KR102016794B1 - Method Of Producing Antibacterial and Deodorizing Fabrics Having Excellent Stretch And Comfortness - Google Patents

Method Of Producing Antibacterial and Deodorizing Fabrics Having Excellent Stretch And Comfortness Download PDF

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KR102016794B1
KR102016794B1 KR1020170122203A KR20170122203A KR102016794B1 KR 102016794 B1 KR102016794 B1 KR 102016794B1 KR 1020170122203 A KR1020170122203 A KR 1020170122203A KR 20170122203 A KR20170122203 A KR 20170122203A KR 102016794 B1 KR102016794 B1 KR 102016794B1
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yarn
inorganic
dty
fabric
polyester
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KR1020170122203A
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KR20190033712A (en
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김희진
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(주)영원코포레이션
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    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/56—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads elastic
    • D03D15/08—
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/26—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre with characteristics dependent on the amount or direction of twist
    • D02G3/28—Doubled, plied, or cabled threads
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/38—Threads in which fibres, filaments, or yarns are wound with other yarns or filaments, e.g. wrap yarns, i.e. strands of filaments or staple fibres are wrapped by a helically wound binder yarn
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/13—Physical properties anti-allergenic or anti-bacterial

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Artificial Filaments (AREA)
  • Woven Fabrics (AREA)

Abstract

본 발명은 무기물함유 폴리에스테르 DTY사를 사용하여 항균소취성능을 발휘하면서도 신축성이 우수하고 착용시 쾌적성이 우수한 하계용 원단의 제조방법에 관한 것이다.The present invention relates to a method for producing a summer fabric using excellent inorganic stretch-containing polyester DTY yarn while exhibiting antibacterial deodorizing performance and excellent comfort when worn.

Description

신축성 및 쾌적성이 우수한 하계용 항균소취원단의 제조방법{Method Of Producing Antibacterial and Deodorizing Fabrics Having Excellent Stretch And Comfortness}Method of Producing Antibacterial and Deodorizing Fabrics Having Excellent Stretch And Comfortness

본 발명은 무기물함유 폴리에스테르 DTY사를 사용하여 항균소취성능을 발휘하면서도 신축성이 우수하고 착용시 쾌적성이 우수한 원단의 제조방법에 관한 것이다.The present invention relates to a method for manufacturing a fabric having excellent elasticity and excellent comfort when worn while using an inorganic-containing polyester DTY yarn.

섬유는 인체의 땀과 직접 접촉하기 때문에 다량의 암모니아 발생으로 인한 불쾌한 냄새 문제를 일으킬 수 있으며, 인체에 유해한 미생물이 섬유 제품에 부착되어 각종 질병을 유발할 수 있다. 이와 같이 섬유 제품이 유해 미생물로부터 변색 취화되거나 각종 악취로부터 오염되는 것을 예방하기 위하여, 섬유 제품에 세균이나 곰팡이 등의 미생물이 서식하거나 번식되는 것을 억제시키기 위한 항균성 및 항곰팡이성 방취 가공을 수행하게 된다. Since the fiber is in direct contact with the sweat of the human body, it may cause an unpleasant odor problem due to the generation of ammonia, and microorganisms harmful to the human body may be attached to the fiber product and cause various diseases. As described above, in order to prevent discoloration embrittlement from harmful microorganisms or contamination from various odors, antimicrobial and antifungal deodorization processing is performed to suppress the growth or propagation of microorganisms such as bacteria and fungi in the fiber products. .

여기서 항균성이라 함은 세균의 번식을 억제하고 살균시키는 성질을 말하며, 항곰팡이성이라 함은 곰팡이의 번식을 억제하고 곰팡이를 죽임으로써 악취의 발생을 없애는 성질, 즉 소취성과 탈취성을 말한다.Here, the antimicrobial refers to the property of inhibiting and sterilizing the growth of bacteria, and the antifungal refers to the property of eliminating the occurrence of odor by inhibiting the growth of mold and killing the mold, that is, deodorant and deodorant.

항균 방취 가공 방법으로 통상적으로는 은, 구리, 아연, 산화은 및 산화아연과 같은 무기화합물을 도포하거나 염화 벤질과 같은 유기 화합물을 도포하는 방법 등이 려져 있다. 그러나 이와 같은 항균성 화합물로 된 위생 가공제들은 섬유에 유기적으로 접착되지 못하는 문제와 세탁에 따른 내구성에 문제가 있다As an antibacterial and deodorizing processing method, a method of coating inorganic compounds such as silver, copper, zinc, silver oxide, and zinc oxide, or applying organic compounds such as benzyl chloride is usually used. However, sanitary processing agents made of such antimicrobial compounds have problems of organic adhesion to fibers and durability of washing.

이에 섬유의 방사시에 항균작용을 하는 무기입자를 함유시켜 방사하는 다수의 방법이 개발되었다. 대한민국공개특허제10-2011-0044478호에서는 코어성분으로 알칼리 이용출성 폴리에스테르계 폴리머를 공급하고, 쉬쓰성분으로 유기화된 몬모릴로나이트 2~10중량%, 커플링제 0.5∼5 중량% 및 잔부로서 나일론 6 수지를 포함하는 개질 폴리아마이드계 폴리머 90~99중량%와 이산화티탄, 탄산칼슘 및 이산화실리카 중에서 선택된 1종이상의 무기입자가 포함된 알칼리 이용출성 폴리에틸렌테레프탈레이트 또는 폴리랙타이드 폴리머인 이용출성 폴리에스테르계 폴리머를 혼합하여 공급하여 쉬쓰/코어형 복합필라멘트를 제공하고 있다.Accordingly, a number of methods for spinning by containing inorganic particles that act as antibacterial agents during the spinning of fibers have been developed. Korean Patent Application Publication No. 10-2011-0044478 discloses an alkali-elutable polyester polymer as a core component, and 2 to 10 wt% of montmorillonite organicated as a sheath component, 0.5 to 5 wt% of a coupling agent, and nylon 6 resin as the balance. A water-soluble polyester polymer which is an alkali-soluble polyethylene terephthalate or a polylactide polymer containing 90 to 99% by weight of a modified polyamide-based polymer and at least one inorganic particle selected from titanium dioxide, calcium carbonate and silica Is supplied by mixing to provide sheath / core composite filament.

또한, 대한민국공개특허제10-2015-0120005호에서는 탄소화합물 25~95 중량%와 산화제일철, 산화제이철 및 사산화삼철로 이루어진 군 중에서 선택되는 적어도 어느하나로서 구형도 0.5 이상의 구형입자로 이루어진 산화철화합물 5~75 중량%로 구성되고 입자크기가 10 ㎚~100㎛이며 주파수 300 ㎒~300 ㎔의 장파장 파에 의해 발열하는 산화철-탄소 조성물이 섬유의 1~10 중량% 함유되어 있으며, 상기 산화철-탄소 조성물은 산화 알루미늄, 산화칼슘, 산화마그네슘, 산화아연, 이산화망간, 이산화규소 및 이산화티탄으로 이루어진 군 중에서 선택되는 적어도 어느 하나의 금속산화물을 조성물 전체중량 기준 1~50 중량%더 포함하는 광에 의해 발열하는 항균섬유를 제공하고 있다.In addition, Korean Patent Laid-Open Publication No. 10-2015-0120005 has at least one selected from the group consisting of 25 to 95% by weight of a carbon compound and ferric oxide, ferric oxide, and triiron tetraoxide, and an iron oxide compound 5 to 5 composed of spherical particles having a sphericity of 0.5 or more. The iron oxide-carbon composition composed of 75% by weight and having a particle size of 10 nm to 100 µm and generating heat by a long wavelength wave having a frequency of 300 MHz to 300 Hz contains 1 to 10% by weight of the fiber. Antibacterial to generate heat by light containing at least one metal oxide selected from the group consisting of aluminum oxide, calcium oxide, magnesium oxide, zinc oxide, manganese dioxide, silicon dioxide and titanium dioxide, based on the total weight of the composition Providing fiber.

그러나 상기 선행기술에 의한 항균섬유를 사용하여 제직하는 경우 직물의 신축성이 충분하다 할 수 없고, DTY 특유의 달라붙는 듯한 유연함에 의해 착용시, 촉감이 나쁜 문제점을 안고 있어 의류용 직물에는 적용하기가 쉽지 않은 문제점이 있었다.However, when weaving using the antimicrobial fiber according to the prior art, the elasticity of the fabric can not be sufficient, and due to the softness of the DTY peculiar to stick, there is a bad touch when worn, it is difficult to apply to clothing fabrics There was a problem that was not easy.

대한민국공개특허제10-2011-0044478호(2011년04월29일 공개)Republic of Korea Patent Publication No. 10-2011-0044478 (published April 29, 2011) 대한민국공개특허제10-2015-0120005호(2015년10월27일 공개)Republic of Korea Patent Publication No. 10-2015-0120005 (published 27 October 2015)

그러므로 본 발명에서는 항균, 소취성능을 가지면서도 신축성이 우수하고 착용시 쾌적성이 우수한 원단을 제공하여 가슬가슬한 촉감과 신축 쾌적성을 가지는 여름철용 원단을 제공하여 작업복, 단체복(경찰복) 등 고온다습의 열악한 환경용 하복지에 사용할 수 있는 직물을 제공하는 것을 기술적과제로 한다.Therefore, in the present invention, by providing a fabric with excellent anti-bacterial, deodorant performance and excellent elasticity and comfortable comfort when worn to provide a summer fabric having a stiff touch and stretch comfort, such as work clothes, group clothes (police clothes) It is a technical task to provide a fabric that can be used in a low-humid environment for high humidity.

그러므로 본 발명에 의하면, 경사로서 무기물함유 폴리에스테르 DTY사를 사이징작업을 하지않고 연사하여 사용하고, 위사로서 무기물함유 폴리에스테르DTY/스판덱스사의 커버링사를 사용하여 제직하는 것을 특징으로 하는 신축성 및 쾌적성이 우수한 항균소취원단의 제조방법이 제공된다. Therefore, according to the present invention, elasticity and comfort, characterized in that weaving using inorganic D-containing polyester DTY yarn as a warp without sizing, and weaving using inorganic-containing polyester DTY / spandex yarn as a weft yarn Provided is a method for producing this excellent antibacterial deodorant fabric.

이하 본 발명을 보다 상세히 설명하기로 한다.Hereinafter, the present invention will be described in more detail.

본 발명은 무기물함유 폴리에스테르사를 사용하여 항균소취성능을 발휘하면서도 신축성이 우수하고 착용시 쾌적성이 우수한 원단의 제조방법에 관한 것이다.The present invention relates to a method for producing a fabric having excellent elasticity and excellent comfort when worn while exhibiting antibacterial deodorizing performance using inorganic-containing polyester yarn.

본 발명에서는 경사로서 무기물함유 폴리에스테르 DTY사를 사이징작업을 하지 않고 연사하여 사용하고, 위사로서 무기물함유 폴리에스테르사/스판덱스사의 커버링사를 사용하여 제직하게 된다.In the present invention, the yarn-containing polyester DTY yarn is used as a warp yarn without sizing, and the weaving yarn is woven using a covering yarn of the mineral-containing polyester yarn / spandex yarn.

상기 경사 및 위사에 공통적으로 함유되는 무기물함유 폴리에스테르사는 폴리에스테르사에 TiO2 2~5중량% 및 ZnO 0.5~1중량%를 함유한 무기물함유 폴리에스테르사를 사용하게 된다. 본 발명의 상기 무기물함유 폴리에스테르사는 사내부에 TiO2 2~5중량% 및 ZnO 0.5~1중량%를 함유하여 항균, 소취능력이 우수한 특성을 가지나, 사자체의 신도 및 신축회복력이 그다지 뛰어나지 않다. 또한, 상기 무기물함유 폴리에스테르사는 DTY의 형태로 주로 사용하고 있는데, DTY 특유의 포근한 촉감이 하계 기후하에서는 피부에 달라붙어 불쾌감을 일으키는 단점을 안고 있다 하겠다.Inorganic-containing polyester yarns commonly contained in the warp and weft yarns are inorganic yarn-containing polyester yarns containing 2-5 wt% TiO 2 and 0.5-1 wt% ZnO in polyester yarn. The inorganic-containing polyester yarn of the present invention contains 2-5% by weight of TiO 2 and 0.5-1% by weight of ZnO, and has excellent antibacterial and deodorizing properties, but the elongation and elasticity recovery of the lion body is not very good. . In addition, the inorganic-containing polyester yarn is mainly used in the form of DTY, the soft touch unique to the DTY will have the disadvantage of causing discomfort to stick to the skin under the summer climate.

따라서 본 발명에서는 상기무기물함유 폴리에스테르 DTY사를 사용하되 경사와 위사에 각각 상이한 조합의 실을 사용하여 제조된 직물이 신축성이 우수하고 착용시 쾌적성이 우수하도록 하는데 그 주안점이 있다.Therefore, in the present invention, the inorganic polyester-containing polyester DTY yarn, but the fabric produced by using a different combination of yarns for warp and weft yarn, respectively, has excellent elasticity and excellent comfort when worn.

우선, 경사로서 무기물함유 폴리에스테르 DTY사를 사이징작업을 하지 않고 연사하여 사용하게 되는데, 본 발명의 상기 무기물함유 폴리에스테르사를 경사로 사용할 때 사이징을 하게 되면 피부와의 접촉 면적이 커져, 의복 착용시 원단이 몸에 들러붙는 등 쾌적성이 저하되므로 본 발명에서는 사이징(가호)공정을 행하지 않고 적정 연수를 부여하는 연사공정을 통하여 쾌적성을 부여하게 된다. 상기 경사로는 DTY형태로 가공한 것을 사용하여 직물태를 향상시킬 수도 있다.First of all, the inorganic yarn-containing polyester DTY yarn is used as a warp yarn without sizing, but when the inorganic yarn-containing polyester yarn of the present invention is used as a warp yarn, the contact area with the skin becomes large, and the clothing is worn. Since comfort is impaired, such as a fabric sticking to the body, in the present invention, comfort is imparted through a twisting step of imparting proper training without performing a sizing (protection) step. The ramp may be processed in the form of DTY to improve the weave.

특히 상기 경사인 무기물함유 폴리에스테르사는 800~1200 TM(75d.의 경우)의 꼬임수를 가지는 강연사를 사용하는 것이 쾌적성 측면에서 바람직하다.In particular, it is preferable to use a twisted yarn having a twist number of 800 ~ 1200 TM (75d.) Of the inclined inorganic material polyester yarn in terms of comfort.

또한 본 발명에서는 위사로서 무기물함유 폴리에스테르사/스판덱스사의 커버링사를 사용하여 신축성을 향상시키게 되는데, 상기 위사인 무기물함유 폴리에스테르사/스판덱스사의 커버링사는 폴리에스테르사 75~150d/36~72fila가 스판덱스사 40~50d의 주위로 500~600T/M으로 커버링된 커버링사를 사용하는 것이 바람직하다.In addition, the present invention is to improve the elasticity by using a covering yarn of inorganic material polyester / spandex yarn as the weft yarn, the covering yarn of the inorganic material polyester yarn / spandex yarn of the weft polyester polyester 75 ~ 150d / 36 ~ 72fila is spandex It is preferable to use a covering yarn covered at 500 to 600 T / M around the yarn 40 to 50 d.

400T/M 미만에서는 꼬임불량, 스판덱스의 표면 돌출 등의 문제점이 발생할 수 있으며, 600T/M을 초과하는 경우에는 필라멘트 끊어짐, 집속성의 차이로 인한 필라멘트 분리현상, 모우 발생, 커버링사의 터치감 불량의 문제점이 발생할 수 있으므로 꼬임수의 조절이 필요하다.If it is less than 400T / M, problems such as twisting or spandex surface protruding may occur, and if it exceeds 600T / M, filament breakage, filament separation due to the difference in focusing ability, moor occurrence, poor touch feeling of covering yarn Problems can arise, so it is necessary to adjust the number of twists.

상기와 같이 경사 및 위사를 엄정하여 제직하게 되면, 항균, 소취능력이 우수한 특성을 가지면서도 경사방향의 원사가 발휘하는 청량감과 함께 위사 부분이 갖는 신축성으로 인하여, 착용시 쾌적성이 우수한 직물을 제공할 수 있게 되는 것이다. When weaving the warp and weft strictly as described above, the fabric has excellent antibacterial and deodorizing ability, but also provides a comfortable fabric when worn due to the elasticity of the weft part along with the refreshing feel of the yarn in the warp direction. You can do it.

그러므로 본 발명에 의하면, 항균 소취능력 및 자외선차단율이 우수하면서도 가슬가슬한 촉감과 신축 쾌적성을 가지는 여름철용 원단을 제공하여 작업복, 단체복(경찰복) 등 고온다습의 열악한 환경용 하복지에 사용할 수 있는 효과가 있다.Therefore, according to the present invention, by providing a summer fabric having excellent antibacterial deodorizing ability and UV blocking rate, but with a stiff feel and stretch comfort, it can be used in poor environment for high temperature and high humidity such as work clothes, group clothes (police clothes), etc. It has an effect.

다음의 실시예에서는 본 발명의 신축성 및 쾌적성이 우수한 항균소취원단을 제조하는 비한정적인 예시를 하고 있다.In the following examples are non-limiting examples of producing an antibacterial deodorant fabric excellent in elasticity and comfort of the present invention.

[실시예 1]Example 1

TiO2 2중량%, ZnO 0.5중량% 함유하는 무기물함유 폴리에스테르 DTY(75d/36f, 성안합섬사산)를 구입하여 경사로는 75d/36f Z 1000TM 강연사로 준비하고, 위사로는 무기물함유 폴리에스테르 DTY(75d/36f, 성안합섬사산)와 스판덱스 40d의 커버링사(550T/M)를 사용하여 성폭 74인치로 제직하여 60인치로 염색 가공하였고, 완성된 원단의 물성을 측정하여 표 1에 나타내었다.2 wt% TiO 2 and 0.5 wt% ZnO were purchased to prepare inorganic DTY (75d / 36f, Sungshap Synthetic Co., Ltd.). 75d / 36f, Seongsaeseomsa) and spandex 40d covering yarn (550T / M) was woven with a width of 74 inches and dyed to 60 inches, and measured the physical properties of the finished fabric is shown in Table 1.

구 분division 실시예 1Example 1 비 고Remarks 신축회복율(5)New recovery rate (5) 위방향 97%97% up KSK0508KSK0508 신도(%)Elongation (%) 위방향 15%15% up 치수변화율(%)Dimensional rate of change (%) 3% 이내Within 3% KSK ISO 5077:2014KSK ISO 5077: 2014 항균성(%)Antimicrobiality (%) 99.999.9 KSK 0693
폐렴균, 포도상구균 대상KSK 0693
Pneumococcal, staphylococcus target 소취성(%)Deodorant (%) 65%65% 가스검지관법Gas detection tube method

Claims (3)

경사로서 폴리에스테르사에 TiO2 2~5중량% 및 ZnO 0.5~1중량%를 함유한 무기물함유 폴리에스테르DTY사를 사이징작업을 하지않고 800~1200 TM의 꼬임수를 가지도록 연사하여 사용하고, 위사로서 폴리에스테르사 75~150d/36~72fila가 스판덱스사 40d의 주위로 400~600T/M으로 커버링된 무기물함유 폴리에스테르DTY/스판덱스사의 커버링사를 사용하여 제직하는 것을 특징으로 하는 신축성 및 쾌적성이 우수한 하계용 항균소취원단의 제조방법. Insulating polyester DTY yarn containing 2-5% by weight of TiO 2 and 0.5-1% by weight of ZnO as a warp yarn to be twisted to have a twist number of 800-1200 TM without sizing. Elasticity and comfort characterized by weaving polyester yarn 75 ~ 150d / 36 ~ 72fila as the weft yarn using inorganic DTY / spandex covering yarn covered with 400 ~ 600T / M around 40d spandex yarn The manufacturing method of this excellent antibacterial deodorant for summer. 삭제delete 삭제delete
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