KR102247527B1 - detergent using a kaffir lime - Google Patents
detergent using a kaffir lime Download PDFInfo
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- KR102247527B1 KR102247527B1 KR1020200002089A KR20200002089A KR102247527B1 KR 102247527 B1 KR102247527 B1 KR 102247527B1 KR 1020200002089 A KR1020200002089 A KR 1020200002089A KR 20200002089 A KR20200002089 A KR 20200002089A KR 102247527 B1 KR102247527 B1 KR 102247527B1
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/143—Sulfonic acid esters
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D13/00—Making of soap or soap solutions in general; Apparatus therefor
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
- C11D3/323—Amides; Substituted amides urea or derivatives thereof
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Abstract
Description
본 발명은 카피르 라임을 이용한 세제 제조방법 및 이로부터 제조된 세제에 관한 것으로써, 카피르 라임에 잎을 열수추출하여 추출된 카피르 라임 추출물을 감압 농축하여 농축액을 만들고 세제에 투입하면서 살균과 박테리아 제거, 방충효과 및 악취제거 효과를 갖는 것을 특징으로 하는 카피르 라임을 이용한 세제 제조방법 및 이로부터 제조된 세제에 관한 것이다. The present invention relates to a detergent manufacturing method using kaffir lime and a detergent prepared therefrom, wherein the kaffir lime extract extracted by hot water extraction of kaffir lime leaves is concentrated under reduced pressure to make a concentrated solution, and sterilization and It relates to a method for preparing a detergent using kaffir lime, which has an effect of removing bacteria, insect repellent, and odor, and a detergent prepared therefrom.
일반적으로 우리 가족과 아이들이 사용하는 식기와 젖병 등을 세정할 때 쓰는 세제는 예민할 수밖에 없다. In general, detergents used for washing dishes and baby bottles used by our family and children are inevitably sensitive.
세제의 세정효과가 좋지 않으면 아무리 꼼꼼하게 식기를 세척한다고 하여도 각종 박테리아와 세균에 노출되어 각종 질병에 감염될 수 있고 특히 면역력이 약한 어린 아이와 같은 경우 질병에 더욱 쉽게 노출되기 쉽다.If the detergent's cleaning effect is not good, no matter how meticulously washing dishes, you can be exposed to various bacteria and germs and infect various diseases. In particular, children with weak immunity are more susceptible to disease.
상기 문제를 해결하기 위하여 종래에는 항균 효과를 갖는 주방용 세정제로 알려진 항균 성분을 포함한 다양한 주방용 세정제가 제조, 판매되었으나, 항균 효과가 뛰어난 세제는 평균적으로 강한 자극적 냄새와 피부접착시 인체에 좋지 않아 주방 세제로 사용되기에는 어려운 문제점이 있었다. In order to solve the above problem, various kitchen cleaners including antibacterial ingredients, which are known as kitchen cleaners with antibacterial effect, have been manufactured and sold in the past, but detergents with excellent antibacterial effect have a strong irritating odor on average and are not bad for the human body when adhered to the skin. There was a problem that was difficult to be used as.
또한, 천연재료 추출물로 만들어 인체에 해롭지 않은 세제가 많이 개발되었다고 하나 상기와 같은 세제는 해롭지는 않으나, 세정력이 많이 떨어져 살균기능을 완벽하게 구현하지 못한 문제가 있었다. In addition, although it is said that a lot of detergents that are made of natural material extracts and are not harmful to the human body have been developed, such detergents are not harmful, but there is a problem that the sterilization function is not fully implemented due to a lot of cleaning power.
또한, 종래의 세제는 무분별한 성분의 사용으로 수질오염문제를 발생시켜 심각하게는 해양생물들이 집단폐사 하는 일도 종종 있었다.In addition, conventional detergents often cause water pollution problems due to the use of indiscriminate ingredients, and seriously, marine organisms often die.
상기 문제점을 해결하기 위하여 본 발명자는 지금까지 활용한 적 없는 카피르 라임 조성물을 이용하여 상기 문제점을 해결하고자 한다. In order to solve the above problem, the present inventor attempts to solve the above problem by using a kaffir lime composition that has not been utilized so far.
본 발명은 상기 기재한 바와 같은 문제점을 해결하기 위해서,The present invention in order to solve the problems as described above,
카피르 라임에 잎을 열수추출하고, 추출한 카피르 라임 추출물을 감압 농축하여 생성된 농축액을 세제에 투입하면서 살균과 박테리아 제거, 방충효과와 악취제거 및 발향효과를 갖는 것을 특징으로 하는 카피르 라임을 이용한 세제 제조방법 및 이로부터 제조된 세제를 제공하는 것을 목적으로 한다.Kaffir lime, characterized in that it has sterilization, bacteria removal, insect repellent effect, odor removal, and scent scent effect, while hot water extracting leaves on kaffir lime and adding the resulting concentrate to a detergent by concentrating the extracted kaffir lime extract under reduced pressure. It is an object of the present invention to provide a method for preparing a detergent used and a detergent prepared therefrom.
상기 목적을 달성하기 위하여 본 발명은 ,In order to achieve the above object, the present invention,
물을 NaOH(수산화나트륨)와 교반하여 완전용해하고 LAS(알킬벤젠설폰네이트)를 투입해 제1혼합물을 만드는 단계와,Water is stirred with NaOH (sodium hydroxide) to completely dissolve, and LAS (alkylbenzene sulfonate) is added to make a first mixture;
상기 제1혼합물에 SLES(라우릴에테르황산나트륨) 과 BETAINE(코코넛아미도프로필베타인), M-AO(알킬디메틸아민옥사이드) 및 AOS (알파올레핀설폰산나륨)을 순서대로 투입하고 30분~45간 교반하여 제2혼합물을 만드는 단계와, SLES (sodium lauryl ether sulfate), BETAINE (coconutamidopropyl betaine), M-AO (alkyldimethylamine oxide), and AOS (sodium alpha olefin sulfonate) were sequentially added to the first mixture, followed by 30 minutes to 45 minutes. A step of making a second mixture by stirring the mixture,
상기 제2혼합물에 카피르 라임 잎 농축액과 CDE-G(코코넛디에탄올아마이드)를 첨가하여 제3혼합물을 만드는 단계와 ,Adding kaffir lime leaf concentrate and CDE-G (coconut diethanolamide) to the second mixture to prepare a third mixture; and
상기 제3혼합물에 파인향 과 EDTA-4Na, UREA 및 구연산을 순서대로 투입하여 20~30분동안 교반 한 후 점도를 측정하여 NaCl(염화나트륨)으로 세제의 적정점도를 유지하는 단계를 포함하는 카피르 라임을 이용한 세제 제조방법을 제공한다. Kaffir comprising the step of sequentially adding pine flavor, EDTA-4Na, UREA, and citric acid to the third mixture, stirring for 20 to 30 minutes, measuring the viscosity, and maintaining the appropriate viscosity of the detergent with NaCl (sodium chloride). Provides a method of manufacturing detergent using lime.
또한, 상기 제조방법으로 제조된 것으로써 ,In addition, as produced by the above manufacturing method,
물 70~90중량%와,NaOH(수산화나트륨),0.1~5중량%와, LAS(알킬벤젠설폰네이트) 1~8중량%와,SLES(라우릴에테르황산나트륨) 0.5~4 중량%와, BETAINE(코코넛아미도 프로필베타인) 0.1~6중량%와,M-AO(알킬디메틸아민옥사이드) 0.1~4중량% 와,AOS(알파올레핀설폰산나트륨)0.5~1.2중량%와,CDE-G(코코넛디에탄올아마이드) 0.1~1중량%와, 카피르라임 잎 농축액 0.1~0.7중량%와, NaCl,0.1~0.3중량% 와, 파인향 0.07~0.015중량%와, EDTA-4Na 0.01~0.03중량%와, UREA(우레아) 0.01~0.03중량% 와, 구연산 0.31~0.75중량% 로 구성되는 카피르라임 세제를 제공한다. 70 to 90% by weight of water, NaOH (sodium hydroxide), 0.1 to 5% by weight, LAS (alkylbenzene sulfonate) 1 to 8% by weight, SLES (sodium lauryl ether sulfate) 0.5 to 4% by weight, BETAINE (Coconutamido propyl betaine) 0.1 to 6% by weight, M-AO (alkyldimethylamine oxide) 0.1 to 4% by weight, AOS (sodium alpha olefin sulfonate) 0.5 to 1.2% by weight, CDE-G ( Coconut diethanolamide) 0.1 to 1% by weight, kaffir lime leaf concentrate 0.1 to 0.7% by weight, NaCl, 0.1 to 0.3% by weight, pine flavor 0.07 to 0.015% by weight, EDTA-4Na 0.01 to 0.03% by weight With, UREA (urea) 0.01 ~ 0.03% by weight and, to provide a kaffir lime detergent consisting of 0.31 ~ 0.75% by weight citric acid.
본 발명은 카피르 라임을 이용한 세제 제조방법 및 이로부터 제조된 세제에 관한 것으로써,The present invention relates to a method for preparing a detergent using kaffir lime and a detergent prepared therefrom,
카피르 라임을 열수추출하여 카피르 라임 추출물을 제조하고 제조된 카피르 라임 추출물을 일정량 감압농축하고 이렇게 생성된 카피르 라임 농축액과 일정량의 물과 완전용해된 NaOH(수산화나트륨) 와 LAS(알킬벤젠설폰네이트)를 혼합하고 상기 혼합물을 중성화하여 세제에 투입하면서 살균과 박테리아 제게 방충효과 및 악취제거 효과를 갖는다, Kaffir lime extract was prepared by hot water extraction of kaffir lime, and the prepared kaffir lime extract was concentrated under reduced pressure, and the resulting kaffir lime concentrate and NaOH (sodium hydroxide) and LAS (alkylbenzene) completely dissolved with a certain amount of water Sulfonate) and neutralize the mixture to have a sterilization and anti-bacterial effect and odor removal effect while being added to a detergent.
또한, 인체에 해롭지 않은 천연재료를 사용함에 있어 피부손상과, 피부트러블와 같은 피부질환을 개선하는 동시에 카피르 라임의 자체의 살균효과,박테리아 제거 효과가 있어 세척력 또한 우수하고 천연재료를 사용함으로 수질오염 또한 개 선할수있다, In addition, when using natural materials that are not harmful to the human body, it improves skin damage and skin diseases such as skin troubles, and at the same time, Kaffir Lime has its own sterilizing effect and bacteria removal effect, so it is excellent in cleaning power and water pollution by using natural materials. It can also be improved,
또한, 카피르 라임은 유효성분인 시트로넬롤과 리모넨에 의해 방충효과를 갖아 벌레와 미생물의 번식을 근본적으로 차단함에 있어 악취와 곰팡이를 제거하고 감귤향이 나는 효과를 갖는다. In addition, kaffir lime has an insect repellent effect by the active ingredients citronellol and limonene, so it has the effect of removing odors and molds and having a citrus scent in fundamentally blocking the reproduction of insects and microorganisms.
이하 본 발명에 따른 카피르 라임을 이용한 세제 제조방법 대해 구체적으로 살펴보도록 한다. Hereinafter, a method for preparing a detergent using kaffir lime according to the present invention will be described in detail.
물을 NaOH(수산화나트륨)와 교반하여 완전용해하고 LAS(알킬벤젠설폰네이트)을 투입해 제1혼합물을 만드는 단계와,Water is stirred with NaOH (sodium hydroxide) to completely dissolve, and LAS (alkylbenzene sulfonate) is added to make a first mixture;
상기 제1혼합물에 SLES(라우릴에테르황산나트륨) 과 BETAINE(코코넛아미도프로필베타인), M-AO(알킬디메틸아민옥사이드) 및 AOS(알파올레핀설폰산나트륨)를 순서대로 투입하고 30분~45분간 교반하여 제2혼합물을 만드는 단계와, SLES (sodium lauryl ether sulfate), BETAINE (coconutamidopropyl betaine), M-AO (alkyldimethylamine oxide), and AOS (sodium alpha olefin sulfonate) were sequentially added to the first mixture, followed by 30 minutes to 45 minutes. Stirring for a minute to make a second mixture, and
상기 제2혼합물에 카피르 라임 잎 농축액과 CDE-G(코코넛디에탄올아마이드)를 첨가하여 제3혼합물을 만드는 단계와,Adding kaffir lime leaf concentrate and CDE-G (coconut diethanolamide) to the second mixture to prepare a third mixture; and
상기 제3혼합물에 파인향과 EDTA-4Na ,UREA 및 구연산을 순서대로 투입하여 20~30분동안 교반한 후 점도를 측정하고 NaCl(염화나트륨)으로 세제의 적정 점도를 유지하는 단계로 만들어진다.Pine flavor, EDTA-4Na, Urea, and citric acid are sequentially added to the third mixture, stirred for 20 to 30 minutes, and then the viscosity is measured and the appropriate viscosity of the detergent is maintained with NaCl (sodium chloride).
. .
이때 상기 세제의 적정 점도는 25℃ 기준 600~1000 cps을 특징으로 한다. At this time, the appropriate viscosity of the detergent is characterized by 600 ~ 1000 cps based on 25 ℃.
또한, 상기 세제의 점도가 600 cps 미만이면 점도가 낮아 세척력의 성능이 In addition, if the viscosity of the detergent is less than 600 cps, the viscosity is low and the cleaning power performance is reduced.
떨어지고 세척시에 물에 쉽게 씻겨져 나가 불편할 수 있고 , It may fall off and be easily washed off with water during washing, which may be inconvenient.
세제의 점도가 1000cps 초과이면 너무 묽고 끈적여 세척 후에 세제 잔여물이 잘 씻겨져 나가지 않아 세제 잔여물이 남을 수 있다.If the viscosity of the detergent exceeds 1000 cps, it may be too thin and sticky, and the detergent residue may not be washed off well after washing, leaving a detergent residue.
또한, 상기 카피르 라임 잎 농축액은 키피르 라임의 잎과 정제수를 100~120℃에 8시간~15시간 열수추출하여 라임 추출물을 추출하고 추출된 0.2~0.5brix의 카피르 라임 잎 추출물을 7~10시간 감압 농축하여 카피르 라임 잎 농축액을 만든다. In addition, the kaffir lime leaf concentrate extracts the lime extract by hot water extraction of the leaves of Kipir lime and purified water at 100 to 120°C for 8 to 15 hours, and extracts 0.2 to 0.5 brix of the kaffir lime leaf extract from 7 to Concentrate under reduced pressure for 10 hours to make a kaffir lime leaf concentrate.
상기 카피르 라임 잎을 100℃ 미만으로 열수추출 하면 열수추출이 제대로 이루어지지 않을 수 있고 120℃를 초과하여 열수추출을 하면 유효성분이 파괴될 수도 있다.If the kaffir lime leaves are extracted with hot water below 100°C, hot water extraction may not be performed properly, and when hot water extraction exceeds 120°C, the active ingredient may be destroyed.
상기 카피르 라임 잎 추출물을 7시간 미만으로 감압 농축하면 농축률이 저하될 수 있고 10시간을 초과하여 농축하면 카피르 라임 잎의 유효성분이 파괴될 수도 있다. When the kaffir lime leaf extract is concentrated under reduced pressure for less than 7 hours, the concentration rate may decrease, and when concentrated for more than 10 hours, the active ingredient of the kaffir lime leaf may be destroyed.
다음으로 본 발명에 따른 카피르 라임 세제에 대해 구체적으로 살펴보도록 한다. Next, let's look at the kaffir lime detergent according to the present invention in detail.
카피르 라임을 이용한 세제는, The detergent using kaffir lime,
물70~90중량%와 70 to 90% by weight of water and
NaOH(수산화나트륨) 0.1~5중량%와 , NaOH (sodium hydroxide) 0.1-5% by weight and,
LAS(알킬벤젠설폰네이트) 1~8중량%와, 1 to 8% by weight of LAS (alkylbenzenesulfonate), and
SLES(라우릴에테르황산나트륨) 0.5~4 중량%와, SLES (sodium lauryl ether sulfate) 0.5 to 4% by weight,
BETAINE(코코넛아미도프로필베타인) 0.1~6중량%와 , BETAINE (coconut amidopropyl betaine) 0.1 to 6% by weight and,
M-AO(알킬디메틸아민옥사이드) 0.1~4중량%와, 0.1 to 4% by weight of M-AO (alkyldimethylamine oxide),
AOS(알파올레핀설폰산나트륨) 0.5~1.2중량%와, 0.5 to 1.2% by weight of AOS (sodium alpha olefin sulfonate),
CDE-G(코코넛디에탄올아마이드) 0.1~1중량%와, 0.1 to 1% by weight of CDE-G (coconut diethanolamide),
카피프 라임 잎 농축액 0.1~0.7중량%와, 0.1 to 0.7% by weight of the kapipe lime leaf concentrate,
NaCl(염화나트륨) 0.1~0.3중량%와, NaCl (sodium chloride) 0.1 to 0.3% by weight,
파인향 0.07~0.015중량%와, 0.07 to 0.015% by weight of pine flavor, and
EDTA-4Na 0.01~0.03중량%와, EDTA-4Na 0.01 to 0.03% by weight,
UREA(우레아) 0.01~0.03중량%와, UREA (urea) 0.01 to 0.03% by weight,
구연산 0.31~0.75중량% 로 혼합 조성한다. The composition is mixed with 0.31 to 0.75% by weight of citric acid.
상기 물은 세제 전체 조성물 대비 70~90중량% 을 함유하고 The water contains 70 to 90% by weight of the total detergent composition,
또한, 전체 조성물 대비 NaOH(수산화나트륨)이 0.1증량% 미만이면 부적절할 수 있고 5중량% 초과이면 알맞지 않다. In addition, if NaOH (sodium hydroxide) is less than 0.1% by weight relative to the total composition, it may be inappropriate, and if it is more than 5% by weight, it is not suitable.
또한, 전체 조성물 대비 LAS(알킬벤젠설폰네이트)가 1~8중량% 초과나 미만이면 부적절할 수 있다. In addition, it may be inappropriate if LAS (alkylbenzene sulfonate) is greater than or less than 1 to 8% by weight relative to the total composition.
또한, 전체 조성물 대비 SLES(라우릴에테르황산나트륨)가 0.5중량% 미만이면 입자의 형성이 잘되지 않아 세제의 세정력이 떨어질 수 있고 4중량%를 초과이면 심하게 끈적일 수 있어 세제 조성물 혼합에 용이하지 않을 수 있다. In addition, if the amount of SLES (sodium lauryl ether sulfate) relative to the total composition is less than 0.5% by weight, the cleaning power of the detergent may be degraded due to poor formation of particles, and if it exceeds 4% by weight, it may be very sticky, making it difficult to mix the detergent composition. I can.
또한, 전체 조성물 대비 BETAINE(코코넛아미도프로필베타인)이 0.1미만이면 거품 형성을 충분히 나타낼 수 없으며 6%를 초과하는 경우에는 다른 성질들의 감소를 초래할 수 있다.In addition, if BETAINE (coconutamidopropyl betaine) relative to the total composition is less than 0.1, foam formation cannot be sufficiently exhibited, and if it exceeds 6%, other properties may be reduced.
또한, 전체 조성물 대비 M-AO(알킬디메틸아민옥사이드)가 0.1중량% 미만이면 항균효과와 세정효과가 떨어지고 4중량% 초과이면 추가함량에 따른 긍정적인 변화가 없다.In addition, when M-AO (alkyldimethylamine oxide) is less than 0.1% by weight of the total composition, the antibacterial effect and cleaning effect are inferior, and when it is more than 4% by weight, there is no positive change according to the additional content.
또한, 전체 조성물 대비 AOS(알파올레핀설폰산나트륨)가 0.5중량% 미만이면 In addition, if AOS (sodium alpha olefin sulfonate) is less than 0.5% by weight of the total composition,
세정력이 좋지 않을 수 있고 1.2중량% 초과이면 피부에 좋지 않은 영향을 줄수 있다. Detergency may be poor, and if it exceeds 1.2% by weight, it may adversely affect the skin.
또한, 전체 조성물 대비 CDE-G(코코넛디에탄올아마이드)가 0.1 중량% 미만이면 거품발생효과와 세척효과 증진 효과가 미미할 수 있고 1중량% 초과이면 추가함량에 따른 긍정적인 뚜렷한 변화가 없다. In addition, if CDE-G (coconut diethanolamide) is less than 0.1% by weight of the total composition, the foaming effect and the effect of improving the washing effect may be insignificant, and if it exceeds 1% by weight, there is no positive change according to the additional content.
또한, 전체 조성물 대비 키피르 라임 잎 농축액은 0.1중량% 미만이면 발향과 , 세척, 방충, 살균 및 박테리아 제거와 같은 효과가 미미할 수 있고 7중량%를 초과하게 되면 다른 성질들의 감소를 초래할 수 있다.In addition, when the Kipir lime leaf concentrate is less than 0.1% by weight of the total composition, effects such as fragrance, washing, insect repellent, sterilization, and bacteria removal may be insignificant, and when it exceeds 7% by weight, other properties may be reduced.
또한, 전체 조성물 대비 NaCl(염화나트륨)은 0.1중량% 미만이면 찌든 때를 제거할 수 있는 효과와 점도를 조절할 수 있는 효과가 미미할 수 있고 0.3 중량% 초과이면 초과함량에 따른 변화가 크지 않아 무의미하다. In addition, if NaCl (sodium chloride) compared to the total composition is less than 0.1% by weight, the effect of removing stains and the effect of adjusting the viscosity may be insignificant, and if it exceeds 0.3% by weight, the change according to the excess content is not large, so it is meaningless.
또한, 전체 조성물 대비 파인향은 0.07중량% 미만이면 살균과 소독의 효과가 미미할수 있고 0.015중량% 를 초과하면 피부에 좋지 않을 수도 있다In addition, if the pine scent relative to the total composition is less than 0.07% by weight, the effect of sterilization and disinfection may be insignificant, and if it exceeds 0.015% by weight, it may not be good for the skin.
또한, 전체 조성물 대비 EDTA-4Na 가 0.01중량% 미만이면 조성물 전체의 안정성과, 균일성을 유지시키는 효과가 미미하고 0.03중량% 초과이면 함량에 증가에 따른 큰 효과가 보이지 않아 경제적으로 유익하지 않다.In addition, if EDTA-4Na is less than 0.01% by weight of the total composition, the effect of maintaining the stability and uniformity of the entire composition is insignificant, and if it exceeds 0.03% by weight, a large effect due to the increase in the content is not seen, which is not economically beneficial.
또한, 전체 조성물 대비 UREA(우레아)가 0.01 미만이면 UREA(우레아)는 세제를 투명하게 하기 위해 세제에 함유하는데 그 효과가 미미할 수 있고 0.03중량% 초과이면 다른 성질들의 감소를 초래할 수 있다.In addition, if UREA (urea) relative to the total composition is less than 0.01, UREA (urea) is contained in the detergent to make the detergent transparent, but its effect may be insignificant, and if it exceeds 0.03% by weight, other properties may be reduced.
또한, 전체 구성물 대비 구연산이 0.31중량% 미만이면 찌꺼기나 물때가 굳어져서 생긴 알칼리성 때를 녹이는 효과가 미미할 수 있고 0.75중량%을 초과하는 경우에는 식초보다 산이 강해 주방도구를 상하게 할 수도 있다.In addition, when citric acid is less than 0.31% by weight of the total composition, the effect of dissolving alkaline grime caused by hardening of debris or scale may be insignificant, and when it exceeds 0.75% by weight, the acid is stronger than vinegar and may damage kitchen utensils.
이하 실시예에 따른 더욱 구체적인 배합예를 살펴보면 다음의 표 1과 같다.Looking at more specific mixing examples according to the following examples are shown in Table 1 below.
[시험예1][Test Example 1]
(살균력 평가)(Evaluation of sterilization power)
상기 실시예 1 내지 4 에 따라 제조한 카피프 라임 세제 조성물에 살모넬라, 이질균을 접종하고 24시간 동안, 40℃에서 방치 후, 살균력을 측정하였다.Salmonella and Shigella were inoculated into the copyprime detergent compositions prepared according to Examples 1 to 4, and left to stand at 40° C. for 24 hours, and sterilizing power was measured.
이때 측정결과는 다음에 표 2에 제시된 평가기준표에 따라 표시된다.At this time, the measurement results are displayed according to the evaluation criteria table shown in Table 2 below.
(( 소취력Deodorant 평가) evaluation)
상기 실시예 1 내지 4 에 따라 제조한 카피르 라임 세제의 악취 평가는 , 악취원으로는 암모니아(암모니아 검지관 사용, 003% 수용액 05 mL 사용), 아민(아민류 검지관 사용, 03 % 수용액 05 mL사용), 머캅탄(머캅탄류 검지관 사용, (0.1벤젠용액, 0.1 mL)를 사용하였다.Evaluation of the odor of the Kaffir Lime detergent prepared according to Examples 1 to 4 was performed as a source of odor: ammonia (using an ammonia detection tube, using a 003% aqueous solution, 05 mL), amine (using an amine detection tube, using a 03% aqueous solution, 05 mL) Use), mercaptan (using a mercaptan detection tube, (0.1 benzene solution, 0.1 mL)) was used.
밀폐된 용기에 상기 실시예 1 내지 2의 제조한 카피프 라임 세제 조성물을 넣고 동량의 악취원을 각각 넣은 후, 일정시간 뒤 소취되지 않은 악취의 잔류량을 검지관에 흡입시켜 잔류 가스 농도를 측정하여 하기의 평가기준에 의해 평가하였다. After putting the prepared copy lime detergent composition of Examples 1 to 2 in a sealed container and putting the same amount of odor sources, respectively, after a certain period of time, the residual amount of odor that was not deodorized was sucked into the detection tube to measure the residual gas concentration. It evaluated according to the following evaluation criteria.
이때 측정결과는 다음에 표 3에 제시된 평가기준표에 따라 표시된다.At this time, the measurement results are displayed according to the evaluation criteria table shown in Table 3 below.
(( 자극정도평가Stimulation level evaluation ))
상기 실시예 1 내지 4에 따라 제조한 카피르 라임 세제 자극정도 평가는 젊고 건강한 토끼 3kg 5마리를 사용하고 투여량은 카피르 라임 세제 0.5ml과 도포부위는 털 깎은 등 부위의 피부이고, 2.5cm×2.5cm의 크기로 하고 도포 방법은 가로세로 2.5cm의 피부에 시험물질을 적용한 후 거즈로 덮고, 거즈를 테잎로 고정하고 거즈 상부에 카피르 라임 세제 증발을 막기 위해 침투성이 없고 반응성이 없는 고형 재질로 덮고 테잎 등을 이용하여 고정하고 카피르 라임 세제 투여 후 24시간 실시하고 피부 자극 정도를 평가한다. Kaffir Lime detergent irritation level evaluation prepared according to Examples 1 to 4 was performed using 5 young and healthy rabbits 3kg, and the dosage was 0.5ml of Kaffir Lime detergent and the application site was the skin of the shaved back area, and 2.5cm ×2.5cm in size, and the application method is to apply the test substance to the skin of 2.5cm in width and length, cover with gauze, fix the gauze with tape, and to prevent evaporation of the kaffir lime detergent on the top of the gauze, it is a non-penetrating and non-reactive solid. Cover with material, fix with tape, etc., and conduct 24 hours after administration of Kaffir Lime detergent, and evaluate the degree of skin irritation.
이때 측정결과는 다음에 표 4에 제시된 평가기준표에 따라 표시된다.At this time, the measurement results are displayed according to the evaluation criteria table shown in Table 4.
상기 제시된 시험예 1 내지 시험예 4 따른 측정결과를 종합하여 살펴보면 다음의 표 5와 같다.A comprehensive look at the measurement results according to Test Examples 1 to 4 presented above is shown in Table 5 below.
살균력과 소취력 및 자극정도에 따른 측정결과를 종합하여 판단한 결과 The result of judging by combining the measurement results according to the sterilizing power, deodorizing power and degree of stimulation
시험예1과 시험예2 ,시험예3 및 시험예4를 비교해 보았을 때 시험예3이 제일 만족스러운 결과를 얻을 수 있었다. When comparing Test Example 1 with Test Example 2, Test Example 3, and Test Example 4, Test Example 3 was able to obtain the most satisfactory results.
즉 제일 바람직하게는 실시예3와 같이 물 85.5중량%과, NaOH(수산화나트륨)0.8중량%과 , LAS(알킬벤젠설폰네이트) 8중량% 와 , SLES(라우릴에테르황산나트륨) 2중량% 와 BETAINE(코코넛아미도프로필베타인) 0.5중량%와 ,M-AO( 알킬디메틸아민옥사이드) 0.5%중량와 , AOS(알파올레핀설폰산나트륨) 0.7중량%와 , CDE-G(코코넛디에탄올아마이드) 0.8중량%와 , 카피르라임 농축액 0.4중량%와, NaCl(염화나트륨) 0.3중량%와 , 파인향 0.01중량%와 EDTA-4Na 0.02중량%와, UREA(우레아) 0.02중량% 및 구연산 0.45중량% 로 구성된 카피르 라임을 제작하는 것이다. That is, most preferably, as in Example 3, 85.5% by weight of water, 0.8% by weight of NaOH (sodium hydroxide), 8% by weight of LAS (alkylbenzene sulfonate), and 2% by weight of SLES (sodium lauryl ether sulfate) and BETAINE 0.5% by weight of (coconutamidopropylbetaine) and 0.5% by weight of M-AO (alkyldimethylamine oxide), 0.7% by weight of AOS (sodium alpha olefin sulfonate) and 0.8% by weight of CDE-G (coconut diethanolamide) % And, a copy consisting of 0.4% by weight of kaffirlime concentrate, 0.3% by weight of NaCl (sodium chloride), 0.01% by weight of pine flavor and 0.02% by weight of EDTA-4Na, 0.02% by weight of UREA (urea) and 0.45% by weight of citric acid It is to make Le Lime.
현대인들의 세제를 고르는 기준은 인체에 무해함과, 세척력, 살균력, 및 역한 냄새가 나지 않는 것으로 미루어 보았을 때 본 발명은 상기와 같은 문제를 모두 개선할 수 있고 더 나아가 방충효과와 박테리아 제거 효과 및 특유의 감귤 향기를 갖아 산업성 이용가능성이 매우크다. Considering that modern people's criteria for selecting detergents are harmless to the human body, cleansing power, sterilization power, and no unpleasant odor, the present invention can improve all of the above problems, and furthermore, the insect repellent effect and the bacteria removal effect and peculiarity It has a citrus scent of, so it is highly industrially available.
Claims (5)
상기 제1혼합물에 SLES(라우릴에테르황산나트륨)과 BETAINE(코코넛아미도프로필베타인), M-AO(알킬디메틸아민옥사이드) 및 AOS(알파올레핀설폰산나트륨) 순서대로 투입하고 30 ~ 45분간 교반하여 제2혼합물을 만드는 단계와,
상기 제2혼합물에 카피르 라임 잎 농축액과 CDE-G(코코넛디에탄올아마이드)를 첨가하여 제3혼합물을 만드는 단계와,
상기 제3혼합물에 파인향, EDTA-4Na ,UREA 및 구연산을 순서대로 투입하여 20 ~ 30분동안 교반한 후 점도를 측정하여 NaCl(염화나트륨)로 세제의 적정 점도를 유지하는 단계를 포함하는 것에 있어서,
상기 세제는,
물 85.5중량%과, NaOH(수산화나트륨) 0.8중량%과, LAS(알킬벤젠설폰네이트) 8중량%와, SLES(라우릴에테르 황산나트륨) 2중량%와, BETAINE(코코넛아미도프로필베타인) 0.5중량%와, M-AO(알킬디메틸아민옥사이드) 0.5중량%와, AOS(알파올레핀설폰산나트륨) 0.7중량%와, CDE-G(코코넛디에탄올아마이드) 0.8중량%와, 카피르라임 잎 농축액 0.4중량%와, NaCl(염화나트륨) 0.3중량%와, 파인향 0.01중량%와, EDTA-4Na 0.02중량%와, UREA(우레아) 0.02중량% 및 구연산 0.45중량%로 구성된 적정점도 25℃ 기준 600 ~ 1000 cps의 세제인 것이고,
상기 카피르 라임 잎 농축액은,
카피르 라임 잎과 정제수를 100 ~ 120 ℃에 8시간 ~ 15시간 열수추출하여 라임 추출물을 추출하고, 상기 추출된 0.2 ~ 0.5 brix의 카피르 라임 잎 추출물을 7 ~ 10시간 감압 농축하여 제조된 것을 특징으로 하는 카피르 라임을 이용한 세제 제조방법.
Water is stirred with NaOH (sodium hydroxide) to completely dissolve, and LAS (alkylbenzene sulfonate) is added to make a first mixture;
SLES (sodium lauryl ether sulfate), BETAINE (coconutamidopropyl betaine), M-AO (alkyldimethylamine oxide) and AOS (sodium alpha olefin sulfonate) were added in the order to the first mixture and stirred for 30 to 45 minutes. To make a second mixture,
Adding kaffir lime leaf concentrate and CDE-G (coconut diethanolamide) to the second mixture to prepare a third mixture,
Including the step of maintaining the proper viscosity of the detergent with NaCl (sodium chloride) by measuring the viscosity after adding pine flavor, EDTA-4Na, Urea and citric acid in order to the third mixture and stirring for 20 to 30 minutes. ,
The detergent,
Water 85.5% by weight, NaOH (sodium hydroxide) 0.8% by weight, LAS (alkylbenzene sulfonate) 8% by weight, SLES (sodium lauryl ether sulfate) 2% by weight, BETAINE (coconutamidopropylbetaine) 0.5 Wt%, M-AO (alkyldimethylamine oxide) 0.5 wt%, AOS (sodium alpha olefin sulfonate) 0.7 wt%, CDE-G (coconut diethanolamide) 0.8 wt%, and kaffir lime leaf concentrate Appropriate viscosity consisting of 0.4% by weight, 0.3% by weight of NaCl (sodium chloride), 0.01% by weight of pine flavor, 0.02% by weight of EDTA-4Na, 0.02% by weight of UREA (urea), and 0.45% by weight of citric acid 600 ~ 1000 cps detergent,
The kaffir lime leaf concentrate,
The lime extract was extracted by hot water extraction of kaffir lime leaves and purified water at 100 to 120° C. for 8 to 15 hours, and the extracted 0.2 to 0.5 brix kaffir lime leaf extract was concentrated under reduced pressure for 7 to 10 hours. Detergent manufacturing method using kaffir lime, characterized in that.
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