolide), 플루오피람(fluopyram), 플루오로이미드(fluoroimide), 플룩사피록사드(fluxapyroxad), 플루퀸코나졸(fluquinconazole), 푸르코나졸(furconazole), 푸르코나졸·시스(furconazole-cis), 플루디옥소닐(fludioxonil), 플루실라졸(flusilazole), 플루설파마이드(flusulfamide), 플루티아닐(flutianil), 플루톨라닐(flutolanil), 플루트리아폴(flutriafol), 플루페녹시스트로빈(flufenoxystrobin), 플루메토버(flumetover), 플루몰프(flumorph), 프로퀴나지드(proquinazid), 프로클로라즈(prochloraz), 프로시미돈(procymidone), 프로티오카브(prothiocarb), 프로티오코나졸(prothioconazole), 브로노폴(bronopol), 프로파모카브·염산염(propamocarb-hydrochloride), 프로피코나졸(propiconazole), 프로피네브(propineb), 프로베나졸(probenazole), 브로무코나졸(bromuconazole), 플로메토퀸(flometoquin), 헥사코나졸(hexaconazole), 베날락실(benalaxyl), 베날락실·M(benalaxyl-M), 베노다닐(benodanil), 베노밀(benomyl), 페푸라조에이트(pefurazoate), 펜코나졸(penconazole), 펜시쿠론(pencycuron), 벤조빈디플루필(benzovindiflupyr), 벤티아졸(benthiazole), 벤티아발리카브·아이소프로필(benthiavalicarb-isopropyl), 펜티오피라드(penthiopyrad), 펜플루펜(penflufen), 보스칼리드(boscalid), 포세틸(fosetyl)(알루미늄, 칼슘, 나트륨), 폴리옥신(polyoxin), 폴리카바메이트(polycarbamate), 보르도액(Bordeaux mixture), 만코제브(mancozeb), 만디프로파미드(mandipropamid), 만데스트로빈(mandestrobin), 만네브(maneb), 미클로부타닐(myclobutanil), 광유(mineral oil), 밀디오마이신(mildiomycin), 메타설포카브(methasulfocarb), 메탐(metam), 메탈락실(metalaxyl), 메탈락실·M(metalaxyl-M), 메티람(metiram), 메트코나졸(metconazole), 메토미노스트로빈(metominostrobin), 메트라페논(metrafenone), 메파니피림(mepanipyrim), 메펜트라이플루코나롤(mefentrifluconazole), 메프틸디노캅(meptyldinocap), 메프로닐(mepronil), 아이오도카브(iodocarb), 라미나린(laminarin), 아인산 및 염(phosphorous acid and salts), 옥시염화구리(copper oxychloride), 은(silver), 산화제일구리(cuprous oxide), 수산화제이구리(copper hydroxide), 중탄산칼륨(potassium bicarbonate), 중탄산나트륨(sodium bicarbonate), 황(sulfur), 황산옥시퀴놀린(oxyquinoline sulfate), 황산구리(copper sulfate), (3,4-다이클로로아이소티아졸-5-일) 메틸-4-(tert-부틸)벤조산에스터(화학명, CAS 등록번호: 1231214-23-5), 3-((3,4-다이클로로아이소티아졸-5-일)메톡시)벤조[d]아이소티아졸-1,1-다이옥사이드(화학명, CAS 등록번호: 957144-77-3), BAF-045(코드 번호), BAG-010(코드 번호), UK-2A(코드 번호), DBEDC(도데실벤젠설폰산 비스에틸렌다이아민 구리[II]염), MIF-1002(코드 번호), TPTA(에세트산 트라이페닐주석), TPTC(트라이페닐주석 클로라이드), TPTH(수산화트라이페닐주석), 비병원성 에르위니아·카로토보라.Azaconazole, acibenzolar-S-methyl, azoxystrobin, anilazine, amisulbrom, amethoctradin, aldimorph, isotianil, isopyrazam, isopetamid, isoprothiolane, ifconazole, ipfentrifluconazole, if Rhodione, iprovalicarb, iprobenfos, imazalil, iminoctadine-trialbesilate, iminoctadine-triacetate , imibenconazole, edifenphos, etaconazole, ethaboxam, ethirimol, ethoxyquin, etridiazole, enestro enestroburin, enoxastrobin, epoxiconazole, organic oil, oxadixyl, oxazinylazole, oxathiapiproline, oxy oxycarboxin, oxine-copper, oxytetracycline, oxpoconazole-fumarate, oxolinic acid, copper dioctanoate, jade octhilinone, ofurace, orysastrobin, o-phenylphenol, kasugamycin, captafol, carpropamid, carbendazim, carboxin, carvone, quinoxyfen, quinofumelin, quinomethionat ( chinomethionat), captan, quinconazole, quintozene, guazatine, cupraneb, coumoxystrobin, cresoxim-methyl ), clozylacon, clozolinate, chlorothalonil, chloroneb, cyazofamid, diethofencarb, diclocymet ), diclofluanid, diclomezine, dichloran, dichlorophen, dithianon, diniconazole, diniconazole M (diniconazole-M), zineb, dinocap, dipymetitrone, diphenylamine, difenoconazole, cyflufenamide, di Flumetorim, cyproconazole, cyprodinil, simeconazole, dimethirimol, dimethyl disulfide, dimethomorph , cymoxanil, dimoxystrobin, ziram, silthiofam, streptomycin, spiroxamine, sedaxane, zoxamide ( zoxamide), dazomet, tiadinil, thiabendazole, thiram, thiophanate, thiophenate-methyl, tifluzamide (thifluzamide), tecnazene, tecloftalam, tetraconazole, debacarb, tebuconazole, tebufloquin, terbinafine , dodine, dodemorph, triadimenol, triadimefon, triazoxide, trichloramide, triclopyricarb (triclopyricarb), tricy tricyclazole, triticonazole, tridemorph, triflumizole, trifloxystrobin, triforine, tolylfluanid, tol Clofos-methyl, tolnifanide, tolprocarb, nabam, natamycin, naftifine, nitrapyrin, nitrotal isopropyl (nitrothal-isopropyl), nuarimol, nonyl phenol sulphonate copper (copper nonyl phenol sulphonate), Bacillus subtilis (Strain: QST 713), validamycin (validamycin), Bali valifenalate, picabutrazox, bixafen, picoxystrobin, pydiflumetofen, Bitertanol, binapacryl, biphenyl, piperalin, hymexazol, pyraoxystrobin, pyraclostrobin, pyraziflu Mid (pyraziflumid), pyrazophos, pyrametostrobin, pyriofenone, pyrisoxazole, pyrifenox, pyributicarb, pyriben pyribencarb, pyrimethanil, pyroquilon, vinclozolin, ferbam, famoxadone, phenazine oxide, fenamidone , fenaminstrobin, fenarimol, fenoxanil, ferimzone, fenpiclonil, fenpicoxamid, fenpyrazamine ), fenbuconazole, fenfuram, fenpropidin, fenpropimorph, fenhexamid, folpet, phthalide, buri mate (bupirimate), buperidazole (fuberidazole), blasticidin-S (blasticidin-S), furametpyr, furalaxyl, furancarboxylic acid, fluazinam , fludapyr, fluoxastrobin, fluopicolide, fluopyram, fluoroimide, fluxapyroxad, fluquinconazole ( fluquinconazole, furconazole, furconazole-cis, fludioxonil, flusilazole, flusulfamide, flutianil, flutolanil, flutriafol, flufenoxystrobin, flumetover, flumorph, proquinazid, prochloraz, pro Simidone, prothiocarb, prothioconazole, bronopol, propamocarb-hydrochloride, propiconazole, propineb propineb), probenazole, bromuconazole, flometoquin, hexaconazole, benalaxyl, benalaxyl M (benalaxyl-M), benodanil ( benodanil), benomyl, pefurazoate, penconazole, pencicuron, benzovindiflupyr, benthiazole, benthiavalicab iso propyl (benthiavalicarb-isopropyl), penthiopyrad, penflufen, boscalid, fosetyl (aluminum, calcium, sodium), polyoxin, polycarbamate ( polycarbamate), Bordeaux mixture, mancozeb, mandipropamid, mandestrobin, maneb, myclobutanil, light Mineral oil, mildiomycin, metasulfocarb, metam, metalaxyl, metalaxyl-M, metiram, metcona sol (metconazole), metominostrobin (metominostrobin), metrafenone (metrafenone), mepanipyrim (mepanipyrim), mefentrifluconazole (mefentrifluconazole), meptyldinocap (meptyldinocap), mepronil (mepronil) , iodocarb, laminarin, phosphorous acid and salts, copper oxychloride, silver, cuprous oxide, copper hydroxide hydroxide), potassium bicarbonate, sodium bicarbonate, sulfur, oxyquinoline sulfate, copper sulfate, (3,4-dichloroisothiazol-5-yl ) methyl-4-(tert-butyl)benzoic acid ester (chemical name, CAS registration number: 1231214-23-5), 3-((3,4-dichloroisothiazol-5-yl)methoxy)benzo[d ]Isothiazole-1,1-dioxide (chemical name, CAS registration number: 957144-77-3), BAF-045 (code number), BAG-010 (code number), UK-2A (code number), DBEDC ( Dodecylbenzenesulfonic acid bisethylenediamine copper [II] salt), MIF-1002 (code number), TPTA (triphenyltin acetic acid), TPTC (triphenyltin chloride), TPTH (triphenyltin hydroxide), Non-pathogenic Erwinia Carotobora.

［식물생육조정활성성분］[Plant growth regulation active ingredient]

1-메틸사이클로프로펜(1-methylcyclopropene), 1-나프틸아세트아마이드(1-naphthylacetamide), 2,6-다이아이소프로필나프탈렌(2,6-diisopropylnaphthalene), 4-CPA(4-클로로페녹시아세트산), 벤질아미노퓨린(benzylaminopurine), 안시미돌(ancymidol), 아비글리신(aviglycine), 카르본(carvone), 클로르메쿼트(chlormequat), 클로프로프(cloprop), 클록시포낙(cloxyfonac), 클록시포낙·칼륨염(cloxyfonac-potassium), 사이클라닐라이드(cyclanilide), 사이토키닌(cytokinins), 다미노자이드(daminozide), 디케굴락(dikegulac), 디메티핀(dimethipin), 에테폰(ethephon), 에포콜레온(epocholeone), 에티클로제이트(ethychlozate), 플루메트랄린(flumetralin), 플루레놀(flurenol), 플루르프리미돌(flurprimidol), 포르클로르페누론(forchlorfenuron), 지베렐린(gibberellins), 이나벤파이드(inabenfide), 인돌 아세트산(indole acetic acid), 인돌 부티르산(indole butyric acid), 말레산 하이드라자이드(maleic hydrazide), 메플루이다이드(mefluidide), 메피쿼트 클로라이드(mepiquat chloride), n-데칸올(n-decanol), 파클로부트라졸(paclobutrazol), 프로헥사다이온·칼슘염(prohexadione-calcium), 프로하이드로자스몬(prohydrojasmon), 신토펜(sintofen), 티디아주론(thidiazuron), 트라이아콘타놀(triacontanol), 트라이넥사팍·에틸(trinexapac-ethyl), 운아이코나졸(uniconazole), 운아이코나졸-P(uniconazole-P), 4-옥소-4-(2-페닐에틸)아미노부티르(화학명, CAS 등록번호: 1083-55-2), 과산화칼슘.1-methylcyclopropene, 1-naphthylacetamide, 2,6-diisopropylnaphthalene, 4-CPA, 4-chlorophenoxyacetic acid ), benzylaminopurine, ancymidol, aviglycine, carvone, chlormequat, cloprop, clooxyfonac, cloxifo cloxyfonac-potassium, cyclanilide, cytokinins, daminozide, dikegulac, dimethipin, ethephon , epocholeone, ethychlozate, flumetralin, flurenol, flurprimidol, forchlorfenuron, gibberellins, or benfide, indole acetic acid, indole butyric acid, maleic hydrazide, mefluidide, mepiquat chloride, n- decanol (n-decanol), paclobutrazol, prohexadione-calcium, prohydrojasmon, sintofen, thidiazuron, tri acontanol, trinexapac-ethyl, uniconazole, uniconazole-P, 4-oxo-4- (2-phenylethyl) aminobutyr (Chemical name, CAS registration number : 1083-55-2), calcium peroxide.

본 발명의 입상 농약조성물의 제조방법은, 3-(3,4-다이클로로아이소티아졸-5-일메톡시)-1,2-벤조티아졸-1,1-다이옥사이드를 함유하는 입자 핵을 제조하는 공정, 및 상기 공정에서 얻은 입자 핵의 표면을, 상온에서 결정화되지 않는 당류인 액당을 함유하는 액상물로 피복하여, 상기 입자 핵의 표면에 외층부를 형성시키는 공정을 갖는다. 본 발명의 입상 농약조성물의 제조 방법은, 상기 외층부를 형성시키는 공정 후, 필요에 따라, 농약 활성성분을 상기 외층부에 담지시키는 공정을 더 포함해도 된다.The manufacturing method of the granular pesticide composition of the present invention prepares particle nuclei containing 3-(3,4-dichloroisothiazol-5-ylmethoxy)-1,2-benzothiazole-1,1-dioxide and coating the surface of the particle nuclei obtained in the above step with a liquid containing liquid sugar, which is a saccharide that does not crystallize at room temperature, to form an outer layer portion on the surface of the particle nuclei. The method for producing a granular agricultural chemical composition of the present invention may further include, if necessary, a step of supporting an agrochemical active ingredient on the outer layer portion after the step of forming the outer layer portion.

본 발명의 입상 농약조성물에 있어서, 상기 화합물 A를 함유하는 입자 핵을 제조하는 공정은, 예를 들면 화합물 A를 미분상 고체 담체와의 혼합물로 하고, 상기 혼합물을 교반 혼합 조립법, 전동 조립법, 압출 조립법, 파쇄 조립법, 유동층 조립법, 압축 조립법, 진공 건조 조립법 등의 공지의 조립 방법에 의해 조립물로 함으로써 행해진다.In the granular agrochemical composition of the present invention, the step of producing the particle nuclei containing the compound A is, for example, compound A as a mixture with a fine powdery solid carrier, and the mixture is stirred and mixed granulation method, rolling granulation method, extrusion It is performed by making into a granulated product by well-known granulation methods, such as a granulation method, a crushing granulation method, a fluidized bed granulation method, a compression granulation method, and a vacuum drying granulation method.

상기 공정에서 얻은 입자 핵의 표면을, 액당을 함유하는 액상물로 피복하여, 상기 입자 핵의 표면에 외층부를 형성시키는 공정은, 전형적으로, 먼저 입자 핵을 콘크리트 믹서나, 나우타 믹서 등의 일반적인 혼합기를 이용하여 혼합하면서, 이에 액당을 함유하는 입상물을 투입하여 입자 핵의 표층을 피복함으로써, 외층부를 형성시킨다. 액당을 함유하는 입상물을 투입하여 입자 핵의 표층을 피복하는 것이 곤란한 경우에는, 미리 액상물을 가온 또는 액당에 물 등의 용매를 약간량 첨가하여 액상물의 점성을 저하시킨 후에 투입해도 된다.In the step of coating the surface of the particle nuclei obtained in the above step with a liquid containing liquid sugar to form an outer layer on the surface of the particle nuclei, typically, the particle nuclei are first mixed with a general mixer such as a concrete mixer or Nauta mixer. While mixing using , a granular material containing liquid sugar is added thereto to cover the surface layer of particle nuclei, thereby forming an outer layer portion. When it is difficult to coat the surface layer of particle nuclei by adding the granular material containing liquid sugar, the liquid may be heated in advance or added after a small amount of a solvent such as water is added to the liquid sugar to lower the viscosity of the liquid material.

다음으로, 외층부에 담지시키는 농약 활성성분을 상기 입자 핵 외층부에 담지시키는 공정에서는, 상기 공정에서 얻은 입자 핵 외층부에 농약 활성성분을 투입하여 상기 외층부에 담지시키면 된다. 외층부에 담지시키는 농약 활성성분은, 그대로 사용해도 되지만, 통상 50㎛ 이하, 바람직하게는 10㎛ 이하의 입자 크기로 미리 미분쇄시켜두는 것이 바람직하다. 이러한 미분쇄 수단으로는 공지의 분쇄 장치를 임의로 사용할 수 있으며, 구체적으로는 충격식 분쇄기, 기류식 분쇄기 등을 사용할 수 있지만, 특별히 한정되지 않는다. 또한, 상기 미분쇄시, 외층부에 담지시키는 농약 활성성분은 단독으로 분쇄시켜도 되고, 필요에 따라 미리 상기 보조제 등과 혼합하여, 함께 분쇄시킬 수 있다. 그리고 또한, 농약 활성성분이 액체인 경우에는, 미리 상기 흡유성 미분에 흡착시켜 분말 형태로 조제해도 된다.Next, in the step of supporting the agrochemical active ingredient to be supported on the outer layer on the outer layer of the particle nucleus, the agrochemical active ingredient is added to the outer layer of the particle nucleus obtained in the above step and supported on the outer layer. The agrochemical active ingredient to be supported on the outer layer may be used as it is, but it is usually preferable to pre-pulverize it to a particle size of 50 µm or less, preferably 10 µm or less. A known pulverizing device may be optionally used as such a fine pulverizing means, and specifically, an impact pulverizer, an airflow pulverizer, or the like may be used, but is not particularly limited. In addition, during the fine grinding, the agrochemical active ingredient supported on the outer layer may be pulverized alone, or if necessary, it may be mixed in advance with the auxiliary agent and the like, and pulverized together. In addition, when the agrochemical active ingredient is a liquid, it may be prepared in a powder form by adsorbing it to the oil-absorbing fine powder in advance.

본 발명의 입상 농약조성물은 농약 시용에 있어서의 모든 경우에 적용 가능하지만, 특히 종자의 발아·발근 또는 어린 묘종의 생육 단계에 시용하는 경우, 이른바 파종 육묘기에 있어서 효과적이다. 예를 들어, 논벼 육묘에 있어서의, 육묘 배토(培土) 혼합할 때, 파종 시 복토 전 또는 복토 후, 발아기에서부터 이식 직전까지의 기간이 파종 육묘 시기에 해당한다. 또한, 최근 이식 동시 시용도 개발되어 있으며, 이 분야에의 적용도 가능하다. 또한, 채소 등의 셀트레이 육묘에 있어서도 마찬가지로, 육묘 배토 혼합 시부터 이식 시까지 적용될 수 있으나, 특히 바람직하게는 파종 시 및 발아기 시용이나, 이식 시에 있어서 식혈(植穴) 처리 등을 들 수 있다. 또한 파종 육묘기에서의 재배는, 통상 육묘 배토가 이용되지만, 육묘 매트나 시트 등, 배토 이외의 재배에 있어서도 적용 가능하다.The granular agrochemical composition of the present invention can be applied in all cases in the application of pesticides, but is particularly effective in the so-called seeding and seedling period when applied to the germination and rooting of seeds or the growth stage of young seedlings. For example, in paddy rice seedling, when mixing seedling soil, the period from the germination period to just before transplantation corresponds to the sowing and seedling period before or after cover soiling at the time of sowing. In addition, the simultaneous application of transplantation has recently been developed, and application to this field is also possible. In addition, in cell tray seedlings of vegetables, etc., it can be applied from the time of mixing the seedling soil to the time of transplantation, but particularly preferably, application at the time of sowing and germination, or blood transplantation at the time of transplantation, etc. are mentioned. . In addition, although seedling soil is normally used for cultivation in a sowing and seedling period, it is applicable also in cultivation other than soil, such as a seedling mat and a sheet|seat.

시용 방법으로는, 통상 농약 입제와 마찬가지 방법에 의해서 시용할 수 있으며, 예를 들어, 손으로 직접 산립(散粒)), 인력식 산립기, 전동식 산립기, 등에 메는 형태의 동력식 산립기, 주행형 동력 산립기, 트랙터 탑재형 산립기, 이앙기 탑재형 산립기, 측조 시용용 시약기, 무인 헬기 등의 항공 산립기에 의한 방법 등을 들 수 있다. 또한 논벼 묘종 시용 시에 있어서는, 입상 농약조성물을 소정량 계량해서 취하는 계량 컵으로 퍼내어, 육묘 상자에 뿌리는 방법, 전용의 육묘 상자 살포 용기에 넣고 육묘 상자에 산립하는 방법, 입상 농약조성물의 포장 용기에 형성된 배출구나 구멍 등으로부터 직접 육묘 상자에 산립하는 방법, 동력식 산립기를 이용하여 광범위하게 배치된 다수의 육묘 상자에 산립하는 방법, 파종 작업 시에 전용의 장치에서 육묘 상자에 산립하는 방법, 육묘 토양과 혼합하는 방법 등이 예시된다.As a method of application, it can be applied by the same method as that of normal pesticide granulation, for example, a hand-held granulator), a hand-operated granulator, a motor-operated granulator, etc. and a method by means of an aerial stand such as a traveling power erector, a tractor-mounted granulator, a rice transplanter-mounted granulator, a reagent instrument for side-beaming, and an unmanned helicopter, and the like. In addition, at the time of application of rice seedlings, a method of measuring a predetermined amount of the granular pesticide composition and scooping it out with a measuring cup and sprinkling it in a seedling box, a method of putting it in a dedicated seedling box spraying container and setting it up in a seedling box, packaging of a granular pesticide composition A method of laying in a seedling box directly from an outlet or a hole formed in a container, a method of laying in a large number of seedling boxes widely arranged using a motorized granulator, a method of laying in a seedling box with a dedicated device during sowing operation, The method of mixing with seedling soil, etc. are illustrated.

상기 살포를 적정하게 실시하기 위해서는, 본 발명의 입상 농약조성물의 물리성은 다양한 항목에 대해 각각 일정한 범위 내에 있는 것이 바람직하다. 예를 들어, 겉보기 비중은, 농약 공정 검사법에서 0.3 내지 2가 바람직하고, 보다 바람직하게는 0.5 내지 1.5이다. 입자의 경도는 전농 볼밀법(whole farmer ball mill method)에서 20 이하가 바람직하고, 보다 바람직하게는 10 이하이다. 입도는 메시 개구(mesh opening) 1700㎛의 체를 통과하고, 메시 개구 300㎛인 체를 통과하지 못한 입자가 입상 조성물 전체의 90질량% 이상인 것이 바람직하다.In order to properly carry out the spraying, the physical properties of the granular agrochemical composition of the present invention are preferably within a certain range for various items. For example, 0.3-2 are preferable in the agricultural chemical process inspection method, As for an apparent specific gravity, More preferably, it is 0.5-1.5. The hardness of the particles is preferably 20 or less in the whole farmer ball mill method, and more preferably 10 or less. As for the particle size, it is preferable that the particles that pass through a sieve with a mesh opening of 1700 µm and do not pass through a sieve with a mesh opening of 300 µm are 90% by mass or more of the total granular composition.

또한 입상 농약조성물은, 입자 핵의 형상이 대략 원기둥 형상인 경우에는, 단면 원형의 직경은 보통 0.3 내지 1.7㎜, 바람직하게는 0.5 내지 1.5㎜, 보다 바람직하게는 0.8 내지 1.2㎜이다. 원기둥의 높이에 해당하는 입자 길이는, 단면 원 직경에 대해 0.5 내지 6배인 것이 바람직하지만, 파종 작업 시 전용 장치를 이용하여 살포할 경우, 예를 들어 종자상자 시용약제 살포장치(미선제, 모델 KS-25 : 롤러식 산립기)와 종자 상자 시약 호퍼(스즈텍제, 모델 SDP-33S, SDP-103S : 롤러식 산립기), 포트 육묘용 상자 시약 장치(미노루산업주식회사제, 모델 MPA-21 : 롤러식 산립기)에서 살포하는 경우에는, 단면 원 직경에 대해 2.5배 이상의 입자 길이를 갖는 입자가 입상 조성물 전체의 50질량% 이하인 것이 바람직하고, 보다 바람직하게는 40질량% 이하이다.Further, in the case of the granular agrochemical composition, when the particle nuclei have a substantially cylindrical shape, the cross-sectional circular diameter is usually 0.3 to 1.7 mm, preferably 0.5 to 1.5 mm, more preferably 0.8 to 1.2 mm. The particle length corresponding to the height of the cylinder is preferably 0.5 to 6 times the cross-sectional circle diameter, but when spraying using a dedicated device during sowing, for example, a seed box application agent spraying device (Miseon-made, model KS -25: roller-type granulator) and seed box reagent hopper (manufactured by Suztech, model SDP-33S, SDP-103S: roller-type granulator), pot seedling box reagent device (manufactured by Minoru Industrial Co., Ltd., model MPA-21: roller In the case of spraying with a formula granulator), it is preferable that the particles having a particle length of 2.5 times or more with respect to the cross-sectional circular diameter are 50 mass % or less of the whole granular composition, and more preferably 40 mass % or less.

또한, 본 발명의 입상 농약조성물을 시용할 때의 시용량은, 논이나 밭의 경우, 10아르당 0.1 내지 20kg, 바람직하게는 0.2 내지 5kg이며, 논벼 육묘 상자의 경우, 육묘 상자(일반적으로 0.16㎡) 하나당 10 내지 200g, 바람직하게는 10 내지 100g이다. 또한 셀 트레이에 시용할 때는 셀트레이(128 홀)당 30g 정도의 시용량이면 된다.In addition, the application amount when applying the granular pesticide composition of the present invention is 0.1 to 20 kg per 10 ares, preferably 0.2 to 5 kg, in the case of paddy fields or fields, and in the case of rice seedling boxes, seedling boxes (generally 0.16 m 2 ) 10 to 200 g per one, preferably 10 to 100 g. In addition, when applying to the cell tray, the application amount of about 30 g per cell tray (128 holes) is sufficient.

[실시예][Example]

이하, 본 발명의 구체적인 실시예에 대하여 설명하지만, 본 발명은 이러한 실시예에 한정되는 것은 아니다. 또한, 이하의 실시예, 비교예에서 「부」는 질량 부, 「%」는 질량%를 나타낸다. 또한 「단경」은 대략 원기둥 형상 조립물의 단면 원 직경을, 「애스펙트비」는 대략 원기둥 형상 조립물의 입자 길이를 상기 단경으로 나눈 몫을 가리킨다.Hereinafter, specific examples of the present invention will be described, but the present invention is not limited to these examples. In addition, in the following examples and comparative examples, "part" represents a mass part, and "%" represents mass %. In addition, "minor diameter" refers to the cross-sectional circular diameter of the substantially cylindrical granulated material, and "aspect ratio" refers to the quotient obtained by dividing the particle length of the substantially cylindrical granulated material by the minor diameter.

[실시예 1][Example 1]

화합물 A 2부, 알킬벤젠설폰산염 0.35부, 알파화 전분 3부 및 점토 90.45부에 소정량의 물을 첨가하여 반죽한 후, 구멍 직경 1.2㎜인 스크린을 장착한 바스켓 리유저를 이용해서 압출 조립하고, 조립물을 건조시켜 단경 1.2㎜, 애스펙트비 약 3의 대략 원기둥 형상인 입자 핵을 얻었다. 이 입자 핵 95.8부를 나우타 믹서로 혼합하면서, 환원 당분을 약 50% 함유하는 액당(상품명 닛토 하이 슈트 디럭스, 미츠비시 화학푸드사제) 1.2부를 70℃로 가온한 액상물을 첨가하여 입자 핵의 표층을 피복하여, 입자 핵의 표면에 외층부를 형성시킴으로써, 액당으로 피복된 입자 핵 외층부를 갖는 입상 농약조성물을 얻었다.2 parts of compound A, 0.35 parts of alkylbenzenesulfonate, 3 parts of pregelatinized starch, and 90.45 parts of clay were added to a predetermined amount of water and kneaded, and then extruded and granulated using a basket reuser equipped with a screen with a hole diameter of 1.2 mm. Then, the granulated material was dried to obtain substantially cylindrical particle nuclei with a minor diameter of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of the particle nuclei with a Nauta mixer, 1.2 parts of a liquid sugar (trade name: Nitto High Suit Deluxe, manufactured by Mitsubishi Chemical Foods Co., Ltd.) containing about 50% of reduced sugar is added and heated to 70° C. to cover the surface layer of the particle nuclei. Thus, by forming the outer layer portion on the surface of the particle nucleus, a granular agrochemical composition having the particle nucleus outer layer portion coated with liquid sugar was obtained.

[실시예 2][Example 2]

화합물 A 2부, 알킬벤젠설폰산염 0.35부, 알파화 전분 3부 및 점토 90.45부에 소정량의 물을 첨가하여 반죽한 후, 구멍 직경 1.2㎜인 스크린을 장착한 바스켓 리유저를 이용해서 압출 조립하고, 조립물을 건조시켜, 단경 1.2㎜, 애스펙트비 약 3의 대략 원기둥 형상인 입자 핵을 얻었다. 이 입자 핵 95.8부를 나우타 믹서로 혼합하면서, 환원 당분을 약 50% 함유하는 액당(상품명 닛토 하이 슈트 디럭스, 미츠비시 화학푸드사제) 1.2부에 약간량의 물을 혼합한 액상물을 첨가하여 입자 핵의 표층을 피복하여, 건조에 의해 상기 액상물의 물을 제거해서, 입자 핵의 표면에 외층부를 형성시킴으로써, 액당으로 피복된 상기 입자 핵 외층부를 갖는 입상 농약조성물을 얻었다.2 parts of compound A, 0.35 parts of alkylbenzenesulfonate, 3 parts of pregelatinized starch, and 90.45 parts of clay were added to a predetermined amount of water and kneaded, and then extruded and granulated using a basket reuser equipped with a screen with a hole diameter of 1.2 mm. Then, the granulated material was dried to obtain substantially cylindrical particle nuclei with a minor diameter of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of the particle nuclei with a Nauta mixer, 1.2 parts of a liquid sugar containing about 50% reduced sugar (trade name: Nitto High Suit Deluxe, manufactured by Mitsubishi Chemical Foods Co., Ltd.) and a small amount of water were added to the particle nuclei. A granular agrochemical composition having the particle nucleus outer layer portion coated with liquid sugar was obtained by coating the surface layer, removing water from the liquid product by drying, and forming an outer layer portion on the surface of the particle nucleus.

[실시예 3][Example 3]

실시예 1에서 얻은 입상 농약조성물 97부를 나우타 믹서로 혼합하면서, 기류 식 분쇄기로 미분쇄한 메프로닐 3부를 첨가하여 입자 핵 외층부에 담지시킴으로써, 액당으로 피복된 입자 외층부를 가지며, 상기 입자 핵 외층부에 메프로닐을 담지하는 입상 농약조성물을 얻었다.97 parts of the granular agrochemical composition obtained in Example 1 was mixed with a Nauta mixer, and 3 parts of mepronil finely pulverized with an airflow mill was added and supported on the outer particle nuclei part, thereby having an outer particle layer coated with liquid sugar, the particle nucleus A granular pesticide composition supporting mepronil on the outer layer was obtained.

[실시예 4][Example 4]

실시예 1에서 얻은 입상 농약조성물 97부를 나우타 믹서로 혼합하면서, 습식 분쇄기로 미분쇄한 피리벤카브 3부를 물 7부의 혼합물인 분산액을 첨가하여 입자 핵 외층부에 담지시키고, 건조에 의해 상기 분산액의 물을 제거함으로써, 액당으로 피복된 입자 외층부를 가지며, 상기 입자 핵 외층부에 피리벤카브를 담지하는 입상 농약조성물을 얻었다.While mixing 97 parts of the granular pesticide composition obtained in Example 1 with a Nauta mixer, 3 parts of pyribencarb finely pulverized with a wet grinder is added to the dispersion, which is a mixture of 7 parts of water, supported on the outer layer of the particle nucleus, and the dispersion of the dispersion is dried By removing the water, a granular agrochemical composition having an outer layer of particles coated with liquid sugar and carrying pyribencarb on the outer layer of the nucleus of the particle was obtained.

[실시예 5][Example 5]

실시예 1에서 얻은 입상 농약조성물 97부를 나우타 믹서로 혼합하면서, 기류식 분쇄기로 미분쇄한 벤티아발리카브·아이소프로필 1.5부와 점토 1.5부의 혼합물을 첨가해서 입자 핵 외층부에 담지시킴으로써, 액당에서 피복된 입자 핵 외층부를 가지며, 상기 입자 핵 외층부에 벤티아발리카브·아이소프로필을 담지하는 입상 농약조성물을 얻었다.While mixing 97 parts of the granular pesticide composition obtained in Example 1 with a Nauta mixer, a mixture of 1.5 parts of benthiavalicarb/isopropyl and 1.5 parts of clay finely pulverized with an airflow grinder was added and supported on the outer layer of the particle core, and A granular agrochemical composition having a coated particle nucleus outer layer portion and carrying benthiavalicarb/isopropyl on the particle nucleus outer layer portion was obtained.

[실시예 6][Example 6]

실시예 2에서 얻은 입상 농약조성물 97부를 나우타 믹서로 혼합하면서, 충격식 분쇄기로 미분쇄한 메파니피림 3부를 첨가해서 입자 핵 외층부에 담지시킴으로써, 액당에서 피복된 입자 핵 외층부를 가지며, 상기 입자 핵 외층부에 메파니피림을 담지하는 입상 농약조성물을 얻었다.97 parts of the granular agrochemical composition obtained in Example 2 was mixed with a Nauta mixer, and 3 parts of mepanipyrim finely pulverized with an impact mill was added and supported on the particle core outer layer portion, thereby having an outer particle core outer layer coated with liquid sugar, the particle A granular pesticide composition supporting mepanipyrim on the outer nuclear layer was obtained.

[실시예 7][Example 7]

실시예 2에서 얻은 입상 농약조성물 97부를 나우타 믹서로 혼합하면서, 이프로벤포스 3부를 첨가해서 입자 핵 외층부에 담지시킴으로써, 액당에서 피복된 입자 핵 외층부를 가지며, 상기 입자 핵 외층부에 이프로벤포스를 담지하는 입상 농약조성물을 얻었다.97 parts of the granular agrochemical composition obtained in Example 2 was mixed with a Nauta mixer, and 3 parts of iprovenfos was added and supported on the outer particle nuclei. A granular pesticide composition carrying

[실시예 8][Example 8]

실시예 2에서 얻은 입상 농약조성물 97부를 나우타 믹서로 혼합하면서, 기류식 분쇄기로 미분쇄한 페노티오카브 3부를 첨가해서 입자 핵 외층부에 담지시킴으로써, 액당에서 피복된 입자 핵 외층부를 가지며, 상기 입자 핵 외층부에 펜오티오카브를 담지하는 입상 농약조성물을 얻었다.97 parts of the granular agrochemical composition obtained in Example 2 was mixed with a Nauta mixer, and 3 parts of phenothiocarb finely pulverized with an airflow mill was added and supported on the particle core outer layer portion, thereby having an outer particle core outer layer coated with liquid sugar, and the particle A granular pesticide composition supporting phenothiocarb on the outer nuclear layer was obtained.

[비교예 1][Comparative Example 1]

화합물 A 2부, 알킬벤젠설폰산염 0.35부, 알파화 전분 3부 및 점토 90.45부에 소정량의 물을 첨가하여 반죽한 후, 구멍 직경 1.2㎜인 스크린을 장착한 바스켓 리유저를 이용해서 압출 조립하고, 조립물을 건조시켜 단경 1.2㎜, 애스펙트비 약 3의 대략 원기둥 형상인 입자 핵을 얻었다. 이 입자 핵 95.8부를 나우타 믹서로 혼합하면서, 리그닌설폰산염 1.2부에 약간량의 물을 혼합한 액상물을 첨가하여 입자 핵의 표층을 피복하여, 건조에 의해 상기 액상물의 물을 제거함으로써, 리그닌설폰산염으로 피복된 입자 핵 외층부를 갖는 입상 농약조성물을 얻었다.2 parts of compound A, 0.35 parts of alkylbenzenesulfonate, 3 parts of pregelatinized starch, and 90.45 parts of clay were added to a predetermined amount of water and kneaded, and then extruded and granulated using a basket reuser equipped with a screen with a hole diameter of 1.2 mm. Then, the granulated material was dried to obtain substantially cylindrical particle nuclei with a minor diameter of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of the particle nuclei with a Nauta mixer, a liquid product in which 1.2 parts of lignin sulfonate is mixed with a small amount of water is added to coat the surface layer of the particle nuclei, and the liquid is removed by drying, whereby lignin sulfone A granular agrochemical composition having an outer layer of particle nuclei coated with an acid salt was obtained.

[비교예 2][Comparative Example 2]

화합물 A 2부, 알킬벤젠설폰산염 0.35부, 알파화 전분 3부 및 점토 90.45부에 소정량의 물을 첨가하여 반죽한 후, 구멍 직경 1.2㎜인 스크린을 장착한 바스켓 리유저를 이용해서 압출 조립하고, 조립물을 건조시켜, 단경 1.2㎜, 애스펙트비 약 3의 대략 원기둥 형상인 입자 핵을 얻었다. 이 입자 핵 95.8부를 나우타 믹서로 혼합하면서, 폴리비닐알코올 1.2부에 약간량의 물을 혼합한 액상물을 첨가하여 입자 핵의 표층을 피복하여, 건조에 의해 상기 액상물의 물을 제거함으로써, 폴리비닐알코올으로 피복된 입자 핵 외층부를 갖는 입상 농약조성물을 얻었다.2 parts of compound A, 0.35 parts of alkylbenzenesulfonate, 3 parts of pregelatinized starch, and 90.45 parts of clay were added to a predetermined amount of water and kneaded, and then extruded and granulated using a basket reuser equipped with a screen with a hole diameter of 1.2 mm. Then, the granulated material was dried to obtain substantially cylindrical particle nuclei with a minor diameter of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of the particle nuclei with a Nauta mixer, a liquid product obtained by mixing 1.2 parts of polyvinyl alcohol with a small amount of water is added to cover the surface layer of the particle nuclei, and the water of the liquid is removed by drying. A granular agrochemical composition having an outer layer of particle nuclei coated with alcohol was obtained.

[비교예 3][Comparative Example 3]

화합물 A 2부, 알킬벤젠설폰산염 0.35부, 알파화 전분 3부 및 점토 90.45부에 소정량의 물을 첨가하여 반죽한 후, 구멍 직경 1.2㎜인 스크린을 장착한 바스켓 리유저를 이용해서 압출 조립하고, 조립물을 건조시켜 단경 1.2㎜, 애스펙트비 약 3의 대략 원기둥 형상인 입자 핵을 얻었다. 이 입자 핵 95.8부를 나우타 믹서로 혼합하면서, 폴리부타다이엔 폴리올인 액상물 1.2부를 첨가하여 입자 핵의 표층을 피복함으로써, 폴리부타다이엔 폴리올로 피복된 입자 핵 외층부를 갖는 입상 농약조성물을 얻었다.2 parts of compound A, 0.35 parts of alkylbenzenesulfonate, 3 parts of pregelatinized starch, and 90.45 parts of clay were added to a predetermined amount of water and kneaded, and then extruded and granulated using a basket reuser equipped with a screen with a hole diameter of 1.2 mm. Then, the granulated material was dried to obtain substantially cylindrical particle nuclei with a minor diameter of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of the particle nuclei with a Nauta mixer, 1.2 parts of a liquid substance, which is a polybutadiene polyol, was added to coat the surface layer of the particle nuclei, thereby obtaining a granular agrochemical composition having an outer particle nuclei coated with polybutadiene polyol.

[비교예 4][Comparative Example 4]

화합물 A 2부, 알킬벤젠설폰산염 0.35부, 알파화 전분 3부 및 점토 90.45부에 소정량의 물을 첨가하여 반죽한 후, 구멍 직경 1.2㎜인 스크린을 장착한 바스켓 리유저를 이용해서 압출 조립하고, 조립물을 건조시켜, 단경 1.2㎜, 애스펙트비 약 3의 대략 원기둥 형상인 입자 핵을 얻었다. 이 입자 핵 95.8부를 나우타 믹서로 혼합하면서, 폴리옥시알킬렌 알킬 에터 1.2부인 액상물을 첨가하여 입자 핵의 표층을 피복함으로써, 폴리옥시알킬렌알킬에터로 피복된 입자 핵 외층부를 갖는 입상 농약조성물을 얻었다.2 parts of compound A, 0.35 parts of alkylbenzenesulfonate, 3 parts of pregelatinized starch, and 90.45 parts of clay were added to a predetermined amount of water and kneaded, and then extruded and granulated using a basket reuser equipped with a screen with a hole diameter of 1.2 mm. Then, the granulated material was dried to obtain substantially cylindrical particle nuclei with a minor diameter of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of the particle nuclei with a Nauta mixer, a liquid substance containing 1.2 parts of polyoxyalkylene alkyl ether is added to coat the surface layer of the particle nuclei. got

[비교예 5][Comparative Example 5]

화합물 A 2부, 알킬벤젠설폰산염 0.35부, 알파화 전분 3부 및 점토 90.45부에 소정량의 물을 첨가하여 반죽한 후, 구멍 직경 1.2㎜인 스크린을 장착한 바스켓 리유저를 이용해서 압출 조립하고, 조립물을 건조시켜, 단경 1.2㎜, 애스펙트비 약 3의 대략 원기둥 형상인 입자 핵을 얻었다. 이 입자 핵 95.8부를 나우타 믹서로 혼합하면서, 프탈산 다이아이소데실 1.2부인 액상물을 첨가하여 입자 핵의 표층을 피복함으로써, 프탈산 다이아이소데실로 피복된 입자 핵 외층부를 갖는 입상 농약조성물을 얻었다.2 parts of compound A, 0.35 parts of alkylbenzenesulfonate, 3 parts of pregelatinized starch, and 90.45 parts of clay were added to a predetermined amount of water and kneaded, and then extruded and granulated using a basket reuser equipped with a screen with a hole diameter of 1.2 mm. Then, the granulated material was dried to obtain substantially cylindrical particle nuclei with a minor diameter of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of the particle nuclei with a Nauta mixer, a liquid substance containing 1.2 parts of diisodecyl phthalate was added to coat the surface layer of the particle nuclei, thereby obtaining a granular agrochemical composition having an outer layer of particle nuclei coated with diisodecyl phthalate.

[비교예 6][Comparative Example 6]

화합물 A 2부, 알킬벤젠설폰산염 0.35부, 알파화 전분 3부 및 점토 90.45부에 소정량의 물을 첨가하여 반죽한 후, 구멍 직경 1.2㎜인 스크린을 장착한 바스켓 리유저를 이용해서 압출 조립하고, 조립물을 건조시켜, 단경 1.2㎜, 애스펙트비 약 3의 대략 원기둥 형상인 입자 핵을 얻었다. 이 입자 핵 95.8부를 나우타 믹서로 혼합하면서, 폴리옥시알킬렌알킬에터인산에스터 1.2부인 액상물을 첨가하여 입자 핵의 표층을 피복함으로써, 폴리옥시알킬렌알킬에터인산에스터로 피복된 입자 핵 외층부를 갖는 입상 농약조성물을 얻었다.2 parts of compound A, 0.35 parts of alkylbenzenesulfonate, 3 parts of pregelatinized starch, and 90.45 parts of clay were added to a predetermined amount of water and kneaded, and then extruded and granulated using a basket reuser equipped with a screen with a hole diameter of 1.2 mm. Then, the granulated material was dried to obtain substantially cylindrical particle nuclei with a minor diameter of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of the particle nuclei with a Nauta mixer, 1.2 parts of a polyoxyalkylene alkyl ether phosphate ester is added to coat the surface layer of the particle nuclei, whereby the particle nuclei outer layer is coated with polyoxyalkylene alkyl ether phosphate ester. A granular pesticide composition having parts was obtained.

[비교예 7][Comparative Example 7]

화합물 A 2부, 알킬벤젠설폰산염 0.35부, 알파화 전분 3부 및 점토 90.45부에 소정량의 물을 첨가하여 반죽한 후, 구멍 직경 1.2㎜인 스크린을 장착한 바스켓 리유저를 이용해서 압출 조립하고, 조립물을 건조시켜, 단경 1.2㎜, 애스펙트비 약 3의 대략 원기둥 형상인 입자 핵을 얻었다. 이 입자 핵 95.8부를 나우타 믹서로 혼합하면서, 카복시메틸셀룰로스 1.2부에 약간량의 물을 혼합한 액상물을 첨가하여 입자 핵의 표층을 피복하고, 건조에 의해 상기 액상물의 물을 제거함으로써, 카복시메틸셀룰로스로 피복된 입자 핵 외층부를 갖는 입상 농약조성물을 얻었다.2 parts of compound A, 0.35 parts of alkylbenzenesulfonate, 3 parts of pregelatinized starch, and 90.45 parts of clay were added to a predetermined amount of water and kneaded, and then extruded and granulated using a basket reuser equipped with a screen with a hole diameter of 1.2 mm. Then, the granulated material was dried to obtain substantially cylindrical particle nuclei with a minor diameter of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of the particle nuclei with a Nauta mixer, a liquid substance obtained by mixing 1.2 parts of carboxymethylcellulose with a small amount of water is added to cover the surface layer of the particle nuclei, and the water of the liquid is removed by drying, whereby carboxymethyl A granular agrochemical composition having an outer layer of particle nuclei coated with cellulose was obtained.

[비교예 8][Comparative Example 8]

화합물 A 2부, 알킬벤젠설폰산염 0.35부, 알파화 전분 3부 및 점토 90.45부에 소정량의 물을 첨가하여 반죽한 후, 구멍 직경 1.2㎜인 스크린을 장착한 바스켓 리유저를 이용해서 압출 조립하고, 조립물을 건조시켜, 단경 1.2㎜, 애스펙트비 약 3의 대략 원기둥 형상인 입자 핵을 얻었다. 이 입자 핵 95.8부를 나우타 믹서로 혼합하면서, 메틸셀룰로스 1.2부에 약간량의 물을 혼합한 액상물을 첨가하여 입자 핵의 표층을 피복하고, 건조에 의해 상기 액상물의 물을 제거함으로써, 메틸셀룰로스로 피복된 입자 핵 외층부를 갖는 입상 농약조성물을 얻었다.2 parts of compound A, 0.35 parts of alkylbenzenesulfonate, 3 parts of pregelatinized starch, and 90.45 parts of clay were added to a predetermined amount of water and kneaded, and then extruded and granulated using a basket reuser equipped with a screen with a hole diameter of 1.2 mm. Then, the granulated material was dried to obtain substantially cylindrical particle nuclei with a minor diameter of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of the particle nuclei with a Nauta mixer, a liquid product obtained by mixing 1.2 parts of methylcellulose with a small amount of water is added to cover the surface layer of the particle nuclei, and the liquid is removed by drying to form methylcellulose A granular agrochemical composition having a coated particle nucleus outer layer was obtained.

[비교예 9][Comparative Example 9]

화합물 A 2부, 알킬벤젠설폰산염 0.35부, 알파화 전분 3부 및 점토 90.45부에 소정량의 물을 첨가하여 반죽한 후, 구멍 직경 1.2㎜인 스크린을 장착한 바스켓 리유저를 이용해서 압출 조립하고, 조립물을 건조시켜, 단경 1.2㎜, 애스펙트비 약 3의 대략 원기둥 형상인 입자 핵을 얻었다. 이 입자 핵 95.8부를 나우타 믹서로 혼합하면서, 전분 1.2부에 약간량의 물을 혼합한 액상물을 첨가하여 입자 핵의 표층을 피복하고, 건조에 의해 상기 액상물의 물을 제거함으로써, 전분으로 피복된 입자 핵 외층부를 갖는 입상 농약조성물을 얻었다2 parts of compound A, 0.35 parts of alkylbenzenesulfonate, 3 parts of pregelatinized starch, and 90.45 parts of clay were added to a predetermined amount of water and kneaded, and then extruded and granulated using a basket reuser equipped with a screen with a hole diameter of 1.2 mm. Then, the granulated material was dried to obtain substantially cylindrical particle nuclei with a minor diameter of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of the particle nuclei with a Nauta mixer, a liquid product obtained by mixing 1.2 parts of starch with a small amount of water is added to cover the surface layer of the particle nuclei, and the water of the liquid is removed by drying. A granular agrochemical composition having a particle nucleus outer layer was obtained.

[비교예 10][Comparative Example 10]

화합물 A 2부, 알킬벤젠설폰산염 0.35부, 알파화 전분 3부 및 점토 90.45부에 소정량의 물을 첨가하여 반죽한 후, 구멍 직경 1.2㎜인 스크린을 장착한 바스켓 리유저를 이용해서 압출 조립하고, 조립물을 건조시켜, 단경 1.2㎜, 애스펙트비 약 3의 대략 원기둥 형상인 입자 핵을 얻었다. 이 입자 핵 95.8부를 나우타 믹서로 혼합하면서, 덱스트린 1.2부에 약간량의 물을 혼합한 액상물을 첨가하여 입자 핵의 표층을 피복하고, 건조에 의해 상기 액상물의 물을 제거함으로써, 덱스트린으로 피복된 입자 핵 외층부를 갖는 입상 농약조성물을 얻었다2 parts of compound A, 0.35 parts of alkylbenzenesulfonate, 3 parts of pregelatinized starch, and 90.45 parts of clay were added to a predetermined amount of water and kneaded, and then extruded and granulated using a basket reuser equipped with a screen with a hole diameter of 1.2 mm. Then, the granulated material was dried to obtain substantially cylindrical particle nuclei with a minor diameter of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of the particle nuclei with a Nauta mixer, a liquid product obtained by mixing 1.2 parts of dextrin with a small amount of water is added to coat the surface layer of the particle nuclei, and the water of the liquid is removed by drying. A granular agrochemical composition having a particle nucleus outer layer was obtained.

[비교예 11][Comparative Example 11]

화합물 A2 부, 알킬벤젠설폰산염 0.35부, 알파화 전분 3부 및 점토 90.45부에 소정량의 물을 첨가하여 반죽한 후, 구멍 직경 1.2㎜인 스크린을 장착한 바스켓 리유저를 이용해서 압출 조립하고, 조립물을 건조시켜, 단경 1.2㎜, 애스펙트비 약 3의 대략 원기둥 형상인 입자 핵을 얻었다. 이 입자 핵 95.8부를 나우타 믹서로 혼합하면서, 글리옥실산 0.2부에 약간량의 물을 혼합한 액상물을 첨가하여 입자 핵의 표층을 피복하고, 건조에 의해 상기 액상물의 물을 제거함으로써, 글리옥실산으로 피복된 입자 핵 외층부를 갖는 입상 농약조성물을 얻었다After adding a predetermined amount of water to 2 parts of compound A, 0.35 parts of alkylbenzenesulfonate, 3 parts of pregelatinized starch and 90.45 parts of clay, knead it, and then extrude and assemble using a basket reuser equipped with a screen with a hole diameter of 1.2 mm. , the granulated material was dried to obtain substantially cylindrical particle nuclei with a minor diameter of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of the particle nuclei with a Nauta mixer, a liquid product in which 0.2 parts of glyoxylic acid is mixed with a small amount of water is added to cover the surface layer of the particle nuclei, and the water of the liquid is removed by drying, whereby glyoxyl A granular agrochemical composition having an outer layer of particle nuclei coated with an acid was obtained.

[비교예 12][Comparative Example 12]

화합물 A 2부, 알킬벤젠설폰산염 0.35부, 알파화 전분 3부 및 점토 90.45부에 소정량의 물을 첨가하여 반죽한 후, 구멍 직경 1.2㎜인 스크린을 장착한 바스켓 리유저를 이용해서 압출 조립하고, 조립물을 건조시켜, 단경 1.2㎜, 애스펙트비 약 3의 대략 원기둥 형상인 입자 핵을 얻었다. 이 입자 핵 95.8부를 나우타 믹서로 혼합하면서, 폴리옥시에틸렌알킬아릴에터 1.5부를 첨가하여 입자 핵의 표층을 피복함으로써, 폴리옥시에틸렌알킬아릴에터로 피복된 입자 핵 외층부를 갖는 입상 농약조성물을 얻었다2 parts of compound A, 0.35 parts of alkylbenzenesulfonate, 3 parts of pregelatinized starch, and 90.45 parts of clay were added to a predetermined amount of water and kneaded, and then extruded and granulated using a basket reuser equipped with a screen with a hole diameter of 1.2 mm. Then, the granulated material was dried to obtain substantially cylindrical particle nuclei with a minor diameter of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of the particle nuclei with a Nauta mixer, 1.5 parts of polyoxyethylene alkylaryl ether was added to coat the surface layer of the particle nuclei, thereby obtaining a granular agrochemical composition having an outer layer of particle nuclei coated with polyoxyethylene alkylaryl ether.

[비교예 13][Comparative Example 13]

화합물 A 2부, 알킬벤젠설폰산염 0.35부, 알파화 전분 3부 및 점토 90.45부에 소정량의 물을 첨가하여 반죽한 후, 구멍 직경 1.2㎜인 스크린을 장착한 바스켓 리유저를 이용해서 압출 조립하고, 조립물을 건조시켜, 단경 1.2㎜, 애스펙트비 약 3의 대략 원기둥 형상인 입자 핵을 얻었다. 이 입자 핵 95.8부를 나우타 믹서로 혼합하면서, 폴리옥시에틸렌피마자유에터 1.5부를 첨가해서 입자 핵의 표층을 피복함으로써, 폴리옥시에틸렌피마자유에터로 피복된 입자 핵 외층부를 갖는 입상 농약조성물을 얻었다2 parts of compound A, 0.35 parts of alkylbenzenesulfonate, 3 parts of pregelatinized starch, and 90.45 parts of clay were added to a predetermined amount of water and kneaded, and then extruded and granulated using a basket reuser equipped with a screen with a hole diameter of 1.2 mm. Then, the granulated material was dried to obtain substantially cylindrical particle nuclei with a minor diameter of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of the particle nuclei with a Nauta mixer, 1.5 parts of polyoxyethylene castor oil ether was added to coat the surface layer of the particle nuclei, thereby obtaining a granular agrochemical composition having an outer layer of particle nuclei coated with polyoxyethylene castor oil ether.

[비교예 14][Comparative Example 14]

화합물 A 2부, 알킬벤젠설폰산염 0.35부, 알파화 전분 3부 및 점토 90.45부에 소정량의 물을 첨가하여 반죽한 후, 구멍 직경 1.2㎜인 스크린을 장착한 바스켓 리유저를 이용해서 압출 조립하고, 조립물을 건조시켜, 단경 1.2㎜, 애스펙트비 약 3의 대략 원기둥 형상인 입자 핵을 얻었다. 이 입자 핵 95.8부를 나우타 믹서로 혼합하면서, 폴리옥시에틸렌아릴페닐에터황산염 0.61부에 약간량의 물을 혼합한 액상물을 첨가하여 입자 핵의 표층을 피복함으로써, 건조에 의해 상기 액상물의 물을 제거하고, 폴리옥시에틸렌아릴페닐에터황산염으로 피복된 입자 핵 외층부를 갖는 입상 농약조성물을 얻었다2 parts of compound A, 0.35 parts of alkylbenzenesulfonate, 3 parts of pregelatinized starch, and 90.45 parts of clay were added to a predetermined amount of water and kneaded, and then extruded and granulated using a basket reuser equipped with a screen with a hole diameter of 1.2 mm. Then, the granulated material was dried to obtain substantially cylindrical particle nuclei with a minor diameter of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of the particle nuclei with a Nauta mixer, a liquid obtained by mixing 0.61 parts of polyoxyethylene arylphenyl ether sulfate with a small amount of water is added to coat the surface layer of the particle nuclei, and the water of the liquid is dried by drying. was removed to obtain a granular agrochemical composition having an outer layer of particle cores coated with polyoxyethylene arylphenyl ether sulfate.

[실험예 1][Experimental Example 1]

실시예, 비교예의 입상 농약조성물에 있어서의 화합물 A의 함유율을 고속 액체 크로마토그래피법에 의해 정량하였다. 이어서, 각 조성물을 54℃ 항온에서 14 일간 정치 보관한 후, 마찬가지로 해서 다시 화합물 A의 함유율을 정량하여, 하기 식에 의해 분해율을 구했다. 결과를 표 1에 나타낸다.The content of Compound A in the granular agrochemical compositions of Examples and Comparative Examples was quantified by high performance liquid chromatography. Next, after each composition was left still for 14 days at 54 degreeC constant temperature, the content rate of compound A was quantified again similarly, and the decomposition rate was calculated|required by the following formula. A result is shown in Table 1.

Figure 112018102357809-pct00001
Figure 112018102357809-pct00001

조성물composition 분해율
(%)decomposition rate
(%) 실시예 1Example 1 0.2 0.2 실시예 2Example 2 감소없음no reduction 실시예 3Example 3 0.1 0.1 실시예 4Example 4 0.2 0.2 실시예 5Example 5 감소없음no reduction 실시예 6Example 6 0.2 0.2 실시예 7Example 7 0.4 0.4 실시예 8Example 8 0.3 0.3 비교예 1Comparative Example 1 7.4 7.4 비교예 2Comparative Example 2 19.8 19.8 비교예 3Comparative Example 3 4.0 4.0 비교예 4Comparative Example 4 11.8 11.8 비교예 5Comparative Example 5 2.1 2.1 비교예 6Comparative Example 6 2.0 2.0 비교예 7Comparative Example 7 10.5 10.5 비교예 8Comparative Example 8 6.3 6.3 비교예 9Comparative Example 9 5.7 5.7 비교예 10Comparative Example 10 3.4 3.4 비교예 11Comparative Example 11 10.4 10.4 비교예 12Comparative Example 12 10.8 10.8 비교예 13Comparative Example 13 12.0 12.0 비교예 14Comparative Example 14 11.8 11.8

Claims (8)

입자 핵과, 상기 입자 핵을 피복하는 외층부를 갖는 입상 농약조성물로서,
상기 입자 핵이 3-(3,4-다이클로로아이소티아졸-5-일메톡시)-1,2-벤조티아졸-1,1-다이옥사이드를 함유하며, 그리고
상기 외층부가 상온에서 결정화되지 않는 당류인 액당을 함유하여 이루어지고,
상기 입자 핵이 압출 조립법에 의해 얻어진 조립물이며,
상기 입자 핵이 대략 원기둥형이고, 그 단면 원 직경이 0.5 내지 1.5㎜인,
입상 농약조성물.A granular agrochemical composition having particle nuclei and an outer layer portion covering the particle nuclei,
wherein the particle nucleus contains 3-(3,4-dichloroisothiazol-5-ylmethoxy)-1,2-benzothiazole-1,1-dioxide, and
The outer layer is made by containing liquid sugar, which is a saccharide that does not crystallize at room temperature,
The particle nuclei are granulated products obtained by extrusion granulation,
The particle nuclei are approximately cylindrical and have a cross-sectional circle diameter of 0.5 to 1.5 mm,
granular pesticide composition. 삭제delete 제1항에 있어서,
상기 액당이 환원당을 함유하는 전화형 액당인, 입상 농약조성물.According to claim 1,
The granular agrochemical composition, wherein the liquid sugar is an inversion liquid sugar containing a reducing sugar. 제1항에 있어서,
상기 액당의 함유량이 입상 농약조성물 전체에 대해서 0.5 내지 5질량%인, 입상 농약조성물.According to claim 1,
The granular pesticide composition, wherein the content of the liquid sugar is 0.5 to 5% by mass relative to the whole granular pesticide composition. 제1항에 있어서,
추가로 농약 활성성분을 상기 외층부에 담지하여 이루어진, 입상 농약조성물.According to claim 1,
A granular pesticide composition comprising further supporting an agrochemical active ingredient on the outer layer. 삭제delete 제1항 또는 제3항 내지 제5항 중 어느 한 항에 기재된 입상 농약조성물의 제조 방법에 있어서,
3-(3,4-다이클로로아이소티아졸-5-일메톡시)-1,2-벤조티아졸-1,1-다이옥사이드를 함유하는 입자 핵을 제조하는 공정, 및
상기 공정에서 얻은 입자 핵의 표면을, 상온에서 결정화되지 않는 당류인 액당을 함유하는 액상물로 피복하여, 상기 입자 핵의 표면에 외층부를 형성시키는 공정을 포함하는 것을 특징으로 하는 입상 농약조성물의 제조 방법.In the method for producing the granular agricultural chemical composition according to any one of claims 1 to 5,
A process for preparing particle nuclei containing 3-(3,4-dichloroisothiazol-5-ylmethoxy)-1,2-benzothiazole-1,1-dioxide, and
A granular pesticide composition comprising the step of coating the surface of the particle nuclei obtained in the above step with a liquid containing liquid sugar, which is a saccharide that does not crystallize at room temperature, to form an outer layer portion on the surface of the particle nuclei. Way. 제7항에 있어서,
상기 외층부를 형성시키는 공정 후에, 농약 활성성분을 상기 외층부에 담지시키는 공정을 더 포함하는, 입상 농약조성물의 제조 방법.8. The method of claim 7,
After the step of forming the outer layer portion, the method for producing a granular agricultural chemical composition further comprising a step of supporting the agrochemical active ingredient on the outer layer portion.
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